• Title/Summary/Keyword: Single walled carbon nanotube

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Carbon nanotubes-properties and applications: a review

  • Ibrahim, Khalid Saeed
    • Carbon letters
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    • v.14 no.3
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    • pp.131-144
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    • 2013
  • The carbon nanotube (CNT) represents one of the most unique inventions in the field of nanotechnology. CNTs have been studied closely over the last two decades by many researchers around the world due to their great potential in different fields. CNTs are rolled graphene with $SP^2$ hybridization. The important aspects of CNTs are their light weight, small size with a high aspect ratio, good tensile strength, and good conducting characteristics, which make them useful as fillers in different materials such as polymers, metallic surfaces and ceramics. CNTs also have potential applications in the field of nanotechnology, nanomedicine, transistors, actuators, sensors, membranes, and capacitors. There are various techniques which can be used for the synthesis of CNTs. These include the arc-discharge method, chemical vaporize deposition (CVD), the laser ablation method, and the sol gel method. CNTs can be single-walled, double-walled and multi-walled. CNTs have unique mechanical, electrical and optical properties, all of which have been extensively studied. The present review is focused on the synthesis, functionalization, properties and applications of CNTs. The toxic effect of CNTs is also presented in a summarized form.

Preparation of gold nanoparticle/single-walled carbon nanotube nanohybrids using biologically programmed peptide for application of flexible transparent conducting films

  • Yang, MinHo;Choi, Bong Gill
    • Carbon letters
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    • v.20
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    • pp.26-31
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    • 2016
  • In this study, we report a general method for preparation of a one-dimensional (1D) arrangement of Au nanoparticles on single-walled carbon nanotubes (SWNTs) using biologically programmed peptides as structure-guiding 1D templates. The peptides were designed by the combination of glutamic acid (E), glycine (G), and phenylalanine (F) amino acids; peptides efficiently debundled and exfoliated the SWNTs for stability of the dispersion and guided the growth of the array of Au nanoparticles in a controllable manner. Moreover, we demonstrated the superior ability of 1D nanohybrids as flexible, transparent, and conducting materials. The highly stable dispersion of 1D nanohybrids in aqueous solution enabled the fabrication of flexible, transparent, and conductive nanohybrid films using vacuum filtration, resulting in good optical and electrical properties.

Theoretical Analysis of Carbon Nanotube Actuators (탄소나노튜브 작동기의 이론적 해석)

  • Park C.H.;Park H.C.;So H.K.;Jung B.B.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.927-931
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    • 2005
  • Carbon nanotube actuator, working under physical conditions (in aqueous solution) and converting electrical energy into mechanical energy directly, can be a good substitute for artificial muscle. The carbon nanotube actuator simulated in this paper is an isotropic cantilever type with an adhesive tape which is sandwiched between two single-walled carbon nanotubes. For predicting the static and dynamic characteristic parameters, the analytical model for a 3 layer bimorph carbon nanotube actuator is developed by using Euler-Bernoulli beam theory. The governing equation and boundary conditions are derived from energy principles. The induced displacements of the theoretical model are presented in order to investigate the performance of the carbon nanotube actuator with different control voltages. The developed model presents invaluable means for designing and predicting the performance of carbon nanotube actuator that can be used in artificial muscle applications.

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Development of single walled-carbon nanotubes based pH sensor using ultra-precision spray method (초정밀 스프레이 방법을 이용한 단일벽 탄소나노튜브 pH센서 개발)

  • Kwon, Jae-Hong;Lee, Kyong-Soo;Lee, Yun-Hi;Ju, Byeong-Kwon
    • Journal of Sensor Science and Technology
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    • v.15 no.2
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    • pp.127-133
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    • 2006
  • Recent studies demonstrated the ability of carbon nanotube (CNT) to promote electron transfer reactions of important compounds and to impart higher stability onto electrochemical sensors. CNT-based sensors measured by hydroxyl radical concentration or pH value suggest great promise for biosensors. This paper describes a new method for fabricating a very simple and inexpensive pH sensor compose of single walled-carbon nanotubes (SW-CNTs) using an ultra-precision spray. CNT-based sensor shows pH sensitivity in buffer solution at different pH range. Our experimental results show the sensor responses to pH buffer solution and the conductance of depends on the pH values. These results support application possibility of SW-CNTs based pH sensor for mass production.

Characterization of Single-walled Carbon Nanotubes Synthesized by Water-assisted Catalytic Chemical Vapor Deposition

  • Lee, Yeon-Ja;Kim, Bawl;Yu, Zhao;Lee, Cheol-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.381-381
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    • 2011
  • The influence of the water vapor on the growth of single-walled carbon nanotubes (SWCNTs) was investigated. SWCNTs were synthesized by catalytic chemical vapor deposition of acetylene over Fe-Mo/MgO catalyst with injection of water vapor. The morphologies and structures of the water-assisted SWCNTs were investigated according to the growth conditions such as water vapor concentrations, flow rate of the gas, furnace temperature, and growth time. Water-assisted SWCNTs exhibited large bundle morphological features with well-alignment of each CNT, while SWCNTs synthesized in the absence of water vapor showed entangled CNT with the random orientation. We also found that the diameter of the SWCNT bundle could be controlled by the growth condition. In our optimal growth condition, the product yield and the purity were 300 wt. % and 75%, which were 7.5 and 2.5 times higher than those of SWCNTs synthesized without water vapor, respectively. More detail discussion will be offered at the poster presentation.

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Analytical Modeling of Carbon Nanotube Actuators (탄소나노튜브 액츄에이터의 이론적 모델링)

  • 염영일;박철휴
    • Journal of Institute of Control, Robotics and Systems
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    • v.10 no.11
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    • pp.1006-1011
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    • 2004
  • Carbon nanotubes have outstanding properties which make them useful for a number of high-technology applications. Especially, single-walled carbon nanotube (SWNT), working under physical conditions (in aqueous solution) and converting electrical energy into mechanical energy directly, can be a good substitute for artificial muscle. The carbon nanotube structure simulated in this paper is an isotropic cantilever type with an adhesive tape which is sandwiched between two SWNTs. For predicting the geometrical and physical parameters such as deflection, slope, bending moment and induced force with various applied voltages, the analytical model for a 3 layer bimorph nanotube actuator is developed by applying Euler-Bernoulli beam theory. The governing equation and boundary conditions are derived from energy Principles. Also, the brief history of carbon nonotube is overviewed and its properties are compared with other functional materials. Moreover, an electro-mechanical coupling coefficient of the carbon nanotube actuator is discussed to identify the electro-mechanical energy efficiency.

Fabrication of a Resonator using suspended Multi-wall Carbon Nanotubes (다중벽 탄소나노튜브를 이용한 공진기 제작)

  • Lee J.H.;Seo H.W.;Song J.W.;Han C.S.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.465-466
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    • 2006
  • A single-wall carbon nanotube (SWCNT) has been studied as a material of Nano-Eletro-Mechanical-System (NEMS) device together with various nanowires. In order for oscillation of a multi-wall carbon nanotube (MWCNT) or a single-walled carbon nanotube (SWCNT) on plane surface, it needs suspension of a CNT across trench electrodes. So we propose fabrication method of a MWCNT resonator using dielectrophoresis and show successful results of suspeneded MWNT. Thin electrodes with large gaps could not suspend small diameter MWNT but thicker electrodes could. Thin MWNT could be suspended only when the electrode gap was reduced.

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Supercapacitive Properties of RuO2 and Ru-Co Mixed Oxide Deposited on Single-Walled Carbon Nanotube (단일벽 탄소나노튜브 상에 석출된 산화루테늄과 루테늄-코발트 혼합산화물의 수퍼커패시터 특성)

  • Ko, Jang Myoun;Kim, Kwang Man
    • Korean Chemical Engineering Research
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    • v.47 no.1
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    • pp.11-16
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    • 2009
  • Composite electrodes for redox supercapacitor were prepared potentiodynamically by the deposition of $RuO_2$ and the co-deposition of Ru-Co mixed oxide on the surface of single-walled carbon nanotube. Electrode of Ru-Co mixed oxide, in which Ru(13.13 wt%) and Co(2.89 wt%) were deposited on the carbon nanotube, exhibited a similar specific capacitance(${\sim}620\;F\;g^{-1}$) with $RuO_2$ electrode at a low potential scan rate($10\;mV\;s^{-1}$), but showed a superior one ($570\;F\;g^{-1}$) at a high scan rate($500\;mV\;s^{-1}$) than that of $RuO_2$($475\;F\;g^{-1}$). Such increase in the specific capacitance at high scan rate by the co-deposition of Ru and Co species was due to the structural support of Co species to provide the electronic conduction through Ru species.

Biocompatible Individual Dispersion of Single-walled Carbon Nanotubes

  • Najeeb, C.K.;Kim, Duck-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.529-529
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    • 2012
  • Dispersion of carbon nanotubes in biocompatible media are of particular interest for diverse biomedical and nanomedicine applications. Various biomolecules and biopolymers such as DNA, proteins, poly L-lysine, starch, gelatin, steroid biosurfactants, and chitosan have shown capability for the effective dispersion of carbon nanotubes in water. Chitosan has demonstrated capacity for effective dispersion of single-walled carbon nanotubes (SWCNTs) in acidic medium and it also showed tendency to preferentially disperse smaller diameter nanotubes. Chemical functionalizations of chitosan enable its solubility in neutral pH water by reducing the intra and inter molecular hydrogen bonding. Herein, we present a neutral pH water soluble chitosan derivative, chitosan-hydroxyphenyl acetamide (CHPA), obtained by functionalizing the amino groups of chitosan with 4-hydroxyphenyl acetic acid, as an efficient biocompatible dispersant for debundling and solubilization of SWNTs in neutral aqueous solutions. Various process conditions for individual dispersion of SWCNTs are analyzed based on optical absorption and Raman spectroscopy.

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