• Title/Summary/Keyword: Silver reduction

Search Result 225, Processing Time 0.031 seconds

Fishing Mortality and Abundance of the Silver croaker, Otolithes argenteus in the Kuwait's Waters

  • LEE J. U.
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.23 no.6
    • /
    • pp.443-450
    • /
    • 1990
  • The virtual population analysis technique was applied to the silver croaker, Otolithes argenteus, stock based on length frequency composition, age-length key and nominal catches taken by the trawl fleet and fixed-stake nets in the Kuwait's waters during $1981\~1988$. One-year-old fish was dominant, whereas three-year-old and older fish were at a very low level. Fishing mortality was much higher in the age groups of 2 and 3 than in the others. A strong year-class occurred in 1980 and 1981. Population size of fishable stock markedly decreased from 1982 to 1985 and remained at a low level during $1986\~1987$. The effects of changes in fishing effort showed that an increase in fishing effort would not lead to benefits in yield and would comprise more young and fewer old fish, whereas a reduction in fishing effort to a certain level (by $20\~40\%$ ) from the fishing effort level on the average during $1981\~1988$ could bring some small advantage to the fishery consisting of fewer young and older fish.

  • PDF

A Study on AC Loss of Ag Sheathed Bi-2223 Superconducting Tapes (Bi계 초전도 테이프의 교류손실 연구)

  • Jeong, Jong-Man;Jang, Hyeon-Man;Sin, Jae-Hwa;Choe, Jae-Seok;Kim, Sang-Hyeon
    • The Transactions of the Korean Institute of Electrical Engineers C
    • /
    • v.48 no.1
    • /
    • pp.29-33
    • /
    • 1999
  • Superconducting tape is being developed for electrical equipment such as superconducting transformers and generators etc. AC loss reduction is primary concerned in the development of such high-efficiency equipment. AC losses in Bi-2223 silver-sheathed tapes, both single and multi-filamentary, were investigated by means of AC magnetization techniques when longitudinal fields are applied. The experiment resultswere compared with the hysteresis loss equation based on Bean model and the eddy current loss equation. The AC loss of the mono-filamentary tape was dominated by the hysteresis. On the contrary, the AC loss of the multi-filamentary tape was substantially dominated by the eddy current loss in the silver matrix.

  • PDF

Trends on Synthesis of Cu Nanoparticles by a Wet Reduction Method (습식 환원법에 의한 Cu 나노입자의 합성 동향)

  • Shin, Yong Moo;Chee, Sang-Soo;Lee, Jong-Hyun
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.20 no.3
    • /
    • pp.11-18
    • /
    • 2013
  • Interest in copper nanoparticles has increased as an alternative for substituting silver nanoparticles because of its lower cost and less electromigration effect than silver. In this paper, the recent research trends and main results in wet-chemical synthesis of sub-100 nm Cu nanoparticles were summarized. The characteristics of synthesis were discussed with a classification such as modified polyol synthesis, modified hydrothermal synthesis, solvothermal synthesis, and the others, focussing on effects of capping agents, reductants, and pH. Information on the oxidation of synthesized copper nanoparticles were additionally commented.

Characterization of tissue conditioner containing chitosan-doped silver nanoparticles (키토산-은나노 복합체가 함유된 의치 연성이장재 특성에 관한 연구)

  • Nam, Ki Young;Lee, Chul Jae
    • The Journal of Korean Academy of Prosthodontics
    • /
    • v.58 no.4
    • /
    • pp.275-281
    • /
    • 2020
  • Purpose: Development of a latent antimicrobial soft liner is strongly needed to overcome a possible inflammation related with its dimensional degrade or surface roughness. Modified tissue conditioner (TC) containing chitosan-doped silver nanoparticles (ChSN) complexes were synthesized and assessed for their characterizations. Materials and methods: ChSN were preliminarily synthesized from silver nitrate (AgNO3), sodium borohydride (NaBH4) as a reducing agent and chitosan biopolymer as a capping agent. Ultraviolet-visible and Fourier transform infrared spectroscopy were conducted to confirm the stable reduction of nanoparticles with chitosan. Modified TC blended with ChSN by 0 (control), 1.0, 3.0 and 5.0 % mass fraction were mechanically tested by ultimate tensile strength (UTS), silver ion elution and color stability (n=7). Results: At 24 hour and 7 day storage periods, UTS values were not significant (P>.05) as compared with pristine TC (control) and silver ion was detected with the dose-dependent values of ChSN incorporated. Color stability of TC were influenced by ChSN add, with the higher doses, the significantly greater color changes (P<.05). Conclusion: A stable synthesized ChSN was acquired and modified TC loading ChSN was characterized as silver ion releasing without detrimental physical property. For its clinical application, antimicrobial test, color control and multifactor investigations are still required.

Catalytic Decomposition of Hydrogen Peroxide for Application on Micro Propulsion (마이크로 추력기 응용을 위한 과산화수소 촉매 분해 반응)

  • An Sung-Yong;Lee Jong-Kwang;Rang Seong-Min;Kwon Se-Jin
    • Journal of the Korean Society of Propulsion Engineers
    • /
    • v.9 no.4
    • /
    • pp.1-8
    • /
    • 2005
  • An experimental investigation of a microthruster that uses hydrogen peroxide as a monopropellant is described. The study comprises of preparation method of silver as a catalyst and performance evaluation of a mesoscale reactor. Reduction of silver in $H_2\;at\;500^{\circ}C$ resulted in the best reactivity of all the treatment method tested. A mesoscale reactor was built to find the optimum configuration for full decomposition of propellant. The catalyst bed was made of a glass wafer substrate sputtered with silver and had a length of 20 mm. We measured the conversion rate with varying feed rate of $H_2O_2$ and preheating temperature. With the feed rate of $H_2O_2$, the space time within the reactor varies as well. For the bed length of 20 mm, space time more than 480 s was required for full conversion.

Effects of Chloride and Sulfate Ions on Corrosion Behaviors of Structural Materials Based on Design of Experiment (실험계획에 기반한 수돗물 성분(Chloride and Sulfate Ions)의 구조재료 부식 영향성 고찰)

  • Dong-In Lim;Heng-Su Noh;Hyeok-Jun Kwon;Sung-Ryul Park;Man-Sik Jo;Doo-Youl Lee
    • Corrosion Science and Technology
    • /
    • v.22 no.3
    • /
    • pp.201-213
    • /
    • 2023
  • Corrosion management of an aircraft and its engine relies on rinsing and cleaning using tap water. Few studies have reported effects of tap water species on corrosion behaviors of structural materials. In this study, a series of experiments were conducted based on the design of experiment. Solutions with different levels of chloride and sulfate ions were prepared using a full factorial design. Two structural materials (aluminum alloy and steel) were used for an alternate immersion test. Weight loss was then measured. In addition, a silver specimen was utilized as a sensor for chloride deposition measurement. The silver specimen was examined using the electrochemical reduction method, XPS, and SEM-EDS. Surface analysis revealed that levels of chloride and sulfate ions were sufficient for the formation of silver chloride and silver surface. Statistical analysis of weight loss and chloride deposition rate showed significant differences in measured values. Concentration of chloride ions greatly affected corrosion behaviors of structural materials. Sulfate ion hindered the adsorption reaction. These results emphasize the importance of controlling ion concentration of tap water used for cleaning and rinsing an aircraft.

Electorchemical Reduction Behavior of Aliphatic Acetylenic Alcohol (Aliphatic Acetylenic Alcohol의 電極反應過程)

  • Kim Won Taik;Kim, Jin Il;Kwak Tai-Young;Lee Ju-Seong
    • Journal of the Korean Chemical Society
    • /
    • v.23 no.3
    • /
    • pp.180-185
    • /
    • 1979
  • Electrochemical reduction behavior from 2-butyne-1, 4-diol (BID) to 2-butene-1,4-diol (BED) by the use of various cathodes, such as Ti, Zr, Ni, Pt, Cu, Ag, Au, Zn, Hg, Pb and graphite has been studied. It has been found that cathodic polarization curve with metal of IB subgroup such as Cu, Ag and Au consisted of one wave in BID-alkaline solution, whereas it was not formed any wave in BED solution. Therefore, it was found that the cathode which was the most suitable in order to proceed in this reaction was Cu, Ag and Au. At cyclic voltammetry using a silver cathode in BID-alkaline solution, the current of the peak was proportional to square root of the sweep rate of potential and also proportional to concentration of BID. Activation energy was calculated for 3.75 kcal/mole from the plot of log $I_l$ vs. 1/T. Consequently, the reduction current of BID with a silver cathode in alkaline solution was found the diffusion current.

  • PDF

Synthesis of Ag-Pd Alloy Nanoparticles by Chemical Reduction Method (화학환원법을 이용한 Ag-Pd 합금 나노분말의 합성)

  • Seo, Won-Sik;Kim, Yun-Do;Choung, Il-Yeop;Lee, Ho-Seok;Song, Ki-Chang
    • Journal of the Korean Ceramic Society
    • /
    • v.43 no.4 s.287
    • /
    • pp.224-229
    • /
    • 2006
  • Ag-Pd alloy nanoparticles were prepared by a chemical reduction method using hydrazine $(N_2H_4)$ as a reductant in $AgNO_3\;and\;Pd(NO_3)_2$ aqueous solutions. Characterization of these particles by X-ray powder diffraction revealed a bimetallic and crystalline silver-palladium alloy. The average size of the particles was influenced not by the reductant $(N_2H_4)$ concentration, but the concentration of the starting materials $(AgNO_3\;and\;Pd(NO_3)_2)$.

Effect of Sterilization Conditions on Microbial Reduction in Cleaning Tools (살균 조건이 세척 도구 중 미생물 저감화에 미치는 영향)

  • Im, Ji-Yu;Kim, Chae-Young;Kim, Eun-yeong;Kim, Min-jin;Kim, Jung-Beom
    • Journal of Food Hygiene and Safety
    • /
    • v.37 no.5
    • /
    • pp.310-316
    • /
    • 2022
  • In this study, we compared the microbial reduction effects of drying, hot water, and microwave sterilization in scourers and dishcloths to suggest a most suitable sterilization method. Three scourer types (silver, copper, and mesh) were used, and three dishcloth types (silver, bamboo, and cotton) were used. Drying time dependent reduction in Escherichia coli was high in silver and copper scourers, but minimal bacterial reduction was obtained against Bacillus cereus in all scourers and dishcloths. In scourers, E. coli was not detected after ≥30 s of hot water sterilization at 77℃, and B. cereus was not detected after ≥60 s of hot water sterilization at 100℃. In dishcloths, E. coli was not detected after hot water sterilization at 77℃ for ≥30 s, but B. cereus was detected after hot water sterilization at 100℃ for ≥60 s. In scourers, E. coli was not detected after microwave sterilization at 700 W for 3 min, but B. cereus was detected. In dishcloths, E. coli was not detected after microwave sterilization with 700 W for ≥1 min, but B. cereus was detected in the cotton dishcloth even after sterilization for 3 min. In conclusion, the use of antimicrobial scourers (silver and copper) and dishcloths (silver and bamboo) are not sufficient to reduce the microbial contamination. The guideline provided by the Ministry of Food and Drug Safety suggesting dishcloth sterilization via hot water at 100℃ for 30 s was also found to be insufficient. Based on our research, we suggest that the most effective methods of microbial management are submerging scourers in hot water at 100℃ for ≥1 min, and sterilizing dishcloths for ≥3 min using a 700 W microwave.

Fabrication and Catalysis of $SiO_2$-Coated Ag@Au Nanoboxes

  • Lee, Jae-Won;Jang, Du-Jeon
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.02a
    • /
    • pp.588-588
    • /
    • 2013
  • Nanoscale noble-metals have attracted enormous attention from researchers in various fields of study because of their unusual optical properties as well as novel chemical properties. They have possible uses in diverse applications such as devices, transistors, optoelectronics, information storages, and energy converters. It is well-known that nanoparticles of noble-metals such as silver and gold show strong absorption bands in the visible region due to their surface-plasmon oscillation modes of conductive electrons. Silver nanocubes stand out from various types of Silver nanostructures (e.g., spheres, rods, bars, belts, and wires) due to their superior performance in a range of applications involvinglocalized surface plasmon resonance, surface-enhanced Raman scattering, and biosensing. In addition, extensive efforts have been devoted to the investigation of Gold-based nanocomposites to achieve high catalytic performances and utilization efficiencies. Furthermore, as the catalytic reactivity of Silver nanostructures depends highly on their morphology, hollow Gold nanoparticles having void interiors may offer additional catalytic advantages due to their increased surface areas. Especially, hollow nanospheres possess structurally tunable features such as shell thickness, interior cavity size, and chemical composition, leading to relatively high surface areas, low densities, and reduced costs compared with their solid counterparts. Thus, hollow-structured noblemetal nanoparticles can be applied to nanometer-sized chemical reactors, efficient catalysts, energy-storage media, and small containers to encapsulate multi-functional active materials. Silver nanocubes dispersed in water have been transformed into Ag@Au nanoboxes, which show highly enhanced catalytic properties, by adding $HAuCl_4$. By using this concept, $SiO_2$-coated Ag@Au nanoboxes have been synthesized via galvanic replacement of $SiO_2$-coated Ag nanocubes. They have lower catalytic ability but more stability than Ag@Au nanoboxes do. Thus, they could be recycled. $SiO_2$-coated Ag@Au nanoboxes have been found to catalyze the degradation of 4-nitrophenol efficiently in the presence of $NaBH_4$. By changing the amount of the added noble metal salt to control the molar ratio Au to Ag, we could tune the catalytic properties of the nanostructures in the reduction of the dyes. The catalytic ability of $SiO_2$-coated Ag@Au nanoboxes has been found to be much more efficient than $SiO_2$-coated Ag nanocubes. Catalytic performances were affected noteworthily by the metals, sizes, and shapes of noble-metal nanostructures.

  • PDF