• 한국분말재료학회지
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• 제28권1호
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• pp.51-58
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• 2021

The conversion of carbon preforms to dense SiC by liquid infiltration is a prospectively low-cost and reliable method of forming SiC-Si composites with complex shapes and high densities. Si powder was coated on top of a 2.0wt.% Y2O3-added carbon preform, and reaction bonded silicon carbide (RBSC) was prepared by infiltrating molten Si at 1,450℃ for 1-8 h. Reactive sintering of the Y2O3-free carbon preform caused Si to be pushed to one side, thereby forming cracking defects. However, when prepared from the Y2O3-added carbon preform, a SiC-Si composite in which Si is homogeneously distributed in the SiC matrix without cracking can be produced. Using the Si + C → SiC reaction at 1,450℃, 3C and 6H SiC phases, crystalline Si, and Y2O3 were generated based on XRD analysis, without the appearance of graphite. The RBSC prepared from the Y2O3-added carbon preform was densified by increasing the density and decreasing the porosity as the holding time increased at 1,450℃. Dense RBSC, which was reaction sintered at 1,450℃ for 4 h from the 2.0wt.% Y2O3-added carbon preform, had an apparent porosity of 0.11% and a relative density of 96.8%.

• 한국결정성장학회지
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• 제27권1호
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• pp.57-63
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• 2017

High-purity ${\beta}-SiC$ powders for SiC single-crystal growth were synthesized by direct carbonization. The use of high-purity raw materials to improve the quality of a SiC single crystal is important. To grow SiC single crystals by the PVT method, both the particle size and the packing density of the SiC powder are crucial factors that determine the sublimation rate. In this study, we tried to produce high-purity ${\beta}-SiC$ powder with large particle sizes and containing low silicon by introducing a milling step during the direct carbonization process. Controlled heating improved the purity of the ${\beta}-SiC$ powders to more than 99 % and increased the particle size to as much as ${\sim}100{\mu}m$. The ${\beta}-SiC$ powders were characterized by SEM, XRD, PSA, and chemical analysis to assess their purity. Then, we conducted single-crystal growth experiments, and the grown 4H-SiC crystals showed high structural perfection with a FWHM of about 25-48 arcsec.

• 한국재료학회지
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• 제29권9호
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• pp.532-541
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• 2019

Information and communication technologies are developing rapidly as IC chip size becomes smaller and information processing becomes faster. With this development, digital circuit technology is being widely applied to mobile phones, wireless LANs, mobile terminals, and digital communications, in which high frequency range of GHz is used. In high-density electronic circuits, issues of noise and EMC(Electro-Magnetic Compatibility) arising from cross talk between interconnects or devices should be solved. In this study, sheet-type electromagnetic wave absorbers that cause electromagnetic wave attenuation are fabricated using composites based on soft magnetic metal powder and silicon rubber to solve the problem of electromagnetic waves generated in wireless communication products operating at the frequency range of 2.4 GHz. Sendust(Fe-Si-Al) and carbonyl iron(Fe-C) were used as soft magnetic metals, and their concentrations and sheet thicknesses were varied. Using soft magnetic metal powder, a sheet is fabricated to exhibit maximum electromagnetic attenuation in the target frequency band, and a value of 34.2dB(99.9 % absorption) is achieved at the target frequency.

• 한국분말재료학회지
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• 제30권4호
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• pp.339-345
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• 2023

This study investigates the melting point and brazing properties of the aluminum (Al)-copper (Cu)-silicon (Si)-tin (Sn) alloy fabricated for low-temperature brazing based on the alloy design. Specifically, the Al-20Cu-10Si-Sn alloy is examined and confirmed to possess a melting point of approximately 520℃. Analysis of the melting point of the alloy based on composition reveals that the melting temperature tends to decrease with increasing Cu and Si content, along with a corresponding decrease as the Sn content rises. This study verifies that the Al-20Cu-10Si-5Sn alloy exhibits high liquidity and favorable mechanical properties for brazing through the joint gap filling test and Vickers hardness measurements. Additionally, a powder fabricated using the Al-20Cu-10Si-5Sn alloy demonstrates a melting point of around 515℃ following melting point analysis. Consequently, it is deemed highly suitable for use as a low-temperature Al brazing material.

• 한국세라믹학회지
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• 제34권8호
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• pp.854-860
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• 1997

The tribological property of ceramics is very important for use in seal rings, pump parts, thread guides and mechanical seal, etc. In the present study, which RBSC/graphite composites were manufactured by adding graphite powders with different particle sizes to mixtures of SiC powder, metallic silicon, carbon black and alumina, effects on the tribological property of each RBSC/graphite composite was investigated in accordance with the particle size of the added graphite powder. The water absorption, the bending strength and the resistance for the friction and wear were measured, and the crystalline phase and the microstructure were respectively examined by using XRD and SEM. In case that the particle size of the graphite powder was fine(2${\mu}{\textrm}{m}$), the formation of $\beta$-SiC was accelerated, thereby making the increase of the bending strength and the decrease of the water absorption, but no improvement for the tribological properties. Furthermore, in case that the particle size of the graphite powder was some large(88~149${\mu}{\textrm}{m}$), the formation of $\beta$-SiC was not accelerated, to thereby make the decrease of the bending strength and the increase of the water absorption, but the improvement for the tribological property of only the composite having the graphite powder of 20 vol%. In addition, in case that the particle size distribution of the graphite powder was large (under 53 ${\mu}{\textrm}{m}$), there was no improvement for every properties. However, the composites, which the graphite powder with the particle size of 53~88 ${\mu}{\textrm}{m}$ was added in 10~15 vol%, had the most increased resistance for the friction and wear which show the worn out amount of 0.4~0.6$\times$10-3 $\textrm{cm}^2$, and the value of the bending strength is 380~520 kg/$\textrm{cm}^2$.

• 디지털콘텐츠학회 논문지
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• 제14권1호
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• pp.35-40
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• 2013

연마재와 Coolant를 이용한 슬러리는 그동안 반도체 웨이퍼를 시작으로 태양광 산업의 Wire Saw에서 사용량이 급격히 증가하였다. 이에 본 논문에서는 슬러리를 분리 정제하여, 수세뿐만 아니라 화학적 처리를 통하여 보다 고순도의 실리콘카바이드 분말을 얻어, 마이크로웨이브 건조방식으로 건조하였다. 건조한 슬러리 벌크를 분쇄하고 화학적 처리까지 수행하여 제작한 Powder를 각각 열분석, 입도분석, SEM 촬영, 성분분석, XRF, XRD을 통하여 분석하였다. 본 연구 결과 화학적 처리를 통하여 얻은 Powder의 회수율이 수세 처리를 통하여 얻은 Powder 보다 더 높아지는 것을 알 수 있었다. 태양광 소재 산업에서 발생하는 다량의 슬러리를 통합, 재활용함으로 점차 강화되고 있는 국내외 환경 규제에 적극 대응하고, 관련 소재 산업의 인프라 구축 효과를 기대할 수 있다.

• 자원리싸이클링
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• 제16권5호
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• pp.41-45
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• 2007

폐실리콘 슬러지로부터 테트라메틸오쏘실리케이트(TMOS)와 실리카 나노분말을 제조하였다. 먼저, 실리카 나노분말의 전구체인 TMOS를 폐실리콘 슬러지로부터 촉매 화학반응에 의해 합성하였다. TMOS의 합성실험에서 반응온도가 $130^{\circ}C$ 이상에서는 반응시간이 5시간 경과 시 반응온도에 무관하게 100%의 반응율을 나타내었다. 그러나 $150^{\circ}C$ 이상에서는 초기 반응속도가 빨라졌다. 메탄올 주입속도를 0.8 ml/min에서 1.4 ml/min로 증가시에는 3시간 경과 후에는 반응율이 변화하지 않았다. 이와 같이 합성된 TMOS로부터 화염분무열분해법에 의해 실리카 나노분말을 제조하였다. 제조된 실리카 나노분말은 구형이며, 무응집 형태이었다. 평균입자 크기는 전구체의 주입속도 및 농도변화에 따라 9 nm에서 30 nm로 변화하였다.

• 융합정보논문지
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• 제7권5호
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• pp.123-128
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• 2017

나노구조를 갖는 물질들은 나노구조물이 갖는 고유의 체적 대비 높은 표면적 비와 양자 갇힘 효과에 기인하는 독특한 전기적, 광학적, 광전기적, 자기적 특성으로 인하여 많은 주목을 받아왔다. 열화학 기상 증착 공정은 나노 구조물의 성장과정에서 다양한 구조를 갖는 나노소재의 합성 능력 때문에 더욱 주목을 받아왔다. 본 연구에서는 두 영역 열화학 기상 증착법과 소스 물질 $TiO_2$ 파우더를 이용하여 VLS 공정으로 Si\$SiO_2$(300 nm)\Pt(5~40 nm) 기판 위에 실리콘 옥사이드 나노와이어를 성장시켰다. 성장된 실리콘 옥사이드 나노와이어의 형상과 결정학적 특성을 전계방출 주사전자현미경과 투과전자현미경으로 분석하였다. 분석결과, 성장된 실리콘 옥사이드 나노와이어의 형상인 지름과 길이는 촉매 박막의 두께에 의존하여 다른 모양을 나타내었다. 또한 성장된 실리콘 옥사이드 나노와이어는 비정질 상을 갖는 것으로 분석되었다.

• 한국결정성장학회지
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• 제4권4호
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• pp.370-377
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• 1994

비이송식DC 플라즈마 토치를 제작하고 이를 이용하여 질화규소 분말을 제조하였다. Ar 가스를 사용하여 플라즈마를 발생시켯으며, 발생된 플라즈마 flame으로 반응가스 및 reactive quenching 가스를 도입하였다. 토치의 하단부에 2개의 slit를 장착하여 가스의 도입 위치를 변화시킬 수 있게 하였다. $SiCl_4와 NH_3$를 출발원료로 하여 질화규소 분말을 제조하였다. 얻어진 분말은 무정형이었으며, 반응부산물을 제거하고 $1420^{\circ}C$에서 질소 분위기하에서 가열함으로써 결정화된 질화규소 분말을 얻었다. XPD pattern 및 IR 스펙트럼으로부터 질화규소 분말을 확인하였고, TEM을 사용하여 전후의 형상을 관찰하였다.

• 한국세라믹학회지
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• 제45권8호
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• pp.486-492
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• 2008

Reaction bonded silicon carbide(RBSC) composite for heat-exchanger was fabricated by molten Si infiltration method. The raw materials with variable particle sizes were used in this experience. The finer the particle size in sintered silicon carbide was the more increasing 3-point bending strength and fracture toughness. As the adaptable particle sizes had been occupied interstice arising from packing sample, the mechanical properties were increased. In the PCS1-1 sample, the 3-point bending strength and fracture toughness were 323MPa and $4.9\;MPa{\cdot}m^{1/2}$, respectively.