• Korean Journal of Materials Research
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• v.28 no.12
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• pp.714-718
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• 2018

Anti-reflection thin films are fabricated on glass substrates using the screen printing method. Tetra ethyl silicate(TEOS) and methyl tri methoxy silane(MTMS) are used as starting materials and buthyl carbitol acetate(BCA) and buthyl cellusolve(BC) are mixed to improve the viscosity of the solution. Anti-reflection thin films are fabricated according to the number of the screen mesh and the characteristics improve as the mesh size increases. The transmittance and reflectance of the coated thin film using 325 mesh are about 94 % and 0.43 % in the visible wavelength. The thickness and refractive index of the AR thin film are 107 nm and n = 1.26, respectively.

• Advances in concrete construction
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• v.7 no.4
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• pp.263-275
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• 2019

In the present work, Granulated Blast Furnace Slag (GBFS) and Fly ash (FA) were used as partial replacement of Natural Sand (NS) and Ordinary Portland Cement (OPC) by weight. One control mix, one with GBFS, three with FA and three with GBFS-FA combined mixes were prepared. Replacements were 50% GBFS with NS and 20%, 30% and 40% FA with OPC. Preliminary investigation on development of compressive strength was carried out at 7, 28 and 90 days to ensure sustainability of waste materials in concrete matrix at room temperature. After 90days, thermo-mechanical study was performed on the specimen for a temperature regime of $200^{\circ}-1000^{\circ}C$ followed by furnace cooling. Weight loss, visual inspection along with colour change, residual compressive strength and microstructure analysis were performed to investigate the effect of replacement of GBFS and FA. Although adding waste mineral by-products enhanced the weight loss, their pozzolanicity and formation history at high temperature played a significant role in retaining higher residual compressive strength even up to $800^{\circ}C$. On detail microstructural study, it has been found that addition of FA and GBFS in concrete mix improved the density of concrete by development of extra calcium silicate gel before fire and restricts the development of micro-cracks at high temperature as well. In general, the authors are in favour of combined replacement mix in view of high volume mineral by-products utilization as fire protection.

• Geomechanics and Engineering
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• v.28 no.3
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• pp.239-253
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• 2022

Suitable techniques to stabilize organic soil and improve its engineering behaviour are in demand. Despite various alternatives, nano-additives proved to be an effective stabilizer owing to their strength enhancing properties. The study focuses on using nano-silica as a potential stabilizer to improve organic silt. Soil was treated with four dosages of nano-silica namely 0.2%, 0.4%, 0.6% and 0.8% of dry weight of the soil. Nano-silica treated soil showed a strength increase of nearly 25% at a dosage of 0.4% after curing for two hours. Strength of the treated soil improved with age. Strength improved by nearly 62.9% after 28 days of curing and 221.4% after 180 days of curing due to formation of Calcium - Silicate - Hydrate (CSH) gel in the soil matrix. Dosage of 0.6% nano-silica is observed to be the optimum dosage. Coefficient of permeability and compression index showed an increase by 13.32 and 5.5 times respectively owing to aggregation of particles and creation of void spaces as visualized from the scanning electron micrographs. Further model foundation study and numerical parametric studies using PLAXIS 2D indicate that optimized and economic results can be obtained by varying the additive dosage with depth.

• Computers and Concrete
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• v.29 no.4
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• pp.237-246
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• 2022

The concrete quality relies on general factors like preparation technique, uniformity of the compaction, amount and appropriateness of the additives. The current article investigates the impact of a well knows amino acid, L-arginine as an additive on water requirements, setting durations and characterization of various cement samples. Compressive strength tests of reference and L-arginine added cements at age of 2, 7 and 28 days were carried out according to TS-EN 196-1. Samples were blended by incorporating various amounts of L-arginine (25 ppm, 50 ppm and 75 ppm) in the cement water mixture which were tested with Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermo-gravimetric analysis (TG), scanning electron microscopy (SEM) and the energy-dispersive X-ray spectroscopy (EDS) on the 28th day. Results revealed that L-arginine does not affect the setting time, volume expansion of cement and water demands negatively; rather it imparts enhanced sustainability to the samples. It was determined that the highest value belonged to the 75L mortar with an increase of 2.6% compared to the reference sample when the compressive strengths of all mortars were compared on the 28th day. Besides, it has been observed that the development of calcium silicate hydrate or C-S-H gel, calcium hydroxide or CH and other hydrated products are associated with each other. L-arginine definitely has a contribution in the consumption of CH formed in the hydration process.

• Corrosion Science and Technology
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• v.22 no.2
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• pp.99-107
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• 2023

Layered silicate clay montmorillonite (MMT) has been used in nanocomposite coating to improve corrosion protection by reinforcing the barrier property. The better dispersion of MMT in the coating produces a higher barrier effect. Pretreatment with MMT could favor the delamination of clay platelets, facilitating MMT dispersion in the coating. In the present work, a montmorillonite/silica (MMT/Si) composite was prepared by the in situ sol-gel method. x-ray diffraction measurements and field-emission scanning electron microscopy observations showed silica crystal formation and increased basal spacing between the MMT platelets. Composite MMT/Si particles were introduced in an epoxy resin to reinforce the corrosion protection of the coating applied on the AA2024 surface. Electrochemical impedance spectroscopy (EIS) was performed to characterize the protective property of the coating. The results demonstrated the high barrier effect of the coating containing 5 wt% of MMT/Si. Adhesion evaluation after a salt spray test exhibited a high adherence to the epoxy coating containing MMT/Si.

• Geomechanics and Engineering
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• v.38 no.4
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• pp.353-366
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• 2024

Organic soils pose significant challenges in geotechnical engineering due to their high compressibility and low stability, which can result in issues like differential settlement, rutting, and pavement deformation. This study explores effective methods for stabilizing organic soils. Rather than conventional ordinary Portland cement (OPC), the focus is on using environmentally friendly calcium sulfoaluminate (CSA) cement, known for its rapid setting, high early strength development, and environmental benefits. Mechanical behavior is analyzed through 1-D free swell, unconfined compressive strength (UCS), and bender element (BE) tests. Microstructural analyses, including Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM), characterize the soil mixed with CSA cement. Experimental results demonstrate improved soil properties with increasing cement dosage and curing periods. A notable strength increase is observed in soil samples with 15% cement content, with UCS doubling after 7 days. This trend aligns with shear wave velocity results from the BE test. SEM and FTIR spectroscopy reveal how CSA cement hydration forms hydrated calcium silicate gel and ettringite, enhancing soil properties. CSA cement is recommended for reinforcing organic subgrade soil due to its eco-friendly nature and rapid strength gain, contributing to improved durability.

• Journal of the Korean GEO-environmental Society
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• v.10 no.2
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• pp.21-28
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• 2009

A grouting method has been widely used in construction of large-scale structure to reduce permeability and reinforce the ground. If cement and grout material were not mixed well in the injection tip equipment, an opposite flow and interception state of the chemical grouting can occur. McG (Multi-mixing counterflow prevented Grouting, McG) method installed a special grouting device to allow better mixing of the grouting material(above fineness $6,000cm^2/g$) and prevent backward flow. The block of nozzle also diversify powder rate of cement. YSS (Youngil Special Silicate, YSS) that lowers $Na_2O$ and thereby increases durability was developed by gel-forming reaction material. The seepage state and unconfined compressive strength of the injection material using the special injection tip equipment was tested in this study. The results of this study showed that the uniaxial compressive strength, permeability, N-value, TCR and RQD were improved by this method. Engineering characteristics obtained by the special injection tip method will be compared with those by the other method through various field tests from now on.

• Journal of the Mineralogical Society of Korea
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• v.25 no.4
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• pp.283-293
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• 2012

In order to have better insights into the chemical differentiation of Earth from its magma ocean phase to the current stratified structure, detailed information of crystallization kinetics of silicate melts consisting of the magma ocean is essential. The structural transitions in oxide glasses and melts upon crystallization provide improved prospects for a systematic and quantitative understanding of the crystallization processes. Here, we report the $^{27}Al$ 3QMAS NMR spectra for sol-gel synthesized $Al_2O_3$ glass with varying temperature and annealing time. The NMR spectra for the amorphous $Al_2O_3$ show well-resolved Al coordination environments, characterized with mostly $^{[4,5]}Al$ and a minor fraction of $^{[6]}Al$. The fraction of $^{[5]}Al$ in the alumina phase decreases with increasing annealing time at constant temperature. The NMR results of $Al_2O_3$ phases also imply that multiple processes (e.g., crystallization and/or changes in structural disorder within glasses) could involve upon its phase transition. The current results and method can be useful to understand crystallization kinetics of diverse natural and multi-component silicate glasses and melts. The potential result may yield atomic-level understanding of Earth's chemical evolution and differentiation from the magma ocean.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.27 no.6
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• pp.295-302
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• 2017

In this study, the effect of pre-curing process on the enhancement of mechanical properties of IGCC-slag-based-geopolymer was studied. Pre-curing is a process in which the green geopolymer is left at room temperature for a certain period of time prior to the high-temperature curing, and it is known as increasing the strength of a specimen. Therefore, in this experiment, the compressive strength of the geopolymers was measured according to various pre-curing conditions, and microstructure and crystal phase changes were observed by SEM and XRD, respectively. The W/S ratio was determined to be 0.26, which can offer the maximum geopolymer strength with easy molding ability, and the concentration of the alkali solution was 15 M. Pre-curing was performed at room temperature for 0 to 27 days. Compressive strength of the geopolymer made with pre-curing process increased by 36~87 % compared with the specimens made with no pre-curing process. Those improved compressive strength for the pre-cured geopolymer was confirmed owing to promotion effect of pre-curing process on generation of C-S-H gel and zeolite phases, which were analyzed using by XRD and SEM measurement.

• Journal of the Korea Concrete Institute
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• v.20 no.4
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• pp.431-437
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• 2008

The concrete pavement at Seohae Expressway in Korea has suffered from serious distress, only after four to seven years of construction. The deterioration of ASR has seldom been reported per se in Korea, because the aggregate used for the cement concrete has been considered safe against alkali-silica reaction so far. The purpose of this study is to examine the expansion behavior of aggregates of Korea due to alkali-silica reaction by ASTM C 1260 standard method of the accelerated mortar bar test (AMBT), stereo microscopic analysis, scanning electronic microscope (SEM) analysis, and electron dispersive X-ray spectrometer (EDX) analysis. The results are presented as it follows. The accelerated mortar bar test (AMBT) showed that mica granite and felsite of igneous rocks, aroke, red sandstone and shale of sedimentary rocks, slate of metamorphic rock, and dendrite and quartz of mineral rock showed more expansion than 0.1% at 14 days. But, some sedimentary rocks and metamorphic rocks expanded more than 0.1% at 28 days even though they were less than 0.1% at 14 days. The mortar bars, which showed more than occurred 0.1% expansion, resulted in cracking on surface. SEM and EDX analysis confirmed that the white gel was a typical reaction product of ASR. The ASR gel in Korea mainly consisted of Silicate (Si) and Potassium (K) from the cement. The crack in the concrete pavement was caused by ASR. It seems that Korea is no longer safe zone against alkali-silica reaction.