• 한국수소및신에너지학회논문집
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• 제22권5호
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• pp.706-713
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• 2011

The effects of silica-alumina type catalysts addition on the thermal decomposition of ethylene vinyl acetate (EVA) resin have been studied in a thermal analyzer (TGA, DSC) and a small batch reactor. The silica-alumina type compounds tested were kaolinite, bentonite, perlite, activated clay and clay. As the results of TGA experiments, pyrolysis starting temperature for EVA resin had the 1st pyrolysis temperature range of 300~$400^{\circ}C$ and the 2nd pyrolysis temperature range of 425~$525^{\circ}C$. The silica-alumina type catalysts did not affect the pyrolysis rate in EVA pyrolysis reaction. In the DSC experiments, addition of kaolinite and bentonite catalysts reduced the heat of fusion and heat of 2nd pyrolysis reaction. In the batch system experiments, the mixing of silica-alumina type catalysts enhanced the yield of fuel oil, and affected to the distribution of carbon numbers. In the silica-alumina type inorganic material used in this experiments, bentonite was the most effective from the pyrolysis heat, yields, and the characteristics of fuel oil.

• 한국전기전자재료학회논문지
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• 제31권7호
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• pp.496-501
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• 2018

In this study, we prepared 40, 45, 50, 55, 60, 65, and 70 wt% content composites filled in epoxy matrix for two micro silica and three micro alumina types for use as a GIS heavy electric machine. As a filler type of epoxy composite, micro silica composites showed excellent AC breakdown strength properties compared to micro alumina composites in the case of electrical properties of micro silica and alumina. The electrical breakdown properties of micro silica composites increased with increasing filler content, whereas those of micro alumina decreased with increasing filler content. In the case of mechanical properties, the micro silica composite showed improved tensile strength and flexural strength compared with the micro alumina composite. In addition, mechanical properties such as tensile strength and flexural strength of micro silica and alumina composites decreased with increasing filler content. This is probably because O-H groups are present on the surface of silica in the case of micro silica but are not present on the surface of alumina in the case of micro alumina.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 추계학술대회
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• pp.336-339
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• 2006

With the steady depletion off fossil fuel reserves, hydrogen based energy sources become increasingly attractive. Therefore hydrogen production or separation technologies, such as Bas separation membrane based on adsorption technology, have received enormous attention in the industrial and academic fields. In this study, the transport mechanisms of the MTES (methyltriethoxysilane) templating silica/a-alumina composite membrane were evaluated by using unary, binary and quaternary hydrogen gas mixtures permeation experiments at unsteady- and steady-states. Since the permeation flux in the MTES membrane, through the experimental and theoretical study, was affected by molecular sieving effects as well as surface diffusion properties, the kinetic and equilibrium separation should be considered simultaneously in the membrane according to molecular properties. In order to depict the transient multi-component permeation on the templating silica membrane, the GMS (generalized Maxwell-Stefan) and DGM (dust Bas model) were adapted to unsteady-state material balance

• The Journal of Advanced Prosthodontics
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• 제9권2호
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• pp.130-137
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• 2017

PURPOSE. The purpose of this study was to evaluate the effect of nano-structured alumina surface coating on shear bond strength between Y-TZP ceramic and various dual-cured resin cements. MATERIALS AND METHODS. A total of 90 disk-shaped zirconia specimens (HASS CO., Gangneung, Korea) were divided into three groups by surface treatment method: (1) airborne particle abrasion, (2) tribochemicalsilica coating, and (3) nano-structured alumina coating. Each group was categorized into three subgroups of ten specimens and bonded with three different types of dual-cured resin cements. After thermocycling, shear bond strength was measured and failure modes were observed through FE-SEM. Two-way ANOVA and the Tukey's HSD test were performed to determine the effects of surface treatment method and type of cement on bond strength (P<.05). To confirm the correlation of surface treatment and failure mode, the Chi-square test was used. RESULTS. Groups treated with the nano-structured alumina coating showed significantly higher shear bond strength compared to other groups treated with airborne particle abrasion or tribochemical silica coating. Clearfil SA Luting showed a significantly higher shear bond strength compared to RelyX ARC and RelyX Unicem. The cohesive failure mode was observed to be dominant in the groups treated with nano-structured alumina coating, while the adhesive failure mode was prevalent in the groups treated with either airborne particle abrasion or tribochemical silica coating. CONCLUSION. Nano-structured alumina coating is an effective zirconia surface treatment method for enhancing the bond strength between Y-TZP ceramic and various dual-cured resin cements.

• 대한환경공학회지
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• 제28권6호
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• pp.596-602
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• 2006

저밀도폴리에틸렌에 첨가되는 무적제와 장수제가 수지의 열분해에 미치는 영향과 폐수지에 함께 포함되어 수집되는 황토 성분 및 촉매로서의 실리카-알루미나 계열의 무기물이 수지의 연료유 변환 반응에 미치는 영향을 열분석기(열중량분석기, 시차주사열량계)와 배치형 반응기에서 살펴보았다. TGA 실험에서 무적제, 장수제, 황토의 첨가는 LDPE 만의 열분해에 비하여 최대열분해속도 온도($T_{max}$)를 증가시켰다. 실리카알루미나 계열 무기물은 활성백토, 규조토, 벤토나이트, 퍼라이트, 고령토 순으로 반응속도를 증가시켰다. DSC 실험에서 무적제와 황토가 첨가되면 LDPE 수지만의 경우보다 융해열과 열분해열을 낮추는 효과를 보였다. 실리카-알루미나 계열에서는 벤토나이트 첨가 시가 융해열을 20% 정도, 열분해열은 25% 정도 감소시켰다. 회분식 반응기에서 황토를 첨가 할 경우 초기 연료유 생성 속도는 다소 낮으나 최종 오일 수율은 높아지는 효과를 보였다. 실리카-알루미나 계열의 촉매에서는 벤토나이트 첨가 시가 오일 수율 향상이 높게 나타났다. 탄소분석에서는 전체적으로 무촉매 열분해실험에서보다는 무적제나 장수제 첨가 시 생성 연료유의 탄소 수가 낮은 쪽으로 이동되었다. 황토 첨가 시는 $C_{12}$ 이하의 휘발유 성분이 감소되었다. $C_{23}$ 이하의 성분 함유량은 벤토나이트, 퍼라이트, 고령토, 활성백토 첨가 시 무촉매 열분해의 경우 보다 증가하였으나 규조토 첨가 시는 큰 차이가 없는 것으로 나타났다. 실험에 사용된 실리카-알루미나 계열의 무기물 중 벤토나이트가 열분해열과 연료유 수율 및 연료유 특성을 고려하여 가장 유효하였다.

• 대한화학회지
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• 제28권6호
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• pp.393-398
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• 1984

겔투과 크로마토그래피와 실리카겔크로마토그래피등을 이용하여 여러가지 천연아스팔트에서 금속포르핀을 얻었으며 크로마토그래피 용액을 알루미나로 처리한 후 피리딘으로 추출하여 보다 농축된 금속 포르피린을 얻을 수 있었다. 금속 포르피린에서 포르피린 고리를 파괴하지 않고 금속을 제거하여 여러가지 형태의 프르피린을 얻었다.

• 한국대기환경학회지
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• 제14권1호
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• pp.63-72
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• 1998

Simultaneous CO and $C_3H_6$ oxidation was carried out over noble metal supported monolith catalysts in a flow thorugh type reactor at the temperature ranging from room temperature to $500^\circ$C. Pt and Pd were selected as major active species, 10wt% of Ce was impregnated as an additive and alumina and silica were used as supports. The reactant gases were simulated and the reaction products were analyzed by on-line G.C.. EDX, SEM, TGA, XRD and optical microscope were used to analyze the characteristics of the prepared catalysts. Under the given conditions in this study, the catalysts supported on alumina showed better activity for CO oxidation, while Pd catalysts showed better activity for $C_3H_6$ oxidation. The improvement of conversion due to increase in thermal stability possibily by Ce addition was observed only for Pt catalysts.

• 공업화학
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• 제23권3호
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• pp.320-325
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• 2012

$SiO_2/Al_2O_3$ 비가 10.5인 실리카-알루미나(SA), 10인 수소형 모더나이트(HM), 12.5인 탈알루미늄 모더나이트(DM) 등을 이용하여 폐윤활유의 촉매분해를 수행하였다. 촉매의 분해능은 SA > DM > HM 시료 순으로 높았다. SA 시료 상에서 얻어진 분해오일은 휘발유의 탄소수 분포와 가까웠고 반면 DM 시료의 경우에는 경유의 탄소수 분포와 가까웠다. HM시료 상에서 얻어진 분해오일의 탄소수 분포는 휘발유와 경유의 중간 정도였다. 산량은 $SA\;{\approx}\;HM$ > DM 시료 순으로 많았다. 10 A 이하의 균일 세공을 가지는 HM과 DM 시료와는 달리, SA 시료의 세공은 10~50 A 범위의 분포를 나타내었다. 이러한 결과들은 촉매의 산량과 세공 크기가 분해오일의 탄소수 분포와 관계가 있음을 보여준다. 촉매 표면에 탄소 및 불순물의 침적에 의한 표면적 감소는 SA > HM > DM 시료 순으로 컸다.

• 한국세라믹학회지
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• 제31권9호
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• pp.1076-1086
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• 1994

This study covers synthetic effect of the various hydrothermal treatments on formation of artificially made kaolinite mineral. The hydrothermal treatment includes the temperature treatment with time duration, addition of seeds, particle size of the starting material used, pH variation and the different types of organic acids. A colloidal silica and alumina sol which are commercially available are used for this study. A colloidal silica and alumina sol are mixed by the atomic ratio of Al/Si = 1, based on the theoretical kaolinite composition and calcined at $600^{\circ}C$ for 8 hours duration. It was found that the kaolinitic clay mineral was well developed; thereby, the different patterns of crystalline mineral are appeared. Spherical type as a crystal form was distinctively formed at the temperature of 20$0^{\circ}C$ to 25$0^{\circ}C$ with short duration time, while platy type as a crystal was highly yielded at 300~35$0^{\circ}C$. Moreover, by adding more than 20 wt% of seed as the natural kaolinitic clay to the starting material is widely distributed and developed when 2 ${\mu}{\textrm}{m}$ or less particle size of the starting material is used; also, when they are heat-treated at the temperature of 25$0^{\circ}C$ with 5 hours duration. With respect of the effect of pH variation on formation of the synthetic kaolinite minerals, the crystalline minerals are highly yielded at less than pH 2 and gradually diminished at more than pH9. Regarding to the effect of different acids on development of the kaolinite mineral, the organic acids with high chelating capacity produces good formation of crystalline minerals; whereas, amine radical-(NH2) is not an effective agent to generate the crystalline minerals.

• 센서학회지
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• 제7권3호
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• pp.188-196
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• 1998

$WO_{3}$계 n-형 반도체 가스센서의 검지특성 및 전기적 특성을 조사하였다. 공기중에서 결합제가 첨가되지 않은 $WO_{3}:TiO_{2}$(4 wt. %) 센서의 낱알경계에서의 전위장벽의 크기는 0.26 V로 나타났으며, 결합제로서 $Al_{2}O_{3}$, PVA (polyvinyl alcohol ), silica sol이 첨가된 센서의 경우는 전위장벽이 각각 0.17, 0.22, 0.26 V로 관측되었다. 이들 시료를 $NO_{x}$가 120 ppm 첨가된 분위기에 노출시켰을 때, 결합제가 첨가되지 않은 센서의 경우는 낱알경계에서의 전위장벽이 0.59 V로 증가하였으며, 결합제로서 $Al_{2}O_{3}$, PVA, silica sol이 첨가된 경우는 전위장벽이 각각 0.43, 0.66, 0.52 V로 나타나, PVA가 첨가된 센서에서 전위장벽의 변화가 가장 높아 감도가 우수하게 되는 것을 알 수가 있었다. 한편 센서 최적 작동온도 이상의 온도에서 나타나는 감도의 감소는 흡착가스 입자의 탈착보다는 공기중에서 다결정이 보이는 저항의 온도 의존성에 따라 나타남이 판명되었다. 또한 결합제가 첨가되지 않은 센서와 결합제로서 Pt가 첨가된 센서의 경우, CO가 250 ppm 존재할 때까지도 전위장벽의 크기가 약 0.2 V로 공기중에서와 비슷한 크기를 나타내어, CO와 $NO_{x}$가 혼합된 분위기에서 $NO_{x}$만을 선택적으로 검지하는데 유리함이 밝혀졌다.