• Title/Summary/Keyword: Silica-alumina

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Properties of reduced and quenched converter slag

  • Ko, In-Yong;Ionescu Denisa;T. R. Meadowcroft
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.542-546
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    • 2001
  • Converter slag has some compositional similarities to portland cement. But it has no hydration properties due to it's quite high concentrations of FeO(20-35%), MnO(4-6.5%). So it is needed to reduce the concentrations of iron and manganese of converter slag to use as cement additives by enhancing it's hydration properties. In this study, converter slag was modified it's composition by mixing of silica, alumina and quenched BF slag and reduced in induction furnace and quenched in running water. The hydraulic properties and structures of modified and quenched converter slag are significantly changed depend on the amount and kinds of additives. The addition of alumina up to 10% and BFQ slag up to 20% by weight on converter slag was effective to enhance the hydraulic properties of modified and quenched slag. The addition of reduced and quenched converter slag up to 20% by weight in replacement of portland cement in mixing of concrete mortar were shown higher compressive strength than 100% cement concrete mortar.

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Advances in Zinc Oxide-Based Devices for Active Matrix Displays

  • Mann, Mark;Li, Flora;Kiani, Ahmed;Paul, Debjani;Flewitt, Andrew;Milne, William;Dutson, James;Wakeham, Steve J.;Thwaites, Mike
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.389-392
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    • 2009
  • Metal oxides have been proposed as an alternative channel material to hydrogenated amorphous silicon in thin film transistors (TFTs) because their higher mobility and stability make them suitable for transistor active layers. Thin films of indium zinc oxide (IZO) were deposited using a High Target Utilization Sputtering (HiTUS) system on various dielectrics, some of which were also deposited with the HiTUS. Investigations into bottom-gated IZO TFTs have found mobilities of 8 $cm^2V\;^1s^{-1}$ and switching ratios of $10^6$. There is a variation in the threshold voltage dependent on both oxygen concentration, and dielectric choice. Silica, alumina and silicon nitride produced stable TFTs, whilst hafnia was found to break down as a result of the IZO.

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Fabrication of Light-weight Ceramic Insulation Materials by Using Oxide Ceramic Fibers for Reusable Thermal Protection Systems (산화물 세라믹섬유를 이용한 재사용 열보호시스템용 경량 세라믹 단열소재의 제조)

  • Seongwon, Kim;Min-Soo, Nam;Yoon-Suk, Oh;Sahn, Nahm;Jaesung, Shin;Hyeonjun, Kim;Bum-Seok, Oh
    • Journal of Powder Materials
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    • v.29 no.6
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    • pp.477-484
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    • 2022
  • Thermal protection systems (TPS) are a group of materials that are indispensable for protecting spacecraft from the aerodynamic heating occurring during entry into an atmosphere. Among candidate materials for TPS, ceramic insulation materials are usually considered for reusable TPS. In this study, ceramic insulation materials, such as alumina enhanced thermal barrier (AETB), are fabricated via typical ceramic processing from ceramic fiber and additives. Mixtures of silica and alumina fibers are used as raw materials, with the addition of B4C to bind fibers together. Reaction-cured glass is also added on top of AETB to induce water-proof functionality or high emissivity. Some issues, such as the elimination of clumps in the AETB, and processing difficulties in the production of reusable surface insulation are reported as well.

Synthesis of Low-Priced Catalyst from Coal Fly Ash for Pyrolysis of Waste Low Density Polyethylene (석탄비산재(石炭飛散災)로부터 저밀도(低密度) 폴리에틸렌 폐기물(廢棄物) 열분해용(熱分解用) 저가(低價) 촉매(觸媒) 합성(合成))

  • Jeong, Byung-Hwan;Na, Jeong-Geol;Kim, Sang-Guk;Mo, Se-Young;Chung, Soo-Hyun
    • Resources Recycling
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    • v.16 no.2 s.76
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    • pp.48-55
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    • 2007
  • A low-priced catalyst for pyrolysis of LDPE has been synthesized. Fly ash, which is waste material generated from coal-fired power plants was used as silica and alumna sources for solid acid catalyst. Amorphous silica-alumina catalysts (FSAs) were pre-pared by dissolution of silica and alumina from fly ash, followed by co-precipitation of the dissoluted ions. A series of LDPE pyrolysis were carried out in a thermogravimetric analyzer to investigate the effects of synthesis conditions such as NaOH/fly ash weight ratio and activation time one catalytic performance of FSAs. The physical properties of FSAs were examined and related to their catalytic performances. FSA(1.2-8) synthesized with NaOH/fly ash weight ratio of 1.2 and the activation time of 8 hours showed the best catalytic performance. The catalytic performance of FSA(1.2-8) was comparable with that of commercial catalysts and it was concluded that the FSA could be a good candidate for catalytic use in the recycling of waste polyolefins.

Development of Ceramic Media for Yeast Immobilization (효모 고정화용 세라믹 담체의 개발)

  • 이율락;박상재
    • KSBB Journal
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    • v.15 no.3
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    • pp.285-292
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    • 2000
  • Support media for yeast immobilization was prepared from a porous volcanic rock used as a moisturizer in orchid growing. The rock was broken to the size of 2-3 mm and burned at $600^{\circ}C$ in a furnace in order to remove organic materials blocking the pores or treated with HCI solution or NaOH solution to remove the inorganic dirts by dissolving. Even through both the acid and the akali solution were effective the latter was not recommendable because it broke the pore structure by dissolving the elements of the media. This media was mainly consisted of SiO2 with $Al_2O_3$ as a minor component and CaO and K2O as trace elements. It had the finely developed pores of $15-80\mu\textrm{m}$size. Yeast immobilization capacity of this media was about $5{\times108}$ cells/ml bed which is large enough to be used for the practical applications. Yeast immobilization capacities of Alumina and Cordierite were much smaller than that of silica-based media. Scanning electron micrograph of Cordierite and Alumina showed uneven surfaces and small size of pores in contrast to relatively smooth surface and large pores of silica based media which means that smooth surface and large pores are desirable for the good adsorption of microbes on the media.

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Effect of SiO2, Al2O3, and Clay Additions on the Sintering Characteristics of Zircon (Silica, Alumnia, Clay를 첨가한 지르콘의 소결특성에 미치는 영향)

  • Lee, Keun-Bong;Jung, Seung-Hwa;Lee, Ju-Sung;Hong, Gyung-Pyo;Jo, Bum-Rae;Moon, Jong-Su;Kang, Jong-Bong
    • Korean Journal of Materials Research
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    • v.18 no.7
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    • pp.352-356
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    • 2008
  • Effect The effect of sintering additives ($SiO_2$, $Al_2O_3$, Clay) on the mechanical characteristics of sintered zircon was investigated. 1 vol% of additives in zircon powder was was sintered at $120{\sim}1500^{\circ}C$, the mechanical characteristics were measured, and microstructure analysis were was conducted. $Al_2O_3$ and clay additions increase the formation of monoclinic and tetragonal-$ZrO_2$ formation. An addition of SiO2 addition suppressed the formation of tetragonal-$ZrO_2$ formation., The A specimen sintered at $1400^{\circ}C$ showed the a density of $4.05\;g/cm^3$ and the a microhardness of 1120 HV, respectively.

A Study on CMP Properties of SnO2 Thin Film for Application of Gas Sensor (가스센서 적용을 위한 SnO2 박막의 CMP 특성 연구)

  • Lee, Woo-Sun;Choi, Gwon-Woo;Kim, Nam-Hoon;Park, Jin-Seong;Seo, Yong-Jin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.12
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    • pp.1296-1300
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    • 2004
  • SnO$_2$ is one of the most suitable gas sensor materials. The microstructure and surface morphology of films must be controlled because the electrical and optical properties of SnO$_2$ films depend on these characteristics. The effects of chemical mechanical polishing(CMP) on the variation of morphology of SnO$_2$ films prepared by RF sputtering system were investigated. The commercially developed ceria-based oxide slurry, silica-based oxide slurry, and alumina-based tungsten slurry were used as CMP slurry. Non-uniformities of all slurries met stability standards of less than 5 %. Silica slurry had the highest removal rate among three different slurries, sufficient thin film topographies and suitable root mean square(RMS) values.

Hydrothermal Preparation of Artificial Stone Plate from Stone Powder Sludge (수열양생법에 의한 석분 슬러지로부터 인조석판재의 제조)

  • 김치권;배광현
    • Korean Journal of Crystallography
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    • v.12 no.4
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    • pp.216-221
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    • 2001
  • Artificial stone plates were hydrothermally prepared in order to utilize the stone powder sludge which were generated from stone quarry . Calcium hydroxide and silica were added to sludge of which main phases were quartz and alumina, and the effect of vapour pressure, reaction time and added amount on the properties of plates were investigated. The compressive strength, water absorp-tion and apparent specific gravity of the plates, which were prepared from the mixture of 70% stone sludge, 20% calcium hydroxide and 10% silica for 3 hours at the conditions of pressing pressure of 200kg/㎠ and vapour pressure of 20 kg/㎠, were 614kg/㎠, 0.48%, 1.88 respectively. It was also possible to produce various colours and appearances by adding inorganic pigments.

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토양 중 브롬화다이옥신류의 분석법 고찰

  • 김태승;신선경;이정희
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.413-417
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    • 2003
  • The last few decades have seen drastic growth in the use of brominated flame retardants(BFRs). There is the problems of polybrominated dibenzo-p-dioxins(PBDDS) and polybrominated dibenzofurans(PBDFs) generation as by-products in combustion process of BFRs. PBDDs/PBDFs are highlighted the new pollutants of environmental contamination, recently. In this study, the 10 kinds of PBDDs/PBDFs standards were used to perform the experiments of recoveries. The analysis of PBDDs/PBDFs in soil environmental samples. was carried out. In silica gel column cleanup, PBDDs/PBDFs eluted until 80mL of n-hexane, and the recovery was obtained 73∼105%. In multi-layer silica gel column cleanup, the recovery was obtained 56∼125% with various elution solvents. In alumina clean process, the standard mixture(PBDES, PBDDs/PBDFs) eluted the first fraction of 2% dichloromethane with n-hexane in the range of 0∼100mL, PBDEs compounds eluted in the second fraction of 50% dichloromethane with n-hexane. In activated carbon column cleanup, the PBBEs eluted to the first fraction(n-hexane) and second fraction(toluene), but PBDDs/PBDFs only eluted to the second fraction. The analytical methods of PBDDs/PBDFs for soil was established based on the experimental results of the environmental samples.

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Utilization of Fly Ash as a Source of Mineral Fertilizers -I. Mineralogical Characteristics (Fly ash 비료화(肥料化) 연구(硏究) -I. Fly ash의 광물학적(鑛物學的) 특성(特性))

  • Shin, Jae-Sung;Seong, Ki-Seog;Kim, Maun-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.20 no.4
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    • pp.309-314
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    • 1987
  • This study was conducted to examine mineralogical aspects on anthractite and bituminous coal-fired power-plant ashes as a source of mineral fertilizer. Fly ashes contain dominant amounts of silica and alumina and considerable quantitites of potassium and boron. However, potassium and silica present in unavailable forms for plant growth. X-ray, DTA, and IR analysis of ash particles indicated the formation of new mineral, mullite with shape of which were spherical in the surface morphologies of SEM. Detailed SEM investigation showed the presence of imbedded blocky shape silicate material.

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