• Title/Summary/Keyword: Silica waste

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A Numerical Study for the Heat and Mass Transfer in Silica gel/Water Adsorption Chiller's Adsorber (흡착식 냉동기의 흡착탑에서 열 및 물질전달에 관한 수치적 연구)

  • Kwon, Oh-Kyung;Yun, Jae-Ho;Kim, Joung-Ha;Kim, Yong-Chan;Joo, Young-Ju
    • Proceedings of the SAREK Conference
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    • 2005.11a
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    • pp.341-346
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    • 2005
  • Nowadays, adsorption chillers have been receiving considerable attentions as they are energy-saving and environmental1y benign systems. A Fin & tube type heat exchanger in which adsorption/desorption take place is required more compact size. The adsorption chiller is expected to have high energy-efficiency in utilizing the waste heat exhausted from a process. The objectives of this paper are to investigate the effect of fin pitch of fin & tube on the adsorption performance and to develop an optimal design fin & tube heat exchanger in the silica gel/water adsorption chiller. Previous study concluded that optimal particle size selected 0.5mm, type HO silica gel, and fundamental heat transfer & mass transfer experiments carried out. From the numerical results, the adsorption rate for the fin pitch 2.5mm is the highest than that for the fin pitch 5mm, 7.5mm and 10mm. Also cooling water & hot water temperature affect the adsorption rate.

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Strength properties of concrete with fly ash and silica fume as cement replacing materials for pavement construction

  • Chore, Hemant Sharad;Joshi, Mrunal Prashant
    • Advances in concrete construction
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    • v.12 no.5
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    • pp.419-427
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    • 2021
  • The overuse level of cement for civil industry has several undesirable social and ecological consequences. Substitution of cement with industrial wastes, called by-products, such as fly ash, ground granulated blast furnace slag, silica fume, metakaoline, rice husk ash, etc. as the mineral admixtures offers various advantages such as technical, economical and environmental which are very important in the era of sustainability in construction industry. The paper presents the experimental investigations for assessing the mechanical properties of the concrete made using the Pozzolanic waste materials (supplementary cementitious materials) such as fly ash and silica fume as the cement replacing materials. These materials were used in eight trial mixes with varying amount of ordinary Portland cement. These SCMs were kept in equal proportions in all the eight trial mixes. The chemical admixture (High Range Water Reducing Admixture) was also added to improve the workability of concrete. The compressive strengths for 7, 28, 40 and 90 days curing were evaluated whereas the flexural and tensile strengths corresponding to 7, 28 and 40 days curing were evaluated. The study corroborates that the Pozzolanic materials used in the present investigation as partial replacement for cement can render the sustainable concrete which can be used in the rigid pavement construction.

Waste to shield: Tailoring cordierite/mullite/zircon composites for radiation protection through controlled sintering and Y2O3 addition

  • Celal Avcioglu;Recep Artir
    • Nuclear Engineering and Technology
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    • v.56 no.7
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    • pp.2767-2774
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    • 2024
  • In this study, investment casting shell waste successfully utilized to produce cordierite/mullite/zircon composites. Green pellets, consisting of investment casting shell waste, alumina, and magnesia, were prepared and sintered at temperatures between 1250 and 1350 ℃. The influence of the sintering temperature on the crystalline phase composition, densification behavior, flexural strength, microstructure, and radiation shielding properties of the cordierite/mullite/zircon composites is investigated. Phase analysis showed that characteristic cordierite peaks appear at 1250 ℃, but the complete conversation of silica from investment casting shell waste into cordierite requires a sintering temperature of at least 1300 ℃. Notably, the cordierite/mullite/zircon composite sintered at 1350 ℃ exhibited a sixfold increase in flexural strength compared to the ceramic composite directly fabricated from investment casting shell waste at the same sintering temperature. Furthermore, the effect of Y2O3 addition on composites' radiation shielding properties is investigated. The results show that the Y2O3 addition improves densification behavior, enhancing the shielding capabilities of the composites against fast neutron and gamma radiation. Our findings suggest that the developed ceramic composites show significant potential for gamma-ray and neutron shielding applications.

Characteristics Evaluation of Radiation Shielding Materials Used Waste Glass and Chelate Resins (폐유리와 킬레이트 수지를 사용한 방사선 차폐재의 재료특성 평가)

  • Kim, Hyo-Jung;Jang, Jong-Min;Song, Young-Soon;Noh, Jae-Ho;Yi, Seong-Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.3
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    • pp.56-64
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    • 2019
  • Various approaches have been attempted to develop recycling technologies related to industrial waste resources containing metals. Among them, glass is not decomposed into microorganisms, so landfill is not suitable, and interest in the recycling of waste glass is increasing. In this paper, by incorporating chelate resin to suppress the elution of heavy metals in waste glass and using waste glass as a fine aggregate and we want to evaluate the strength, drying shrinkage, alkali-silica reaction and heavy metal leaching of shielded filler materials and to provide basic data for utilizing waste glass as an economical and environmentally friendly shielding filler. As a result of the test, it was found that the use of waste glass as a fine aggregate was effective in the development of strength, but the incorporation of chelate resin had an influence on the strength development. In addition, the addition of chelate resin was effective in improving drying shrinkage but it was found to affect the alkali - silica reaction. As a result of the heavy metal leaching test, the KSLP test method satisfies all the criteria for heavy metal leaching. However, in case of lead, the limit of US ANSI 67-2007a was exceeded and further study should be done.

Synthesis of Na-A Type of Zeolite from Funnel-Glass Waste (브라운관의 후면유리 폐기물을 이용한 제올라이트 합성)

  • 장영남;배인국;채수천;류경원
    • Economic and Environmental Geology
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    • v.34 no.2
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    • pp.167-173
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    • 2001
  • Through alkaline hydrothermal activation processes, Na-A type zeolite was synthesized as a single phase with funnel-glass waste from a television tube factory. The autoclaving was performed in a closed teflon vessel in the range of 80~95$^{\circ}$C. The silica-rich solution as a starting material was hydrothermally synthesized with quartz in IN NaOH by heating 350uC under the pressure of 1,500 atm. $NaAlO_2$ was made from NaOH and Al(OHh by heating 95$^{\circ}$C for 2-3 hours and the molar ratios of it were $Na_2O/Al_2O_3$ = 1.4 and $H_2O/Na_2O$=8. The equi-dimensional A type zeolite (1-2 11) was formed by the simple mixing of the silica-rich solution, glass waste and $NaAlO_23$ for 1-3 hours-heating at $80^{\circ}C$. The characterization of the reaction product shows Na-A as a single phase. The synthesized zeolite has cuba-dodecahedral form and $Ca^{2+}$ ion exchange capacity of the Na-A was in the range of 215-220 mequiva1entilOO g.

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Evaluation of Mechanical Properties and Alkali-Silica Reaction of High Strength Mortar Using Waste Glass Sand (폐유리 잔골재를 치환한 고강도 모르타르의 역학적 특성 및 알칼리-실리카 반응 평가)

  • Eu, Ha-Min;Kim, Gyu-Yong;Choe, Gyeong-Cheol;Son, Min-Jae;Nam, Jeong-Soo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.528-536
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    • 2020
  • In this study, high strength mortar and normal strength mortar using waste glass sand were evaluated. The main parameters studied were mechanical properties, alkali-silica reaction(ASR) and residual mechanical properties after ASR. As a result of this experiment, it was found that the increase in strength of the mortar has a limitation in improving the slip of the waste glass sand(GS), and rather, it causes a larger ASR. However, the possibility of improving the slip of GS was confirmed by the temporary increase of initial residal compressive and flexural strength of the mortar containing GS after the ASR. Therefore, to improve the slip of GS, the additional research is required, such as modification of the surface of GS and the incorporation of a binder which can increase the strength and makes matrix compact.

Experimental Study on the Mechanical Properties of Glass Concrete with Powdered Waste Glasses (폐유리 분말을 혼입한 유리 콘크리트의 역학적 특성에 관한 실험적 연구)

  • 배수호;정영수
    • Journal of the Korea Concrete Institute
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    • v.13 no.1
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    • pp.54-61
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    • 2001
  • As a part of the movement of natural resources conservation, there have been doing many recycling research works for obsolete aged tire, wasted plastic materials, etc. The purpose of this experimental study is to develop glass concrete by recycling wasted glasses as a cementitious constituent in concrete. First of all, the optimum replacement ratio of powdered waste glasses(PWG) can be determined through pilot compressive strength test on normal and high strength concrete cylinders, which have been made in various mix proportions by changing the replacement ratio of PWG. Then, further tests have been done to figure out mechanical properties of most desirable glass concrete with optimum replacement ratio of PWG, such as static modulus of elasticity, compressive and tensile strengths, flexural strength. On the other hand, the alkali-silica reactions by the mortar-bar method(KS F 2546) have been experimentally doing in various grain sizes of PWG, since the alkali in the cement has a tendency to react with the silica in the PWG. In can be confirmed from the test that glass concrete can have better workability than concrete with silica fume, and they are alike in compressive strength. It is concluded that wasted glasses can be used as pratical additives for economic and environmentally friendly concrete.

Comparative Analysis of Various Industrial By-Products Pozzolanic Activity (다양한 산업부산물들의 포졸란 반응성 비교분석)

  • Choi, Ik-Je;Kim, Ji-Hyun;Chung, Chul-Woo;Lee, Soo-Yong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.32-33
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    • 2016
  • In this work, pozzolanic activities of various waste materials were compared with those of well-known pozzolanic materials. Uncondensed and densified silica fume, two ASTM class F fly ashes with different calcium contents, and bentonite powder, ceramic powder obtained from wash basin, and waste glass wool, which can possibly possess pozzolanic property were chosen for comparison. Drop in electrical conductivity at 40℃ saturated lime solution was measured for each materials. The amount of Ca(OH)2 decomposed from cement paste at 450~500℃ was also measured used to evaluate pozzolanic activity. The 28 day compressive strength were used to observe the mechanical property enhanced by various waste materials.

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Production of concrete paving blocks using electroplating waste - Evaluation of concrete properties and solidification/stabilization of waste

  • Sgorlon, Juliana Guerra;Tavares, Celia Regina Granhen;Franco, Janaina de Melo
    • Advances in environmental research
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    • v.3 no.4
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    • pp.337-353
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    • 2014
  • The determination of the effectiveness of the immobilization of blasting dust (waste generated in galvanic activities) in cement matrix, as well of mechanical, physical and microstructural properties of concrete paving blocks produced with partial replacement of cement was the objective of this work. The results showed that blasting dust has high percentage of silica in the composition and very fine particle size, characteristics that qualify it for replacement of cement in manufacturing concrete blocks. The replacement of Portland cement by up to 5% residues did not cause a significant loss in compressive strength nor increase in water absorption of the blocks. Chemical tests indicated that there is no problem of leaching or solubilization of contaminants to the environment during the useful life of the concrete blocks, since the solidification/stabilization process led to the immobilization of waste in the cement mass. Therefore, the use of blasting dust in the manufacture of concrete paving blocks is promising, thus being not only an alternative for proper disposal of such waste as well as a possibility of saving raw materials used in the construction industry.

Physical Characteristics of Cement Mortar Prepared Using Waste Glass and Graphene Oxide (폐유리와 산화 그래핀을 사용한 시멘트 모르타르의 물성 연구)

  • Kim, Kyoungseok;Chu, Yongsik
    • Resources Recycling
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    • v.28 no.6
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    • pp.54-63
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    • 2019
  • This study investigated on the compressive strength and the length change test with using the waste glass and graphene oxide for recycling the waste glass as the aggregate. Curing on 3-day and 7-day, the compressive strength was enhanced as the usage of waste glass was increased. Especially, the huge difference in the compressive strength was observed when the amount of substituting on the waste glass was used on 10~50%. With 50% of waste glass condition, the compressive strength was portionally enhanced as the usage of graphene oxide was increased and its value was 42.6 N/㎟ with 0.2% of graphene oxide. In terms of the length change test, the use of high content of waste glass led length change value to increase, but it was dropped down as the portion of waste glass was above 50%. Furthermore, in the case of using 50% of waste glass, the use of high amount of graphene oxide tended to decrease the length change value. That is, graphene oxide may contribute on boosting the cement hydration reaction and blocking the ion's movement.