• Title/Summary/Keyword: Silica composites

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Wear Characteristics of SiC by Sintered Temperature and SiO2 Contents (소결온도 및 SiO2 첨가량에 따른 탄화규소의 마모 특성)

  • Park, Sung-Ho;Park, Won-Jo;Yoon, Han-Ki
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.11
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    • pp.1003-1009
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    • 2008
  • In this study, liquid phase sintered SiC (LPS-SiC) materials were made by hot pressing method. The particle size of nano-SiC powder was 30nm. Alumina ($Al_2O_3$), yttria ($Y_2O_3$) and silica ($SiO_2$) were used for sintering additives. To investigate effects of $SiO_2$, ratios of $SiO_2$ contents were changed by five kinds. Materials have been sintered for 1 hour at $1760^{\circ}C$, $1780^{\circ}C$ and $1800^{\circ}C$ under the pressure of 20MPa. The system of sintering additives which affects a property of sintering as well as the influence depending on compositions of sintering additives were investigated by measurement of density, mechanical properties such as flexural strength, vickers hardness and sliding wear resistance were investigated to make sure of the optimum condition which is about matrix of $SiC_f$/SiC composites. The abrasion test condition apply to load of 20N at 100RPM for 20min. Sintered density, flexural strength of fabricated LPS-SiC increased with increasing the sintering temperature. And in case of LPS-SiC with low $SiO_2$, sliding wear resistance has very excellent. Monolithic SiC $1800^{\circ}C$ sintering temperatures and 3wt% have excellent wear resistance.

New Engineering Techniques for Carbon Master Batch (탄소 마스터배치를 위한 새로운 엔지니어링 기술)

  • Pyo, Sang-Gil;Kang, Chang-Gi;Kim, Ki-Seok;Park, Soo-Jin
    • Elastomers and Composites
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    • v.48 no.2
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    • pp.125-132
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    • 2013
  • In this work, we have discussed new engineering systems for preparing carbon master batch composed by carbon black and various organic compounds. In general, polymer resin, which applied for automobile tire, household items, and various industry items, is used with the fillers including carbon black and silica to control the color or properties. Domestic part and material industry has been remarkably developed in that the development of materials including the compounding of raw materials. Meanwhile, the engineering technique for mass production has not reached to a requirement of industry due to slow technique development and high dependence on foreign. Thus, we will focus on the introduction of new engineering technique developed by domestic company for preparing carbon master batch.

Improved Corrosion and Abrasion Resistance of Organic-Inorganic Composite Coated Electro-galvanized Steels for Digital TV Panels

  • Jo, Du-Hwan;Noh, Sang-Geol;Park, Jong-Tae;Kang, Choon-Ho
    • Corrosion Science and Technology
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    • v.14 no.5
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    • pp.213-217
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    • 2015
  • Recently, household electronic industries require environmentally-friendly and highly functional steels in order to enhance the quality of human life. Customers especially require both excellent corrosion and abrasion resistant anti-fingerprint steels for digital TV panels. Thus POSCO has developed new functional electro-galvanized steels, which have double coated layers with organic-inorganic composites on the zinc surface of the steel for usage as the bottom chassis panel of TVs. The inorganic solution for the bottom layer consists of inorganic phosphate, magnesium, and zirconium compounds with a small amount of epoxy binder, and affords both improved adhesion properties by chemical conversion reactions and corrosion resistance due to a self-healing effect. The composite solution for the top layer was prepared by fine dispersion of organic-inorganic ingredients that consist of a urethane modified polyacrylate polymer, hardener, silica sol and a titanium complex inhibitor in aqueous media. Both composite solutions were coated on the steel surface by using a roll coater and then cured through an induction furnace in the electro-galvanizing line. New anti-fingerprint steel was evaluated for quality performance through such procedures as the salt spray test for corrosion resistance, tribological test for abrasion resistance, and conductivity test for surface electric conductance regarding to both types of polymer resin and coating weight of composite solution. New composite coated anti-fingerprint steels afford both better corrosion resistance and abrasion properties compared to conventional anti-fingerprint steel that mainly consists of acrylate polymers. Detailed discussions of both composite solutions and experimental results suggest that urethane modifications of acrylate polymers of composite solutions play a key role in enhanced quality performances.

Crack Growth and Wear Properties of Silica-reinforced Styrene-butadiene Rubber Compounds: Effect of Processing Oil Type (실리카충전 스티렌-부타디엔 고무컴파운드의 균열성장 및 마모특성: 공정오일 종류의 영향)

  • Kang, S.L.;Lee, J.Y.;Go, J.Y.;Go, Y.H.;Kaang, S.;Nah, C.
    • Elastomers and Composites
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    • v.44 no.4
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    • pp.401-407
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    • 2009
  • Commercial grades of solution styrene-butadiene rubbers extended with high aromatic oils having high polycyclic aromatic compounds (PCA) and low PCA oils were used to study the effect of the processing oil particularly on the crack propagation resistance and frictional wear resistance of the vulcanizates. The aromatic oil based vulcanizates exhibited superior fracture behavior over the low PCA oil extended vulcanizates based on tensile and trouser tear tests. Compounds with aromatic oil showed superior crack propagation resistance compared with those containing low PCA oil, especially at the lower ranges of tearing energy. In terms of frictional wear resistance, the aromatic oil extended compounds showed superior performance particularly in the lower frictional work ($W_f$) range but in the higher $W_f$ range the low PCA oil extended vulcanizates performed better.

Advanced Synthetic Technology for High Performance Energy Tire Tread Rubber (고성능 에너지 절약형 타이어 트레드 고무의 합성 제조 기술)

  • Lee, Bum-Jae;Lim, Ki-Won;Ji, Sang-Chul;Jung, Kwon-Young;Kim, Tae-Jung
    • Elastomers and Composites
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    • v.44 no.3
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    • pp.232-243
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    • 2009
  • The specialized and diversified synthetic and compounding technologies are used to meet the requirements for the advanced high performance tire tread materials with better balance of fuel economy(rolling resistance), safety(wet traction) and wear resistance. These techniques involve the methodology for the improvement of chemical and physical interaction between filler and the rubber matrix using coupling agents as well as a variety of chemically-modified solution SBRs. The research trends about the high performance functional SBRs and coupling agents which can interact with the surface of fillers and their working mechanism were investigated in the conventional carbon black-filled rubber and silica-filled SBR systems developed recently as "green tire".

Determination of Strain Energy Function of Rubber Materials Considering Stress Softening Behavior (응력연화거동을 고려한 고무 재료의 변형률 에너지 함수 결정)

  • Kim, W.S.;Hong, S.I.
    • Elastomers and Composites
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    • v.42 no.3
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    • pp.168-176
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    • 2007
  • When the rubber vulcanizates reinforced with carbon black or silica are subjected to cyclic loading from its virgin state, the stress required on reloading is less than that on the initial loading. This stress softening phenomenon is referred to as the Mullins effect. The strain energy function of rubber vulcanizates was investigated using theory of pseudo-elasticity incorporated damage parameter that Ogden and Roxburgh have proposed to describe the damage-induced stress softening effect in rubber-like solids. The quasi-static cyclic loading test was performed using the NR-SBR vulcanizates reinforced with carbon black, and then the effect of a damage parameter to stress-strain curve in reloading and subsequent reloading paths was studied. The strain energy function of the rubber vulcanizates with a different filler content was also evaluated.

Effects of temperature on Hardness and Stiffness of NR and SBR Vulcanizates (NR과 SBR 가황물의 경도와 강성도 대한 온도의 영향)

  • Jin, Hyun-Ho;Hong, Chong-Kook;Cho, Dong-Lyun;Kaang, Shin-Young
    • Elastomers and Composites
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    • v.42 no.3
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    • pp.143-150
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    • 2007
  • Hardness of rubbery materials, which is important for dimensional stability and product performance, was investigated upon temperature change in this study. A newly developed IRHD (International Rubber Hardness Degree) tester was used to measure the hardness changes of NR and SBR specimens at various temperatures and the hardness values were compared with the Young's modulus. The harness and Young's modulus of NR and SBR showed an abrupt change near the glass transition temperatures. The hardness and Young's modulus were increased by increasing temperature due to the increased random chain conformation of molecules. The effect of temperature on hardness and Young's modulus of NR and SBR specimens filled with carbon black and silica was decreased by increasing filler content.

Thermal properties and mechanical properties of dielectric materials for thermal imprint lithography

  • Kwak, Jeon-Bok;Cho, Jae-Choon;Ra, Seung-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.242-242
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    • 2006
  • Increasingly complex tasks are performed by computers or cellular phone, requiring more and more memory capacity as well as faster and faster processing speeds. This leads to a constant need to develop more highly integrated circuit systems. Therefore, there have been numerous studies by many engineers investigating circuit patterning. In particular, PCB including module/package substrates such as FCB (Flip Chip Board) has been developed toward being low profile, low power and multi-functionalized due to the demands on miniaturization, increasing functional density of the boards and higher performances of the electric devices. Imprint lithography have received significant attention due to an alternative technology for photolithography on such devices. The imprint technique. is one of promising candidates, especially due to the fact that the expected resolution limits are far beyond the requirements of the PCB industry in the near future. For applying imprint lithography to FCB, it is very important to control thermal properties and mechanical properties of dielectric materials. These properties are very dependent on epoxy resin, curing agent, accelerator, filler and curing degree(%) of dielectric materials. In this work, the epoxy composites filled with silica fillers and cured with various accelerators having various curing degree(%) were prepared. The characterization of the thermal and mechanical properties wasperformed by thermal mechanical analysis (TMA), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), rheometer, an universal test machine (UTM).

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Preparation of Shape Stabilized PCM Using Porous Materials for Application to Buildings (건축적용을 위한 다공성 물질을 이용한 상안정 PCM 제조)

  • Jeong, Su-Gwang;Yu, Seulgi;Jang, Seulae;Park, Jin-Sung;Kim, Taehyun;Lee, Jeong-Hun;Kim, Sumin
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.25 no.8
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    • pp.432-437
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    • 2013
  • The increase of greenhouse gas emission and decrease of fossil fuel are being caused by the indiscreet consumption of energy by people. Recently, green policy has been globally implemented to reduce energy consumption. This paper studied the research to reduce the energy consumption in buildings, by using the heat storage properties of PCM. PCM has to prevent leakage from the liquid state. Therefore, we prepared form stable PCM, by using the vacuum impregnation method. Three kinds of organic PCMs were impregnated into the structure of porous material. The characteristics of the composites were determined by using SEM, DSC, FTIR and TGA. SEM morphology showed the micro structure of silica fume/PCM. Also, thermal properties were examined by DSC and TGA analyses; and the chemical bonding of the composite was determined by FTIR analysis.

Hydrophobic Organic/Inorganic Composite Films with 3D Hierarchical Nanostructured Surfaces (3D 계층적 나노구조화된 표면을 갖는 소수성 유/무기 복합 필름)

  • Seo, Huijin;Ahn, Jinseong;Park, Junyong
    • Composites Research
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    • v.34 no.4
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    • pp.264-268
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    • 2021
  • In this study, we propose a method for fabricating hydrophobic coatings/films with three-dimensional (3D) hierarchical nanostructured organic/inorganic composite surfaces. An epoxy-based, large-area 3D ordered nanoporous template is first prepared through an advanced photolithography technique called Proximity-field nanoPatterning (PnP). Then, a hierarchically structured surface is generated by densely impregnating the template with silica nanoparticles with an average diameter of 22 nm through dip coating. Due to the coexisting micro- and nano-scale roughness on the surface, the fabricated composite film exhibits a higher contact angle (>137 degrees) for water droplets compared to the reference samples. Therefore, it is expected that the materials and processes developed through this study can be used in various ways in the traditional coating/film field.