• Structural Engineering and Mechanics
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• v.59 no.2
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• pp.261-275
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• 2016

Effect of silica fume on fresh properties, compressive strength at 28 days and fracture behavior of fly ash concrete composite were studied in this paper. Test results indicated that the fluidity and flowability of fly ash concrete composites decreased and fly ash concrete composite are more cohesive and appear to be sticky with the addition of silica fume. Addition of silica fume was very effective in improving the compressive strength at 28 days of fly ash concrete composite, and the compressive strength of fly ash concrete composite has a trend of increase with the increase of silica fume content. Results also indicated that all the fracture parameters of effective crack length, fracture toughness, fracture energy, the critical crack opening displacement and the maximum crack opening displacement of fly ash concrete composite decreased with the addition of silica fume. When the content of silica fume increased from 3% to 12%, these fracture parameters decreased gradually with the increase of silica fume content. Furthermore, silica fume had great effect on the relational curves of the three-point bending beam specimen. As the silica fume content increased from 3% to 12%, the areas surrounded by the three relational curves and the axes were becoming smaller and smaller, which indicated that the capability of concrete composite containing fly ash to resist crack propagation was becoming weaker and weaker.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2015.11a
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• pp.263-263
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• 2015

절연층이 코팅된 연자성복합체(Soft magnetic composites) 분말 성형 시 발생하는 밀도와 강도 저하의 문제를 개선하기 위해 금속산화물 전구체로 표면 개질된 자성분말을 성형 후 경화시키는 방법으로 분말 자심을 제조하였다. 이를 통해 공정이 단순화 되면서 자심의 물리적 내구성을 향상시킬 수 있음을 확인하였다.

• Korean Chemical Engineering Research
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• v.49 no.4
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• pp.465-469
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• 2011

In this study, poly(ethyleneoxide) and poly(ethylene imine) polymer blends containing fumed silica fillers were studied in order to enhance the ion conductivity and interfacial properties. Lithium perchlorate ($LiClO_4$) as a salt, and silica($SiO_2$) as the inorganic filler were introduced into the polymer composite electrolyte composites and the composites were examined to evaluate their ionic conductivity for a possibility test of electrolyte application. As the diameter of semicircle in an impedance test became smaller, ionic conductivity of composite electrolytes had been enhanced by addition of 20 wt% silica filler. However, the conductivity was not greatly changed over 20 wt% content because the silica was sufficiently saturated in the polymer electrolytes. Diffraction peaks of PEO became weaker with the addition of inorganic fillers using XRD analysis. It showed that a crystallinity was proportionally reduced by increasing filler contents. The morphology of composite electrolyte films has been investigated by SEM. The heterogeneous morphology which silica was evenly dispersed by the strong adhesion of PEI was shown at higher contents of silica.

• Journal of Conservation Science
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• v.27 no.4
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• pp.431-440
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• 2011

The thermal expansion coefficient of epoxy/inorganic additives composites was controlled by changing the amount of the inorganic additives such as talc and fused silica. The epoxy resin comprises hydrogenated bisphenol A (HBA)-based epoxide, difunctional polyglycidyl epoxide (DPE) as a diluent and isophorone-diamine (IPDA) as a crosslinking agent, which was subsequently mixed with inorganic additives (talc and fused silica). The thermal expansion coefficient was decreased by increasing amount of inorganic additives, nearly to fresh granite. Fused silica was more effective than talc in lowering the thermal expansion coefficient. Additionally, lexural and tensile strengths of the composites were getting lower and higher with the amount of the inorganic fillers, respectively. It was thus concluded that an epoxy composite containing inorganic fillers was developed to show much lower thermal expansion coefficient, similar to fresh granite, than the neat epoxy resin, and also proper mechanical strengths for applications.

• Composites Research
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• v.33 no.5
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• pp.268-274
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• 2020

This paper analyzed the degradation behaviors of silica nano epoxy composite based on the isoconversional method. The size of the silica nano particle was about 12 nm and the particles were mixed by three different weight ratios to make the degradation test samples. The thermogravimetric analyses were performed under six different temperature increase rates to measure the weight changes. Four different methods, Friedman, Flynn-Wall-Ozawa, Kissinger and DAEM (Distributed Activation Energy Method), were employed to calculate the activation energies depending on the conversion ratios, and their calculation results were compared. The results represented that the activation energy was increased when the silica nano particles were mixed up to 10%, indicating the definite contribution of the particles to the degradation behavior enhancements. However, the enhancement was not proportional to the particle mixture ratio by demonstrating the similar activation energies between 10% and 18% samples. The calculation results by the different methods were also compared and discussed.

• Elastomers and Composites
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• v.43 no.3
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• pp.147-156
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• 2008

In this work, epoxy/carboxyl-terminated butadiene acrylonitirile (EP/CTBN) composites were prepared by employing a reinforcing filler, silica treated with silane coupling agent in different ratio by dry and wet method. Their curing characteristics, surface free energy, interface morphologies and mechanical properties such as tensile strength and impact resistance were carefully investigated. Differential scanning calorimetry(DSC) results showed that curing temperature was lowered with the increase of silane coupling agent because of the increase of relative curing agent cotent by filling the pores of silica. Wet method was proved to be more effective for lowering curing temperature of EP/CTBN composite. In general, surface free energy and impact resistance were increased with the increase of silane coupling agent in this work. Tensile strength, however, was observed to be decreased at 4 wt% of silane coupling agent. It was found that the dry method was proved to be preferable for pretreatment of silica with coupling agent.

• Journal of the Korean Ceramic Society
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• v.35 no.1
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• pp.23-32
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• 1998

Al2O3/Al composites were produced by immersing the sintered silica preform in molten aluminum which contained magnesium as impurity. Three distinct regions existed in the penetration behavior of molten me-tal with changing the reaction temperature. These regions are denoted as low temperature regime(75$0^{\circ}C$-85$0^{\circ}C$) intermediate regime(90$0^{\circ}C$-95$0^{\circ}C$) and high temperature regime(100$0^{\circ}C$$\leq$) In the low temperature regime the penetration speed of molten aluminum increased with increasing reaction temperature whereas it decreased in the intermediate regime due to the phase transition of alumina formed by displacement reac-tion. In the high temperature regime the penetration speed of molten aluminum was the highest at 100$0^{\circ}C$ which was 3.6 mm/hr But above 105$0^{\circ}C$ molten aluminum did not penetrate into the silica preform because of the formation of a dense spinel layer at the preform surface by magnesium in molten Al.

• Elastomers and Composites
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• v.39 no.1
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• pp.51-60
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• 2004

The cure, viscoelastic and mechanical characteristics of organoclay filled NR/BR blends were studied and compared with the properties of carbon black and silica filled NR/BR blends. The nanocomposites with extensive exfoliation state can be fabricated by a solution mixing method. In the composites, the amount of filler content was fixed to 10 phr. Degree of intercalation and exfoliation was characterized by X-ray diffraction (XRD). XRD results indicated exfoliation of the silicate layers into the rubber matrix. While the degree or intercalation and exfoliation is lowered by the conventional mixing method, extensive exfoliation can be obtained by the solution mixing method. It was found that the clay filled NR/BR compound showed better viscoelastic (tan ${\delta}$) and mechanical properties than the carbon black or silica filled NR/BR compounds.

• Journal of Adhesion and Interface
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• v.4 no.1
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• pp.9-17
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• 2003

The UV hard coating materials are attracting more and more attention to modern industry, in terms of the development of low or non solvent coating materials which will contribute to economizing both materials and energy and to reducing pollution. This study was performed in order to invent UV curable coating materials containing colloidal silica which have actual industrial applications. As results of experiments, the oligomers type and the concentration of colloidal silica acrylate oligomer (SAOC) have an influence on various especially, The properties of UV hardening cooling, such as chemical, abrasion resistance and weatherability, were greatly enhanced, the impact properties of coated polycarbonate substrate were improved compared with the noncoated that. The UV cured films containing 30 wt% SAOC obtained showed the best properties.

• Journal of the Korean Ceramic Society
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• v.28 no.12
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• pp.1012-1018
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• 1991

SiC whisker-reinforced LAS matrix composites were developed by a mixed colloidal processing route. An optimization of processing conditions was made using the zeta potential data of silica, boehmite, and SiC whisker dispersions. Similarly, the SiC whisker-reinforced composites were also fabricated by the conventional sol-gel process using the hydrolysis-condensation reaction of relevant metal alkoxides. The composites fabricated by the mixed colloidal processing route were characterized by a uniform spatial distribution of SiC whisker throughout the matrix. The fracture toughness increased from 1.3 MPa.m1/2 for the LAS specimen to 5.0 Mpa.m1/2 for the hot-pressed composite (95$0^{\circ}C$ and 20 MPa for 20 min) containing 20 wt% SiC whisker. The increase in fracture toughness appears to result mainly from the crack deflection and the crack bridging by whiskers with some additional toughenings from the whisker pullout and the matrix prestressing mechanisms.