• Title/Summary/Keyword: Side Reaction

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An Analytical Study on Inclination of Vertical Piles (연직말뚝의 경사도 오차에 관한 해석적 연구)

  • 장정욱;박춘식;최차석
    • Proceedings of the Korean Geotechical Society Conference
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    • 2003.03a
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    • pp.463-468
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    • 2003
  • This paper studied the effects of inclination of piles on pile behaviors. The following are the conclusions of this study. (1) When all the piles are inclined to a same direction, the piles reaction, maximum moment and horizontal displacement of footing increase as the angle of inclination increases. (2) When the piles of each opposite side are inclined symmetrically, the vertical reaction either increases or decreases in proportion to the angle of inclination. In this case, the vertical reaction of inclined piles decreases but the vertical reaction of non-Inclined piles increases.

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Coordination Chemistry of Chlorophylls: Which Side of the Chlorin Macrocycle is Favored for the Ligand Coordination\ulcorner

  • Oba, Toru;Tamiaki, Hitoshi
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.362-363
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    • 2002
  • Since chlorophyll a and bacteriochlorophyll a are asymmetric molecules, an external ligand can coordinate to the central Mg atom either from the chiorin macrocycle side where the C13$^2$-methoxycarbonyl moiety protrudes (denoting as the 'back' side) or frome the other side (the 'face' side). We investigated which side of the macrocycle is favored for the ligand coordination, by survey of the highly resolved crystal structures of various photosynthetic proteins and theoretical model calculations. It is found that chlorophyll a as well as bacteriochlorophyll a and b in the photosynthetic proteins mostly bind their ligands on the 'back' sides. This finding was confirmed by the theoretical calculations for methyl chlorophyllide a and methyl bacteriochlorophyllide a as models: the 'back' type ligand-(bacterio )chlorophyll complex was more stable than the 'face' type one. The calculations predicted influence of the Cl3$^2$-stereochemistry on the choice of the side of the ligand coordination, which is discussed in relation to the presence of the Cl3$^2$-epimer of chlorophyll a in photosystem I reaction center [I].

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A Study on the Development of the Side Load Coil Spring (횡력발생 코일스프링 설계 및 제조에 관한 연구)

  • Kwon, H. H.;Choi, S. J.
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.7 no.5
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    • pp.98-105
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    • 1998
  • In the automotive suspension system, especially, Mcpherson strut type, if the resultant of the force through tire and the link reaction force is not coincident with the spring force, the side load against shock-absorber occur. The magnitude of side load is proportional to the difference between resultant force and spring force. To reduce side load, several method can be used, and one is to use the side load coil spring. This study summarize the development results of side load coil spring, i.e., how to design, analysis, manufacture, and test.

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Rigorous Modeling and Simulation of Multi-tubular Reactor for Water Gas Shift Reaction (Water Gas Shift Reaction을 위한 Multi-tubular Reactor 모델링 및 모사)

  • Park, Junyong;Choi, Youngjae;Kim, Kihyun;Oh, Min
    • Korean Chemical Engineering Research
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    • v.46 no.5
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    • pp.931-937
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    • 2008
  • Rigorous multiscale modelling and simulation of the MTR for WGSR was carried out to accurately predict the behavior of process variables and the reactor performance. The MTR consists of 4 fixed bed tube reactors packed with heterogeneous catalysts, as well as surrounding shell part for the cooling purpose. Considering that fluid flow field and reaction kinetics give a great influence on the reactor performance, employing multiscale methodology encompassing Computational Fluid Dynamics (CFD) and process modeling was natural and, in a sense, inevitable conclusion. Inlet and outlet temperature of the reactant fluid at the tube side was $345^{\circ}C$ and $390^{\circ}C$, respectively and the CO conversion at the exit of the tube side with these conditions approached to about 0.89. At the shell side, the inlet and outlet temperature of the cooling fluid, which flows counter-currently to tube flow, was $190^{\circ}C$ and $240^{\circ}C$. From this heat exchange, the energy saving was achieved for the flow at shell side and temperature of the tube side was properly controlled to obtain high CO conversion. The simulation results from this research were accurately comparable to the experimental data from various papers.

The Relationship between Grip Strength and Ground Reaction Force by Change of Position when Lifting Tasks (들기 작업할 때 자세의 변화에 따른 악력과 지면 반발력의 상관관계)

  • Jung, Sang-Yong;Gang, Jin-Woo;Koo, Jung-Wan
    • Journal of the Ergonomics Society of Korea
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    • v.28 no.3
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    • pp.41-47
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    • 2009
  • The purpose of this study, during the lifting task was researching the difference and a relationship between the ground reaction force and the grip strength by change of position. After grip strength has measured in symmetry position and asymmetry position at 45cm and 75cm of height of hand, ground reaction force was measured by same attitude lifting wooden box. We analyzed the difference of grip strength and ground reaction force in each position change. The results of grip strength, the grip strength of both hand were significant difference that in study subject symmetry and asymmetry position (p<0.01). The results of symmetry lifting task, the study subjects was significant difference of the ground reaction force difference by height (p<0.05). Asymmetry lifting task was significant difference of ground reaction force difference by direction of rotation was changed (p<0.01). The result of it will rotate with non-dominant hand side of lifting tasks from height 75cm where it easily maintains a balance possibility and decreasing the load of the hand. Therefore, from the workshop in the work people, it will be between the height 75cm and non-dominant hand side of trunk rotatory direction in the lifting tasks. Future study is necessary researched about the change of grip strength when the height of the hand is higher, and the difference of the ground reaction force when the change of weight.

Differentiation of Reaction Tissues in the First Internode of Acer saccharinum L. Seedling Positioned Horizontally (수평으로 위치한 은단풍(Acer saccharinum L.) 유식물의 제1절간에 있어서 반응조직의 분화)

  • 강경덕
    • Journal of Plant Biology
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    • v.35 no.3
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    • pp.211-217
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    • 1992
  • In order to elucidate the formation of reaction tissues during the transition from primary to secondary growth, the developmental anatomy was conducted in the first internode of Acer sacchan'num seedling in horizontal position. During the transition from primary to secondary growth, tension wood(gelatinous fiber) was gradually developed on the upper side only, And the tension wood formation in the upper side of the horizontal first internode proceeds acropetally from base to apical portion. Some of the anatomical features of tension wood start to be in the primary vascular tissue and a typical tension wood show during the secondary growth, Therefore, the procambium seems to respond to the gravity as well as vascular cambium. For this reason, both procambium and vascular cambium has to regard as the same meristem, On the other hand, the upper side vessels were longer than those of the lower side in the horizontal first internode. The lateral-wall pitting of vessel elements, however, showed no differences between upper and lower sides which have alternate type. The width and height of rayon the upper side of horizontal first internode was larger as compared with the lower side.r side.

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Density Functional Studies of Ring-Opening Reactions of Li+-(ethylene carbonate) and Li+-(vinylene carbonate)

  • Han, Young-Kyu;Lee, Sang-Uck
    • Bulletin of the Korean Chemical Society
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    • v.26 no.1
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    • pp.43-46
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    • 2005
  • Reaction energies were determined for reductive ring-opening reactions of Li$^+$-coordinated ethylene carbonate (EC) and vinylene carbonate (VC) by a density functional method. We have also explored the ring-opening of Li$^+$-EC and Li$^+$-VC by reaction with a nucleophile (CH$_3$O$^-$.) thermodynamically. Our thermodynamic calculations led us to conclude that the possible reaction products are CH$_3$OCH$_2$CH$_2$OCO$_2$Li (O$_2$-C$_3$ cleavage) for Li$^+$-EC +CH$_3$O$^-$., and CH$_3$OCHCHOCO$_2$Li (O$_2$-C$_3$ cleavage) and CH$_3$OCO$_2$CHCHOLi (C$_1$-O$_2$ cleavage) for Li$^+$-VC +CH$_3$O$^-$.. The opening of VC would occur at the C$_1$-O$_2$ side by a kinetic reason, although the opening at the O$_2$-C$_3$ side is more favorable thermodynamically.

Control of Damping Forces by Side Clearance in Leaf Spring Damper (겹판스프링댐퍼에서 측면틈새에 의한 감쇠력 조절)

  • 김종수;김상도;제양규
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1999.06a
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    • pp.285-290
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    • 1999
  • This paper describes that the leaf spring damper(LSD) developed by authors can be controled by side clearance between side cover and leaf spring. The test rig and two prototype dampers with different side clearance were manufactured. Experiments were performed to investigate the effects of side clearance on the damping of leaf spring damper. The stiffness and damping coefficients are obtained from the displacements and the reaction forces generated by rotating the eccentric shaft. All dynamic coeffficients are plotted with the excitation frequency which is adjusted by rotating speed of shaft.

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A Research of Psychosomatic disorders caused by Qi-experience (기수련부작용의 정신신체장애에 대한 임상적 연구)

  • Shin, Yong-Cheol
    • Journal of Oriental Neuropsychiatry
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    • v.11 no.1
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    • pp.97-102
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    • 2000
  • In the study of psychosomatic disorders caused by Qi-experience, the results were as follows: 1. People are becoming more and more interested in qigong, but sometimes peple are suffer from side effects from Qi-experience. In oder to treat this side effects of qigong, it is important to control Qi unbalance. And this is associated with the mechanism of stress-reaction. 2. The causes of side-effects were tension of body and mind, concentration of head, enduring breath, and wrong qigong-method, etc. 3. The symptoms of side-effects were headache, flushing face, chest discomfort, neck stiffness, indigestion, etc. 4. The theraphy of side-effects is herb-medicine, acupuncture, moxibution, and more effective by application of psychotheraphy, relaxation-theraphy, music, aroma, taping.

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