• Title/Summary/Keyword: SiCN

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Morphology Control of Active Layers for Efficient Organic Indoor Photovoltaics (광활성층 모폴로지 제어를 통한 실내광 유기태양전지의 효율 향상 연구)

  • Yongchan Jang;Soyoung Kim;Jeonga Kim;Jongbok Kim;Wonho Lee
    • Journal of Adhesion and Interface
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    • v.23 no.4
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    • pp.130-136
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    • 2022
  • Recently, organic semiconductor based indoor photovoltaics have gained attention since they exhibit excellent photovoltaic performance than that of conventional Si-based photovoltaics. In this study, we synthesize the medium bandgap polymer of PTBT and optimize PTBT:PC71BM blend films by introducing solvent additives. To this end, we select DIO and CN solvent additives and vary their contents from 0 to 3 vol%. As a result, we produce the highest power conversion efficiency of 11.31% under LED 1000 lx conditions with DIO (1.5 vol%) + CN (0.5 vol%)

Synthesis and Properties of Anionic Tetrakis(pentafluorophenyl)indium(Ⅲ) Complexes (Tetrakis(pentafluorophenyl)indium(Ⅲ) 음이온 착물의 합성과 특성)

  • Choi, Zel Ho
    • Journal of the Korean Chemical Society
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    • v.43 no.1
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    • pp.52-57
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    • 1999
  • The anionic complexes, [ln($C_6F_5)_4$]-, which are thermal and moisture sensitive, have been prepared by the reaction of In($C_6F_5)_3{\cdot}D(D=CH_3CN$, O($C_2H_5)_2$) with the system ($CH_3)_3SiC_6F_5$/CsF, $C_6F_5$MgBr or Cd($C_6F_5)_2$. The stable anionic indium(III) complexes are obtained through cation exchange with PNPCI ([PNP]= bis(triphenylphosphino)ammonium). The pure substance is obtained by column chromatography. These new anionic complexes are unambiguously identifed by NMR-spectroscopy, IR spectroscopy, molecular weight, DTA/TG and elemental analysis.

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Synthesis of Crystalline film from ${CH_4}-{H_2}-{N_2}$ gases with MW-PACVD (${CH_4}-{H_2}-{N_2}$ 기체계에서 MW-PACVD를 이용한 결정상 합성)

  • Kim, Do-Geun;Baek, Young-Joon;Seong, Tae-Yeon
    • Korean Journal of Materials Research
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    • v.10 no.9
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    • pp.648-655
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    • 2000
  • Synthesis of the crystalline film was investigated under the diamond growth condition with altering the addition of the nitrogen from 0% to 95%. With increasing the nitrogen concentration, surface morphology of the film was changed from the diamond film with {100} growth plane to the non-faceted diamond film with nano-scale grains. It also showed that the deposition of the diamond film could be synthesized using only methane and nitrogen gases without hydrogen gas. Separated particles with diamond structure showed an octahedral shaped I the nitrogen ranges between 30% and 80%, and newly formed hexagonal crystals are observed when substrate temperature with diamond structure, however, also identify that the hexagonal crystal was SiCN composite composed of Si, C and N atoms.

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Capability of Accumulation Mode Aerosols Containing Black Carbon as CCN Observed during the PACDEX Campaign (PACDEX 캠페인 자료로 분석한 블랙카본을 포함한 축적모드 에어로솔의 구름응결핵 가능성)

  • Lee, Si-Hye;Ghim, Young-Sung;Kim, Sang-Woo;Yoon, Soon-Chang
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.4
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    • pp.380-391
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    • 2010
  • Airborne in-situ measurements of aerosol/cloud number concentrations were analyzed to investigate the effects of aerosols on warm cloud formation in the Pacific Dust Experiment (PACDEX) during April and May 2007. In the air masses originating from the Asian continent, high concentrations of fine particles including black carbon (BC) were observed when compared to other regions. A strong correlation (r=0.88) between condensation nuclei (CN) having sizes ranging from 0.1 to 1.0 mm ($CN_{0.1-1.0}$) and cloud condensation nuclei (CCN) at 0.4% supersaturation ($CCN_{0.4%}$) suggests that most of the $CN_{0.1-1.0}$ can contribute to cloud formation. The possibility of a cloud droplet formation by BC particles was expected at the high water vapor mixing ratio (WVMR) and the abundance of water-soluble components at the low altitude less than 3 km.

SNU WASHINGTON 측광계의 표준화와 WASHINGTON 측광계의 일반적 특성

  • An, Seong-Min;Lee, Si-U
    • Publications of The Korean Astronomical Society
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    • v.7 no.1
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    • pp.167-188
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    • 1992
  • 서울대 천문학과(SNU)의 Washington 측광계를 사용하여 관측한 자료와 ADC (Astronomical Data Center)의 자료를 분석함으로써 SNU Washington 측광계를 표준화 시켰다. SNU Washington 측광계중에서 C필터에 나타나는 적색광 누출은 V필터와의 결합을 통해 보정했으며, 그 최대값은 K0형에서 약 $0^{m}.14$까지 이른다. ADC의 자료분석 결과 G. K형 별들에 대해 중원소 측광지수와 중원소함량과 서로 잘 일치함을 알 수 있었고. 주계열성의 경우 온도 측광지수와 온도와는 좋은 관계를 보임을 알 수 있었다. 또한 ($M-T_2$)과 ($M-T_1$) 평면상에서는 중원소함량과 광도계급에 무관한 좋은 온도관계를 나타냄을 알았다. 그리고 이 측광계의 장점으로 나타난 CN지수와 CN 특이성과는 특별한 관계를 찾기가 어려웠고, 이 측광계만으로는 상도계급의 구분을 다른 측광계 만큼 분명하게 결정짓기가 어려웠다. 그러나 표면중력과이 측광계의 색지수와의 관계를 본 결과 초거성, 거성, 주계열성을 비교적 잘 구분해 낼 수 있었다.

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Tool Geometry for Improving Tool-Life in Turning of STS 304 (STS 304의 선삭에서 공구수명 향상을 위한 공구형상)

  • 이재우
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.581-584
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    • 2003
  • The austenitic STS 304 stainless steel was turned to clarify the effects of tool geometry on the tool wear. The wear of TiN-TiCN-TiC-TiAlN coated tungsten carbide tool was the smallest, exhibiting larger wear in the order of Si-Al-O-N ceramic, TiN coated tungsten carbide, TiN-TiCN-TiN coated tungsten carbide, TiC-TiN cermet and M20 tungsten carbide tools at the same cutting conditions. The S-type tool of M20 with large approach angle showed the longest tool life of all tools used in this tests due to preventing the groove wear of the side cutting edge. The wear of the S-type tool with the rake angle of 15$^{\circ}$became smaller than with that of -5$^{\circ}$, but the tool with the nose radius of 0.8mm did not perform much better with increasing the rake angle.

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Tool-Wear Characteristics in Turning of STS 304 (STS 304 선삭시의 공구마멸 특성)

  • 이재우
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.10
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    • pp.56-64
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    • 2003
  • The effect of tool geometry on the tool wear in turning the austenitic stainless steel, STS 304 was investigated. The wear of TiN-TiCN-TiC-TiAlN coated tungsten carbide tool was the smallest, showing larger wear in the order of Si-Al-O-N ceramic, TiN coated tungsten carbide, TiN- TiCN- TiN coated tungsten carbide, TiC-TiN cermet and M20 tungsten carbide tools at the same cutting conditions. The S-type tool of M20 with the larger side cutting edge angle showed the smallest tool wear in all tests due to preventing the groove wear of the side cutting edge. The wear of the S-type tool with the rake angle of $15^{\circ}$ became smaller than with that of $-5^{\circ}$, but the tool with the nose radius of 0.8mm did not perform much better with increasing the rake angle.

Capacitance - Voltage Characteristics of MIS Capacitors Using Carbon Nitride Films (질화탄소막을 이용한 MIS 캐패시터의 정전용량 - 전압 특성)

  • Ha, Se-Geun;Lee, Ji-Gong;Lee, Sung-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.84-87
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    • 2003
  • Carbon nitride ($CN_x$) films were prepared by reactive RF magnetron sputtering system with DC bias at various deposition conditions and the electrical properties were investigated. The films were characterized by fourier transform infrared (FTIR) spectroscopy, and X-ray photoelectron spectroscopy (XPS). The metal-insulator-semiconductor (MIS) capacitor which has $Al/CN_x/Si$ structure was designed and fabricated to investigate the capacitance-voltage (C-V) characteristics. Dielectric constant of carbon nitride films is very small.

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Heterogeneous Electron Transfer at Polyoxometalate-modified Electrode Surfaces

  • Choi, Su-Hee;Seo, Bo-Ra;Kim, Jong-Won
    • Bulletin of the Korean Chemical Society
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    • v.31 no.1
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    • pp.104-111
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    • 2010
  • The heterogeneous electron transfer at $SiMo_{12}O_{40}^{4-}$ monolayers on GC, HOPG, and Au electrode surfaces are investigated using cyclic voltammetric and electrochemical impedance spectroscopic (EIS) methods. The electron transfer of negatively charged $Fe(CN)_6^{3-}$ species is retarded at $SiMo_{12}O_{40}^{4-}$-modified electrode surfaces, while that of positively charged $Ru(NH_3)_6^{3+}$species is accelerated at the modified surfaces. This is due to the electrostatic interactions between $SiMo_{12}O_{40}^{4-}$ layers on surfaces and charged redox species. The electron transfer kinetics of a neutral redox species, 1,1‘-ferrocenedimethanol (FDM), is not affected by the modification of electrode surfaces with $SiMo_{12}O_{40}^{4-}$, indicating the $SiMo_{12}O_{40}^{4-}$ monolayers do not impart barriers to electron transfer of neutral redox species. This is different from the case of thiolate SAMs which always add barriers to electron transfer. The effect of $SiMo_{12}O_{40}^{4-}$ layers on the electron transfer of charged redox species is dependent on the kind of electrodes, where HOPG surfaces exhibit marked effects. Possible mechanisms responsible for different electron transfer behaviors at $SiMo_{12}O_{40}^{4-}$ layers are proposed.