• 한국세라믹학회지
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• 제45권5호
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• pp.303-308
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• 2008

Mullite precursors were synthesized with aluminosilicate gels from mixture of aluminum nitrate and sodium orthosilicate by the geopolymer technique at ambient temperature. Then, the gel was heat-treated in air up to $1200^{\circ}C$ at intervals of $100^{\circ}C$. Raw and heat-treated gels were characterized by TG-DTA, XRD, FTIR, $^{29}Si$ MAS-NMR, TEM. The result to examine the crystallization of behavior though DTA, the synthesized precursors were crystallized in the temperature range from $950^{\circ}C$ to $1050^{\circ}C$. The XRD results showed that the gel compositions were begun to crystallize at various temperature. Also, it was found that the precursors of M-4 begun to crystallize at about $950^{\circ}C$. The M-4 XRD peaks were characterized better than $M-1{\sim}M-3$ at $1000^{\circ}C$. The formation temperature of mullite in this study is much lower than that of previous sol-gel methods, which crystallized at up of $1200^{\circ}C$. TEM investigations revealed that the sample with 10 nm particle size was obtained via heat-treated at $1000^{\circ}C$ for M-4.

• 공업화학
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• 제20권6호
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• pp.617-621
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• 2009

Zinc oxide (ZnO)을 금(Au)과 fluorine-doped tin oxide (FTO) 촉매로 산화실리콘($SiO_2$) 기판에 산화아연입자 20 nm, $20{\mu}m$를 각각 사용하여 기체-액체-고체(VLS) 합성법으로 성장시켰다. 나노로드의 표면특성, 화학조성, 그리고 결정특성을 엑스레이회절(X-ray diffraction (XRD)), 에너지 분산형 X선 분광기(Energy-dispersive X-ray spectroscopy (EDX)), 표면 방출주사현미경(Field-emission scanning electron microscope (FE-SEM))으로 분석하였다. ZnO의 입자 크기 뿐만 아니라 결정형태가 성장에 크게 영향을 미쳤다. ZnO의 모든 나노구조가 6방정계(六方晶系), 단일결정구조를 가지고 있었다. 최적온도는 $1030^{\circ}C$, 입자크기는 20 nm이다. 그러므로 Au 대신 플루오린 첨가 도핑으로 전기음성도가 증가된 FTO 증착에 의해서 생성된 나노로드는 경제성 있는 대체물질로서의 가치가 있을 것으로 사료된다.

• 한국재료학회지
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• 제3권6호
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• pp.624-631
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• 1993

Alumimium Titanate-Mullite 복합체는 $Al_{2}O_{3}$분말 알콜용액에서 $Si(OC_{2}H_{5})_{4}$와 $Ti(OC_{2}H_{5})_4$ 의 단계적인 가수분해로 합성하였다. Sol-Gel 방법으로 합성된 모든 분말은 비정질과 단분산이고 좁은 분말크기의 분포를 보였다. 소결체($1600 ^{\circ}C$/2h)는 임계분해온도인 $1100^{\circ}C$에서 100시간 동안과 750와 $1400^{\circ}C$ 100시간동안 반복적인 열적 내구성 및 열충격 시험을 수행하였다. 가장 좋은 열적 내구성은 aluminium titanate함유량이 70rhk 80vol%일때 얻어졌으며, 이들은 위 실험을 한후 아주 적은 미세구조와 열팽창 곡선의 변화를 나타내었다. 소결체 미세구조의 붕괴는 주사현미경, X-선회절분석과 Dil-atometer로 연구하였다. 위 연구는 이와같은 과정에 의하여 합성된 aluminium titanate-mullite복합체의 서비스 수명을 예상하기 위하여 시도되었다.

• 대한기계학회논문집A
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• 제24권5호
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• pp.1146-1154
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• 2000

Fatigue strength of NiAl and Ni$_3$Al particulate reinforced aluminum alloy composites fabricated by the diecasting method was examined at room and elevated temperatures. The results were compared wit h that of SiC particulate reinforced one. The particulate reinforced composites showed some improvement in the static and fatigue strength at elevated temperatures when compared with that of Al alloy. The composites reinforced by intermetallic compound particles showed good fatigue strengths at elevated temperatures especially $Ni_3AI_{p}/Al$ alloy composite showed good fatigue limit up to high temperature of 30$0^{\circ}C$. Adopting intermetallic compound particle as a reinforcement phase, it will be possible to develop MMC representing better fatigue property at elevated temperature.

• 한국세라믹학회지
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• 제45권7호
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• pp.401-404
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• 2008

Willemite ($Zn_2SiO_4$) are a wide range of applications such as a phosphor host and an important crystalline phase in glass ceramics, electrical insulators, glazes, and pigments. In this study, Willemite precursors were synthesized with zinc silicate gels from mixture of zinc nitrate solution and various sodium silicate solution by the geopolymer technique. To examine the crystallization behavior, precursors were have been monitored by the XRD. A pure willemite phase was obtained at $900^{\circ}C$. TEM investigations revealed that the sample with 50 nm particle size was obtained via heat-treated at $900^{\circ}C$ for W-3.

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2005년도 춘계 학술대회
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• pp.352-361
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• 2005

In this study, conventional head-end processes of spent TRISO fuel have been reviewed to develope more effective treatment methods. The main concerns in the TRISO treatment are to effectively separate the carbon and SiC contained in the TRISO particles. The crush-burn scheme which was considered in the early stages of the development has been replaced by the crush-leach process because of $^{14}C$ problems as a second waste during the process. However there are still many obstacles to overcome in the reported processes. Hence, innovative thermomechanical concepts to breach the coating layers of the TRISO particle with a minimized amount of second waste are proposed in this paper and their principles are described in detail.

• Archives of Pharmacal Research
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• 제28권7호
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• pp.866-874
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• 2005

The objective of this study was to elucidate the feasibility to improve the solubility and bioavailability of poorly water-soluble itraconazole via solid dispersions by using supercritical fluid (SCF). Solid dispersions of itraconazole with hydrophilic polymer, HPMC 2910, were prepared by the aerosol solvent extraction system (ASES) under different process conditions of temperature/pressure. The particle size of solid dispersions ranged from 100 to 500 nm. The equilibrium solubility increased with decrease (15 to 10 MPa) in pressure and increase (40 to $60^{\circ}C$) in temperature. The solid dispersions prepared at $60^{\circ}C$/15 MPa showed a slight increase in equilibrium solubility (approximately 27-fold increase) when compared to pure itraconazole, while those prepared at $60^{\circ}C$/10MPa showed approximately 610-fold increase and no endothermic peaks corresponding to pure itraconazole were observed, indicating that itraconazole might be molecularly dispersed in HPMC 2910 in the amorphous form. The amorphous state of itraconazole was confirmed by DSC/XRD data. The pharmacokinetic parameters of the ASES-processed solid dispersions, such as $T_{max},\;C_{max},\;and\;AUC_{0-24h}$ were almost similar to $Sporanox_{\circledR}$ capsule which shows high bioavailability. Hence, it was concluded that the ASES process could be a promising technique to reduce particle size and/or prepare amorphous solid dispersion of drugs in order to improve the solubility and bioavailability of poorly water-soluble drugs.

• 한국세라믹학회지
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• 제28권3호
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• pp.215-224
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• 1991

The synthesis of SrTiO3 powders having high purity and homogeneous submicron particle size was attempted by the oxalate method. The microstructure and dielectric properties of SrTiO3 based boundary layer capacitor (BLC) were investigated. Strontium titanyl oxalate[SrTiO(C2O4)2.4H2O] was prepared from the mixing solution of (Sr, Ti) using oxalic acid(H2C2O4) as a precipitating agent at 8$0^{\circ}C$. The crystalline SrTiO3 powder was obtained by thermal decomposition of the precipitate above $600^{\circ}C$. The crystalline SrTiO3 powder containing Nb2O5 as a dopant, TiO2 and SiO2 as additives was sintered at 1360~144$0^{\circ}C$ in the reducing atmosphere to get semiconductive SrTiO3. Insulating material containing PbO-Bi2O3-B2O3 frit was printed on the sintered semiconductive SrTiO3 and fired at 120$0^{\circ}C$ for 2h to get the grain boundary diffusion.

• Composites Research
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• 제22권4호
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• pp.50-53
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• 2009

이 논문은 주로 방탄재료 중에서 세라믹재료를 바탕으로 한 개인용 방호장비와 헬리콥터용 방탄장비 등 재료의 무게가 중요한 부위에 사용되어지는 재료에 대하여 서술하였다. 세라믹 방탄재료는 원자번호가 작은 보론이 4개원자가 포함되어있고 탄소원자가 1개 들어있는 화합물인 $B_4C$를 근간으로한 재료이기 때문에 무게가 굉장히 적게 나간다. 그러나 이 재료는 용융옹도가 높아 높은 온도에서 소결되어야하고, 소결말도가 높아야 제대로 물성이 나오기 때문에 잘 소결할 수 있도록 하기 위하여 소결조제를 사용하던지 일축 가압소결을 하던지 분말사이즈를 조절하여 쉽게 소결하는 방법을 사용하던지 하여 제품을 만든다.

• E2M - 전기 전자와 첨단 소재
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• 제10권5호
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• pp.440-446
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• 1997

This research has been performed for the fabrication of high quality ferrite plastic magnet. The magnetic properties of S $r_{5.9}$F $e_2$ $O_3$ ferrite bonded magnets by injection moulding with a variety of applied magnetic field were investigated. 0.3wt% CaCO3, 0.2wt% $SiO_2$, 0.5wt% $Al_2$ $O_3$and 0.5wt% N $a_2$ $SiO_3$are added in order to improve the magnetic properties of Sr-ferrite plastic magnets during the powder fabrication. For carbon coating on chemical compound specimen, 5wt% polyvinyl alcohol is added, and then calcinated under $N_2$ environment of 12$25^{\circ}C$. The particle size is distributed from 0.9~1.2${\mu}{\textrm}{m}$ which approximates to the single domain. The obtained Sr ferrite powder is well mixed with silane coupling and calcium stearate of 1wt%. Nest, the specimen is pelleted after kneading each of them with polyamidel2 as a binder. When the temperature of injection and mould were 25$0^{\circ}C$ and 8$0^{\circ}C$ respectively at injection pressure of 200kgf/$\textrm{cm}^2$, the degree of orientation was 85.3% under the applied magnetic field of 12kOe. As the results, when the packing density of Sr ferrite powder was 90wt%, the magnetic properties of Sr ferrite bonded magnet were follows : $_{B}$ $H_{c}$=2.41kOe, Br=3.1kG, (BH)$_{max}$=2.21MgOe. Especially, the Sr-ferrite bonded magnet with 10wt% N $d_2$F $e_{14}$B additive were as follows : $_{B}$ $H_{c}$=2.57kOe, Br=3.14kG and (BH)$_{max}$=2.39MGOe.GOe.GOe.GOe.e.