• Title/Summary/Keyword: SiC foam

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Preparation and Characterization of SiC Coated Graphite Foam (SiC가 코팅된 그라파이트 Foam의 제조 및 특성 분석)

  • Kyung, Jae-Jin;Kim, Jung-Ju;Kim, Soo-Ryong;Kwon, Woo-Teck;Cho, Kwang-Youn;Kim, Young-Hee
    • Journal of the Korean Ceramic Society
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    • v.44 no.11
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    • pp.622-626
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    • 2007
  • Graphite is widely used in electronic industry due to its excellent electrical and thermal properties. However, graphite starts to oxidize around $400^{\circ}C$ that seriously degrades its properties. SiC coating can be applied to graphite foam to improve its high temperature oxidation resistance. In this research, SiC coating on graphite foam was made via preceramic polymer using a polyphenylcarbosilane. 20% of polyphenylcarbosilane in hexane solution was coated onto graphite by dip coating method. Thermal oxidation was carried out at $200^{\circ}C$ for crosslink of the preceramic polymer and the sample were pyrolysized at $800^{\circ}C{\sim}1200^{\circ}C$ under nitrogen to convert the preceramic polymer to SiC film. The microstructure of the SiC coating after pyrolysis was investigated using FESEM and oxidation resistance up to $800^{\circ}C$ was evaluated.

Particle Stabilized Wet Foam to Prepare SiO2-SiC Porous Ceramics by Colloidal Processing

  • Bhaskar, Subhasree;Park, Jung Gyu;Han, In Sub;Lee, Mi Jai;Lim, Tae Young;Kim, Ik Jin
    • Journal of the Korean Ceramic Society
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    • v.52 no.6
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    • pp.455-461
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    • 2015
  • Porous ceramics with tailored pore size and shape are promising materials for the realization of a number of functional and structural properties. A novel method has been reported for the investigation of the role of SiC in the formation of $SiO_2$ foams by colloidal wet processing. Within a suitable pH range of 9.9 ~ 10.5 $SiO_2$, particles were partially hydrophobized using hexylamine as an amphiphile. Different mole ratios of the SiC solution were added to the surface modified $SiO_2$ suspension. The contact angle was found to be around $73^{\circ}$, with an adsorption free energy $6.8{\times}10^{-12}J$. The Laplace pressure of about 1.25 ~ 1.6 mPa was found to correspond to a wet foam stability of about 80 ~ 85%. The mechanical and thermal properties were analyzed for the sintered ceramics, with the highest compressive load observed at the mole ratio of 1:1.75. Hertzian indentations are used to evaluate the damage behavior under constrained loading conditions of $SiO_2$-SiC porous ceramics.

Steam Reforming of Methane in a Solar Concentrated Receiver Reactor (집광된 태양열을 반응기에서의 메탄 수증기개질 연구)

  • Kim, Ki-Man;Nam, Woo-Seok;Han, Gui-Young;Seo, Tae-Beom;Kang, Yong-Heack
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.172-175
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    • 2006
  • Steam reforming of methane using Xe-arc solar simulator was studied for converting solar radiation into energy foam that one can readily utilize. The Xe-arc lamp produce a spectrum similar to that of the sun. SiC ceramic foam, resist high temp.$(>900^{\circ}C)$, is used to catalytically active foam absorber, and to support of reforming catalyst. The catalyst on the surface of foam were directly irradiated with solar simulated xe-light in order to carry out the steam reforming of methane. The reactor was made of stainless steel and quartz window was located on a place of the xe-light irradiation and temperature was controlled using K-type thermocouple in contact with catalyst located inside the reactor. The result show that a possibility of solar reforming using catalytically active foam absorber is exist.

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Investigation of design values computation of wood shear walls constructed with structural foam sheathing

  • Shadravan, Shideh;Ramseyer, Chris C.
    • Advances in Computational Design
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    • v.4 no.3
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    • pp.223-238
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    • 2019
  • This study investigated the ultimate lateral load capacity of shear walls constructed with several types of structural foam sheathing. Sixteen tests were conducted and the results were compared to the published design values commutated by the manufactures for each test series. The sheathing products included 12.7 mm (1/2 in) SI-Strong, 25.4 mm (1 in) SI-Strong, 12.7 mm (1/2 in) R-Max Thermasheath, and 2 mm (0.078 in) ThermoPly Green. The structural foam sheathing was attached per the manufacturers' specification to one side of the wood frame for each wall tested. Standard 12.7 mm (1/2 in) gypsum wallboard was screwed to the opposite side of the frame. Simpson HDQ8 tie-down anchors were screwed to the terminal studs at each end of the wall and anchored to the base of the testing apparatus. Both monotonic and cyclic testing following ASTM E564 and ASTM E2126, respectively, were considered. Results from the monotonic tests showed an 11 to 27 percent smaller capacity when compared to the published design values. Likewise, the test results from the cyclic tests showed a 24 to 45 percent smaller capacity than the published design values and did not meet the seismic performance design criteria computation.

Comparison of Combustion Characteristics With and Without Water Tube Simulating Heat Exchanger in Two Sections Porous Media Burner (2단 다공성 매체버너에서 열교환기를 모사한 수관 유무에 따른 연소 특성 비교)

  • Lee, Hui-Do;Kim, Jae-Hyeon;Lee, Kee-Man
    • Journal of the Korean Institute of Gas
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    • v.23 no.5
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    • pp.24-34
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    • 2019
  • In this study, the experimental studies were conducted to analyzing characteristics of combustion and flame stabilizing according to with and without water tube in boiler. The burner has consisted of SiC foam where has the location of submerged flame between a ceramic board acting as flash-back arrestor. Porous burner is also insulated to minimize heat loss in the radial direction. In the condition of fixed equivalence ratio, the flame mode was divided into three stability zones by the flow rate. The main factor for blow-off and flash-back depends on mixture flow rate. Consequently, the case of burner with water-tube has higher NOx emissions than without case. This result explains that the presence of water-tube makes the heat loss resistant to ambient temperature with increasing of NOx. This tendency was proved by predicting the relationship between O2 emission and NO production rate, and by analysing temperature profiles.

Syngas and Hydrogen Production from $CeO_2/ZrO_2$ coated Foam Devices under Simulated Solar Radiation (다공성 폼에 코팅된 $CeO_2/ZrO_2$ 를 이용한 고온 태양열 합성가스 및 수소 생산 연구)

  • Jang, Jong-Tak;Yoon, Ki-June;Han, Gui-Young
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.260-266
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    • 2012
  • Syngas and hydrogen from the $CeO_2/ZrO_2$ coated foam devices were investigated under simulated solar radiation. The $CeO_2/ZrO_2$ coated SiC, Ni and Cu foam device were prepared using drop-coating method. Syngas production step was performed at $900^{\circ}C$, and hydrogen production process was performed for ten repeated cycles to compare the CeO2 conversion in syngas production step, $H_2$ yield in hydrogen production step and cycle reproducibility. The produced syngas had the $H_2$/CO ratio of 2, which was suitable for methanol synthesis or Fischer-Tropsch synthesis process. In addition, syngas and hydrogen production process is one of the promising chemical pathway for storage and transportation of solar heat by converting solar energy to chemical energy. After ten cycles of redox reaction, the $CeO_2/ZrO_2$ was analyzed using XRD pattern and SEM image in order to characterize the physical and chemical change of metal oxide at the high temperature.

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Syngas and Hydrogen Production from $CeO_2/ZrO_2$ coated foam device under concentrated solar radiation (고온 태양열을 이용한 합성가스 및 수소 생산에서 $CeO_2/ZrO_2$가 코팅된 다공성 폼의 영향)

  • Jang, Jong-Tak;Yoon, Ki-June;Han, Gui-Young
    • 한국태양에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.307-313
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    • 2011
  • 금속산화물을 이용한 2단계 산화/환원 반응은 GTL, CTL 의 반응원료인 합성가스 및 수소 생산기술이다. 이 기술은 메탄을 환원제로 사용함으로써 비교적 저온에서 산화/환원 반응을 할 수 있는 장점이 있다. 하지만 반복 사이클의 시연에서 금속산화물의 소결현상으로 인한 활성저하가 이 기술의 문제점 중의 하나이다. 본 연구에서는 2.5 kW Xenon arc lamp 가 설치된 solar simulator를 사용 하였으며, 무기물 다공성 폼 (SiC foam)및 유기물 다공성 폼 (Ni, Cufoam)에 $CeO_2/ZrO_2$ 를 코팅하여 연속적인 합성가스 및 수소 생산 가능성을 알아보았다. 반응 전 후의 $CeO_2/ZrO_2$ 의 결정 구조를 SEM 과 XRD 를 통해 분석하였다.

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