• Title/Summary/Keyword: Si-Cr

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Conservation Management Methods and Vascular Plants of Major Sites in Changwon-si (창원시 주요지역의 식물상 및 보전관리방안)

  • Oh, Hyun-Kyung;Kang, Hyun-Mi;Choi, Song-Hyun
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.15 no.4
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    • pp.23-40
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    • 2012
  • The vascular plants of major sites in Changwon-si were listed 456 taxa (9.3% of all 4,881 taxa of vascular plants); 112 families, 293 genera, 371 species, 2 subspecies, 66 varieties and 17 forms. The vascular plants of Changwon-cheon were listed 133 taxa, Junam reservoir were listed 90 taxa, Seongju-sa were listed 293 taxa, and Yungji park were listed 164 taxa. Divided into 456 taxa; woody plants were 160 taxa (35.1%) and herbaceous plants were 296 taxa (64.9%). Furthermore, therophytes (Th) were 111 taxa (24.3%), hemicryptophytes (H) were 75 taxa (16.4%), megaphanerophytes (MM) were 63 taxa (13.8%) showed high proportional ratio in life form. Based on the list of rare plants by the Korea Forest Service and Korea National Arboretum, 10 taxa (1.8% of all 571 taxa of rare plants); Aristolochia contorta (LC), Euryale ferox (VU), Melothrua japonica (LC), Utricularia pilosa (CR), Hydrocharis dubia (LC), Carex idzuroei (DD), Acorus calamus var. angustatus (LC), etc. Based on the list of endemic plants by the Korea National Arboretum, 10 taxa (3.0% of all 328 taxa of endemic plants); Salix pseudolasiogyne, Philadelphus incanus, Indigofera koreana, Lespedeza ${\times}$ maritima, Stewartia pseudocamellia, Weigela subsessilis, Carex okamotoi, etc. Based on the list of specific plants by floral region were total 43 taxa (4.0% of all 1,071 taxa of specific plants); 4 taxa (Euryale ferox, Hydrocharis dubia, Carex idzuroei, etc.) in class IV, 9 taxa (Ilex crenata, Acer palmatum, Stewartia pseudocamellia, Melothria japonica, Fatsia japonica, etc.) in class III, 3 taxa (Caltha palustris var. membranacea, Nymphoides indica, etc.) in class II, 26 taxa (Cyrtomium fortunei, Chloranthus japonicus, Quercus variabilis, Ulmus parvifolia, Aphananthe aspera, etc.) in class I. Based on the list of naturalized plants, 48 taxa (Rumex crispus, Chenopodium album var. album, Amaranthus patulus, Phytolacca american, Brassica juncea var. integrifolia, Potentilla paradoxa, Robinia pseudoacacia, Euphorbia maculata, Oenothera odorata, Cuscuta pentagona, Veronica persica, Plantago lanceolata, Diodia teres, Helianthus tuberosus, Dactylis glomerata, etc.), naturalization rate was 10.5% of all 456 taxa of vascular plants and urbanization index was 15.0% of all 321 taxa of naturalized plants. Ecosystem disturbing wild plants were 3 taxa (Rumex acetocella, Solanum carolinense, Ambrosia artemisiifolia).

Distribution of Vascular Plants in Gallasan (Andong-si.Uiseong-gun, Gyeongbuk) (갈라산(경북 안동시.의성군) 관속식물의 분포)

  • Chung, Gyu-Young;Park, Myung-Soon;Nam, Bo-Mi;Hong, Ki-Nam;Jang, Jin;Jeong, Hyung-Jin;Yoo, Ki-Oug
    • Korean Journal of Plant Resources
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    • v.23 no.1
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    • pp.99-114
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    • 2010
  • This study was carried out to clarify the distribution of vascular plants and their usefulness at Gallasan of Andong-si in Gyeongbuk (596.2 m, N $36^{\circ}29'396"{\sim}36^{\circ}29'356"$, E $128^{\circ}43'841"{\sim}128^{\circ}45'799"$). The vascular plants collected 13 times (April 2006 to August 2009) were consisted of total 424 taxa; 92 families, 273 genera, 365 species, 2 subspecies, 47 varieties and 10 forms. Among them, edible, medicinal, industrial, ornamental and unknown of usefulness plants were 239 taxa, 291 taxa, 109 taxa, 135 taxa, 24 taxa, respectively. Korean endemic plants of this area were 9 taxa, and Law-protected plants by Ministry of Environment were 2 taxa, and the special plants species based on floral region by Ministry of Environment were 7 taxa in grade III category, 1 taxa in grade IV category, 5 taxa in grade V category, rare plants were 1 taxon in critically endangered (CR), 3 taxa endangered species (EN), 2 taxa vulnerable (VU), the naturalized plants were 23 taxa.

Occurrence and Chemical Composition of Minerals from the Pallancata Ag Mine, Peru (페루 Pallancata 은 광산에서 산출되는 광물들의 산상 및 화학조성)

  • Yoo, Bong Chul;Acosta, Jorge
    • Journal of the Mineralogical Society of Korea
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    • v.32 no.2
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    • pp.87-102
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    • 2019
  • Pallancata Ag mine is located at the Ayacucho region 520 km southeast of Lima. The geology of mine area consists of mainly Cenozoic volcanic-intrusive rocks, which are composed of tuff, andesitic lava, andesitic tuff, pyroclastic flow, volcano clasts, rhyolite and quartz monzonite. This mine have about 100 quartz veins in tuff filling regional faults orienting NW, NE and EW directions. The Ag grades in quartz veins are from 40 to 1,000 g/t. Quartz veins vary from 0.1 m to 25 m in thickness and extend to about 3,000 m in strike length. Quartz veins show following textures including zonation, cavity, massive, breccia, crustiform, colloform and comb textures. Wallrock alteration features including silicification, sericitization, pyritization, chloritization and argillitization are obvious. The quartz veins contain calcite, chalcedony, adularia, fluorite, rutile, zircon, apatite, Fe oxide, REE mineral, Cr oxide, Al-Si-O mineral, pyrite, sphalerite, chalcopyrite, galena, electrum, proustite-pyrargyrite, pearceite-polybasite and acanthite. The temperature and sulfur fugacity ($f_{s2}$) of the Ag mineralization estimated from the mineral assemblages and mineral compositions are ranging from 118 to $222^{\circ}C$ and from $10^{-20.8}$ to $10^{-13.2}atm$, respectively. The relatively low temperature and sulfur-oxygen fugacities in the hydrothermal fluids during the Ag mineralization in Pallancata might be due to cooling and/or boiling of Ag-bearing fluids by mixing of meteoric water in the relatively shallow hydrothermal environment. The hydrothermal condition may be corresponding to an intermediate sulfidation epithermal mineralization.

Source Identification of Ambient Size-by-Size Particulate Using the Positive Matrix Factorization Model on the Border of Yongin and Suwon (PMF 모델을 이용한 용인-수원경계지역에서의 부유분진의 크기별 오염원 확인)

  • Oh, Mi-Seok;Lee, Tae-Jung;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.2
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    • pp.108-121
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    • 2009
  • The suspended particulate matters have been collected on membrane filters and glass fiber filters by an 8-stage cascade impactor for 2 years (Sep. 2005${\sim}$Sep. 2007) in Kyung Hee University-Global Campus located on the border of Yongin and Suwon. The 20 chemical species (Al, Mn, Si, Fe, Cu, Pb, Cr, Ni, V, Cd, Ba, $Na^+$, ${NH_4}^+$, $K^+$, $Mg^{2+}$, $Ca^{2+}$, $Cl^-$, ${NO_3}^-$, and ${SO_4}^{2-}$) were analyzed by an ICP-AES and an IC after performing proper pre-treatments of each sample filter. Based on these chemical information, the PMF receptor model was applied to identify the source of ambient size-by-size particulate matters. The receptor modeling is the one of the statistical methods to achieve resonable air pollution management strategies. A total of 10 sources was identified in 9 size-ranges such as long-range transport, secondary aerosol, $NH_{4}NO_{3}$ related source, coal combustion, sea-salt, soil, oil combustion, auto emission, incineration, and biomass burning. Especially, the secondary aerosol source assorted in fine and coarse modes was intensively studied.

An Experimental Study of Retting Conditions of Domestic Ramie Fiber (국산 모시섬유의 침지조건에 관한 실험적 연구)

  • 이전숙;최경은
    • Korean Journal of Human Ecology
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    • v.6 no.1
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    • pp.27-34
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    • 2003
  • We investigated the bacterial and chemical retting conditions of ramie grown in Hansan. Bacterial retting was done in troughs at a temperature of 30${\pm}$2$^{\circ}C$ for 1, 2, 3, 4, 5, 6 and 10 days. Chemical retting(CR) was done at the different conditions using sodium silicate (Na$_2$SiO$_3$), sodium carbonate(Na$_2$CO$_3$) and sodium hydroxide(NaOH) as alkali solutions. The retting solution was boiled during 1. 2, 4 and 6 hours respectively at the different concentration(0.5, 2.0, 4.0, 6.0. 8.0 %) with decorticated ramie stems submerged in it. The treated ramie was then rinsing with running tap water thoroughly, which was further soaker in 0.5% acetic acid (v/v) solution for three minutes and washed thoroughly with distilled water. Finally ramie was dried for 2 hours in vacuum oven at 100 $^{\circ}C$. To know change of ramie fiber characteristics retted at the different conditions, weight loss, fiber bundle strength were tested and color, texture, luster etc. were also sensually evaluated. The results were as follows. $.$ Weight loss of ramie retted in each alkali solutions were about 10%, 20% and 30% in sodium silicate, sodium carbonate and sodium hydroxide, respectively. $.$ Chemical retting was faster than bacterial retting, but the color of chemically retted ramies were worse than that of bacterially retted ramies. $.$ The combination of bacterial and chemical processing showed some merits. A combination of either 2 or 3 days of bacterial and then chemical retting might provide the best quality ramie. $.$ Ramie fiber became cottonized ramie when retted in 8% NaOH solution for 6-8hours.

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Stainless steel 기판에서 제조된 CIGS 박막 태양전지의 ZnO 확산 방지막을 이용한 deep level defect 감소 연구

  • Kim, Jae-Ung;Kim, Hye-Jin;Kim, Gi-Rim;Kim, Jin-Hyeok;Jeong, Chae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.393-393
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    • 2016
  • Cu(In,Ga)Se2 (CIGS) 박막 태양전지는 높은 효율과 낮은 제조비용, 높은 신뢰성으로 인해 박막 태양전지 중 가장 각광받고 있다. 특히 유리기판 대신 가볍고 유연한 철강소재나 플라스틱 소재를 이용하여 발전분야 외에 건물일체형, 수송용, 휴대용등 다양한 분야에 적용이 가능하다. 이러한 유연 기판을 이용한 CIGS 태양전지의 개발을 위해서는 기판의 특성에 따른 다양한 공정개발이 선행되어야 한다. Stainless steel과 같은 철강기판의 경우 Fe, Ni, Cr등의 불순물이 확산되어 흡수층의 특성을 저하시켜 효율을 감소시킨다. 따라서 이러한 철강 기판의 경우 불순물의 확산을 방지하는 확산방지막이 필수적이다. 이러한 유연기판의 특성을 고려하여 본 연구에서는 기존의 두껍고 추가 장비가 요구되는 SiOx나 Al2O3 대신 200nm 이하의 ZnO 박막을 이용하여 확산방지막을 제조하였다. 유연기판으로 STS 430 stainless steel을 이용하였다. 먼저 stainless steel 기판을 이용하여 기판에 의한 흡수층의 특성을 분석하였으며 ZnO 확산 방지막의 유무 및 두께에 따른 흡수층 및 소자의 특성을 분석하였다. 이때 확산 방지막은 기존 TCO 공정에서 사용되는 i-ZnO를 사용하였으며 RF sputter를 이용하여 50~200nm로 두께를 달리하며 특성 비교를 실시하였다. 효율은 확산방지막을 적용하지 않았을 때 약 5.9%에서 확산 방지막 적용시 약 10.7%로 증가하였다. 그 후 기판으로부터 확산되는 불순물의 유입에 의한 결함을 분석하기 위해 DLTS를 이용하여 소자 특성을 분석하였다. 온도는 80~300K으로 가변하며 측정을 실시하였으며 그 후 계산을 통해 activation energy와 capture cross section 값을 구하였다. DLTS 분석 결과 Ni이 CIGS 흡수층으로 확산되어 NiCu anti-site를 형성하여 태양전지의 효율을 감소시키는 것을 확인하였다. 모든 흡수층은 Co-Evaporation 방법을 이용하여 제조하였으며 제조된 흡수층은 SEM, XRF, XRD, GD-OES, PL, Raman등을 이용하여 분석하였으며 그 외 일반적인 방법을 이용하여 Mo, CdS, TCO, Al grid를 제조하였다. AR 코팅은 제외 하였으며 제조된 소자는 솔라 시뮬레이터를 이용하여 효율 특성 분석을 실시하였으며 Q.E. 분석을 실시하였다.

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Production of Fe Amorphous Powders by Gas-atomization Process and Subsequent Spark Plasma Sintering of Fe Amorphous-ductile Cu Composite Powders Produced by Ball-milling Process (I) - I. Gas Atomization and Production of Composite Powders - (가스분무법에 의한 Fe계 비정질 분말의 제조와 볼밀링공정에 의한 연질 Cu 분말과의 복합화 및 SPS 거동 (I) - I. 가스분무 및 복합화 -)

  • Ryu, Ho-Jin;Lim, Jae-Hyun;Kim, Ji-Soon;Kim, Jin-Chun;Kim, H.J.
    • Journal of Powder Materials
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    • v.16 no.5
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    • pp.316-325
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    • 2009
  • Fe based (Fe$_{68.2}$C$_{5.9}$Si$_{3.5}$B$_{6.7}$P$_{9.6}$Cr$_{2.1}$Mo$_{2.0}$Al$_{2.0}$) amorphous powder, which is a composition of iron blast cast slag, were produced by a gas atomization process, and sequently mixed with ductile Cu powder by a mechanical ball milling process. The experiment results show that the as-prepared Fe amorphous powders less than 90 $\mu$m in size has a fully amorphous phase and its weight fraction was about 73.7%. The as-atomized amorphous Fe powders had a complete spherical shape with very clean surface. Differential scanning calorimetric results of the as-atomized Fe powders less than 90 $\mu$m showed that the glass transition, T$_g$, onset crystallization, T$_x$, and super-cooled liquid range $\Delta$T=T$_x$-T$_g$ were 512, 548 and 36$^{\circ}C$, respectively. Fe amorphous powders were mixed and deformed well with 10 wt.% Cu by using AGO-2 high energy ball mill under 500 rpm.

Production of Fe Amorphous Powders by Gas-Atomization Process and Subsequent Spark Plasma Sintering of Fe amorphous-ductile Cu Composite Powder Produced by Ball-milling Process (II) - II. SPS Behaviors of Composite Powders and their Characteristics - (가스분무법에 의한 Fe계 비정질 분말의 제조와 볼밀링공정에 의한 연질 Cu분말과의 복합화 및 SPS 거동 (II) - II. 복합분말의 SPS와 특성 -)

  • Kim, Jin-Chun;Kim, Ji-Soon;Kim, H.J.;Kim, Jeong-Gon
    • Journal of Powder Materials
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    • v.16 no.5
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    • pp.326-335
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    • 2009
  • Fe based (Fe$_{68.2}$C$_{5.9}$Si$_{3.5}$B$_{6.7}$P$_{9.6}$Cr$_{2.1}$Mo$_{2.0}$Al$_{2.0}$) amorphous powder, which is a composition of iron blast cast slag, were produced by a gas atomization process, and sequently mixed with ductile Cu powder by a mechanical ball milling process. The Fe-based amorphous powders and the Fe-Cu composite powders were compacted by a spark plasma sintering (SPS) process. Densification of the Fe amorphous-Cu composited powders by spark plasma sintering of was occurred through a plastic deformation of the each amorphous powder and Cu phase. The SPS samples milled by AGO-2 under 500 rpm had the best homogeneity of Cu phase and showed the smallest Cu pool size. Micro-Vickers hardness of the as-SPSed specimens was changed with the milling processes.

Crystal field splitting energy for $CdGa_2Se_4$ epilayers obtained by photocurrent measurement (광전류 측정으로부터 얻어진 $CdGa_2Se_4$ 에피레이어의 결정장 갈라짐에 대한 에너지)

  • Hong, Kwang-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.144-145
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    • 2009
  • Single crystal $CdGa_2Se_4$ layers were grown on a thoroughly etched semi-insulating GaAs(100) substrate at $420^{\circ}C$ with the hot wall epitaxy (HWE) system by evaporating the poly crystal source of $CdGa_2Se_4$ at $630\;^{\circ}C$. The crystalline structure of the single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction (DCXD). The carrier density and mobility of single crystal $CdGa_2Se_4$ thin films measured with Hall effect by van der Pauw method are $8.27\;\times\;10^{17}\;cm^{-3}$, $345\;cm^2/V{\cdot}s$ at 293 K, respectively. The photocurrent and the absorption spectra of $CdGa_2Se_4$/SI(Semi-Insulated) GaAs(100) are measured ranging from 293 K to 10K. The temperature dependence of the energy band gap of the $CdGa_2Se_4$ obtained from the absorption spectra was well described by the Varshni's relation, $E_g$(T) = 2.6400 eV - ($7.721\;{\times}\;10^{-4}\;eV/K)T^2$/(T + 399 K). Using the photocurrent spectra and the Hopfield quasi cubic model, the crystal field energy(${\Delta}cr$) and the spin-orbit splitting energy(${\Delta}so$) for the valence band of the $CdGa_2Se_4$ have been estimated to be 106.5 meV and 418.9 meV at 10 K, respectively. The three photocurrent peaks observed at 10 K are ascribed to the $A_1$-, $B_1$-, and $C_{11}$-exciton peaks.

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A Geochemical Study on the Behaviors of Major and Trace Elements in the Ulsan Granite and Its Contact Serpentinite (울산화강암 및 인접 사문암 중 주/미량 원소의 거동에 관한 지화학적 연구)

  • Lee, Jae Yeong;Lee, In Ho
    • Economic and Environmental Geology
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    • v.28 no.1
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    • pp.53-67
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    • 1995
  • Geochemical characteristics of iron-related Ulsan granite was studied in comparison with the Cretaceous granitoids from the metallogenic provinces of copper, lead-zinc and lead-zinc/molybdenum in the Gyeongsang Basin, and the variation of cheminal compositions at the Ulsan granite/serpentinite contact was investigated. Ulsan granite is plotted in the regions of granite and granodiorite of Streckeisen's diagram. It shows differentiation trend of calc-alkali magma, and the magmatic evolution from granodiorite to granite is consistant with the general crystallization path of the Cretaceous the granitoids in Gyeongsang Basin. Differentiation index(D.I.) of Ulsan granite is 86~95, which is higher than those of Jindong granites (D.I.=45~70) and Onjongri granites (D.I.=67~84), and there are differences in the content of some major and trace elements between Ulsan granite and other Cretaceous granitoids. At the Ulsan granite/serpentinite contact $SiO_2$, $K_2O$, $Na_2O$, $Al_2O_3$, Rb, Sr, Ba which are abundant in Ulsan granite decrease toward serpentinite, while T.Fe, MgO, Ni, Cr which are abundant in serpentinite decrease toward Ulsan granite. Therefore, the geochemical characteristics of Ulsan granite is applicable to distinguish iron province from different metallogenic provinces where other Cretaceous granitoids occur in the Gyeongsang Basin, and it is possible to find serpentinite which was intruded by granite on the basis of chemical variations.

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