• Title/Summary/Keyword: Si Content

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A Study on Dissolution Behaviors of SiCp in Al-SiCp Composite (Al-SiCp복합재료에서 SiCp의 용해거동에 관한 연구)

  • Kim, Sug-Won;Lee, Eui-Kweon;Jeon, Woo-Yeoung
    • Journal of Korea Foundry Society
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    • v.13 no.4
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    • pp.350-358
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    • 1993
  • Aluminum base composites reinforced with various amount of SiC particles and Mg contents have been investigated by different fabrication method for twenty-years. In this paper, how the decomposition and dissolution behaviors of $SiCp(20{\mu}m)$ in the melt of Al composites arised was studied. As the results, the decomposition and dissolution of SiCp into the melt of Al composites increased with increase of the temperature above $720^{\circ}C$, and holding time at a given melting temperature. Because SiC is thermodynamically unstable in this Al-SiCp composite at temperature above the liquidus, SiCp dissolves and reacts with Al in matrix to form $Al_4C_3$ according to following chemical equation $4Al+3SiC{\rightarrow}Al_4C_3+3Si$, Si decomposed and dissolved from SiCp increases Si content of matrix, while liquidus temperature of matrix decrease with increase of SiC content in matrix. The hardness of SiCp decreased with increase of the melting temperature, the hardness of the matrix /particle interface increased with increase of the melting temperature due to increase of the $Mg_2Si$ and $Al_4C_3$ intermetallic compounds, etc.

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MODELING OF INTERACTION LAYER GROWTH BETWEEN U-Mo PARTICLES AND AN Al MATRIX

  • Kim, Yeon Soo;Hofman, G.L.;Ryu, Ho Jin;Park, Jong Man;Robinson, A.B.;Wachs, D.M.
    • Nuclear Engineering and Technology
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    • v.45 no.7
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    • pp.827-838
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    • 2013
  • Interaction layer growth between U-Mo alloy fuel particles and Al in a dispersion fuel is a concern due to the volume expansion and other unfavorable irradiation behavior of the interaction product. To reduce interaction layer (IL) growth, a small amount of Si is added to the Al. As a result, IL growth is affected by the Si content in the Al matrix. In order to predict IL growth during fabrication and irradiation, empirical models were developed. For IL growth prediction during fabrication and any follow-on heating process before irradiation, out-of-pile heating test data were used to develop kinetic correlations. Two out-of-pile correlations, one for the pure Al matrix and the other for the Al matrix with Si addition, respectively, were developed, which are Arrhenius equations that include temperature and time. For IL growth predictions during irradiation, the out-of-pile correlations were modified to include a fission-rate term to consider fission enhanced diffusion, and multiplication factors to incorporate the Si addition effect and the effect of the Mo content. The in-pile correlation is applicable for a pure Al matrix and an Al matrix with the Si content up to 8 wt%, for fuel temperatures up to $200^{\circ}C$, and for Mo content in the range of 6 - 10wt%. In order to cover these ranges, in-pile data were included in modeling from various tests, such as the US RERTR-4, -5, -6, -7 and -9 tests and Korea's KOMO-4 test, that were designed to systematically examine the effects of the fission rate, temperature, Si content in Al matrix, and Mo content in U-Mo particles. A model converting the IL thickness to the IL volume fraction in the meat was also developed.

Variation of Magnetic Properties of Fe-Si Compressed Cores with Si Content (Si 함량에 따른 Fe-Si 압분코어의 자기적 특성)

  • Jang, Pyung-Woo;Lee, Bong-Han;Choi, Gwang-Bo
    • Journal of the Korean Magnetics Society
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    • v.20 no.1
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    • pp.13-17
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    • 2010
  • Fe-3, 4.2 and 6.8% Si compressed cores were fabricated, and then electrical resistivity, AC and DC magnetic properties, microhardness, and other properties were analyzed in order to know whether best soft magnetic properties could be also obtained in an Fe-Si compressed core with the well-known composition of Fe-6.5% Si. With increasing the silicon content, eddy current loss and hysteresis loss decreased and increased, respectively, so that a minimum total loss was not obtained in the well-known Fe-6.8 % Si cores, but obtained in the Fe-4.2 % Si cores. Also electrical resistivity of the cores and hardness of the particles increased monotonously with silicon content so that compaction ratio of the cores decreased. B2 and $DO_3$ ordered phase could be observed only in Fe-6.8% Si powder. A minimum loss and highest permeability of the Fe-4.2 % Si cores can be explained by the ratio of specific electrical resistivity of insulator to that of magnetic particles, micro-hardness, compaction ratio and demagnetization coefficient of the Fe-Si powder particles with silicon content.

Study on the Different Characteristic of Chemical and Electronic Properties (SiOC 박막의 화학적 특성과 전기적인 특성에 대한 차이점에 관한 연구)

  • Oh, Teresa
    • Journal of the Korean Vacuum Society
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    • v.18 no.1
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    • pp.49-53
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    • 2009
  • The chemical properties of SiOC film was studied for inter-layer insulator. SiOC film was formed with non polarity due to the appropriate union by the alkyl and hydroxyl group. An amorphous structure of non polarity can induce the low dielectric constant materials. The chemical properties of thin film can define the bonding structure owing to the ionic variation, and the analysis of chemical properties was researched by the carbon content using the FTIR spectra, and induced the film with non polarity. The electrical properties is the electron flow, and is always not the same as the chemical properties. The electrical properties of SiOC film with various flow rate ratios was analyzed and researched the correlation between the chemical properties. SiOC film showed the increasing of the leakage current after annealing process, and abruptly increased the carbon content at some samples. But the sample with increasing the carbon content decreased the leakage current. It means that the chemical properties is not the same as the electrical properties, and the carbon is related with the variation of the bonding structure, and does not contribute the current flow.

The Effect of Si Content on the Tribological Behaviors of Ti-Al-Si-N Coating Layers (Ti-Al-Si-N 코팅막의 마모거동에 미치는 Si 함량의 영향)

  • Jin, Hyeong-Ho;Kim, Jung-Wook;Kim, Kwang-Ho;Yoon, Seog-Young
    • Journal of the Korean Ceramic Society
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    • v.42 no.2 s.273
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    • pp.88-93
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    • 2005
  • Ti-AI-Si-N coating layers were deposited on WC-Co substrates by a hybrid system of arc ion plating and sputtering techniques. The coatings were prepared with different Si contents to investigate the effect of Si content on their mechanical properties and microstructures. The dry sliding wear experiments were conducted on Ti-AI-Si-N coated WC-Co discs at constant load, 3N, and sliding speed, 0.1 m/s with two different counterpart materials such as steel ball and zirconia ball using a conventional ball-on-disc sliding wear apparatus. In the case of steel ball, the friction coefficient of Ti-AI-Si-N coating layers became lower than that of Ti-AI­N coating layers. The friction coefficient decreased with increasing of Si content due to adhesive wear behavior between coating layer and steel ball. On the contrary, in the case of zirconia ball, the friction coefficient increased with increasing of Si content, indicating that abrasive wear behavior was more dominant when the coating layers slid against zirconia ball.

Effect of Deposition Pressure on the Conductivity and Optical Characteristics of a-Si:H Films (증착 압력이 a-Si:H막의 전도도와 광학적 특성에 미치는 영향)

  • Jeon, Bup-Ju;Jung, Il-Hyun
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.98-104
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    • 1999
  • In this work, we investigated hydrogen content, bond structure, and electrical properties of a-Si:H films prepared by ECR plasma CVD as a function of pressure. In general, the photo sensitivity of a-Si:H films prepared by CVD method decreases as the deposition rate increases, but the photo sensitivity of a-Si:H films prepared by ECR plasma deposition method increases as the deposition rate increases. In the same condition of microwave power, the ratio of $SiH_4/H_2$, and pressure, though film thickness increases linearly with deposition time and hydrogen content in the film is constant, photo conductivity can be decreased because $SiH_2$ bond is made more than SiH bond in the short reaction time. According to increase pressure in the chamber, SiH bond in the film increase and optical energy gap decrease. So, photo conductivity can be increased. But photo sensitivity decreased as dark conductivity increase. It must be grown in the condition of low pressure and hydrogen gas for taking the a-Si:H film of high quality.

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A Study on the Mechanical Properties and Specific Resistivity of Reaction-Bonded Silicon Carbide According to α-SiC of Various Mixed Particle Size (반응소결 탄화규소의 다양한 α-SiC 조성에 따른 기계적 특성과 전기저항 특성에 관한 연구)

  • Kim, Young-Ju;Park, Young-Shik;Jung, Youn-Woong;Song, Jun-Baek;Park, So-Young;Im, Hang-Joon
    • Composites Research
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    • v.25 no.6
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    • pp.172-177
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    • 2012
  • For the manufacture of low resistance Si-SiC composite, the properties of reaction sintering in the green body of various mixed ${\alpha}$-SiC powder size with the various carbon contents from 0wt% to 20wt% were investigated. The samples preparation was green body by CIP method under this condition, molten silicon infiltration process was conducted to reaction bonded silicon carbide. the results of sintered density, 3-point bending strength and resistance of analysis showed that varied carbon and silicon melt reacted to convert to fine ${\beta}$-SiC particle and the structure was changed to dense material. The amount of fine ${\beta}$-SiC particle was gradually increased as carbon content increase. According to mixed composite, it's mechanical and specific resistivity properties was strongly influenced by carbon content within 10wt% more then carbon content 10wt% was strongly influenced by phase transition.

Development of New Titanium Alloys for Castings (주조용 티타늄 신합금 개발)

  • Kim, Seung-Eon;Jeong, Hui-Won;Hyeon, Yong-Taek;Kim, Seong-Jun;Lee, Yong-Tae
    • 연구논문집
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    • s.29
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    • pp.163-171
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    • 1999
  • A new titanium alloy system. Ti-xFe-ySi (x,y=0-4 wt%). was designed and characterized with the point at low cost and high strength for casting applications. Fe improved room and elevated temperature mechanical properties owing to solid solution hardening and beta phase stabilization. Si yielded titanium silicides and Si addition over 1 wt% resulted in poor ductility due to coarse silicide chains at prior beta boundaries. The optimum composition was found to be Ti-4Fe-(0.5-1)Si in the viewpoint of tensile strength and ductility which are comparable to the Ti-6Al-4V. The metal-mould reaction was also examined for Ti-xFe and Ti-xSi binary alloy system. The thickness of surface reaction layer w as not affected significantly with Fe content, while it was decreased with Si content. In the Ti-4Si alloy, no reaction layer was found. The depth of surface hardening layer was about $200\mum$ regardless of the mould materials.

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Deposition Behaviors of Ti-Si-N Thin Films by RF Plasma-Enhanced Chemical Vapor Deposition. (RF-PECVD법에 의한 Ti-Si-N 박막의 증착거동)

  • 이응안;이윤복;김광호
    • Journal of the Korean institute of surface engineering
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    • v.35 no.4
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    • pp.211-217
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    • 2002
  • Ti-Si-N films were deposited onto WC-Co substrate by a RF-PECVD technique. The deposition behaviors of Ti-Si-N films were investigated by varying the deposition temperature, RF power, and reaction gas ratio (Mx). Ti-Si-N films deposited at 500, 180W, and Mx 60% had a maximum hardness value of 38GPa. The microstructure of films with a maximum hardness was revealed to be a nanocomposite of TiN crystallites penetrated by amorphous silicon nitride phase by HRTEM analyses. The microstructure of maximum hardness with Si content (10 at.%) was revealed to be a nanocomposite of TiN crystallites penetrated by amorphous silicon nitride phase, but to have partly aligned structure of TiN and some inhomogeniety in distribution. and At above 10 at.% Si content, TiN crystallite became finer and more isotropic also thickness of amorphous silicon nitride phase increased at microstructure.

The Effects of Si Content on the Cutting Characteristics in the Turing Process of A1-Si Alloy, Using a Polycrystalline Diamond Tool (다결정 다이아몬드공구를 사용한 Al-Si합금의 선삭과정에서 절삭특성에 미치는 Si함량의 영향)

  • Lee, Kyung-Ho;Yun, Young-Sik;Lee, Sang-Jo
    • Journal of the Korean Society for Precision Engineering
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    • v.12 no.6
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    • pp.20-26
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    • 1995
  • With the recent development of light and high efficient automobiles and aircraft, demand of the A1-Si alloy is rapidly increasing. However, there is an inclination that as the content of silicon increases it becomes more difficult to machine. Accordingly, the present study intends to analyse and study the cutting resistance and surface roughness of A1-Si alloy with Si contents of 8%, 12%, 17%, and 20%. The A1-Si alloy specimens were turned by a poly- crystalline diamond tool under selected cutting conditions, and results are here described and discussed.

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