• Title/Summary/Keyword: Si (111)

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Sandstone composition and Paleoclimate of cretaceous Jinju and Iljig Formations of the Western Euiseong Area in the northern Part of Kyongsang Basin (경상분지북부 의성서부지역 백악기 진주층.일직층의 사암성분 및 고기후)

  • 박진아;이용태;김상욱;고인석
    • The Journal of the Petrological Society of Korea
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    • v.6 no.2
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    • pp.111-122
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    • 1997
  • Provenance type and paleoclimate of the Jinju and Iljig formation were studied on the basis of compositions of sandstones from the western Euiseong area in the northern part of Kyong-sang basin. The average compositions of quartz, feldspar and lithic grain(Q:F:L) from the sandstones are 53:40:7 and 50:46:4 for Jinju and Iljig formations, respectively. The values fall into the arkosic arenite field. Petrographic detrital modes of the sandstones mainly suggest transitional continental block for the tectonic setting of the provenance. All sandstones from the Jinju and IIjig formations show chemical compositions close to average values of arkose(Pettijohn, 1975). $Na_2O$ contents is relatively high. $Fe_2O_3$(total iron) and MgO contents decrease with increasing $SiO_2$ contents since the framework grains of arkoses supposed to be derived from granitic rocks are poor in ferromagnesian minerals. The detrital framework grains still possess climatic signs even though the grains were more or less altered during deep burial. Bivariant plot of Suttner and Dutta(1986) suggests semi-arid to semi-humid paleoclimate during the deposition of the Jinju and Iljig sandstones.

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Interconnection Process and Electrical Properties of the Interconnection Joints for 3D Stack Package with $75{\mu}m$ Cu Via ($75{\mu}m$ Cu via가 형성된 3D 스택 패키지용 interconnection 공정 및 접합부의 전기적 특성)

  • Lee Kwang-Yong;Oh Teck-Su;Won Hye-Jin;Lee Jae-Ho;Oh Tae-Sung
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.2 s.35
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    • pp.111-119
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    • 2005
  • Stack specimen with three dimensional interconnection structure through Cu via of $75{\mu}m$ diameter, $90{\mu}m$ height and $150{\mu}m$ pitch was successfully fabricated using subsequent processes of via hole formation with Deep RIE (reactive ion etching), Cu via filling with pulse-reverse electroplating, Si thinning with CMP, photolithography, metal film sputtering, Cu/Sn bump formation, and flip chip bonding. Contact resistance of Cu/Sn bump and Cu via resistance could be determined ken the slope of the daisy chain resistance vs the number of bump joints of the flip chip specimen containing Cu via. When flip- chip bonded at $270^{\circ}C$ for 2 minutes, the contact resistance of the Cu/Sn bump joints of $100{\times}100{\mu}m$ size was 6.7m$\Omega$ and the Cu via resistance of $75{\mu}m$ diameter, $90{\mu}m$ height was 2.3m$\Omega$.

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A Study on the Properties of Mortar using Wet-type Waste Sludge according to Heating Temperature (가열온도별 습식방식 폐슬러지를 활용한 모르타르의 특성에 관한 연구)

  • Kang, Suk-Pyo;Cho, Ku-Young;Lee, Jun;Kim, Chang-Oh
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.1
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    • pp.111-119
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    • 2011
  • Recently, urban redevelopment programs and expansion of social infrastructure have caused massive amounts of construction waste in construction fields, and the mounds of it keep increasing every year. The disposal of construction waste is emerging as a national and social issue and the recycled powder generated by the treatment process of waste concrete is all being abolished or buried. Therefore, the purpose of this study is to utilize waste sludge generated by the wet-type treatment process of waste concrete as materials(binder, filler) for cement composite. This study evaluates physical and mechanical properties of mortar using recycled powder according to heating temperature, contents and applications. As a result of the chemical analysis, recycled powder is composed mainly of CaO and $SiO_2$, and that it is even lower in the content of CaO than OPC. The charateristics of mortar using recycled powder, according to drying and heating temperature, shows that as the heating temperature increases, flow decreases. Also, compressive strength and porosity of mortar using recycled powder was superior when heating temperature was $600^{\circ}C$. Thus, it is revealed that an effective development of recycled powder is possible since the binder by cement composite recovers a hydraulic property during heating at $600^{\circ}C$.

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Platinum 유기착화합물을 이용한 금속박막의 증착에 관한 연구

  • Yoo, Dae-Hwan;Choi, Sung-Chang;Ko, Seok-Geun;Choi, Ji-Yoon;Shin, Gu
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.153-153
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    • 1999
  • platinum 유기착화합물을 사용하여 유리 기판 위에 Pt를 증착시켰다. Pt를 증착하기 위하여 Pt 착화합물을 용해 시킨 후, 유리 기판을 용액속에 담근 후 가열하여 Pt막을 증착하였다. 증착 후 Pt의 면저항은 200~75$\Omega$의 값을 나타내어 비교적 높은 저항값을 나타내었다. 높은 저항값을 낮추기 위해 진공 10-5Torr에서 50, 100, 150, 25$0^{\circ}C$로 열처리를 하였다. 이러한 저항값을 변화의 원인을 살펴보기 위하여 X-선 회절법을 이용하여 결정성의 변화를 살펴보았고, 화학적 조성의 변화는 X-ray 광전자 분광법을 이용하여 조사하였다. 열처리 전 Pt막은 비정질 상태를 나타내었으나, 6$0^{\circ}C$에서 30분간 열처리한 후에는 결정성이 증가하는 것으로 관찰되었다. 열처리 후 결정방향은 {111] 방향이 주 방향이였으며 [002] 방향의 피크도 관찰되었다. 따라서 성장된 막은 다결정 막임을 알 수 있었다. XPS를 이용하여 조성을 조사하여 본 결과 열처리하지 않은 시료의 경우 유기물과 반응하여 Pt의 피크가 넓게 나타나나 열처리 후에는 유기물이 분해되어 Pt의 고유한 피크를 관찰할 수 있었다. 따라서 전기전도도의 변화는 유기물의 분해를 통하여 순수한 Pt로 변해가면서 감소하는 것으로 생각되어 지며 결정성 또한 전기전도도 변화에 중요한 역할을 함을 알 수 있었다. 기존의 방법을 이용하여 Pt를 증착할 경우 기판과 쉽게 박리 되는 현상이 관찰되었으나 본 방법을 이용하여 증착된 Pt 박막의 경우 열처리 후에는 기판과의 접착력이 기존의 방법보다 뛰어나 박리되는 현상이 관찰되지 않았다.$ 이상에서 안정한 것을 볼 수 있었다. 텅스텐 박막은 $\alpha$$\beta$-W 구조를 가질 수 있으나 본 연구에서 성장된 텅스텐은 $\alpha$-W 구조를 가지는 것을 XRD 측정으로 확인하였다. 성장된 텅스텐 박막의 저항은 구조에 따라서 변화되는 것으로 알려져 있다. 증착조건에 따른 저항의 변화는 SiH4 대 WF6의 가스비, 증착온도에 따라서 변화하였다. 특히 온도가 40$0^{\circ}C$ 이상, SiH4/WF6의 비가 0.2일 경우 텅스텐을 증착시킨 후에 열처리를 거치지 않은 경우에도 기존에 발표된 저항률인 10$\mu$$\Omega$.cm 대의 값을 얻을 수 있었다. 본 연구를 통하여 산화막과의 접착성 문제를 해결하고 낮은 저항을 얻을 수 있었으나, 텅스텐 박막의 성장과정에 의한 게이트 산화막의 열화는 심각학 문제를 야기하였다. 즉, LPCVD 과정에서 발생한 불소 또는 불소 화합물이 게이트의 산화막에 결함을 발생시킴을 확인하였다. 향후, 불소에 의한 게이트 산화막의 열화를 최소화시킬 수 있는 공정 조건의 최저고하 또는 대체게이트 산화막이 적용될 경우, 개발된 연구 결과를 산업체로 이전할 수 있는 가능성이 높을 것을 기대된다.박막 형성 메카니즘에 큰 영향을 미침을 알 수 있었다. 또한 은의 전기화학적 다층박막 성장은 MSM (monolayer-simultaneous-multilayer) 메카니즘을 따름을 확인하였다. 마지막으로 구조 및 양이 규칙적으로 조절되는 전극의 응용가능성이 간단히 논의될 것이다.l 성장을 하였다는 것을 알 수 있었다. 결정성

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Geochemical Enrichment and Migration of Environmental Toxic Elements in Stream Sediments and Soils from the Samkwang Au-Ag Mine Area, Korea (삼광 금-은광산 일대의 하상퇴적물과 토양내 함유된 독성원소의 지구화학적 부화와 이동)

  • Lee, Chan Hee;Lee, Byun Koo;Yoo, Bong-Cheal;Cho, Aeran
    • Economic and Environmental Geology
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    • v.31 no.2
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    • pp.111-125
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    • 1998
  • Dispersion, migration and enrichment of environmental toxic elements from the Samkwang Au-Ag mine area were investigated based upon major, minor and rare earth element geochemistry. The Samkwang mine area composed mainly of Precambrian granitic gneiss. The mine had been mined for gold and silver, but closed in 1996. According to the X-ray powder diffraction, mineral composition of stream sediments and soils were partly variable mineralogy, which are composed of quartz, orthoclase, plagioclase, amphibole, muscovite, biotite and chlorite, respectively. Major element variations of the host granitic gneiss, stream sediments and soils of mining and non-mining drainage, indicate that those compositions are decrese $Al_2O_3$, $Fe_2O_3$, MgO, $TiO_2$, $P_2O_5$ and LOI with increasing $SiO_2$ respectively. Average compositional ranges (ppm) of minor and/or environmental toxic elements within those samples are revealed as As=<2-4500, Cd=<1-24, Cu=6-117, Sb=1-29, Pb=17-1377 and Zn=32-938, which are extremely high concentrations of sediments from the mining drainage (As=2006, Cd=l1, Cu=71, Pb=587 and Zn=481 ppm, respectively) than concentrations of the other samples and host granitic gneiss. Major elements (average enrichment index=6.53) in all samples are mostly enriched, excepting $SiO_2$, $Na_2O$ and $K_2O$, normalized by composition of host granitic gneiss. Rare earth element (average enrichment index=2.34) are enriched with the sediments from the mining drainage. Minor and/or environmental toxic elements within all samples on the basis of host rock were strongly enriched of all elements (especially As, Br, Cu, Pb and Zn), excepting Ba, Cr, Rb and Sr. Average enrichment index of trace elements in all samples is 15.55 (sediments of mining drainage=37.33). Potentially toxic elements (As, Cd, Cr, Cu, Ni, Pb, and Zn) of the samples revealed that average enrichment index is 46.10 (sediments of mining drainage=80.20, sediments of nonmining drainage=5.35, sediments of confluent drainage=20.22, subsurface soils of mining drainage=7.97 and subsurface soils of non-mining drainage=4.15). Sediments and soils of highly concentrated toxic elements are contained some pyrite, arsenopyrite, sphalerite, galena and goethite.

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A1E Induces Apoptosis via Targeting HPV E6/E7 Oncogenes and Intrinsic Pathways in Cervical Cancer Cells

  • Ham, Sun Young;Bak, Ye Sol;Kwon, Tae Ho;Kang, Jeong Woo;Choi, Kang Duk;Han, Tae Young;Han, Il Young;Yang, Young;Jung, Seung Hyun;Yoon, Do Young
    • Journal of Applied Biological Chemistry
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    • v.57 no.2
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    • pp.103-111
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    • 2014
  • A1E is an extract from traditional Asian medicinal plants that has therapeutic activities against cancers, metabolic disease, and other intractable conditions. However, its mechanism of action on cervical cancer has not been studied. In order to ascertain if A1E would have pronounced anti-cervical cancer effect, cervical cancer cells were incubated with A1E and apoptosis was detected by nuclear morphological changes, annexin V-FITC/PI staining, cell cycle analysis, western blotting, Reverse-transcription polymerase chain reaction, and measurement of mitochondrial membrane potential. Expression of human papiloma virus E6 and E7 oncogenes was down-regulated in A1E-treated cervical cancer cells, while p53 and retinoblastoma protein levels were enhanced. A1E also perturbed cell cycle progression at sub-G1 and altered cell cycle regulatory factors in SiHa cervical cancer cells. A1E activated apoptotic intrinsic pathway markers such as caspase-9, caspase-3 and poly ADP-ribose polymerase, and down-regulated expression of Bcl-2 and Bcl-xl. A1E induced mitochondrial membrane potential collapse and cytochrome c release, and inhibited phosphatidylinositol 3-kinase (PI3K)/Akt, key factors involved in cell survival signaling. Taken all these results, A1E induced apoptosis via activation of the intrinsic pathway and inhibition of the PI3K/Akt survival-signaling pathway in SiHa cervical cancer cells. In conclusion, A1E exerts anti-proliferative action growth inhibition on cervical cancer cells through apoptosis which demonstrates its anti-cervical cancer properties.

The Comparison of Bunsen Reaction With Phase Separation in Sulfur-lodine Thermochemical Hydrogen Production Process (황-요오드 열화학 수소 제조 공정에서 분젠 반응과 상 분리 비고)

  • Lee, Kwang-Jin;Ahn, Sueng-Hyuk;Kim, Young-Ho;Park, Chu-Sik;Bae, Ki-Kwang
    • Journal of Hydrogen and New Energy
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    • v.19 no.2
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    • pp.111-117
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    • 2008
  • A Bunsen reaction section is a primary stage of Sulfur-iodine thermochemical hydrogen production cycle. This section is important, because it decides the efficiency of next stages. In order to produce hydrogen very efficiently, the characteristics of Bunsen reaction were investigated via two experimental methods. The one is a phase separation of $H_2SO_4-HI-H_2O-I_2$ mixture system, and the other is a direct Bunsen reaction. The characteristics of each method were investigated and compared. As the result of this study, the amount of HI and $I_2$ in $H_2SO_4$ phase via Bunsen reaction was more decreased than that via $H_2SO_4-HI-H_2O-I_2$ mixture system with increasing $I_2$ concentration. However, the amount of $H_2SO_4$ in $HI_x$ phase via Bunsen reaction was remarkably increased with increasing $I_2$ concentration, while that via $H_2SO_4-HI-H_2O-I_2$ mixture system was decreased. On the other hand, the range of initial composition which is able to separate into two liquid phases without $I_2$ solidification was almost alike.

The Convergence Study on the Effects of Three Pelvic Floor Muscle Excercise on Thickness of Pelvic Floor Muscle and Abdominal Muscles (골반바닥근 운동방법이 골반바닥근과 몸통근육의 근두께에 미치는 영향에 대한 융합적 연구)

  • Kang, Si-Eun;Shim, Jae-Hoon;Choung, Sung-Dae
    • Journal of the Korea Convergence Society
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    • v.7 no.1
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    • pp.105-111
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    • 2016
  • The purpose of this study was to investigate effects of three pelvic floor muscle (PFM) exercises on the thickness of PFM and transverse abdominal muscle (TrA), the internal oblique muscle, and the external oblique muscle. The PFM and trunk muscles were measured using ultrasonography in 4 conditions.rest, conventional PFM contraction (Ex A), PFM contraction with hip adductor contraction (Ex B), and PFM contraction with real-time ultrasound imaging (Ex C). The thickness of PFM in Ex C showed a significantly more decrease compared to rest and others (all comparisons, p<.05). The thickness of TrA in Ex C showed a significantly more increase compared to rest and others (all comparisons, p<.05). This study would recommend the use of PFM contraction with real-time ultrasonographic imaging to improve women's incontinence.

Shock Tube and Modeling Study of Ignition in$NH_3-NO-Ar$Mixtures ($NH_3-NO-Ar$혼합기체의 점화 과정에 관한 충격관 실험 및 모델 연규)

  • Shin, Kuan Soo;Bae, Gyun Tack;Shim, Seung Bo;Ryu, Si Ok
    • Journal of the Korean Chemical Society
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    • v.45 no.2
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    • pp.111-115
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    • 2001
  • The ignition of NH$_3$-NO-Ar mixtures was examined in the temperature renge of 1675-2391 K behind reflected shock waves. The ignition delay times were measured by monitoring pressure profiles and the OH emissions at 1.0 cm from the end wall. A correlation between ignition delay times and concentrations of gases could be summarized in the form of mass-action expression, To complement the experiment, computer modeling study of the ignition of NH$_3$-NO-Ar mixtures was carried out using various mechanisms reported previously. The sensitivity analysis shows the reaction of NH$_2$+NO${\rightarrow}$NNH+OH is the most important step in the ignition of NH$_3$-NO-Ar mixtures.

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Effects of ICP Power on the Properties of TiCrN Films (유도결합플라즈마의 전력이 TiCrN 코팅층에 미치는 영향)

  • Cha, B.C.;Kim, J.H.;Lee, B.S.;Kim, S.K.;Kim, D.W.;Kim, D.;You, Y.Z.
    • Journal of the Korean Society for Heat Treatment
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    • v.22 no.5
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    • pp.307-311
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    • 2009
  • In this study, TiCrN films were deposited on STS 316 Land Si (100) wafer by inductively coupled plasma (ICP) assisted D.C. magnetron sputtering. The effect R.F. power for ICP discharge on the mechanical properties of TiCrN films was investigated. XRD, XPS and FE-SEM were used for the structure analysis. Also the Micro-Knoop hardness tester and profilometer were used for measuring hardness of coatings and film stress respectively. As increasing the R.F. power for ICP discharge, thickness of coating was decreased from 1633 nm to 1288 nm but hardness was increased about $Hk_{5g}$ 4200 at 400 W. All of the XRD patterns showed (111), (200) and (220) peaks of TiCrN films. Surface morphology was studied using the profilometer. FE-SEM was used to know morphology and cross-section of the films. Structure of the films was changed dense as increased ICP power.