• Title/Summary/Keyword: Si(IV)

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Mineralogical Study of Sericite in the Daehyun Mine: Formation, Chemistry and Polytype (대현광산 견운모의 생성과정과 화학조성 및 폴리타잎)

  • 이병임;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.11 no.2
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    • pp.69-84
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    • 1998
  • The Daehyun sericite deposit in socheon-myun, Bongwha-gun, Kyungsangbuk-do, Korea, has been formed by the hydrothermal alteration of the Hongjesa granite of Precambrian age, leaving the muscovite granite between ore body and the Hongjesa granite as the wall rock alteration zone. The process of sericitization of granitic rock as well as chemistry and structures of sericites were studied using polarizing microscope, X-ray diffractometer (XRD), electron probe microanalyzer (EPMA) and high resolution transmission electron microscope (HRTEM). There are two genetic types of sericites having different chemistry and structure. The early sericite is of 2M1 polytype and has octahedral composition close to muscovite. It has been formed from the primary muscovite, tourmaline and quartz under a relatively high temperature. The late sericite is of 1M, 2M1 and 3T polytypes and has phengitic composition. It has been formed form feldspar, biotite, muscovite and tourmaline under a relatively low temperature. Chemical analyses show t, the early sericite has less Mg+FeT content and lower Si/AlIV ratio in tetrahedral site than the late sericite.

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Synthesis and Photoactivity of SnO2-Doped TiO2 Thin Films (SnO2가 도핑된 TiO2 박막의 합성 및 광촉매 효과)

  • Jung, Mie-Won;Kwak, Yun-Jung
    • Journal of the Korean Ceramic Society
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    • v.44 no.11
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    • pp.650-654
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    • 2007
  • [ $SnO_2$ ]-doped $TiO_2$ thin films were prepared from tin (IV) bis (acetylacetonate) dichloride and titanium diisopropoxide bis (acetylacetonate) with pluronic P123 or degussa P25 as a structural-directing agent. These hydrolyzed sol were spin coated onto Si(100) wafer substrate. The microstructure, morphology and bonding states of thin films were studied by field-emission scanning electron microscopy (FE-SEM), X-ray diffractometry (XRD), and X-ray photoelectron spectroscopy (XPS). The photocatalytic activity of these films was investigated by using indigo carmine solution.

Occurrence and Chemical Composition of Dolomite and Chlorite from Xiquegou Pb-Zn Deposit, China (중국 Xiquegou 연-아연 광상의 돌로마이트와 녹니석 산상과 화학조성)

  • Yoo, Bong Chul
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.2
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    • pp.125-140
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    • 2022
  • The Xiquegou Pb-Zn deposit is located at the Qingchengzi orefield which is one of the largest Pb-Zn mineralized zone in the northeast of China. The geology of this deposit consists of Archean granulite, Paleoproterozoinc migmatitic granite, Paleo-Mesoproterozoic sodic granite, Paleoproterozoic Liaohe group, Mesozoic diorite and Mesozoic monzoritic granite. The Xiquegou deposit which is a Triassic magma-hydrothermal type deposit occurs as vein ore filled fractures along fault zone in unit 3 (dolomitic marble and schist) of Dashiqiao formation of the Paleoproterozoic Liaohe group. Xiquegou Pb-Zn deposit consists of quartz, apatite, calcite, pyrite, arsenopyrite, pyrrhotite, marcasite, sphalerite, chalcopyrite, stannite, galena, tetrahedrite, electrum, argentite, native silver and pyrargyrite. Wallrock alteration of this deposit contains silicification, pyritization, dolomitization, chloritization and sericitization. Based on mineral petrography and paragenesis, dolomites from this deposit are classified two type (1. dolomite (D0) as wallrock, 2. dolomite (D1) as wallrock alteration in Pb-Zn mineralization quartz vein ore). The structural formulars of dolomites are determined to be Ca1.03-1.01Mg0.95-0.83Fe0.12-0.02Mn0.02-0.00(CO3)2(D0) and Ca1.16-1.00Mg0.79-0.44Fe0.53-0.13Mn0.03-0.00As0.01-0.00(CO3)2(D1), respectively. It means that dolomites from the Xiquegou deposit have higher content of trace elements compared to the theoretical composition of dolomite. The dolomite (D1) from quartz vein ore has higher content of these trace elements (FeO, PbO, Sb2O5 and As2O5) than dolomite (D0) from wallrock. Dolomites correspond to Ferroan dolomite (D0), and ankerite and Ferroan dolomite (D1), respectively. The structural formular of chlorite from quartz vein ore is (Mg1.65-1.08Fe2.94-2.50Mn0.01-0.00Zn0.01-0.00Ni0.01-0.00Cr0.02-0.00V0.01-0.00Hf0.01-0.00Pb0.01-0.00Cu0.01-0.00As0.03-0.00Ca0.02-0.01Al1.68-1.61)5.77-5.73(Si2.84-2.76Al1.24-1.16)4.00O10(OH)8. It indicated that chlorite of quartz vein ore is similar with theoretical chlorite and corresponds to Fe-rich chlorite. Compositional variations in chlorite from quartz vein ore are caused by mainly octahedral Fe2+ <-> Mg2+ (Mn2+) substitution and partly phengitic or Tschermark substitution (Al3+,VI+Al3+,IV <-> (Fe2+ 또는 Mg2+)VI+(Si4+)IV).

Antistress effect of red ginseng in brain cells is mediated by TACE repression via PADI4

  • Kim, Eun-Hye;Kim, In-Hye;Ha, Jung-Ah;Choi, Kwang-Tae;Pyo, Suhkneung;Rhee, Dong-Kwon
    • Journal of Ginseng Research
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    • v.37 no.3
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    • pp.315-323
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    • 2013
  • Ginseng is known to have antistress effects. Previously, red ginseng (RG) was shown to repress stress-induced peptidyl arginine deiminase type IV (PADI4) via estrogen receptor ${\beta}$ ($ER{\beta}$) in the brain, thus inhibiting brain cell apoptosis. Moreover, tumor necrosis factor (TNF)-${\alpha}$ plays a critical role in immobilization (IMO) stress. However, the signaling pathway of RG-mediated repressesion of inflammation is not completely understood. In this study, we determined how RG modulated gene expression in stressed brain cells. Since secretion of TNF-${\alpha}$ is modulated via TNF-${\alpha}$ converting enzyme (TACE) and nuclear factor (NF)-${\kappa}B$, we examined the inflammatory pathway in stressed brain cells. Immunohistochemistry revealed that TACE was induced by IMO stress, but RG repressed TACE induction. Moreover, PADI4 siRNA repressed TACE expression compared to the mock transfected control suggesting that PADI4 was required for TACE expression. A reporter assay also revealed that $H_2O_2$ oxidative stress induced NF-${\kappa}B$ in neuroblastoma SK-N-SH cells, however, RG pretreatment repressed NF-${\kappa}B$ induction. These findings were supported by significant induction of nitric oxide and reactive oxygen species (ROS) by oxidative stress, which could be repressed by RG administration. Taken together, RG appeared to repress stress-induced PADI4 via TACE and NF-${\kappa}B$ in brain cells thus preventing production of ROS and subsequently protecting brain cells from apoptosis.

Development of Korean Version of WHO-CIDI(Composite International Dignostic Interview)-Social Phobia : Its Validity and Reliability (한국어판 WHO-CIDI(Composite International Diagnostic Interview)-사회 공포증의 개발 : 타당도 및 신뢰도 검사)

  • Seo, Joo-Won;Oh, Kang-Seoh;Lee, Si-Hyung
    • Korean Journal of Psychosomatic Medicine
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    • v.8 no.2
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    • pp.191-200
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    • 2000
  • It is our purpose to evaluate the validity & interrater reliability of CIDI-social phobia, Korean Version. Method : CIDI-Social phobia Korean Version was evaluated by 50 Korean social phobia patients who met diagnostic criteria of DSM-IV. The authors calculated diagnostic concordance rate between clinical diagnosis & diagnosis by using the CIDI-social phobia Korean Version for evaluating validity. We also calculated the interrater diagnostic concordance of 20 social phobia patients for evaluating interrater reliability. Results : Validity of the CIDI-social phobia Korean Version was 0.74, & Interrater reliability(kappa) was 0.75. Conclusions : CIDI-Social phobia, Korean version had a good reliability & validity. That was proved a good instrument for diagnosing social phobia for general population and clinical patients

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A Study on the Evaluation of Selection Attributes of Spa Destination by IPA (IP분석에 의한 온천관광지 선택속성 평가 연구)

  • Kim, Si-Joong
    • Journal of the Economic Geographical Society of Korea
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    • v.12 no.2
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    • pp.159-178
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    • 2009
  • The purpose of the current study was to evaluate the importance-performance levels for the selection attributes of spa destination and to analyze the gap between importance levels of the selection attributes. The data were collected from the spa visitors to Yuseong spa complex. The findings of the current study were as belows: 1. as the results of factor analysis of 32 selection attributes, five factors were generated, such as "spa and supporting facilities", "surrounding conditions around spa resort", "friendship and the intention of recommendation", "spa water" and "fees of spa entry". 2. the mean analysis showed the statistically significant difference among the selection attributes for importance-performance levels and the mean levels of five factors were rank-ordered as in "spa and supporting facilities", "friendship and the intention of recommendation", "fees of spa entry", and "surrounding conditions around spa resort", "spa water". 3. as the results of IPA, the selection attributes were distributed as belows: 9 attributes were located in I (Keep up the Good Work), 4 attributes were located in II (Possible Overkill), 7 attributes were located in III (Concentrate Here). and 12 attributes were located in IV (Low Priority).

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The Electrical Characteristics of MOSFET having Deuterium implanted Gate Oxide (중수소 이온 주입된 게이트 산화막을 갖는 MOSFET의 전기적 특성)

  • Lee, Jae-Sung
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.47 no.4
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    • pp.13-19
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    • 2010
  • MOSFET with deuterium-incorporated gate oxide shows enhanced reliability compared to conventional MOSFET. We present an alternative process whereby deuterium is delivered to the location where the gate oxide reside by an implantation process. Deuterium ions were implanted using two different energies to account for the topography of the overlaying layers and placing the D peak at the top of gate oxide. A short anneal at forming gas was performed to remove the D-implantation damage. We have observed that deuterium ion implantation into the gate oxide region can successfully remove the interface states and the bulk defects. But the energy and the dose of the deuterium implant need to be optimized to maintain the Si substrates dopant activation, while generating deuterium bonds inside gate oxide. CV and IV characteristics studies also determined that the deuterium implant dose not degrade the transistor performance.

Floristic Study of Daebudo Island (대부도 일대의 식물상)

  • Lim, Yongseok;Yoo, Kwang-Pil;The Korean Society of Plant Parataxonomists;Hyun, Jin-Oh
    • Korean Journal of Plant Resources
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    • v.27 no.5
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    • pp.447-476
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    • 2014
  • We have investigated the flora of Daebudo Island in Ansan-si, Gyeonggi-do and Seonjaedo Island in Ongjin-gun, Incheon. Thirty-three separate field trips were carried out from March 2012 to October 2013. As a result, 518 taxa including 103 families, 316 genera, 451 species, 9 subspecies, 56 varieties and 16 forms were identified. Among them, a plant protected by the wildlife protection law, 7 Korean endemic plants and 5 threatened plants by National Arboretum and National Institute of Biological Resources were included. The floristic indicator plants were 38 taxa including 3 taxa of grade V, 4 taxa of grade IV, 4 taxa of grade III, 10 taxa of grade II and 17 taxa of grade I. Sixty-seven naturalized plants with naturalization rates of 12.9% were also found.

Speciation and Solubility of Major Actinides Under the Deep Groundwater Conditions of Korea

  • Dong-Kwon Keum;Min-Hoon Baik;Pil-Soo Hahn
    • Nuclear Engineering and Technology
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    • v.34 no.5
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    • pp.517-531
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    • 2002
  • The speciation and solubility of Am, Np, Pu and U have been analyzed by means of the geochemical code MUGREM, under the chemical conditions of domestic deep groundwater, in order to support the preliminary safety assessment for a Korean HLW disposal concept. Under the conditions of groundwaters studied, the stable solid phase is AmOHC $O_3$(s) or Am(OH)$_3$(s), soddyite((U $O_2$)$_2$ $SiO_2$.2$H_2O$) or N $a_2$ $U_2$ $O_{7}$ (c), Np(OH)$_4$(am), and Pu(OH)$_4$(am) for Am, U, Np, and Pu, respectively. The dominating aqueous species are as follows: the complexes of Am(III), Am(OH)$_2$$^{+}$ and Am(C $O_3$)$_2$$^{[-10]}$ , the complexes of U(VI), U $O_2$(OH)$_3$$^{[-10]}$ and U $O_2$(C $O_3$)$_3$$^{4-}$, the complexes of Np(IV), Np(OH)$_4$(aq) and Np(OH)$_3$C $O_3$, and the complexes of Pu(IV), Pu(OH)$_4$(aq) and Pu(OH)$_3$C $O_3$$^{[-10]}$ . The calculated solubilities exist between 1.9E-10 and 1.3E-9 mol/L for Am, between 5.6E-6 and 1.2E-4 mol/L for U, between 3.1E-9 and 1.3E-8 mol/L for Np, and between 6.6E-10 and 2.4E-10 mol/L for Pu, depending on groundwater conditions. The present solubilities of each actinide agree well with the results of other studies obtained under similar conditions.s.

Synthesis of Sphene-pink Pigment under Various Firing Conditions

  • Lee, Hyun-Soo;Park, Joo-Seok;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.615-620
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    • 2009
  • The present research was performed to determine the optimal firing condition and holding time for malayaite crystal, which is responsible for the stable pink-red coloration in glaze at high temperatures, using Cr$Cl_3$ as chromophore for the synthesis of $Cr_2O_3-SnO_2-CaO-SiO_2$ system pigments. The malayaite crystal was influenced by the raw materials used for synthesis, firing temperature, and holding time. Thus there are differences in the crystal phase and in the coloration according to the condition of synthesis. When Cr$Cl_3$ was used as chromophore, the pigment could be synthesized at lower temperatures, because Cr$Cl_3$ melts at $1500{^{\circ}C}$, which is much lower than the temperature at which $Cr_2O_3$ melts (higher than $2435{^{\circ}C}$). And the employed Cr ion showed a change in oxidation state. When a mineralizer was used to improve the employment of malayaite and the Cr ion, and the low temperature was maintained at which the malayaite crystal is produced, the production of malayaite crystal was promoted and the employment of chromophore was also promoted in the oxidation state of Cr (IV). The results of the experiment showed that the optimal firing condition was 18 h of holding time at $800{^{\circ}C}$, using Cr$Cl_3$ as chromophore, followed by 2 h at the raised temperature of $1150{^{\circ}C}$. The change in coloration of the Cr (IV) employed by malayaite showed a very rich color of red. Thus it was possible to effectively synthesize sphene-pink pigments with more red tint at a low temperature.