• Title/Summary/Keyword: Shrinkage Property

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A Study on the Material Characteristics and Functionality Evaluation of a Size Layer of a Canvas (캔버스 차단층(Size Layer)의 재료특성 및 기능평가 연구)

  • Kim, Hwan Ju;Lee, Hwa Soo;Chung, Yong Jae
    • Journal of Conservation Science
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    • v.32 no.2
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    • pp.167-178
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    • 2016
  • Despite the size layer is an important part for conserving the artworks in the configuration of oil painting, the conservation scientific approaches of that have not been made yet. Therefore, this study produced standard samples on the basis of the analysis results of oil painting works, and carried out the evaluation of functions of the size layer materials. As a result of literature material, traditionally, animal glue was used for the size layer, whereas synthetic resin have been used in combination with animal glue since the modern age, in particular, it was identified that Polyvinyl Acetate(PVAc) was in general use. As a result of analysis of oil painting works, size layer was detected on the support and it was identified as animal glue. As a result of analysis based on Funaoka canvas for ground, it showed that the lead oxide and the titanium dioxide were the main constituents. On the basis of these results, standard samples were produced. As a result of evaluation on the functions of the size layer materials, in the case of the animal glue, stable result was observed in the shrinkag expansion rate, whereas slight weakness was observed in moisture proofing, color, and tensile strength, and dense cracks were found on surface. As for PVAc(A), moisture proofing, color, and the tensile strength exhibited stable results. Higher shrinkage rate was observed and the cracks with wide gaps were found on surface. As for PVAc(B), tensile strength, shrinkage expansion rate, and surface observation showed stable results, whereas moisture proofing property showed poor results. Different aspects were observed in each experiment, and this phenomena were considered to be due to the density and the adhesion properties between the hydrophilic and hydrophobic molecules in the size layer materials. The results are expected to be used as materials for the oil painting work conservation henceforth.

A Study on the Variation of Physical Properties on the Secondary Product of Cement by Using Crushed Stone Powder (폐석분을 사용한 시멘트 2차 제품의 물리적 특성에 관한 연구)

  • Park, Ji-Sun;Lee, Sea-Hyun;Song, Hun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.103-111
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    • 2012
  • One of the basic physical properties of the hardened cement paste, the rigidity, is deteriorated during concrete matrix forming, depending on the replacement rate of the crushed stone powder, and due to drying shrinkage. Therefore, the concrete containing crushed stone powder has been limitedly used as non-structural construction material. To improve these disadvantages, a hydrothermal reaction employing method can be considered. High-temperature and high-pressure water is involved in the hydrothermal reaction in the mixing with specific materials. The rigidity improving mechanism is related to the synthesis of calcium silicate. The calcium silicate is produced through reaction between calcium compounds and the silicic acid. Various kinds of calcium silicate can be produced depending on the CaO/$SiO_2$ mole ratio, the temperature of the hydrothermal synthesis, the pressure, and the reaction time. The product of the synthesis mechanism, tobermorite crystal, plays a pivotal role for the rigidity reinforcement. The crushed stone powder, analyzed in this study, contains 50 to 60% of $SiO_2$ and 10 to 20% $Al_2O_3$. The composite rate is appropriate to create the tobermorite crystal through formation of hardened cement matrix under the hydrothermal synthetic conditions and with the CaO in the cement. Moreover, further reinforcement was promoted using the property of material under the identical density through promoting the formation of tobermorite crystal.

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Study on the Thickness Effect of the Separator for Lithium Secondary Batteries (리튬이차전지용 분리막의 두께에 따른 특성 연구)

  • Kim, Sang Woo;Seok, Ji-Hoo;Kim, Byung-Hyun Daniel;Cho, Hee-Min;Cho, Kuk Young
    • Journal of the Korean Electrochemical Society
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    • v.17 no.1
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    • pp.7-12
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    • 2014
  • There is increasing demand on the reducing the weight and the volume of the major components in lithium secondary battery to improve energy density. Separator not only provides pathway for lithium ion movement but also prevents direct contact between anode and cathode. Herein we fabricated polyethylene separator by varying biaxial stretching ratio to obtain membrane thickness of 16, 12, and $9{\mu}m$. Mechanical and thermal properties of the separator with different thickness were investigated. Also rate capability and charge-discharge cycle property up to 500 cycles were studied using coin type full-cell with $LiCoO_2$ and graphite as a cathode and an anode, respectively. All the cells using separator with different thickness demonstrated excellent capacity retention after 500cycles (around 80%). Considering the rate capability, cell using separator with thickness of $9{\mu}m$ showed best performance. Interestingly, separator thickness of $9{\mu}m$ was more resistant to heat contraction compared to that of $16{\mu}m$ separator.

Evaluation of Physico-mechanical Properties and Durability of Larix kaempferi Wood Heat-treated by Superheated Steam (과열증기 열처리 낙엽송재의 물리·역학적 성능 및 내후성능 평가)

  • Park, Yonggun;Park, Jun-Ho;Yang, Sang-Yun;Chung, Hyunwoo;Kim, Hyunbin;Han, Yeonjung;Chang, Yoon-Seong;Kim, Kyoungjung;Yeo, Hwanmyeong
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.5
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    • pp.776-784
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    • 2016
  • In this study, green Larix kaempferi lumber was heat-treated by using superheated steam (SHS) at a pilot scale and then various physico-mechanical properties of the heat-treated wood were evaluated and compared with the properties of conventional hot air (HA) heat-treated wood. Decay resistance of brown rot fungi and compressive strength parallel to the grain of the SHS heat-treated wood without occurrence of drying check from green lumber were increased. On the other hand, density, equilibrium moisture content, shrinkage, and bending strength of the SHS heat-treated wood were lower than those of the conventional HA heat-treated wood. Because heat transfer and thermal hydrolysis of SHS heat treatment was accelerated by a large amount of water, the effect of SHS heat treatment on the physico-mechanical properties was higher than that of HA heat treatment at the similar conditions of temperature and time. From the results of this study, because green lumber can be heat-treated without occurrence of cracks or checks by using SHS and similar heat treatment effect on the physico-mechanical properties of wood can be produced despite a low temperature or short time of heat treatment, it is expected that heat time and energy consumption could be reduced by using SHS.

Evaluation for Applicability of Reinforced Concrete Structure with Domestic Pond Ash (국산 매립회 골재를 사용한 콘크리트 구조물의 적용성 평가)

  • Lee, Bong-Chun;Jung, Sang-Hwa;Chae, Sung-Tae;Kwon, Seung-Jun
    • Journal of the Korea Concrete Institute
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    • v.23 no.5
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    • pp.541-550
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    • 2011
  • Many researches have been performed on concrete with fly ash and bottom ash. However researches on concrete with pond ash (PA) and its application to RC (Reinforced Concrete) structure are limitedly carried out. This paper presents an applicability of PA concrete in construction of real size structure. Referring to the previous study, 2 domestic PA samples with normal performance are selected and 2 replacement ratios (25% and 50%) to fine aggregate are considered for 5 PA concrete structures consisting of column, slab, and wall. In order to evaluate the property of fresh concrete, several tests including air content, slump, and setting time are performed. Using cored out samples from hardened PA concrete structure, tests for strength, resistance to carbonation and chloride penetration are carried out and compared with control samples. Additionally, tests for rebound hardness, drying shrinkage, and hydration heat are performed for PA concrete structure. The test results showed that PA concrete has reasonable strength and durability performances compared to those of normal concrete. Therefore, its potential application to RC structure is promising. The PA aggregate can be more actively used for RC structures with better quality control for content of fly ash, bottom ash, and unburned carbon.

Development of Organic Paste Porcelain for Fixed Prostheses (유기조성물을 이용한 페이스트형 일반도재 시스템)

  • Han, Jung-Suk;Lee, Myung-Hyun;Kim, Dae-Hyun;Chung, Hun-Young
    • Journal of Dental Rehabilitation and Applied Science
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    • v.20 no.2
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    • pp.109-120
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    • 2004
  • INTRODUCTION: The build-up method has been used for application of porcelain powder on the metal framework to make final tooth shape conventionally. This method takes time and need skill to mimic final shade and shape of porcelain fused to metal crown. The purpose of this study was to develop standard shape and shade laminating porcelain forms to reduce build-up time. METHODS: To make tooth form porcelain paste, several liquid organic compounds were added to conventional feldspathic porcelain. The amount of additives and rheologic property were tested to find out best composition. Comparison of mixing methods to reduced porosity, proper heating schedule, and measurement of shrinkage amount and residual organic materials were performed to set-up standard procedures. Finally, biaxial flexural strength and color of preformed laminated paste porcelain were compared with those of porcelain which fabricated by the conventional build-up method. RESULTS: There was no significant difference in physical properties and color stability between two fabrication methods after various testing methods. Conclusion: This new build-up method can be applied to fabricate the PFM crown and bridge without any loss of strength and optical properties.

Production of Nitric Oxide by Siegesbeckia Glabrescens is Associated with Apoptosis of Vascular Smooth Muscle Cell (희렴의 Nitric Oxide 유리를 통한 평활근세포에서의 Apoptosis유도)

  • Jun Soo Young;Shin Dong Hoon;Son Chang Woo;Shin Heung Mook
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.18 no.4
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    • pp.1055-1060
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    • 2004
  • Apoptosis is the ability of cells to self-destruct by the activation of an intrinsic cellular suicide program when the cells are no longer needed or when they are seriously damaged. Morphologically, apoptosis is characterized by the appearance of membrane blebbing, cell shrinkage, chromatin condensation, DNA cleavage, and the fragmentation of the cell membrane-bound apoptotic bodies. Siegesbeckia glabrescens Makino (Siegesbeckiae Herba, SG) has been widely used as treatments for arthritis, and fever, as well as detoxification properties. The present studies were undertaken to evaluate if SG has an anti-apoptotic property. Cell viability was measured by XTT and tryphan blue stain. Morphological characteristic of human aortic smooth muscle cells(HASMC) were visualized with a phase-contrast microscope. SG significantly reduced HASMC, but not human umbilical vein endothelial cell(HUVEC), viability in a dose-dependent manner. Confluent untreated cells at 24hrs showed normal morphology, flat with a uniform polygonal shape. SG-treated cells (0.5㎎/㎖) at 24hrs showed apoptotic morphology. Cells became irregular with elongated lamellipodia, and exhibited condensed chromatin in nuclei with occasional endoucleation. There was an increase in the number of apoptotic cells rounding-up and being detached from the substrate. TUNEL staining of SG-treated cells showed dark-brown stains in nuclei and cytosol. Caspases are central components of the machinery responsible for apoptosis and are generally divided into two categories; the initiator caspases, which include caspases-2,-8,-9, and -10, and the effector caspases, which include caspases-3,-6, and -7. SG decreased anti-caspase-3 protein expression, which means activation of caspases-3 activity. It has been reported that there is a link between NO formation and apoptosis. NO production was accelerated by SG treatment in HASMC. L-NNA, NOS inhibitor, inhibited SG-induced apoptosis. These results, therefore, indicated that both caspases-3 and NO production are involved in apoptosis in smooth muscle cells. According to these results, SG may have a potential effect in the treatment of hypertensive atherosclerosis.

Evaluation of Application of High Quality Recycled Fine Aggregate Manufacturing System by the Drying Specific Gravity Separation Method (건식비중분리법에 의한 고품질 재생잔골재 제조생산 시스템의 적용성 평가)

  • Kim Moo-Han;Kim Jae-Hwan;Kim Yong-Ro;Na Chul-Sung
    • Journal of the Korea Concrete Institute
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    • v.17 no.1 s.85
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    • pp.69-76
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    • 2005
  • In this study, the high qualify recycled fine aggregate manufacturing system by the drying specific gravity separation method was evaluated. For the evaluation of the performance of the recycled aggregate, the engineering properties and durability of recycled aggregate has been tested. From the test results, the quality of recycled fing aggregates was improved by high quality recycled fine aggregate manufacturing system and satisfied with the quality standards of KS and JASS 5. Also, compressive and tensile strengths of recycled concrete show no critical difference caused by recycled fine aggregate replacement ratio. However, durability such as carbonation depth chloride ion penetration depth and drying shrinkage shows more deterioration than the concrete without recycled fine aggregate

An Experimental Study on Properties of Concrete Using Latent Heat Binder (잠열성 결합재를 활용한 콘크리트의 특성에 관한 실험적 연구)

  • Kim, Yong-Ro;Kim, Do-Su;Khil, Bae-Su;Kim, Ook-Jong;Lee, Do-Bum
    • Journal of the Korea Concrete Institute
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    • v.20 no.5
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    • pp.661-668
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    • 2008
  • It is necessary to develop a new technology for effectively reducing hydration heat and controlling thermal cracking caused increasing construction of large size massive concrete structures such as mat foundation of high-rise building, grandiose bridge, and LNG tank. Therefor, to develop a new technology for reducing hydration heat of large size massive concrete in this study, after developing the latent heat binder for controling hydration heat of concrete by application of latent heat material, it was investigated basic properties and durability such as slump, air content and compressive strength, shrinkage properties, permeability, freezing and thawing resistance, corrosion, and hydration heat generation properties of concrete using latent heat binder. As a test result, it was confirmed that latent heat binder was not affected adversely the basic property and durability of concrete, and was advanced on the reduction of hydration heat and control of thermal crack. It is expected to be applied as the excellent technology on the management of hydration heat and thermal crack in large size mass concrete structures.

Strength Properties of Concrete According to Types of High Early Strength Cement and Curing Method (조강형 시멘트의 종류 및 양생방법에 따른 콘크리트의 강도특성)

  • Chang, Chun-Ho;Lee, Wang-Sup;Jung, Yong-Wook;Chung, Youn-In
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.1
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    • pp.76-84
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    • 2017
  • This study selected a method which uses high early strength cement as a way to reduce the curing time and curing energy source of concrete secondary products and reviewed the improvement in the initial strength of concrete secondary products setting the target strength of the concrete capable of removing the form to 15MPa and the curing time to 6 hours. As a result of the test, the only specimen which achieved the form removal strength of 15 MPa only through atmospheric curing within the target curing time of 6hours was ACC-100, and the specimens of TRC-100 and TRC-50 satisfied the values of 6 hours and 15MPa through steam curing. However, we could see that it was difficult to secure workability in the case of the specimen of ACC-100 due to its high rapid setting property and a retarder such as anhydrous citric acid was required to be used to improve the workability. When we look into the pattern following changes in the water to binder ratio, while, in the case of stream curing, OPC-100, TRC-100, and TRC-50 were all found to satisfy achievement of the form removal strength within 6hours as the water to binder ratio decreased, in the case of atmospheric curing, TRC-100, and TRC-50 achieved 15MPa within 12hours.