• Title/Summary/Keyword: Shift factor

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A Study on the Sulfur-Resistant Catalysts for Water Gas Shift Reaction III. Modification of $Mo/γ-Al_2O_3$ Catalyst with Iron Group Metals

  • Park, Jin Nam;Kim, Jae Hyeon;Lee, Ho In
    • Bulletin of the Korean Chemical Society
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    • v.21 no.12
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    • pp.1233-1238
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    • 2000
  • $Mo/{\gamma}-Al_2O_3catalysts$ modified with Fe, Co, and Ni were prepared by impregnation method and catalytic activity for water gas shift reaction was examined. The optimum amount of Mo loaded for the reaction was 10 wt% $MoO_3$ to ${\gamma}-Al_2O_3.$ The catalytic activity of $MoO_3/{\gamma}-Al_2O_3was$ increased by modifying with Fe, Co, and Ni in the order of Co${\thickapprox}$ Ni > Fe. The optimum amounts of Co and Ni added were 3 wt% based on CoO and NiO to 10 wt% $MoO_3/{\gamma}-Al_2O_3$, restectively. The TPR (temperature-programmed reduction) analysis revealed that the addition of Co and Ni enganced the reducibility of the catalysts. The results of both catalytic activity and TPR experiments strongly suggest that the redox property of the catalyst is an important factor in water gas shift reaction on the sulfided Mo catalysts, which could be an evidence of oxy-sulfide redox mechanism.

Interdiffusion at Interfaces of polymers with Similar Physical Properties

  • Kim, Un Cheon;Lee, Chang Jun;Sim, Hun Gu;Park, Hyeong Suk
    • Bulletin of the Korean Chemical Society
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    • v.21 no.6
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    • pp.577-582
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    • 2000
  • Interdiffusion process at interfaces of chemically identical polymers (e.g., deuterated-nondeuterated pairs) with different molecular weights or polymers with similar physical properties, is studied here by varying the diffusion time. Considering the vacancy flux ($J_v$) and adopting the Cahn-Hilliard interracial energy in describing this system, we can see that the variation of the interfacial composition profile with time is asymetric and the interface moves towards the polymer with the lower molecular weight as interdiffusion progresses. Furthermore, interface shift $\Delta\chi$, which characterizes the interdiffusion between polymers, agrees well with the behaviors of the existing experimental data. We can also obtain the interface shift factor C, which can be converted into values of $D_s$ (self-diffusion coefficient of the smaller molecules), from the slopes of the linear fits to the data of the interface shift.

The structure analysis of $Y_1Ba_2Cu_3O_x$ high Tc superconductor based on rietveld method (리트벨트 해석법을 이용한 $Y_1Ba_2Cu_3O_x$ 고온 초전도체의 구조분석)

  • 채기병;소대화
    • Electrical & Electronic Materials
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    • v.8 no.6
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    • pp.780-786
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    • 1995
  • For the execution of RIETAN program adopting Rietveld Analysis Method, the sample superconductor is made according to the solid state synthesis method at 920.deg. C for 24hrs, and was examined for the optimization of parameters needed to analyze Rietveld method with the input of the measured pattern data after measuring the pattern resulted from the X-ray diffraction. It was proven that the lattice constant of the superconductor which was consisted of Pmmm orthorhombic crystal structure in the analyzed space group correspond to the presented theoretical lattice constant a=3.8887(8).angs., b=3.8238(4).angs., c=11.7079.angs.. Therefore, it was examined and confin-ned that the R factor, which was compensated after analyzing the structure of superconductor resulted from this experimented data with the computer simulation, was refined to $R_{wp}$=8.83[%], $R_{P}$=6.47[%], $R_{I}$=10.08[%], $R_{F}$=7.19[%], $R_{E}$=3.76[%]. On the basis of these experimental data, the significant parameter such as the scale factor(S) and the zero point shift(Z) and FWHM value(U,V,W) were optimized as follows; S=2.0827E-3, Z=0.2146, U=4.2761E-2, V=1.7983E-2, and W=2.6768E-2.2.2.2.2.2.

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Compressive Creep Behavior of Rice Starch Gels (쌀 전분 젤의 creep 특성)

  • Hong, Seok-In;Kim, Young-Sug;Choi, Dong-Won;Pyun, Yu-Ryang
    • Korean Journal of Food Science and Technology
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    • v.24 no.2
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    • pp.165-170
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    • 1992
  • The creep behavior of gels made with $30{\sim}45%$ gelatinized rice starch was measured over a wide range of temperature. Compressive creep curves of rice starch gels conformed to a six element mechanical model consisting of one Hookean, two Voigt and one Newtonian component. The creep compliance of gels decreased with increasing starch concentrations. Among viscoelastic constants of the mechanical model, elastic modulus was mainly influenced by the change of starch concentrations. The concentration-invariant compliance curve was obtained by reduction to 38% using reduction parameter $a_{c}$. The creep compliance curves of 45% starch gels increased with temperature, which indicated that rice starch gels became softer and less rigid with increasing temperature. When the compliance at $20^{\circ}C$ was set as a reference curve, creep compliance data for 45% gels at various temperature could be superimposed as a continuous smooth curve. The apparent activation energies of 45% rice starch gels calculated by the modified WLF equation were not intrinsic, but decreased as temperature increased.

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Efficient Design and Performance Analysis of a Hardware Right-shift Binary Modular Inversion Algorithm in GF(p)

  • Choi, Piljoo;Lee, Mun-Kyu;Kong, Jeong-Taek;Kim, Dong Kyue
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.17 no.3
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    • pp.425-437
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    • 2017
  • For efficient hardware (HW) implementation of elliptic curve cryptography (ECC), various sub-modules for the underlying finite field operations should be implemented efficiently. Among these sub-modules, modular inversion (MI) requires the most computation; therefore, its performance might be a dominant factor of the overall performance of an ECC module. To determine the most efficient MI algorithm for an HW ECC module, we implement various classes of MI algorithms and analyze their performance. In contrast to the common belief in previous research, our results show that the right-shift binary inversion (RS) algorithm performs well when implemented in hardware. In addition, we present optimization methods to reduce the area overhead and improve the speed of the RS algorithm. By applying these methods, we propose a new RS-variant that is both fast and compact. The proposed MI module is more than twice as fast as the other two classes of MI: shifting Euclidean (SE) and left-shift binary inversion (LS) algorithms. It consumes only 15% more area and even 5% less area than SE and LS, respectively. Finally, we show that how our new method can be applied to optimize an HW ECC module.

A study on recognition of noise and hearing threshold among workers in a cosmetics manufacturing factory (일개 화장품 제조업체 근로자의 소음 인식도와 청력역치 조사에 관한 연구)

  • Eoh, WonSouk;Ham, WanShik;Kim, Hyunwook
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.21 no.3
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    • pp.162-167
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    • 2011
  • To identify the relationship between types of job classification (typical and atypical) and the levels of recognition of noise and the hearing threshold shift, a total of 457 workers in a cosmetic company were studied utilizing a questionnaire and the audiometric hearing test. The results were analyzed by factor analysis, t-test, and general linear model, as appropriate. The results showed that atypical workers had higher level of noise recognition but had lower levels of hearing ability, noise exposure, and the knowledge on hearing loss prevention, compared with those of typical workers. The high noise level group of typical workers showed higher threshold shift levels than that of atypical workers. Significant differences were found at 4 kHz for both ears and in right ear only for hearing threshold shift after adjusting age.

Technical Survey and Analysis of DSSS (직접대역확산방식 기술조사 및 분석)

  • Lim, You-Chol;Ma, Keun-Soo;Kim, Myung-Hwan;Lee, Jae-Deuk
    • Aerospace Engineering and Technology
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    • v.10 no.1
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    • pp.45-53
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    • 2011
  • This paper is technical review about Direct Sequence Spread Spectrum(DSSS) to apply in launch vehicle system. First, we introduce communication protocol(carrier frequency, code length, process gain, data rate, chip rate etc) about several application system using DSSS. And then, we survey and summarize the effect of doppler shift to the DSSS. The doppler shift is important error factor for PN code tracking in the fast moving system like launch vehicle. So, spread spectrum code acquisition technique for a direct sequence system in the presence of doppler effect must be investigated.

Cyclic Shift Based Tone Reservation PAPR Reduction Scheme with Embedding Side Information for FBMC-OQAM Systems

  • Shi, Yongpeng;Xia, Yujie;Gao, Ya;Cui, Jianhua
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.15 no.8
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    • pp.2879-2899
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    • 2021
  • The tone reservation (TR) scheme is an attractive method to reduce peak-to-average power ratio (PAPR) in the filter bank multicarrier with offset quadrature amplitude modulation (FBMC-OQAM) systems. However, the high PAPR of FBMC signal will severely degrades system performance. To address this issue, a cyclic shift based TR (CS-TR) scheme with embedding side information (SI) is proposed to reduce the PAPR of FBMC signals. At the transmitter, four candidate signals are first generated based on cyclic shift of the output of inverse discrete Fourier transform (IDFT), and the SI of the selected signal with minimum peak power among the four candidate signals is embedded in sparse symbols with quadrature phase-shift keying constellation. Then, the TR weighted by optimal scaling factor is employed to further reduce PAPR of the selected signal. At the receiver, a reliable SI detector is presented by determining the phase rotation of SI embedding symbols, and the transmitted data blocks can be correctly demodulated according to the detected SI. Simulation results show that the proposed scheme significantly outperforms the existing TR schemes in both PAPR reduction and bit error rate (BER) performances. In addition, the proposed scheme with detected SI can achieve the same BER performance compared to the one with perfect SI.

A Study on the Method of Health Promotion in Korean Medicine: Correlation between Night-shift Work and Yin-deficiency (건강증진을 위한 한의학적 방법론 연구 -야간근로와 음허증의 상관관계를 중심으로-)

  • Lee Sang Jae;Park Jong Bae;Lee Sun Dong;Kim Kwang Ho
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.18 no.2
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    • pp.344-348
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    • 2004
  • This study regarded irregular life styles such as nigh-shifts as contrary to the norm advised in the rules of Yang-saeng to analyze the problems brought about in relation to the concept of 'Yin-deficiency syndrome'. Yin-deficiency survey was given to sales workers on a big shopping mall in Seoul to compare the measurements of daytime workers to those of nigh-shift workers. The measurement of complaining symptoms related to Yin-deficiency of daytime workers and night-shift workers were compared, In comparison of the daytime workers and the night-shift workers, night-shift workers showed higher measurements than the daytime workers in the item of irritable fever on the five Hearts, flushing of the zygomatic region in the afternoon, tidal fever, dizziness, insomnia, yellow and scanty urination, and constipation. Especially tidal fever, insomnia, and constipation showed statistically significant difference. The total of ten items consisting of Yin-deficiency-related symptoms showed statistically significant high score in night-shift workers than the daytime workers. 'Factors for deficiency-type Heat' consisting of irritable fever on the five Hearts, flushing of the zygomatic region in the afternoon, tidal fever, and dried mouth and throat showed statistically significant high score in night-shift workers than the daytime workers. 'Accompanying factors' consisting of night sweats, emaciation, dizziness, insomnia, yellowish and scanty urination, and constipation also showed statistically and significantly high score in night-shift workers than the daytime workers. From the above results that night-shift workers show high degree of Yin-deficiency than daytime workers, and those overworking irregularly also show high degree of Yin-deficiency than those who work for adequate amount of time regularly implies that sitting up at night for work and sleeping at daytime, excessive work, and irregular life styles all function as high-risk factor for Yin-deficiency.

An Analysis on the Change Factor Based on the Industrial GRDP of 5 Gun in Chungcheongnam-do (충청남도 5개 군의 GRDP 변화요인 분석)

  • Kim, Jung Tae
    • Journal of Agricultural Extension & Community Development
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    • v.19 no.4
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    • pp.1041-1066
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    • 2012
  • This article aims to analyse the change factor of the industry in rural area. As the regional economy is consist of variety industry in local Revitalization of Rural Economy should consider the growth factor of industry. Analytical method is Shift-Share analysis, analysis data is used GRDP of the 5 target area. Analysis is showed that Agriculture, forestry and fishing is leading position. but Farm population decreased rapidly underway. Side work farmer and industry population is increasing rapidly. the Regional Economic growth inhibitory of 5 Gun is the weakness of the internal factor. especially Competition component is than industry-Mixed component. and the Growth of Agriculture, forestry and fishing is external factor. To improve the regional economy, 5 Gun must improve the fault. and the growth of Agriculture, forestry and fishing should promote the consumption of local products to as the local food system.