• Title/Summary/Keyword: Shape of Diffusion

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The effect of grain shape on grain growth behavior of oxide system during liquid phase sintering (산화물계의 액상소결에서 입자 형상이 입자성장 거동에 미치는 영향)

  • 조동희;박상엽
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.3
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    • pp.127-131
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    • 2001
  • The effect of grain shape on the grain growth behavior of oxide system was investigated as afunction of liquid content during liquid phase sintering. As a model system, the solid grains of $Al_{2}O_{3}$ and MgO were selected during liquid phase sintering, i.e. faceted shape of $Al_{2}O_{3}$ in $CaAl_{2}Si_{2}O_{8}$ liquid phase and spherical shape of MgO in $CaMgSiO_{4}$ liquid phase. The average grain size of MgO with spherical shape was decreased with increasing the liquid phase content, whereas that of $Al_{2}O_{3}$ with faceted shape was independent of liquid phase content. In the case of $Al_{2}O_{3}$ grains with faceted shape, which interfaces are expected to be atomically flat, are likely to grow by the interfacial reaction controled process. Whereas, in the case of MgO grains with spherical shape, which interface are expected to be atomically rough, are likely to grow by the diffusion controlled process.

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A convergence study of cytotoxicity evaluation of adult dentifrices (성인용 치약의 세포독성 평가의 융합적 연구)

  • Choi, Yu-Ri;Shim, Youn-Soo;Jang, Sun-Ok
    • Journal of Digital Convergence
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    • v.17 no.3
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    • pp.305-312
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    • 2019
  • This study was conducted to effect the cell activity and cytotoxicity of dentifrice. For the study, 6 kinds of general dentifrice, 3 kind of whitening dentifrice, 2 kinds of natural dentifrice and SLS(sodium lauryl sulfate) of positive control group. Immortalized human gingiva fibroblast cell was used for the study, WST test for cell activity and Agar diffusion test for cytotoxicity. Agar diffusion test showed high cytotoxicity in general dentifrice test group and whitening dentifrice test group, but low cytotoxicity in natural dentifrice test group. As a result of cell nucleus staining, cell shape and nuclear activity showed that the highest activity in natural dentifrice group, followed by whitening dentifrice group and general dentifrice group. As a result of this study, the cytotoxicity of different ingredient and according to the use to dentifrice. As a result of this study, we confirm cytotoxicity of kind and components according to the purpose of using dentifrice. Therefore, it is necessary to indicate the detailed ingredients of dentifrice for the smart choice of consumers.

Effects of Preferential Diffusion on Downstream Interaction in Premixed $H_2$/CO Syngas-air Flames (상호작용하는 $H_2$-CO 예혼합 화염에서 $H_2$선호확산의 영향에 관한 수치적 연구)

  • Oh, Sanghoon;Park, Jeong;Kwon, Ohboong
    • Journal of the Korean Society of Combustion
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    • v.17 no.3
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    • pp.17-29
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    • 2012
  • The effects of strain rate and preferential diffusion of $H_2$ on flame extinction are numerically studied in interacting premixed syngas-air flames with fuel compositions of 50% $H_2$ + 50% CO and 30% $H_2$ + 70% CO. Flame stability diagrams mapping lower and upper limit fuel concentrations at flame extinction as a function of strain rate are examined. Increasing strain rate reduces the boundaries of both flammable lean and rich fuel concentrations and produces a flammable island and subsequently even a point, implying that there exists a limit strain rate over which interacting flame cannot be sustained anymore. Even if effective Lewis numbers are slightly larger than unity on extinction boundaries, the shape of the lean extinction boundary is slanted even at low strain rate, i.e. $a_g=30s^{-1}$ and is more slanted in further increase of strain rate, implying that flame interaction on lean extinction boundary is strong and thus hydrogen (as a deficient reactant) Lewis number much less than unity plays an important role of flame interaction. It is also shown that effects of preferential diffusion of $H_2$ cause flame interaction to be stronger on lean extinction boundaries and weaker on rich extinction boundaries. Detailed analyses are made through the comparison between flame structures with and without the restriction of the diffusivities of $H_2$ and H in symmetric and asymmetric fuel compositions. The reduction of flammable fuel compositions in increase of strain rate suggests that the mechanism of flame extinction is significant conductive heat loss from the stronger flame to ambience.

Development of Oxygen Combustion Burner for Industrial Gasification and Smelting Furnace (산업용 가스화 용융로를 위한 산소 버너의 개발)

  • Bae, Soo-Ho;Lee, Uen-Do;Shin, Hyun-Dong;Kim, Soung-Hyoun;Gu, Jae-Hoi;Yoo, Young-Don
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.170-178
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    • 2005
  • Multi-hole type oxygen combustion burner was developed for industrial gasification and smelting furnace. We investigated characteristics of flame, radiation transfer, and soot emission in the convectional oxygen burner with respect to the feeding condition of fuel and oxygen. Regarding the results of the conventional burner, we designed new burners which have larger fuel consumption rate and radiation heat transfer. We changed the size and hole number and shape of the exit plane of the burner. In addition, the performance of the burner was tested with respect to the feeding condition of the fuel and air: Normal Diffusion flame(NDF) and Inverse Diffusion Flame(IDF). We investigated the flame configuration, radiation heat transfer, and soot formation by using a CCD camera, heat flux meter, and Laser Induced Incadescence(LII), respectively. The stable operating condition was obtained by the flame configuration and the flame of the burner which has dented exit plane was more stable in whole operating conditions. The characteristics of radiative heat transfer were sensitive to the feeding condition of reactants and the flame of 75% primary oxygen and 25% secondary oxygen of the IDF case shows maximum radiation heat transfer. The soot volume fraction of the flame was measured in the axial direction of the flame and the amount of soot volume fraction is proportion to the radiation heat transfer. As a result, we can get the optimal operating condition of the newly designed burner which enhances the characteristics of flame stabilization and radiation heat transfer.

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Comparison of the ICT Adoption Pattern;In the Case of Korea and the U.S.

  • Yang, Kyung-Hoon;Lee, Sang-Gun
    • 한국경영정보학회:학술대회논문집
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    • 2007.06a
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    • pp.545-550
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    • 2007
  • The aim of this paper is to find out whether there is a difference in adopting and/or diffusing the information and communication technology (ICT) between countries. If there is, what are the primary factors that keep some countries from adopting and diffusing ICT while others do? To analyze the above problem, we adopted the Unified Theory of Acceptance and Use of Technology (UTAUT) suggested by Venkatesh et al. (2003), which consists of effort expectancy, performance expectancy and social influence. We also use the innovation diffusion functions, which are known to have the S-shape and are made up of the introduction, growth, maturity and decline phases. We do not, however, consider the decline phase, because the ICT that we are considering is not believed to be in that phase. Therefore, we researched how the three factors affect adoption in the three phases. We selected the cellular phone as the ICT, because it is considered to be the most popularly used ICT and its technology has been developing rapidly. We surveyed the cellular phone adopters in Korea, and the U.S. for 15 years from 1989 to 2003. Korea, and the U.S. represent newly developed and developed countries, respectively. For the data analysis, a survival analysis was used, as it could explain the characteristics of the potential adopters or non-adopters. We found that the ICT diffusion patterns, as well as the ICT diffusion factors, of the two countries were different. Therefore, we believe that the results of our research can be used in building strategies on reducing the digital divide gaps between countries.

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Combustion Characteristics of a Gaseous Methane-Gaseous Oxygen Diffusion Flame Sprayed by a Shear Coaxial Injector (전단 동축형 인젝터를 통해 분사된 기체메탄-기체산소 확산화염의 연소특성)

  • Hong, Joon Yeol;Bae, Seong Hun;Kwon, Oh Chae;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.3
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    • pp.41-48
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    • 2017
  • The combustion characteristics of gaseous methane-gaseous oxygen, an eco-friendly bipropellant injected by shear coaxial injector, were investigated. Flame was photographed under various combustion conditions using a DSLR camera, and the characteristics of the flame shape was quantified by image post-processing. From the view point of stabilization, the diffusion flame could be divided into anchored flame regime and blow-off regime. As the oxidizer Reynolds number ($Re_o$) increased, a probability of the formation of anchored flame increased with the length of flame. The shear coaxial injector used in this experiment was found to require a large length-to-diameter ratio of combustion chamber because it formed a relatively long flame in the injection direction due to a poor mixing depending only on the momentum diffusion of two propellant jets.

Diffusion-controlled Cure Kinetics of High Performance Epoxy/Carbon Fiber Composite Systems (확산속도에 따라 한계경화도를 갖는 에폭시/탄소섬유 복합재료의 경화반응 속도 연구)

  • 박인경;금성우;이두성;김영준;남재도
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.105-112
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    • 2000
  • Using a commercial epoxy/carbon fiber composite prepreg (DMS 2224) as a model system, the cure kinetics of vitrifying thermoset system were analyzed by isothermal and dynamic-heating experiments. Focusing on the processing condition of high performance composite systems, a phenomenological kinetic model was developed by using differential scanning calorimetry (DSC) and reaction kinetics theories. The model system exhibited a limited degree of cure as a function of isothermal temperature seemingly due to the diffusion-controlled reaction rates. The diffusion-controlled cure reaction was incorporated in the development of the kinetic model, and the model parameters were determined from isothermal experiments. The first order reaction was confirmed from the characteristic shape of isothermal cure thermograms, and the activation energy wes 78.43 kJ/mol. Finally, the proposed model was used to predict a complex autoclave thermal condition, which was composed of several isothermal and dynamic-heating stages.

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Study of Diffusion-Controlled Processes. Potential Shape Dependence in One-dimension

  • Shin, Seok-Min;Shin, Kook-Joe
    • Bulletin of the Korean Chemical Society
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    • v.8 no.2
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    • pp.83-88
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    • 1987
  • The Smoluchowski equations with a linear and a parabolic potentials in one-dimensional case are solved for the reflecting boundary condition. Analytic expressions for the long-time behaviors of the remaining probabilities are obtained. These results, together with the previous result for a step potential, show the dependence of the desorption process on the form of potential. The effect of the radiation boundary condition is also investigated for three types of potentials.

The Grain Growth Mechanism of Sm123 Superconductor in Melt-Textured Growth Method (용융-응고법으로 제조된 Sm123 초전도체의 결정성장 기구)

  • 한상철;성태현;한영희;이준성;김상준
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2001.02a
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    • pp.9-12
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    • 2001
  • The microstructure evolution and the peritectic solidification of Sm$Ba_{2}$$Cu_{3}$ $O_{7-\delta}$ superconducting materials during the isothermal annealing were studied over the temperature range 1030-$1060^{\circ}C$ The faceted growth of the peritectic phase and its dependence upon Sm-diffusion in the liquid phase are discussed. A growth model is proposed to explain the growth shape of Sm123 crystals.

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Effect of bounce resonance heating on Electron Energy Distribution Function in a small Inductively Coupled Plasma

  • 정진욱;서상훈;장홍영
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.208-208
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    • 1999
  • It is found that with increasing power, the measured electron energy distribution by Langmuir probe evolves into a Druyvesteyn-like electron energy distribution in the low-pressure regime of 1mTorr in a small inductively coupled plasma. Electron bounce resonance is introduced to explain the transition of the electron energy distribution against the rf power, The energy diffusion coefficients which determine the shape of the electron energy distribution in elastic range are calculated with and without electron bounce resonance. This electron energy distribution transition is well explained by the electron bounce resonance.

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