• Title/Summary/Keyword: Sequential degradation

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Performance of a Novel Sulfonate Flame Retardant Based on Adamantane for Polycarbonate (아드만탄 기반의 새로운 설포네이트 폴리카보네이트 난연제 성능 연구)

  • Guo, Jianwei;Wang, Yueqin;Feng, Lijuan;Zhong, Xing;Yang, Chufen;Liu, Sa;Cui, Yingde
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.437-441
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    • 2013
  • A novel sulfonate flame retardant, 1,3,5,7-tetrakis(phenyl-4-sodium sulfonate)adamantane (FR-A), was successfully synthesized from 1-bromoadamantane in sequential four-step reactions involving Fiedel-Crafts phenylation, sulphonation, hydrolysis, and neutralization. The success of synthesis was confirmed by FTIR spectra, $^1H$ NMR spectra, elemental analyses and mass spectra. The effect of FR-A on the flame retardacy of polycarbonate (PC) has been studied. Limiting oxygen index (LOI) and thermogravimetric analysis (TGA) showed that this novel sulfonate flame retardant had effective flame retardancy on polycarbonate (PC). With a small amount (0.08 wt%) of FR-A, the flame retardancy of PC was improved obviously, which got to UL 94 V-0 rating. TGA and DTA curves demonstrated that the additive raised the degradation rate of PC by promoting the quick formation of an insulating carbon layer on the surface, and confirmed that the flame retardant mechanism of PC/FR-A system was similar to potassium diphenylsulfone sulfonate (KSS).

Performance Improvement of Parity Logging Scheme in RAID 5 by Eliminating Redundant Parity Image (중복 패리티 이미지 제거를 통한 RAID 5에서의 패리티 로킹 기법 성능 개선)

  • Ghil, Jun-Ho;Lee, Min-Young;Lee, Jin-Ho;Park, Myong-Soon
    • The Transactions of the Korea Information Processing Society
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    • v.2 no.4
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    • pp.543-553
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    • 1995
  • While RAID 5 disk arrays offer advantages of performance and reliability on wide variety of applications, they suffer from the performance degradation with write jobs. To reduce the effect of this problem, parity logging scheme was suggested. This scheme reduces disk busy time by transforming many small random accesses into large sequential accesses. This paper presents a new parity logging technique which prevents parity update image from redundant storing in the disk buffer and reduces parity maintenance overhead. A analytical model and several simulation results of our proposed scheme are presented.

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The Microcosm study for evaluating biobarrier application on sequential degradation of TCE products by Gasoline-Degradaing Mixed Culture

  • Lee, Jae-Sun;Lee, Si-Jin;Lee, Young-Kee;Chang, Soon-Woong
    • 한국생물공학회:학술대회논문집
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    • 2003.10a
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    • pp.440-444
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    • 2003
  • A new approach for ground water treatment combines a permeable Fe(0) barrier to breakdown higher chlorinated solvents like PCE and TCE with a down gradient aerobic biological treatment system to biotransform less chlorinated solvents, such as DCE and vinyl chloride (VC). The expected bacterial performance down gradient of an Fe(0) barrier was evaluated through laboratory batch experiments with a toluene-degrading mixed culture that cometabolically transforms cis-1,2-DCE and VC. The amount of cis-1,2-DCE (initially at 2,000 ppb) and VC (initially at 2,000 ppb) transformed was controlled by the initial toluene(20,000 ppb) concentration. VC was removed much more effectively than Cis-1,2-DCE, and a higher toluene concentration in comparison to the co-substrate concentrations was needed for complete co-substrate removal. Overall, the coupling of an Fe(0) barrier and subsequent biodegradation appears feasible for remediation of complex mixtures of chlorinated solvents and petroleum hydrocarbons in groundwater.

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Design of Sequentially-Rotated Array Antenna with Triangular Lattice (삼각형 격자를 갖는 순차 회전 배열 안테나의 설계)

  • 진경수;정치현;박병우
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.11 no.7
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    • pp.1282-1290
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    • 2000
  • The LHCP circularly polarized antenna operating at the satellite broadcast receiving band is developed by employing the sequential-rotation technique in which each truncated-corner patch square element is arranged in the triangular lattice type. Antenna designed with sequentially rotated technique of triangular lattice type has the effect of improved axial-ratio bandwidth, cross-polarization etc., and the degradation of radiation pattern can be reduced significantly by minimizing the radiation loss of feeding line structure. Characteristics of antenna designed is satisfied with specifications of array antenna for DBS that is -27 dB of side lobe level and -20 dB of cross-polarized level at $\Phi$=45$^{\circ}$ plane.

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The Changes of the Hydrogenation Properties of Zr0.9Ti0.1Cr0.7Fe1.3 Alloy Upon the Pressure Induced Hydriding-Dehydriding Cycling (수소흡수-방출 사이클에 의한 Zr0.9Ti0.1Cr0.7Fe1.3 합금의 수소화 반응 특성의 변화)

  • Lee, Jon-Ha;Lee, Jai-Young
    • Journal of Hydrogen and New Energy
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    • v.2 no.1
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    • pp.29-37
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    • 1990
  • The effect of pressure cycling of $Zr_{0.9}Ti_{0.1}Cr_{0.7}Fe_{1.3}$ on the hydrogenation properties was investigated using the P-C-Isotherm curves and hydrogen absorption rate curves in the isotherm condition. The reversible hydrogen absorption capacity was decreased about 45 % after 3300 cycles. In the case of activated sample, the rate controlling steps of hydriding reaction changed from the surface reaction to the hydrogen diffusion process through hydride phase sequentially as reaction proceeded. After 3300 cycles, the sequential change of rate controlling step was same as activated one. However, the hydrogen absorption rate significantly decreased. It is suggested that the degradation of $Zr_{0.9}Ti_{0.1}Cr_{0.7}Fe_{1.3}$ can be interpreted with the formation of $ZrFe_3$ phase at the particle surface.

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Effect of Rotary Drum on the Speciation of Heavy Metals during Water Hyacinth Composting

  • Singh, Jiwan;Kalamdhad, Ajay S.
    • Environmental Engineering Research
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    • v.18 no.3
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    • pp.177-189
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    • 2013
  • Studies were carried out on the speciation of heavy metals (Zn, Cu, Mn, Fe, Ni, Pb, Cd, and Cr) during rotary drum composting of water hyacinth (Eichhornia crassipes) for a period of 20 days. Five different proportions of cattle manure, water hyacinth and sawdust were prepared for composting. This study concluded that, rotary drum was very efficient for the degradation of organic matter as well as for the reduction of mobility and bioavailability of heavy metals during water hyacinth composting. The results from the sequential extraction procedure of heavy metals shows that rotary drum composting changed the distribution of five fractions of Zn, Cu, Mn, Fe, Ni, Pb, Cd, and Cr. The highest reduction in the bioavailability factors of Pb and Cd was observed during the process. The total concentration of Cu, Cr, and Cd was very low compared to the other metals (Zn, Mn, Fe, Ni, and Pb); however, the percentage of exchangeable and carbonate fractions of these metals was similar to other metals. These results confirmed that the bioavailability of metals does not depend on the total concentration of metals. From this study, it can be concluded that the addition of an appropriate proportion of cattle manure significantly reduced the mobile and easily available fractions (exchangeable and carbonate fractions) during water hyacinth composting in rotary drum.

Isolation and Characterization of Mucinase Complex Secreted from Vibrio parahaemolyticus

  • Jun, In-Joon;Kim, Yoon-Hee;Kim, Min-Jeong;Hwang, Ho-Soon;Lee, Tae-Ho;Cha, Jae-Ho
    • Journal of Microbiology and Biotechnology
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    • v.13 no.5
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    • pp.731-737
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    • 2003
  • Mucinase complex from V. parahaemolyticus ATCC 17802 was purified 6-fold with 0.4% yield by two sequential steps of Q-Sepharose and Superdex 200HR column chromatographies. Partially purified mucinase complex showed at least 8 times higher mucin-degrading activity than the culture filtrates. The mucinase complex also showed gelatin-and-casein-hydrolyzing activities, which demonstrates that the protein is a complex compound containing several proteases. The optimum pH and temperature of partially purified mucinase complex for mucin degradation was 8.0 and $35^{\circ}C$, respectively. The partially purified mucinase complex showed high cytotoxic activity on vero cells when examined by MTT assay and microscopic observations. Cytotoxicity was significantly increased in proportion to the concentration of the mucinase complex. Mouse experiments revealed that the jejunum, ileum. and large intestinal tissues were damaged by the injection of the mucinase complex. In particular, the reduction of the goblet cells in the large intestine was remarkable. Collectively, these data suggest that the mucinase complex partially purified from V. parahaemolyticus ATCC 17802 contributes to the adhesion and invasion of V. parahaemolyticus into the host intestinal tract.

Development of High Aperture Ratio 2.1” QVGA LTPS (Low Temperature Poly Si) LCD Using SLS (Sequential Lateral Solidification) Technology

  • Kang, Myung-Koo;Lee, Joong-Sun;Park, Jong-Hwa;Zhang, Lintao;Joo, Seung-Yong;Kim, Chul-Ho;Kim, Il-Kon;Kim, Sung-Ho;Park, Kyung-Soon;Yoo, Chun-Ki;Kim, Chi-Woo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1033-1034
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    • 2005
  • High resolution 2.1” QVGA LTPS LCD (190ppi) having high aperture ratio of 65% could be successfully developed using state-of-the-art SLS technology and active/gate storage structure. Cost effective P-MOS 6-Mask structure was used. Full gate and transmission gate circuits are integrated in the panel. The high aperture ratio was obtained by using active/gate capacitance structure, which can reduce storage capacitance area. The aperture ratio was increased to 65% from 49% of conventional gate/data capacitance structure. The brightness was increased from 180cd to 270cd without any degradation of optical properties such as contrast ratio, flicker or crosstalk.

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Some Considerations on the Problems of PSA(Pulse Sequence Analysis) as a Partial Discharge Analysis Method (부분방전 해석 방법으로 PSA(Pulse Sequence Analysis)의 문제점에 대한 고찰)

  • Kim, Jeong-Tae;Lee, Ho-Keun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.327-330
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    • 2004
  • Because of its effectiveness for the PD(partial discharge) pattern recognition, PSA(Pulse Sequence Analysis) has been considered as a new analytic method instead of conventional PRPDA(Phase Resolved Partial Discharge Analysis). However, PSA has a big problem that can misanalyze patterns in case of data missing resulting from poor sensitivity because it analyses the correlation between sequential pulses, which leads to hesitate to apply it to on-site. Therefore, in this paper, the problems of PSA such as data missing and noise adding cases were investigated. For the purpose, PD data obtained from various defects including noise adding data were used and analysed, The result showed that both cases can cause fatal errors in recognizing PD patterns. In case of the data missing, the error depends on the kinds of defect and the degree of degradation. Also, it could be noticed that the error due to adding noises was larger than that due to some data missing.

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Probabilistic Fiber Strength of Composite Pressure Vessel (복합재 압력용기의 확률 섬유 강도)

  • 황태경;홍창선;김천곤
    • Composites Research
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    • v.16 no.6
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    • pp.1-9
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    • 2003
  • In this paper, probabilistic failure analysis based on Weibull distribution function is proposed to predict the fiber strength of composite pressure vessel. And, experimental tests were performed using fiber strand specimens, unidirectional laminate specimens and composite pressure vessels to confirm the volumetric size effect on the fiber strength. As an analytical method, the Weibull weakest link model and the sequential multi-step failure model are considered and mutually compared. The volumetric size effect shows the clearly observed tendency towards fiber strength degradation with increasing stressed volume. Good agreement of fiber strength distribution was shown between test data and predicted results for unidirectional laminate and hoop ply in pressure vessel. The site effect on fiber strength depends on material and processing factors, the reduction of fiber strength due to the stressed volume shows different values according to the variation of material and processing conditions.