• Title/Summary/Keyword: Separation technology

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Encapsulation of 2,4-Dihydroxybenzophenone into Dodecylbenzenesulfonate Modified Layered Double Hydroxide for UV Absorption Properties

  • Li, Shifeng;Shen, Yanming;Liu, Dongbin;Fan, Lihui;Wu, Keke
    • Bulletin of the Korean Chemical Society
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    • v.35 no.2
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    • pp.392-396
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    • 2014
  • New organic-inorganic composite of 2,4-dihydroxybenzophenone (BP-1) encapsulation into dodecylbenzenesulfonate (DBS) modified layered double hydroxide (LDH) was successfully prepared. The surface, structural, thermal and absorption properties of the BP-1/DBS-LDH nanohybrid was characterized by BET analysis, scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TG) and diffuse reflectance UV-Vis absorbance spectra (DRUV-vis). The interlayer configuration of composite and the adsorption mechanism of BP-1 on MgAl-DBS-LDH were discussed. It was suspected that DBS anions located in the form of monolayer arrangement with a $75^{\circ}$ anti parallel angle between dodecylbenzenesulfonate chain axis. The diffuse reflectance UV-Vis absorbance results revealed that the UV absorbing wavelength of BP-1/DBS-LDH evidently extends to about 400 nm, which shows that the BP-1/DBS-LDH has the potential application as a UV absorber.

The Inhibition Effect of Phase Separation by addition of MTBE and Inhibitors in the Gasohol (MTBE 및 상분리 억제제에 의한 가소홀의 상분리 억제 효과)

  • Lee, Jin-Hui;Kim, Mi-Hyun;Lee, Jin-Hee;Ahn, Moon-Sung;Won, Jin-Ok;Han, Geu-Seong;Seo, Dong-Ho;Lee, Moon-Young
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.2
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    • pp.252-256
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    • 2008
  • We investigated phase separation by adding different concentrations of MTBE, to the mixtures of naphtha, ethanol and water. The phase separation temperatures of the Naphtha-Ethanol-Water solutions have dropped when the concentration of MTBE increases more. When adding IPA and IBA to the solutions of Gasoline-Ethanol and Gasoline base-Ethanol individually, IBA shows lower temperatures of phase separation than IPA, and it shows synergistic effect when mixtures of IPA and IBA is applied.

Quadrotor wake characteristics according to the change of the rotor separation distance (로터 간격에 따른 쿼드로터의 후류특성 변화 연구)

  • Lee, Seungcheol;Chae, Seokbong;Kim, Jooha
    • Journal of the Korean Society of Visualization
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    • v.17 no.3
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    • pp.46-51
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    • 2019
  • Rotor wake interaction must be considered to understand the quadrotor flight, and the rotor separation distance is an important parameter that affects the rotor wake interaction. In this study, the wake characteristics were investigated with varying the rotor separation distance. The velocity field in the rotor wake was measured using digital PIV for hovering mode at Re = 34,000, and the wake boundaries from the inner and outer rotor tips were quantitatively compared with varying the rotor separation distance. The symmetric rotor-tip vortex shedding about the rotor axis was found at a large rotor separation distance. However, the wake boundary became more asymmetric about the rotor axis with decreasing the rotor separation distance. At the minimum rotor separation distance, in particular, a faster vortex decay was observed due to a strong vortex interaction between adjacent rotors.

PERMEATION OF CARBON DIOXIDE AND NITROGEN GASES THROUGH POLY(AMIDE-IMIDE)/POLYURETHANE AND POLYCARBONATE/POLYURETHANE BLEND MEMBRANES

  • Kim, Min-Joung;Sea, Bong-Kuk;Park, You-In;Youm, Kyung-Ho;Lee, Kew-Ho
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.87-89
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    • 2003
  • Thermoplastic polyurethane(PU)-based blend membranes were prepared by the solvent evaporation process. The gas sorption, diffusion, and permeation properties of PU-based blend membranes have been studied. The morphology of PU-based blend membranes was investigated by SEM. The result showed that phase separation occurred with increasing blend ratio. $CO_2$ permeation behaviors of blend membranes were affect by blend composition. Thermoplastic polyurethane(PU)-based membranes showed high $CO_2$ permeation and $CO_2$/$N_2$ selectivity of the blend membrane was improved with increasing the blend ratio.

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Fabrication and Simulation of Fluid Wing Structure for Microfluidic Blood Plasma Separation

  • Choe, Jeongun;Park, Jiyun;Lee, Jihye;Yeo, Jong-Souk
    • Applied Science and Convergence Technology
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    • v.24 no.5
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    • pp.196-202
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    • 2015
  • Human blood consists of 55% of plasma and 45% of blood cells such as white blood cell (WBC) and red blood cell (RBC). In plasma, there are many kinds of promising biomarkers, which can be used for the diagnosis of various diseases and biological analysis. For diagnostic tools such as a lab-on-a-chip (LOC), blood plasma separation is a fundamental step for accomplishing a high performance in the detection of a disease. Highly efficient separators can increase the sensitivity and selectivity of biosensors and reduce diagnostic time. In order to achieve a higher yield in blood plasma separation, we propose a novel fluid wing structure that is optimized by COMSOL simulations by varying the fluidic channel width and the angle of the bifurcation. The fluid wing structure is inspired by the inertial particle separator system in helicopters where sand particles are prevented from following the air flow to an engine. The structure is ameliorated in order to satisfy biological and fluidic requirements at the micro scale to achieve high plasma yield and separation efficiency. In this study, we fabricated the fluid wing structure for the efficient microfluidic blood plasma separation. The high plasma yield of 67% is achieved with a channel width of $20{\mu}m$ in the fabricated fluidic chip and the result was not affected by the angle of the bifurcation.

Applications and a View of Gas Separation by Membranes in Japan (일본에서의 기체분리막의 현황 및 응용)

  • Nakagawa, Tsutomu
    • Membrane Journal
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    • v.4 no.1
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    • pp.9-29
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    • 1994
  • The development of separation technology is an important research subject as is clear from its role in the Japanese government's research and development program for basic technology for the next generation(1981~1990). Japan is poor not only in mineral resources but also in energy resources and if a sudden change occurs in oil producing facility or an accident occurs in a nuclear power plant, then energy policy must undergo changes and economic foundations may collapse. Japan has already experienced this. Although, oil prices are stable at present and Japan can import oil at low cost due to the yen appreciation, Japan needs to promote development work for any new energy crisis that may come in the future. This has been the motive for gas separation membrane development in Japan. The study of gas permeation through polymer membranes, which is the basis for membranes for gas separation, at Japanese universities began many years ago, but interest in membranes for gas separation was aroused mainly by the Government. The development of gas separation membranes in Japan started with membranes for oxygen separation on an industrial scale.

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An Introduction to Energy-Based Blind Separating Algorithm for Speech Signals

  • Mahdikhani, Mahdi;Kahaei, Mohammad Hossein
    • ETRI Journal
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    • v.36 no.1
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    • pp.175-178
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    • 2014
  • We introduce the Energy-Based Blind Separating (EBS) algorithm for extremely fast separation of mixed speech signals without loss of quality, which is performed in two stages: iterative-form separation and closed-form separation. This algorithm significantly improves the separation speed simply due to incorporating only some specific frequency bins into computations. Simulation results show that, on average, the proposed algorithm is 43 times faster than the independent component analysis (ICA) for speech signals, while preserving the separation quality. Also, it outperforms the fast independent component analysis (FastICA), the joint approximate diagonalization of eigenmatrices (JADE), and the second-order blind identification (SOBI) algorithm in terms of separation quality.

Recovery of Diatom Skeleton from Low Grade Diatomaceous Earth by Shape Separation Method Using Fluid Field

  • Lee, Minyong;Yoon, Ki-Byung;Shigehisa Endoh
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.349-352
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    • 2001
  • Shape separation method - a separation process which utilizes the fact that particles of different shape behave differently in force fields- is regarded as an useful measure for recycling, mineral processing, upgrading powdered material and so on. In this study, a trial was given to shape separation method using fluid field to recover pure diatom skeleton - which is thought to have many uses in itself and potential for various applications -from low grade diatomaceous earth of southeastern part of the Korean Peninsula. The striking difference of shape between diatom skeleton and other minerals like clay and quartz made it natural to choose shape separation method. Considering the size of particles to be separated, among many possible methods of shape separation, hydrodynamic field using hydrocyclone was adopted. And it resulted in recovery of pure diatom skeleton with high purity

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A Study on the Standard Criteria of Solid Particle Separation Test for Marine Centrifugal Purifier (선박용 정유기 고형분 분리 성능시험 규격기준에 관한 연구)

  • Jeong, Sang-Hu
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.8
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    • pp.1028-1034
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    • 2007
  • In order to establish a criteria of solid particle separation performance test on marine centrifugal purifier at factory acceptance test, an investigation had been done on criteria of test standards, regulations and test specifications of purifier manufactures. KS V 7836, fuel oil and lubricating oil purifiers for marine use-centrifugal type, the criteria of solid particle separation is studied in the point of reality, restricts and analysis method. It is proposed that a reasonable criteria and analysis method should be adopted, and the current criteria shall be revised to adequate levels considering reasonable basis and industrial technology levels. Also, the test analysis conceptions, separation efficiency method and particle size restriction method, are reviewed to fulfil separation performance test for marine centrifugal purifiers.

Simulated Moving Bed [SMB] (모사 이동층 크로마토그래피)

  • Lee Chong-Ho;Koo Yoon-Mo
    • KSBB Journal
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    • v.20 no.3
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    • pp.192-196
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    • 2005
  • Chromatography has been a method of choice in the separation of complex biological mixtures for the analytical purpose in particular for the last half of century. In current years, chromatographic method extends its use to the preparative separation where the productivity per resin amount and solvent use become a matter of concern. Recently, simulated moving bed (SMB) method which claims high separation efficiency of the ideal counter-current moving bed chromatography has become a workhorse of preparative separation. SMB technology was developed in the early 1960s for large-scale hydrocarbon separation by UOP and approximately 120 Sorbex units have been licensed to date. Recently, SMB separation technology has been successfully extended from hydrocarbons and sugars to fine chemicals, particularly biochemicals, from laboratory to pilot to production plant. In this paper, the current status of SMB and its modifications were reviewed.