• Membrane Journal
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• v.24 no.5
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• pp.341-349
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• 2014

Molecular dynamics (MD) computer simulation is a very useful tool to calculate the trajectory and velocity of particles (generally, atoms), and thus to analyze the various structures and kinetic properties of atoms and molecules. For gas separation membranes, MD has been widely used for structure analysis of polymers such as free volume analysis and conformation search, and for the study of gas transport behavior such as permeability and diffusivity. In this paper, general methodology how to apply MD on gas separation membranes will be described and various related researches will be introduced.

• Clean Technology
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• v.13 no.1 s.36
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• pp.79-84
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• 2007

Separation of ethylene from ethane and propylene from propane have been conducted using facilitated olefin transport membrane with SPEEK-Ag (Ag substituted sulfonated poly(ether ether ketone)). SPEEK was prepared by the sulfonation of PEEK using cone. $H_2SO_4$ and the reaction time affected the degree of sulfonation (DS) of the resulting SPEEK. SPEEK-Ag composite membrane was formed by soaking SPEEK in the polyester support into the Ag salt solution. With increasing the concentration of SPEEK in MeOH, the thickness of SPEEK on the polyester increased. The selectivity and the flux of SPEEK-Ag membrane for the separation of ethylene/ethane and propylene/propane were changed by the thickness of SPEEK layer on the top of polyester support. The anion of silver salt also affects the membrane performance.

• Applied Chemistry for Engineering
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• v.28 no.4
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• pp.410-419
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• 2017

Since the beginning of the water shortage by disasters such as global warming, environmental pollution, and drought, development of original technology and studies have been undergone to increase availability of water resources. Among them the water treatment separation membrane technology is an environmentally friendly process that does not use chemicals and shows better water quality improvement effect than conventional physicochemical and biological processes. The water treatment membrane can be applied to various fields such as waste water treatment, water purification treatment, seawater desalination, ion exchange process, ultrapure water production, organic solvent separation and water treatment technology, and it tends to expand the range of application. In the core technology of water treatment membrane, researches are being actively carried out to develop a separation membrane of better performance by controlling the pore size to adjust the separation performance. In this review, we summarized the frequency of announcement by country and organization through the technological competitiveness evaluation of patents and papers of the water separation membrane. Also, we evaluated the results from membrane research for waste water treatment, water purification treatment, seawater desalination, ion exchange process and present the future direction of research.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.1
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• pp.13-20
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• 2011

$SO_2$ has been absorbed and separated selectively by an ionic liquid from $SO_2/O_2$ mixture decomposed from sulfuric acid during the thermochemical SI cycle for the water splitting. In order to design and operate high pressure $SO_2/O_2$ separation system, the solubility of $SO_2$ in [EMIm]$EtSO_4$ (1-ethyl-3-methylimidazolium ethylsulfate) has been measured by Magnetic Suspension Balance at high pressure and temperature. Based on the measured solubility, a pressurized separation system was set up and operated. 194 L/h of $SO_2$($SO_2:O_2$=0.65:1) has been separated with 99.85% of $O_2$ at the vent of absorption tower, which is 22.7% of the theoretically ideal capacity of the system. This discrepancy results from the reduced contact between the gaseous $SO_2$ and the ionic liquid. Increased $SO_2$ supply, scale-up of the absorption column, and a faster ionic liquid circulation speed were suggested to improve the separation capacity.

• Korean Journal of Materials Research
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• v.28 no.7
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• pp.417-422
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• 2018

The stereotype of flexible MOFs(Amino-MIL-53) and carbonized porous carbon prepared from renewable resources is successfully synthesized for $CO_2$ reduction application. The textural properties of these microporous materials are investigated, and their $CO_2$ storage capacity and separation performance are evaluated. Owing to the combined effects of $CO_2-Amino$ interaction and its flexibility, a $CO_2$ uptake of $2.5mmol\;g^{-1}$ is observed in Amino-MIL-53 at 20 bar 298 K. In contrast, $CH_4$ uptake in Amino-MIL-53 is very low up to 20 bar, implying potential sorbent for $CO_2/CH_4$ separation. Carbonized samples contain a small quantity of metal residues(K, Ca, Mg, S), resulting in naturally doped porous carbon. Due to the trace metal, even higher $CO_2$ uptake of $4.7mmol\;g^{-1}$ is also observed at 20 bar 298 K. Furthermore, the $CH_4$ storage capacity is $2.9mmol\;g^{-1}$ at 298 K and 20 bar. To evaluate the $CO_2$ separation performance, the selectivity based on ideal adsorption solution theory for $CO_2/CH_4$ binary mixtures on the presented porous materials is investigated.

• Journal of Engineering Education Research
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• v.20 no.4
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• pp.3-11
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• 2017

In this study, more than 2,500 cases using TRIZ methodology for 10 years from 2006 to 2016 in S company were analyzed to identify which TRIZ tools have been used for solving field problems. In the previous studies, some attempts were made to analyze the utilization of TRIZ tools, but all of them were based on very limited surveys or cases. The results of this study show that 40 inventive principles were most used, followed by separation principles, standard solutions, trimming, modeling using little people, patterns of evolution, ARIZ and Effects. In addition, detailed analysis were performed for widely used tools such as 40 inventive principles, separation principles, standard solutions, etc. The analysis would be a useful guide for the study and application of TRIZ tools in industry.

• Carbon letters
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• v.16 no.3
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• pp.183-191
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• 2015

Gas transport through graphene-derived membranes has gained much interest recently due to its promising potential in filtration and separation applications. In this work, we explore Kr-85 gas radionuclide sequestration from natural air in nanoporous graphene oxide membranes in which different sizes and geometries of pores were modeled on the graphene oxide sheet. This was done using atomistic simulations considering mean-squared displacement, diffusion coefficient, number of crossed species of gases through nanoporous graphene oxide, and flow through interlayer galleries. The results showed that the gas features have the densest adsorbed zone in nanoporous graphene oxide, compared with a graphene membrane, and that graphene oxide was more favorable than graphene for Kr separation. The aim of this paper is to show that for the well-defined pore size called P-7, it is possible to separate Kr-85 from a gas mixture containing Kr-85, O₂ and N₂. The results would benefit the oil industry among others.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.3
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• pp.144-150
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• 2008

This research aims to develop parts for advanced fuel/oil filtering re-circulation applicable to this kind of regulation proof engines. These parts can playa role of converting traditional air emission type crankcase into recovery type crankcase so that the engine can deal with environmental regulations, which do not allow minimal amount of toxic gas discharge. For the experiment, test method and specially made testing equipment are prepared. The results showed that oil separation efficiency of the cone type CCV(Crank Case Ventilation) system was higher than one of cylinder type both in bench test and in engine.

• Proceedings of the Membrane Society of Korea Conference
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• 1994.06a
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• pp.33-43
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• 1994

It is the purpose of this paper to review the recent developments and future trends in various membrane processes, which will result in energy savings. Historically, there was a long period of academic curiosity in membrane research covering from gas separation to reverse osmosis. With advent of asymmetric membrane technology, many membrane processes proved to be energy efficient than the conventional separation methods. Thus, membrane technology has gained wide acceptance from many sectors of industry. The commercial sale of membranes is still modest compared to the major technologies, but it is one of the fastest growing industries. Recently the U.S.Department of Energy conducted a study (1) to evaluate and prioritize research needs in the membrane separation industry in order to foster and better support the deveolpment of energy-efficient new technologies. The National Science Foundation (U.S.A.) did also do a similar investigation. Both agencies have arrived neary at the same conclusion, that is, membrane separations can offer many new and alternative methods of separations that are more energy efficient than existing processes. This paper is largely based on these findings.

• Macromolecular Research
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• v.13 no.2
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• pp.162-166
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• 2005