• Title/Summary/Keyword: Separation ratio

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Separation of $Sr^{2+}$ Ion from Seawater by Liquid Membrane Permeator with Two Micro-Porous Films (지지막을 이용한 액막 추출기에 의한 합성해수 중의 $Sr^{2+}$ 이온 분리)

  • 주창식;이회근;정갑섭
    • Journal of Environmental Science International
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    • v.9 no.6
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    • pp.517-522
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    • 2000
  • Separation of strontium ion from synthetic seawater in the contained liquid membrane permeator with two micro-porous films was performed. The permeator consisted of a liquid membrane and two cells for aqueous solutions. The liquid membrane consisted of $D_2EHPA(di-2-ethylhexy1-phosphoric acid)$ and DCH18C6 (dicyclohexano-18-crown-6),diluted to 30 vol% with kerosine and was trapped between two micro-porous hydrophilic films. This liquid membrane separated two aqueous solutions, one of which was synthetic seawater and the other of which was the stripping solutions consisting of 1mol/L $H_2SO_4$ solution. The effects of various operating parameters on the extraction rate and equilibrium extraction ratio of strontium ion from synthetic seawater were experimentally examined. The addition of DCH18C6 to the $D_2EHPA$ solution caused synergy effect on the extraction of strontium ion. The permeator extracted strontium ion from synthetic seawater effectively with high membrane life time.

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Molecular Dynamics Study on the Binary Collision of Nanometer-Sized Droplets of Liquid Argon

  • Chun, In-Beom;Ha, Man-Yeong;Jang, Joon-Kyung;Yoon, Hyun-Sik
    • Bulletin of the Korean Chemical Society
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    • v.32 no.6
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    • pp.2027-2031
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    • 2011
  • Molecular dynamics simulation is used to study the binary collisions of nanometer-sized droplets of argon in the presence of a surrounding gas. By systematically varying the droplet size, the impact parameter and the velocity of collision, the outcome of such collisions were examined and they can be classified into coalescence, separation and shattering. If one of the colliding droplets is half or less than the other in diameter, a shattering is not possible to occur. The threshold of impact parameter for a given separation was studied by adjusting the Weber number. Overall nanoscale droplets were more likely to coalesce than the macroscopic sized ones due to their high surface-to-volume ratio.

Structural and Thermal Characteristics of Silk Fibroin/PHEMA Blend Films (견피브로인/Poly(2-hydroxyethyl methacrylate) 브렌드 필름의 구조 및 열적 특성)

  • 엄인철;권해용;박영환
    • Journal of Sericultural and Entomological Science
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    • v.42 no.1
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    • pp.42-47
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    • 2000
  • Structural and thermal characteristics of silk fibroin/poly(2-hydroxyethyl methacrylate)(PHEMA) blend films were investigated using FTIR, X-ray diffractometer, differential scanning calorimeter, thermogravimeter and scanning electron microscope. FTIR spectra showed that the conformation of silk fibroin prepared by dissolving in formic acid was $\beta$-sheet, which did not affected by blending with PHEMA. The X-ray diffraction patterns also showed that individual crystalline structure of silk fibroin and PHEMA was not affected for the blend films. The initial thermal decomposition temperature of silk fibroin/PHEMA blend film tends to be higher than either of silk fkbroin or PHEMA. Thermal stability of both polymers, more notably PHEMA, can be improved by blending two components. As a result of SEM observation, the phases separation for silk fibroin/PHEMA blend films occured regardless of blend ratio ; continuous and dispersed phase were silk fibroin and PHEMA component, respectively.

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Efficiency Evaluation of the Unconditional Maximum Likelihood Estimator for Near-Field DOA Estimation

  • Arceo-Olague, J.G.;Covarrubias-Rosales, D.H.;Luna-Rivera, J.M.
    • ETRI Journal
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    • v.28 no.6
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    • pp.761-769
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    • 2006
  • In this paper, we address the problem of closely spaced source localization using sensor array processing. In particular, the performance efficiency (measured in terms of the root mean square error) of the unconditional maximum likelihood (UML) algorithm for estimating the direction of arrival (DOA) of near-field sources is evaluated. Four parameters are considered in this evaluation: angular separation among sources, signal-to-noise ratio (SNR), number of snapshots, and number of sources (multiple sources). Simulations are conducted to illustrate the UML performance to compute the DOA of sources in the near-field. Finally, results are also presented that compare the performance of the UML DOA estimator with the existing multiple signal classification approach. The results show the capability of the UML estimator for estimating the DOA when the angular separation is taken into account as a critical parameter. These results are consistent in both low SNR and multiple-source scenarios.

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Development of the Continuous and Instantaneous Light liquid-Heavy liquid Centrifugal Separator using Density Difference (밀도 차를 이용한 경액과 중액의 연속 순간 원심분리기 개발)

  • 김영환;윤지섭;정재후;홍동희;박기용
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2001.04a
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    • pp.655-659
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    • 2001
  • Resident time of the continuous and Instantaneous centrifugal separator using that separates the light and heavy liquids by use of density difference is the orptical factor that affects significantly the chemical metial extraction and the productivity in the chemical and mechanical process. In this paper, the overflow of the device is investigated under consideration of the relationships between inclination angle of liquid feeding screw and the centrifugal force. From the design of the length of a centrifugal separator, the radiuses of rotor and housing, theoretical formulation on the contact radius of separation weir is established through the experiments. From the experiments, it is identified that how much the capacity of inlet impeller and the emulsion phenomenon depend on the screw angle of inlet impeller. Also, we investigate the separation condition and the resident times that are functions of the phase ratio and density.

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Perturbation Analysis of Stokes Flow in Porous Medium (다공성 매질의 내부유동에 관한 섭동해석)

  • Seong, Kwanjae
    • Journal of Korean Society on Water Environment
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    • v.21 no.4
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    • pp.393-397
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    • 2005
  • In this study, flow in a porous medium is analyzed using a computer-extended perturbation series solution. The flow is modelled as a creeping flow in a periodically constricted channel. The channel walls have a sinusoidally varying width and the flow is analyzed in terms of its vorticity and stream functions in the Stokes flow regime. The perturbation series in terms of a small parameter, average width to length ratio, is extended with a computer resulting in purely asymptotic series and Pade summation is used to obtain final results. Resulting flow shows flow separations in the widening section and immobile zones in the widest section of the flow regime with reattachment in the narrowing section. Analysis of the flow separation phenomena resulted in a correlation between the two geometric parameters of the channel walls to predict the onset of flow separation in the Stokes flow regime.

Solvent Extraction of Copper and Nickel from Manganese Nodule Leachate by LIX 84 (망간단괴 침출액으로부터 LIX 84에 의한 구리, 니켈의 용매추출)

  • Lee, Jae-Jang;Roh, Beom-Sik
    • Journal of Industrial Technology
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    • v.19
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    • pp.189-195
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    • 1999
  • A study on the separation Cu, Ni, and Co was carried out using LIX 84 leachate, chelate extractant. For this test, artificial test solution was prepared by varing concentrations of Cu, Ni, Co, $(NH_4)_2CO_3$ and $(NH_4)_2SO_4$. It found that pH of the solution was very important factor for the separation of nickel from copper. The results showed that nickel was effectively extracted from copper by using LIX 84 at pH 1.0 to 1.2. The volume ration or organic to aqueous phases was 1.0. According to the McCabe-Thiele diagram, the extraction rate of copper was 99 percents at the equal ratio of organic to aqueous phase in three stages.

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Hydrogen Prodution by Sulfur Thermochemical Water Splitting Cycle: Part 1. H2O-SO2-I2 Reaction and Separation (황 - 요오드의 열화학적 물분리에 의한 수소제조연구 Part I. 물-이산화황-요오드 반응 및 분리)

  • Lee, K.I.;Min, B.T.;Kwon, S.G.;Kang, Y.H.
    • Transactions of the Korean hydrogen and new energy society
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    • v.1 no.1
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    • pp.40-47
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    • 1989
  • The sulfur-iodine thermochemical water splitting process of GA(General atomic) cycle was studied to produce hydrogen from water by $H_2-I_2-SO_2$ reactions. The experimental scale was 500g based on iodine. The reaction took 100 minutes, products could be separated two liquid phases due to their density difference:HI solution had a density of 2.39~2.61g/cc, and $H_2SO_4$ solution had 1.37~1.38g/cc. The condition of reaction was when weight ratio of $I_2/H_2O$ was 2/1 resulting in good phase separation and productivity.

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Surface Conductance Modulation of Single-Walled Carbon Nanotubes and Effects on Dielectrophoresis (단일벽 탄소나노튜브의 표면 전도도 조절 및 유전영동에 대한 영향)

  • Hong Seung-hyun;Jung Se-hun;Kim Young-jin;Choi Jae-bong;Baik Seunghyun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.2 s.245
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    • pp.179-186
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    • 2006
  • Dielectrophoresis has received considerable attention for separating nanotubes according to electronic types. Here we examine the effects of surface conductivity of semiconducting single-walled carbon nanotubes (SWNT), induced by ionic surfactants, on the sign of dielectrophoretic force. The crossover frequency of semiconducting SWNT increases rapidly as the conductivity ratio between the particle and medium increases, leading to an incomplete separation of ionic surfactant suspended SWNT at an electric field frequency of 10 MHz. The surface charge of SWNT is neutralized by an equimolar mixture of anionic surfactant sodium dodecyl sulfate (SDS) and cationic surfactant cetyltrimenthylammonium bromide (CTAB), resulting in negative dielectrophoresis of semiconducting species at 10 MHz. A comparative Raman spectroscopy study shows a nearly complete separation of metallic SWNT.

The measurement of capacitance of W/O type emulsified fuel using by capacitance sensor (정전용량센서를 이용한 W/O형 유화연료의 정전용량 측정)

  • Cho, Seong-Cheol;Oh, Yang-Hwan;Im, Seok-Yeon
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.4
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    • pp.377-382
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    • 2007
  • We designed capacitance sensor in order to examine characteristics of W/O type emulsified fuel, so it concluded the following conclusions. The capacitance value of emulsified fuel, using with capacitance sensor, increases as water content increases due to the coalescence. When surfactant increases, the capacitance value decreases, the condition of W/O type emulsified fuel was maintained stably. There was revealed the capacitance value difference of W/O type emulsified fuel in in according to water content. We checked the phase separation of emulsified fuel with the capacitance value difference. The surfactant(HLB=5.4) had better stable condition than surfactant(HLB=4.3). Also, we confirmed that two mixture surfactants were better than one surfactant.