• Title/Summary/Keyword: Sensitizing

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ABS 수지상의 화학도금에서의 최적 Eteching 조건에 관한 연구

  • 김원택;이인배
    • Journal of the Korean institute of surface engineering
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    • v.5 no.2
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    • pp.1-4
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    • 1972
  • We have studied about the optimum chemical etching and sensitizing conditions of the plating on plastics. As specimen 'Mitzubishi Nobren MM2A' was used. The results were as follow. 1) The optimum chemical etching conditions. Etched the specimens for $10{\sim}40$ minutes at $70{\sim}80^{\circ}C$ with the etching solution of table 1, and for $10{\sim}15$ minutes at $65{\sim}70^{\circ}C$ with the etching solution of table 2 Table 1. Etching solution (I) Composition : $H_2SO_4(95%)-Component : 250 ml, Composition : $H_3PO_4(85%)$ - Component : 75ml, Composition : $K_2Cr_2O_7$ - Component : 12.5g, 2) The optimum sensitizing conditions. Sensitized the specimens for $60{\sim}90$ seconds at $25^{\circ}C$ with the sensitizing solution of table 3 Table 2. Etching solution (II) Composition : $H_2SO_4(95%)$ - Component : 22.5ml, Composition : $H_3PO_4(85%)$ - Component : 15ml, Composition : $CrO_3$ - Component : 105g, Composition : Water - Component : 150 ml, Table 3. Sensitizing solution Composition : $SnCl_2$ - Component : 9g, Composition : HCl(35%) - Component : 36ml, Composition : Water - Component : 300 ml

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Photovoltaic Effect of Polymer Solar Cells Doped with Sensitizing Dye (감광성 염료를 도핑한 고분자 태양 전지 소자 연구)

  • Yun, Soo Hong;Park, Jae Woo;Huh, Yoon Ho;Park, Byoungchoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.3
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    • pp.252-256
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    • 2013
  • We introduced sensitizing dyes into the bulk-heterojunction (BHJ) photovoltaic (PV) layer of polymer solar cells (PSCs). The sensitizing dyes doped were Bis(tetra butyl ammonium) cis-dithio cyanato bis(2,2'-bipyridine-4-carboxylicacid-4'-carboxylate) ruthenium (II) (N719 dye) and the BHJ PV layer used was made of poly (3-hexylthiophene) (P3HT) and phenyl $C_{61}$-butyric acid methyl ester (PCBM). It was found that the N719 dyes increase the photovoltaic performance, i.e., increasing open-circuit voltage and short-circuit current density with improved fill factor. For the P3HT:PCBM PV cells doped with the N719 dyes (0.24 wt%), an increase in power conversion efficiency of 4.0% was achieved, compared to that of the control cells (3.6%) without the N719 dyes.

The Synthesis of Sensitizing Dye for Photographic Emulsion (사진유제용 증감색소의 합성)

  • Kim, Yeoung-Chan;Kang, Tai-Sung;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.2
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    • pp.5-11
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    • 1995
  • In the study, sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-5-phenyl-benzoxazolium(inner salt) with ortho-ester in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^{1}H$-NMR spectrometer, TGA and DSC. Therefore, it was concluded that benzoxazolo carbocyanine dye can be used as green-sensitizing dye for the spectral sensitization of photographic emulsion.

Corrosion and Corrosion Fatigue Characteristics of Artificially Sensitized STS 304 (STS304 열화재의 부식및 부 식피로특성)

  • Han, Ji-Won;Bae, Dong-Ho
    • Journal of the Korean Society of Safety
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    • v.25 no.6
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    • pp.28-33
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    • 2010
  • Stainless steel is useful material for various industrial facilities such as the nuclear and steam power plant and the heavy chemical industry due to its good corrosion resistance and mechanical properties. However, it has also a large problem that is sensitized in the welding process and its corrosion resistance and mechanical properties decreases by sensitization. Thus, corrosion and corrosion fatigue characteristics of artificially sensitized austenitic STS304 were investigated through the EPR test and corrosion fatigue test. Obtained results are as follows: 1) According to the sensitizing period increase, Cr deficiency layer is linearly expanded. 2) Degree of sensitization(Ia/Ir) proportionally increased with sensitizing period. However, after 4hrs, it showed constant value. 3) Cr-carbide($Cr_{23}C_6$) in the grain boundary increased as sensitizing period increases until six hours. 4) corrosion fatigue strength of sensitized STS304 were remarkably reduced compare to non-sensitized ones.

Experimental Allergic Contact Dermatitis in the Guinea Pig (기니픽에 있어서 실험적(實驗的) 앨러지성(性) 접촉성(接觸性) 피부염(皮膚炎))

  • Lee, Chai-yong;Lee, Chung-gil;Lee, Ju-mook
    • Korean Journal of Veterinary Research
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    • v.24 no.2
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    • pp.169-171
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    • 1984
  • An expeliment was carried out to measure the cellular immune response in guinea pigs by sensitizing the animals with 2, 4-dinitrochlorobenzene(DNCB). The guinea pigs could be sensitized with one application of DNCB. The sensitizing and challenge dose was standardized. The histological response was characteristic of a delayed hypersensitivity reaction.

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The Synthesis of Naphthothiazolo Carbocyanine Dye (Naphthothiazolo Carbocyanine 증감색소의 합성)

  • Kim, Yeoung-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.1
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    • pp.31-39
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    • 1996
  • In this study, sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-4, 5-naphthothiazolium(inner salt) with triethyl orthoformate in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^1H-NMR$ spectrometer, TGA and DSC. Therefore, it was concluded that naphthothiazolo carbocyanine dye can be used as red-sensitizing dye for the spectral sensitization of photographic emulsion.

Curcumin Induces Apoptosis in Pre-B Acute Lymphoblastic Leukemia Cell Lines Via PARP-1 Cleavage

  • Mishra, Deepshikha;Singh, Sunita;Narayan, Gopeshwar
    • Asian Pacific Journal of Cancer Prevention
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    • v.17 no.8
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    • pp.3865-3869
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    • 2016
  • Curcumin, a polyphenolic compound isolated from the rhizomes of an herbaceous perennial plant, Curcuma longa, is known to possess anticancerous activity. However, the mechanism of apoptosis induction in cancers differs. In this study, we have (1) investigated the anticancerous activity of curcumin on REH and RS4;11 leukemia cells and (2) studied the chemo-sensitizing potential of curcumin for doxorubicin, a drug presently used for leukemia treatment. It was found that curcumin induced a dose dependent decrease in cell viability because of apoptosis induction as visualized by annexin V-FITC/ PI staining. Curcumin-induced apoptosis of leukemia cells was mediated by PARP-1 cleavage. An increased level of caspase-3, apoptosis inducing factor (AIF), cleaved PARP-1 and decreased level of Bcl2 was observed in leukemia cells after 24h of curcumin treatment. In addition, curcumin at doses lower than the $IC_{50}$ value significantly enhanced doxorubicin induced cell death. Therefore, we conclude that curcumin induces apoptosis in leukemia cells via PARP-1 mediated caspase-3 dependent pathway and further may act as a potential chemo-sensitizing agent for doxorubicin. Our study highlights the chemo-preventive and chemo-sensitizing role of curcumin.

The Spectral Sensitization and the Photographic Characteristics of Sensitizing Dye for Photographic Emulsion (사진유제용 증감색소의 분광증감과 사진특성)

  • Kim, Yeoung-Chan;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.1
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    • pp.87-98
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    • 1996
  • In this study, benzoxazolo carbocyanine dye was used as sensitizer for photographic emulsion, and the photographic characteristics were examined. The basic properties of sensitizer such as stability in various solvents were examined. The sensitizer was very stable in methanol, acetonitrile, acetone, dimethylformamide, and chloroform solution. Absorption spectra of benzoxazolo carbocyanine dye $2.5{\times}10^{-6}M$ and $5{\times}10^{-6}M$ concentrations in 10% aqueous methanol solutions containing $10^{-2}M$ potassium chloride show the monomer-J-aggregation characteristics. Compared to the absorption peak of the monomer in pure methanol solution, the red shifts of the monomer-J-aggregate peaks of benzoxazolo carbocyanine dye of $2.5{\times}10^{-6}M$ and $5{\times}10^{-6}M$ concentrations in 10% aqueous methanol solutions containing $10^{-2}M$ potassium chloride are 34nm respectively, and the sensitizing peak of benzoxazolo carbocyanine dye in photographic emulsion has red shift of 34nm. Therefore, if was concluded that benzoxazolo carbocyanine dye can be used as green sensitizing dye for the spectral sensitization of photographic emulsion.

A stability on the solvents of 9-Phenyl-5,5'-Diphenyl-3,3'-Bis-(3-sulfopropy)-benzoxazolo carbocyanine triethyl ammonium salt (9-Phenyl-5,5'-Diphenyl-3,3'-Bis-(3-sulfopropy)-Benzoxazolo Carbocyanine Triethyl Ammonium Salt의 용매에 대한 안정성)

  • Kim, Yeoung-Chan
    • The Journal of Information Technology
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    • v.7 no.2
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    • pp.1-5
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    • 2004
  • The symmetric 9-phenyl-5,5'-diphenyl-3,3'-bis-(3-sulfopropyl)-benzoxazolo carbocyanine triethyl ammonium salt is of industrial importance as green-sensitizing dye in the spectral sensitization of emulsion microcrystals in negative film and positive paper-making. The stability on the solvents of benzoxazolo carbocyanine dye was measured by UV-Vis spectrophotometer, and then dye was stabilized in various solvents. The maximum absorption peak range in various solvents was 507nm~515nm. It was identified that the solvents can be used to photographic emulsion.

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The Synthesis of 9-Phenyl-3,3'-Bis(3-Sulfopropyl)-4,5,4',5'-Naphthothiazolo Carbocyanine Triethyl Ammonium Salt (9-Phenyl-3,3'-Bis(3-Sulfopropyl)-4,5,4',5'-Naphthothiazolo Carbocyanine Triethyl Ammonium Salt의 합성)

  • Kim, Yeoung-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.3
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    • pp.73-81
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    • 1996
  • In this study, sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-4,5-naphthothiazolium(inner salt) with triethyl orthobenzoate in the presence of triethylamine. The product was identified by using various analytical tools such as elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^1H-NMR$ spectrometer, TGA and DSC. Therefore, it was concluded that 9-phenyl-3,3'-bis(3-sulfopropyl)-4,5,4',5'-naphthothiazolo carbocyanine triethyl ammonium salt can be used as red-sensitizing dye for the spectral sensitization of photographic emulsion.