• Title/Summary/Keyword: Self-reaction

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EFFECT OF A STANDARDIZED GINSENG EXTRACT ON GENERAL HEALTH, REACTIVE CAPACITY AND PULMONARY FUNCTION

  • Forgo Imre
    • Proceedings of the Ginseng society Conference
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    • 1980.09a
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    • pp.143-150
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    • 1980
  • The purpose of this double-blind study was to study the standardized ginseng-extract (marketed form, GINSANA), in regard to its efficacy on the reaction time, pulmonary function and general health in subjects of various age-groups. The trial was conducted as a double-blind study in a total of 120 subjectsm allocated to different groups, according to age (30 to 39 and 40 to 60 year age-groups), sex and preparation administered (ginseng/placebo). The study lasted 12 weeks and the dosage was fixed at 2 capsules per day. The rusults regarding reaction time and pulmonary function showed significant differences in favour of the GINSANA group, over the placebo group, in the 40 to 60-year-old men and women. In the self-evaluation (performance, mood, concentration) we observed a clear improvement (p < 0.001) in the subjects treated with GINSANA, with the exception of the men age 30-39 years. The results botained, which are specially related to reaction, pulmonary function, self evaluation and tolerability, have shown that GINSANA, as standardized ginseng extract, has a favourable effect on the psychic and physical functions studied. 3. Performance test in top sportsmen before and after 9 weeks' treatment with GINSANA To what extent can GINSANA influence physical performance? It is precisely we the physicians whose task it is to find drugs which in physiological amounts do not have any special pharmacodynamic effects. We were therefore interested in the preparation, GINSANA which was made available to us, since it contains a qualitatively and quantitatively standardized GINSENG EXTRACT and is not doping agent.

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Synthesis of Tungsten Boride using SHS(Self-propagating High-temperature Synthesis) and Effect of Its Parameters (자전연소 합성법을 이용한 W-B 화합물 합성 및 조건 변수의 영향)

  • Choi, Sang-Hoon;Nersisyan, Hayk;Won, Changwhan
    • Korean Journal of Materials Research
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    • v.24 no.5
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    • pp.249-254
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    • 2014
  • Due to their unique properties, tungsten borides are good candidates for the industrial applications where certain features such as high hardness, chemical inertness, resistance to high temperatures, thermal shock and corrosion. In this study, conditions were investigated for producing tungsten boride powder from tungsten oxide($WO_3$) by self-propagating high-temperature synthesis (SHS) followed by HCl leaching techniques. In the first stage of the study, the exothermicity of the $WO_3$-Mg reaction was investigated by computer simulation. Based on the simulation experimental study was conducted and the SHS products consisting of borides and other compounds were obtained starting with different initial molar ratios of $WO_3$, Mg and $B_2O_3$. It was found that $WO_3$, Mg and $B_2O_3$ reaction system produced high combustion temperature and radical reaction so that diffusion between W and B was not properly occurred. Addition of NaCl and replacement of $B_2O_3$ with B successfully solved the diffusion problem. From the optimum condition tungsten boride($W_2B$ and WB) powders which has 0.1~0.9 um particle size were synthesized.

Chromate Refractory by Combustion Process (연소합성에 의한 크로메이트 내화물 제조)

  • 김형순;한정환
    • Journal of the Korean Ceramic Society
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    • v.31 no.12
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    • pp.1437-1442
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    • 1994
  • Self propagating synthesis and thermal explosion of combustion reactions were applied to Al/K2Cr2O7/Al2O3 system as the first stage for a production of magnesia-chromium refractory. Several factors related to products made by two combustion reactions were considered and properties of products were characterised. Two processes were required to preheat upto at least 80$0^{\circ}C$ for the thermal explosion and the self propagating synthesis. These processes were so violent and explosive that alumina as diluent was added to the system in order to absorb the reaction heat and reduce the reaction rate. The products consisted of crystal phases of KAl5O8, Cr2O3, Al2O3, K2CrO4, and K2Al2O4.3H2O. The amount of KAl5O8 and K2Al2O4.3H2O crystal phases of products were decreased with further addition of alumina.

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Study on Self-Propagating High-Temperature Synthesis of TiN Powder (SHS 공정에 의한 TiN 분말합성에 관한 연구)

  • ;S.G. Vadchenco
    • Journal of the Korean Ceramic Society
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    • v.33 no.1
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    • pp.41-48
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    • 1996
  • Self-propagating High-temperature Synthesis of Ti+N system has been investigated using the cylindrical high pressure reactor. The nitrogen pressure was varied from 40 to 80 atmosphere and TiNx(x=0.55) powder produced by SHS process was used as a diluent in order to control the reaction. Both the velocity of surface reaction and the ratio of TiN synthesis increased with increasing the nitrogen pressure. As the amount of diluent increases the degree of conversion to titanium nitride increases. Homogenious TiN powder was obtained in the composition 50Ti+50TiN0.94(diluent)

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Fabrication of AlN Powder by Self-propagating High-temperature Synthesis I. Synthesis of AlN Powder (자전고온 반응 합성법에 의한 AlN 분말의 제조 I.AlN 분말의 제조)

  • 신재선;안도환;김석윤;김용석
    • Journal of the Korean Ceramic Society
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    • v.33 no.9
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    • pp.961-968
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    • 1996
  • The aluminum nitride was synthesized by the self-propagating high-temperature synthesis(SHS). The synthe-sis was used aluminum powder mixed with AlN powder as reactant and the control factors affected to synthesis were considered compact density pressure of reaction gas AlN diluent content and aluminum powder size. The SHS reaction conducted with a reactant containing 50% AlN diluent under 0.8MPa nitrogen gas pressure yielded a complete conversion of aluminum powder to AlN powders. The size and purity of AlN produced were found to be comparable with that of AlN produced by the carbothermal nitrogen method.

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Characterization of biotin-avidin recognition system constructed on the solid substrate

  • Lim, Jung-Hyurk
    • Analytical Science and Technology
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    • v.18 no.6
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    • pp.460-468
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    • 2005
  • The biotin-avidin complex, as a model recognition system, has been constructed through N-hydroxysuccinimide(NHS) reaction on a variety of substrates such as a smooth Au film, electrochemically roughened Au electrode and chemically modified mica. Stepwise self-assembled monolayers (SAMs) of biotin-avidin system were characterized by surface-enhanced resonance Raman scattering (SERRS) spectroscopy, atomic force microscopy (AFM) and surface plasmon resonance (SPR). A strong SERRS signal of rhodamine tags labeled in avidin from the SAMs on a roughened gold electrode indicated the successful complex formation of stepwise biotin-avidin recognition system. AFM images showed the circular shaped avidin aggregates (hexamer) with ca. $60{\AA}$ thick on the substrate, corresponding to one layer of avidin. The surface coverage and concentration of avidin molecules were estimated to be 90% and $7.5{\times}10^{-12}mol/cm^2$, respectively. SPR technique allowed one to monitor the surface reaction of the specific recognition with high sensitivity and precision.

Reaction Phenomena of the Ferrite Steel by Water Leakage into Liquid Sodium (소듐분위기에서 물 누출로 인한 Ferrite Steel에서의 반응현상)

  • Jeong, Kyung-chai;Kim, Byung-ho;Kwon, Sang-woon;Kim, Kwang-rag;Hwang, Sung-tai
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.268-272
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    • 1998
  • Water leak phenomena in the liquid sodium which is a coolant of liquid metal reactor, were investigated by carrying out sodium-water reaction experiment. It was confirmed that sodium and water react each other by the analysis of material composition of aspecimen at the end of experiment. When steam of $100kg/cm^2$ was passed through the leak path of the specimen for 4 hours, reaction products from sodium-water reaction were observed on the leak site. However, re-opening phenomena were not observed at this condition. It was interpretted that the reaction product precipitated on leak path and thermal transient caused self-plugging and re-openning phenomena, respectively.

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Effect of Additives on the Characteristics of Amorphous Nano Boron Powder Fabricated by Self-Propagating High Temperature Synthesis (자전연소합성법을 이용한 비정질 나노 붕소 분말 특성에미치는 첨가제의 영향)

  • Joo, Sin Hyong;Nersisyan, Hayk H.;Lee, Tae Hyuk;Cho, Young Hee;Kim, Hong Moule;Lee, Huk Hee;Lee, Jong Hyeon
    • Korean Journal of Materials Research
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    • v.25 no.12
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    • pp.659-665
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    • 2015
  • The self-propagating high temperature synthesis approach was applied to synthesize amorphous boron nano-powders in argon atmospheres. For this purpose, we investigated the characteristics of a thermally induced combustion wave in the $B_2O_3+{\alpha}Mg$ system(${\alpha}=1.0-8.0$) in an argon atmospheres. In this study, the exothermic nature of the $B_2O_3-Mg$ reaction was investigated using thermodynamic calculations. Experimental study was conducted based on the calculation data and the SHS products consisting of crystalline boron and other compounds were obtained starting with a different initial molar ratio of Mg. It was found that the $B_2O_3$ and Mg reaction system produced a high combustion temperature with a rapid combustion reaction. In order to regulate the combustion reaction, NaCl, $Na_2B_4O_7$ and $H_3BO_3$ additives were investigated as diluents. In an experimental study, it was found that all diluents effectively stabilized the reaction regime. The final product of the $B_2O_3+{\alpha}Mg$ system with 0.5 mole $Na_2B_4O_7$ was identified to be amorphous boron nano-powders(< 100 nm).

First-principles Study of the Structure and Growth Mechanism of Allyl Alcohol Lines on the H-terminated Si(001)

  • Choi, Yun-Ki;Choi, Jin-Ho;Cho, Jun-Hyung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.184-184
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    • 2011
  • Using first-principles density-functional calculations, we investigate the chain reaction mechanism of allyl alcohol (ALA) molecules on the H-terminated Si(001)-2${\times}$1 surface. Recently, it was reported [1] that allyl mercaptan (ALM) molecules show a self-directed line growth across the dimer rows through a chain reaction involving several reaction processes: (i) The created radical at the C atom is transferred to the S atom, (ii) the resulting S-centered radical easily abstracts an H atom from the neighboring dimer row, and (iii) the generated S-H group further reacts with the neighboring dimer row to produce the Si-S bond on the neighboring dimer row, accompanying the associative desorption of H2. This H2-desorption process creates a new DB on the neighboring dimer row, setting off the chain reaction across the dimer rows. In the present study, we find that although the structure of ALA with -OH functional is analogous to that of ALM with -SH functional, ALA and ALM lines show a difference in their growth direction. We predict that ALA undergoes the chain reaction to show a line growth along the dimer row, contrasting with the ALM line growth across the Si dimer rows. Our analysis shows that the different growth direction of ALA is due to the strong instability of oxygen radical intermediate, which prevents from growing across the dimer rows. Thus, we demonstrate that the stability of the radical intermediate plays a crucial role in determining the direction of molecular line growth.

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Electrocatalytic Oxidation of NADH at the Modified Graphite Electrode Incorporating Gold Nano Particles (금 나노입자를 회합시킨 수식된 흑연전극으로 NADH의 전기촉매 산화반응)

  • Cha, Seong-Keuck;Han, Sung-Yub
    • Journal of the Korean Electrochemical Society
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    • v.10 no.1
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    • pp.1-6
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    • 2007
  • Mercaptopropionic acid(mpa) has been used to make self-assembled monolayer(SAMs) on the surface of graphite electrode incorporating gold nano particles, which are subsequently modified with dopamine(dopa). Such modified electrodes haying types of Gr(Au)/mpa-dopa were employed in the electrocatalytic oxidation of NADH. The responses of such modified electrodes were studied in terms of electron transfer kinetics and reaction procedure in the reaction. The reaction of the surface immobilized dopa with NADH was studied using the rotating disk electrode technique and a value of $5.06{\times}10^5M^{-1}s^{-1}$ was obtained for the second-order rate constant in 0.1 M phosphate buffer(pH=7.0), which was a $EC_{cat}$ and kinetic controlled procedure. But, the modified electrodes were diffusion controlled reaction having $4.64{\times}10^{-4}cm^2s^{-1}$ of the coefficient within $10^{-3}s$ after starting the reaction.