• 제목/요약/키워드: Self-reaction

검색결과 739건 처리시간 0.027초

굴착단면 형상에 따른 터널 초기탄성변위의 수치해석적 연구 (A numerical study for initial elastic displacement at tunnel side-wall due to configuration of the tunnel excavation)

  • 김상환;정혁일;이민상
    • 한국터널지하공간학회 논문집
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    • 제4권3호
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    • pp.175-184
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    • 2002
  • 일반적으로 터널 굴착시 지보재의 설치시기에 대한 예측을 위하여서는 지반반응곡선 (Ground reaction curve)을 활용하고 있다. 이 지반반응곡선은 굴착에 따른 지반의 변위 특성을 나타내며, 일반적으로 원형단면이고 등방상태 (K = 1.0)로 가정하여 단순화시킨 Closed Form Solution을 통해서 구해진다. 그러나, 원형단면이 아니고, 비등방 응력상태인 실질적인 현장조건을 고려해 본다면, 이 지반반응특성 예측식을 현장조건에 적용함에 있어서 어떠한 한계점을 갖는지에 대하여 규명할 필요가 있다. 이를 위해, 본 논문에서는 굴착단면 형상에 따른 측벽에서의 초기탄성변위 및 임계지보압의 변화 특성에 대하여 연구하였다. 터널굴착 형상은 단면의 높이 (b)와 폭 (a)의 비, 즉 굴착형상 계수 S (=b/a)값이 1.0, 0.8, 0.6, 0.4로 변화하도록 하였으며, 각각의 굴착형상마다 초기등방응력을 5~30 MPa사이에서 변화시켜가면서 수치해석을 통해 지반반응곡선을 얻었다. 수치해석을 통해 얻어진 측벽에서의 지반반응곡선을 분석하여 그에 따른 특성을 제시하였다. 검토결과 지반의 자립성을 평가하는데 있어서 Closed form solution의 사용에는 한계가 있는 것으로 판단된다.

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연소합성법을 이용한 방사성폐기물 고화체 Hollandite 분말 합성 (Synthesis of Hollandite Powders as a Nuclear Waste Ceramic Forms by a Solution Combustion Synthesis)

  • 정충환;정수지
    • 한국재료학회지
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    • 제33권10호
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    • pp.385-392
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    • 2023
  • A solution combustion process for the synthesis of hollandite (BaAl2Ti6O16) powders is described. SYNROC (synthetic rock) consists of four main titanate phases: perovskite, zirconolite, hollandite and rutile. Hollandite is one of the crystalline host matrices used for the disposal of high-level radioactive wastes because it immobilizes Sr and Lns elements by forming solid solutions. The solution combustion synthesis, which is a self-sustaining oxi-reduction reaction between a nitrate and organic fuel, generates an exothermic reaction and that heat converts the precursors into their corresponding oxide products in air. The process has high energy efficiency, fast heating rates, short reaction times, and high compositional homogeneity. To confirm the combustion synthesis reaction, FT-IR analysis was conducted using glycine with a carboxyl group and an amine as fuel to observe its bonding with metal element in the nitrate. TG-DTA, X-ray diffraction analysis, SEM and EDS were performed to confirm the formed phases and morphology. Powders with an uncontrolled shape were obtained through a general oxide-route process, confirming hollandite powders with micro-sized soft agglomerates consisting of nano-sized primary particles can be prepared using these methods.

자체반응열 고온합성법에 의한 탄화티타늄 합성에 관한 메카니즘 (Mechanism on the Synthesis of Titanium Carbide by SHS (Self-Propagating High-Temperature Synthesis) Method)

  • 하호;황규민;한희동
    • 한국세라믹학회지
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    • 제31권11호
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    • pp.1249-1258
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    • 1994
  • Titanium carbide was synthesized by reacting the prepared titanium powder and carbon black using SHS method sustains the reaction spontaneously, utilizing heat generated by the exothermic reaction itself. In this process, the effect of the particle size of titanium powder on combustion temperature and combustion wave velocity was investigated. By controlling combustion temperature and combustion wave velocity via mixing Ti and C powder with TiC, the reaction kinetics of TiC formation by SHS method was considered. Without reference to the change of combustion temperature and combustion wave velocity, TiC was easily synthesized by combustion reaction. As the particle size of titanium powder was bigger, or, as the amount of added diluent(TiC) increased, combustion temperature and combustion wave velocity were found to be decreased. The formation of TiC by combustion reaction in the Ti-C system seems to occur via two different mechanisms. At the beginning of the reaction, when the combustion temperatures were higher than 2551 K, the reaction was considered to be controlled by the rate of dissolution of carbon into a titanium melt with an apparent activation energy of 148 kJ/mol. For combustion temperatures less than 2551 K, it was considered to be controlled by the atomic diffusion rate of carbon through a TiC layer with an apparent activation energy of 355 kJ/mol. The average particle size of the synthesized titanium carbide was smaller than that of the starting material(Ti).

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고유동성 채움재 타설장비를 이용한 모형시험 (A Small Scale Test using the Coal Ash Placement Equipment)

  • 김주형;조삼덕;함태규;도종남;천병식
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2010년도 춘계 학술발표회
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    • pp.1452-1457
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    • 2010
  • 본 연구에서는 국내 회처리장에 매립되어 있는 매립회를 효율적으로 사용하기 위한 실내 모형시험장치인 CSP 시스템을 제작하여 매립회와 물 그리고 시멘트량을 조절하여 모형지반을 조성하고 이에 대한 강성변화를 평가하였다. 시멘트를 첨가한 모형지반이 시멘트를 첨가하지 않은 경우에 비해 빠른 속도로 경화가 진행되었으며 192시간 경과 후에는 경화속도가 급격히 감소하는 것으로 나타났다. 모형지반 조성시 전체 중량의 30~45% 사이의 물의 양 변화는 지반의 강성 변화에 큰 영향을 끼치지는 않는 것으로 나타났다. 추후에는 지반 조성 초기에 큰 지반강성의 크기를 얻을 수 있도록 시멘트량을 증가시키는 등의 다양한 영향인자에 대한 시험을 수행하여 고유동성 채움재 활용성을 정량적으로 평가하는 것이 필요할 것으로 판단된다.

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기계적 합금화과정에서의 in situ 열분석에 의한 Ti-25.0~37.5at%Si 분말의 합성거동 (Synthesis Behavior of Ti-25.0~37.5at%Si Powders by In situ Thermal Analysis during Mechanical Alloying)

  • 변창섭;현창용;김동관
    • 한국재료학회지
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    • 제14권5호
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    • pp.305-309
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    • 2004
  • Mechanical alloying (MA) of Ti-25.0~37.5at%Si powders was carried out in a high-energy ball mill, and in situ thermal analysis was also made during MA. In order to classify the synthesis behavior of the powders with respect to at%Si, the synthesis behavior during MA was investigated by in situ thermal analysis and X-ray diffraction (XRD). In situ thermal analysis curves and XRD patterns of Ti-25.0~26.1at%Si powders showed that there were no peaks during MA, indicating $Ti_{5}$ $Si_3$ was synthesised by a slow reaction of solid state diffusion. Those of Ti-27.1~37.5at%Si powders, however, showed that there were exothermic peaks during MA, indicating $_Ti{5}$ $Si_3$ and$ Ti_3$Si phase formation by a rapid exothermic reaction of self-propagating high-temperature synthesis (SHS). For Ti-27.1~37.5at%Si powders, the critical milling times for SHS decreased from 38.1 to 18.5 min and the temperature rise, ΔT (= peak temperature - onset temperature) increased form $19.5^{\circ}C$ to $26.7^{\circ}C$ as at%Si increased. The critical composition of Si for SHS reaction was found to be 27.1at% and the critical value of the negative heat of formation of Ti-27.1at%Si to be -1.32 kJ/g.

원자층 증착에 있어서 아르곤 펄스 시간이 Al2O3 박막에 미치는 효과 (Effects on the Al2O3 Thin Film by the Ar Pulse Time in the Atomic Layer Deposition)

  • 김기락;조의식;권상직
    • 반도체디스플레이기술학회지
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    • 제20권4호
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    • pp.157-160
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    • 2021
  • As an insulator for a thin film transistor(TFT) and an encapsulation material of organic light emitting diode(OLED), aluminum oxide (Al2O3) has been widely studied using several technologies. Especially, in spite of low deposition rate, atomic layer deposition (ALD) has been used as a process method of Al2O3 because of its low process temperature and self-limiting reaction. In the Al2O3 deposition by ALD method, Ar Purge had some crucial effects on the film properties. After reaction gas is injected as a formation of pulse, an inert argon(Ar) purge gas is injected for gas desorption. Therefore, the process parameter of Ar purge gas has an influence on the ALD deposited film quality. In this study, Al2O3 was deposited on glass substrate at a different Ar purge time and its structural characteristics were investigated and analyzed. From the results, the growth rate of Al2O3 was decreased as the Ar purge time increases. The surface roughness was also reduced with increasing Ar purge time. In order to obtain the high quality Al2O3 film, it was known that Ar purge times longer than 15 sec was necessary resulting in the self-limiting reaction.

폐경기 경험에 관한 연구 : Q 방법론적 접근 (A Study on the Menopause Experience : A Q Methodological Approach)

  • 신혜숙
    • 대한간호학회지
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    • 제25권4호
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    • pp.807-824
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    • 1995
  • This study was intended to provide women who are experiencing menopause with effective nursing care by exploring the menopause experience. The purpose of the research was to understand the subjective feelings of women about the question of what the menopause experience is. Q-Methodological method was used for that purpose. As the research method, Q-statements were collected preliminary to the study of through in -depth interviews and a literature review. For the study 34 Q-statements were selected. There were 21 women as subjects for the research. The 21 women sorted the 34 statements using the principle of Forced Normal Distribution. The principle of Forced Normal Distribution, which has nine scales to measure the individual opinions, was called Q-Factor Analysis by using PC Quanl Program to supply the material. As a result, there were four categories(self-com-passion type, self-regulation type, self-perception type, self-abandonment type) of special opinion about the menopause experience in these women. The first type was called Self-compassion This type' was associated with varying degrees of emotonal instability(psychological withdrawal). And type in menopause signifies loss of a socially valued status and may result in depressive symptoms. This type expresses the menopause experience as associated with negative reaction. The second type is called Self-regulation. This type overcomes the menopause experience more actively than the other types and do not express the menopause experience as one of suffering. This type make efforts by themselves to regulate the mono-pause experience. The third type is called Self-perception. This type perceives the experience of menopause which as typical menopausal syndrome (hot flashes and decreased vaginal lubrication, decreased estrogen producing atrophic changes of the labia and vaginal mucosa, making intercourse uncomfortable). The fourth type is called Self- abandonment. This type denies the experience of menopause. The meaning of menopausal experience is significantly related with a life accident or life load. Also, This type experiences pain in the musculoskeletal system. As a result, The meaning of the menopausal experience is affected by perceived subjective experience of the nurses, the need to understand each persons meaning of the menopause experience and to develop appropriate nursing interventions based on the typology of menopause experience. Finally. The result of the study will provide basic data for nursing intervention the menopausal women.

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온라인 커뮤니티특징이 소비자 반응에 미치는 영향 - 소비자의 성별과 자기해석 수준차이를 중심으로 (Effects of Online Community Characteristics on Customer Reaction - Based on the Differences of Customer's Gender and Self-Construal Level)

  • 신종국;문민경;김재훈
    • 디지털융복합연구
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    • 제16권3호
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    • pp.261-273
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    • 2018
  • 본 연구는 온라인 브랜드 커뮤니티 특징이 자기 해석 수준 및 성별 차이에 따라 고객 행동에 어떤 영향을 미치는지에 대해 규명하고자 한다. 온라인 커뮤니티의 특징으로 상호작용성, 목적성, 정보제공, 활동보상으로 나누어 실증연구를 하였다. 분석 결과 첫째, 온라인 커뮤니티의 특성 중 상호작용성과 활동보상은 브랜드 커뮤니티 몰입에 긍정적인 영향을 미치는 것으로 나타난 반면, 목적성과 정보제공의 효과는 미흡한 것으로 나타났다. 둘째, 소비자가 브랜드 커뮤니티에 대한 몰입이 강할수록 구전효과 역시 높은 것으로 나타났다. 마지막으로 상호의존적 자기 해석 수준을 갖고 있는 소비자는 독립적 자기 해석 수준을 갖고 있는 소비자에 비해 보다 더 높은 브랜드 커뮤니티의 몰입을 보였으며, 여성이 남성에 비해 더 높은 브랜드 커뮤니티 몰입을 보이는 것으로 나타났다. 본 연구는 소비자의 자기해석이라는 내재적 동기를 알아봄으로써, 기업들에게 브랜드커뮤니티를 통한 효율적인 마케팅 접근법을 제시한다.

격려집단상담 프로그램과 대학생의 자기효능감과 주관적 안녕감과의 관계 (The Relationship of the Encouragement Group Counseling Program on Self-Efficacy and Subjective Well-Being of University Students)

  • 선국진
    • 한국컴퓨터정보학회논문지
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    • 제18권11호
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    • pp.191-199
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    • 2013
  • 본 연구는 대학생들이 예비 사회인이자 지성인으로서 대학생활에 대한 학교적응 뿐만 아니라 사회환경의 변화에 대한 변동대응능력을 확보함으로써 긍정적 자아를 정립하기 위한 방안으로 격려집단상담 프로그램에 의한 자기효능감과 주관적 안녕감의 수준을 분석하는데 연구의 목적을 두었다. 따라서 대학생들을 대상으로 하여 격려집단상담 프로그램의 적용이 그들의 자기효능감과 주관적 안녕감 수준에 미치는 영향에 대해서 분석하였다. 분석결과, 대학생에 대한 격려집단상담 프로그램의 적용은 자기효능감과 주관적 안녕감에 모두 유의미한 영향을 미치는 것으로 밝혀졌다. 이러한 연구결과는 사람은 격려되었을 때, 보다 긍정적이고 높은 자신감과 심리적 안정감을 형성할 수 있다는 것을 의미하는 것으로 보여 진다. 따라서 본 연구에서는 연구결과를 바탕으로 대학생들에 대해서 스스로 자기 자신을 격려하는 사람으로 변화되도록 지원해주는 격려집단상담 프로그램 운영의 필요성을 제시하였다.

Expression and Significance of MicroRNA155 in Serum of Patients with Cerebral Small Vessel Disease

  • Guo, Ying;Li, Dongxue;Li, Jiapei;Yang, Nan;Wang, Deyun
    • Journal of Korean Neurosurgical Society
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    • 제63권4호
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    • pp.463-469
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    • 2020
  • Objective : This study aimed to investigate the changes and significance of microRNA155 levels in serum of patients with cerebral small vessel disease (CSVD). Methods : Thirty patients with CSVD who met the inclusion criteria were selected and divided into eight patients with lacunar infarction (LI) group and 22 patients with multiple lacunar infarction (MLI) combined with white matter lesions (WML) group according to the results of head magnetic resonance imaging (MRI). Thirty samples from healthy volunteers without abnormalities after head MRI examination were selected as the control group. The levels of serum microRNA155 in each group were determined by real-time polymerase chain reaction, and the correlation between microRNA155 in the serum of patients with CSVD and the increase of imaging lesions was analyzed by Spearman correlation analysis. Results : Compared with the control group, the serum microRNA155 level in the LI group, MLI combined with WML group increased, the difference was statistically significant (p<0.05); serum microRNA155 level was positively correlated with the increase of imaging lesions (p<0.05). Conclusion : The change of serum microRNA155 level in patients with CSVD may be one of its self-protection mechanisms, and the intensity of this self-protection mechanism is positively correlated with the number of CSVD lesions.