• 한국재료학회지
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• 제32권6호
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• pp.307-312
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• 2022

Metal halide perovskite (MHP) nanocrystals (NCs) have emerged as promising materials for various optoelectronic applications including photovoltaics, light-emitting devices, and photodetectors because of their high absorption coefficient, high diffusion length, and photoluminescence quantum yield. However, understanding the morphological evolution of the MHP NCs as well as their controlled assembly into optoelectronic devices is still challenging and will require further investigation of the colloidal chemistry. In this study, we found that the amount of n-octylamine (the capping agent) plays a crucial role in inducing further growth of the MHP NCs into one-dimensional nanowires during the aging process. In addition, we demonstrate that the dielectrophoresis process can permit self-alignment of the MHP nanowires with uniform distribution and orientation on interdigitated electrodes. A strong light-matter interaction in the MHP NWs array was observed under UV illumination, indicating the photo-induced activation of their luminescence and electrical current in the self-aligned MHP nanowire arrays.

• 한국토양환경학회지
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• 제1권2호
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• pp.73-81
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• 1996

실험실 내에서 부피비로 약 50%내외의 수분함량을 가진 3개의 서로 다른 깊이의 토양에서 염소와 중수의 확산계수는 4.8$\times$ $10${-7}$ 부터 7.2$\times$ $10${-7}$ $\textrm{cm}^2$/sec와 5.5 $\times$ $10${-5}$ 부터 1.6$\times$ $10${-4}$ $\textrm{cm}^2$//sec였다. 한편, 물과 물질의 이동성에 대한 연구는 중간사로 구성된 토양층 위에 위치하는 점토로부터 미사질 양토에 속하는 약 70cm깊이의 토양에서 실시되었고, 87일간의 실험기간동안 리터당 15.2$m\ell$의 염소와 0.6bq의 중수로 처리된 물을 일정한 유량(2cm/일)으로 관개하였다. 토양의 깊이와 시간에 따른 염소와 중수의 변동위치는 suction probe에 채취된 토양수를 가지고 측정하였는데 실험지 안에서 서로 다른 깊이 또는 동일 위치에서 염소와 중수가 발견되었다. 이러한 실험의 결과로부터 추정컨대 토양수의 유속과 표면확산 계수가 염소와 중수의 분포에 직접적인 영향을 미쳤고 24개의 suction probe에서의 결과는 실질적 물질과 토양의 상호작용의 효과를 나타내는 순수치의 25% 내외에서 평가치를 추정할 수 있었다.

• 한국건설순환자원학회논문집
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• 제8권1호
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• pp.134-142
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• 2020

본 연구에서는 시멘트 복합체의 자기치유 성능평가를 위해 정수위투수시험, 염소이온 확산시험, 반복휨시험을 활용한 시험방법 및 분석방법을 제시하였고, 균열 유발방법과 균열폭 제어방법을 제안하였다. 정수위 투수시험은 시험체의 균열부를 통과하는 단위유출수량의 감소율을 이용하여 치유성능을 평가하는 시험방법으로 등가 균열폭을 활용하여 치유재령에 따른 치유효과를 직관적으로 규명할 수 있다. 염소이온 확산계수시험은 ASTM C 1202의 시험장치를 활용하여 구한 염소이온 확산계수의 감소율로 치유율을 평가하는 방법이다. 또한, 반복 휨 시험을 통하여 얻은 하중과 CMOD의 관계 그래프로부터 강도회복지수(ISR)과 손상복구지수(IDR)을 산정하여 역학적 치유성능을 평가할 수 있다. 마지막으로, 자기치유 소재의 혼입 유무에 따른 균열 시험체의 실험을 통해 본 연구에서 제시한 자기치유 평가방법의 적용성을 검토하였다.

• Bulletin of the Korean Chemical Society
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• 제35권9호
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• pp.2679-2683
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• 2014

Mechanisms underlying the impacts of interactions between carbon nanoparticles (CNPs) and ionic liquids (ILs) on the physicochemical behavior of CNPs need to be more full worked out. This manuscript describes a theoretical investigation at multiple levels on the interactions of fullerene $C_{60}$ with 21 imidazolium-based ILs of varying alkyl side chain lengths and anionic types and their impacts on $C_{60}$ dispersion behavior. Results show that ${\pi}$-cation interaction contributed to mechanism of the $C_{60}$-IL interaction more than ${\pi}$-anion interaction. The calculated interaction energy ($E_{INT}$) indicates that $C_{60}$ can form stable complex with each IL molecule. Moreover, the direction of charge transfer occurred from IL to $C_{60}$ during the $C_{60}$-IL interaction. Quantitative models were developed to evaluate the self-diffusion coefficient of $C_{60}$ ($D_{fullerene}$) in bulk ILs. Three interpretative molecular descriptors (heat of formation, $E_{INT}$, and charge) that describe the $C_{60}$-IL interactions and the alkyl side chain length were found to be determinants affecting $D_{fullerene}$.

• 대한의용생체공학회:의공학회지
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• 제8권2호
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• pp.123-134
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• 1987

The transport phenomena of alkali metal chlorides through poly(2 hydroxyethyl methacrylate) hydrogel membrane have been studied using electrodialysis. The hydrogel membranes were prepared by the polymerization of 2-hydroxvethyl methacrylate in the presence of 45%(V/V) H2O and ethyleneglycodimethacrylate. The initiator used in the polymerization was azobismethylisobutyrate (AMIB) prepared from azobisiobtyronitrile (AIBN) using Mortimer method. The permeability of alkali metal chlorides such LiCl, NaCl and KCI at 50 voltage was obtained. The permeability of NaCl was also observed at 30, 40, 50, and 60 voltages respectively. The concentration of solutes permeated through the membrane was measurer by flame photometry. The experimental results have been discussed with the comparison of apparent solute molecular size, the self-diffusion coefficient of solutes, the transport number of cations in aqueous solution. These indic aloes that poly(2 hydroxyethyl methacrylate) hydrogel membrane shows a specific selectivity for sodium ion.

• Korean Membrane Journal
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• 제6권1호
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• pp.55-60
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• 2004

In recent years, an increasing interest in membrane technology has been observed in chemical and environmental industry. Membrane technology has advantages of low cost, energy saving and environmental clean technology comparing to conventional separation processes. Pervaporation is one of new advanced membrane technology applied for separation of azeotropic mixtures, aqueous organic mixtures, organic solvent and petrochemical mixtures. Sodium alginate composite membranes were prepared for the enhancement of long-term stability of pervaporation performance of water-ethanol mixture using pervaporation. Sodium alginate membranes were crosslinked with CaCl$_2$ and coated with polyelectrolyte chitosan to protect washing out of calcium ions from the polymer. The surface structures of PAN and hydrolysed PAN membrane were confirmed by ATR Fourier transform infrared (FT-IR). A field emission scanning electron microscopy (FE-SEM; Jeol 6340F) operated at 15 kV. Concentration profiles for Ca in the membrane surface and membrane cross-section were taken by an energy dispersive X-ray (EDX) analyser (Jeol) attached to the field emission scanning electron microscopy (Jeol 6340F). Pervaporation experiments were done with several operation run times to investigate long-term stability of the membranes.

• Macromolecular Research
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• 제15권2호
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• pp.160-166
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• 2007

Novel multiblock copolymers, based on segmented sulfonated hydrophilic-hydrophobic blocks, were synthesized and investigated for their application as proton exchange membranes. A series of segmented sulfonated poly(arylene ether sulfone)-b-polyimide multiblock copolymers, with various block lengths, were synthesized via the coupling reaction between the terminal amine moieties on the hydrophilic blocks and naphthalene anhydride functionalized hydrophobic blocks. Successful imidization reactions required a mixed solvent system, comprised of NMP and m-cresol, in the presence of catalysts. Proton conductivity measurements revealed that the proton conductivity improved with increasing hydrophilic and hydrophobic block lengths. The morphological structure of the multiblock copolymers was investigated using tapping mode atomic force microscopy (TM-AFM). The AFM images of the copolymers demonstrated well-defined nanophase separated morphologies, with the changes in the block length having a pronounced effect on the phase separated morphologies of the system. The self diffusion coefficient of water, as measured by $^1H$ NMR, provided a better understanding of the transport process. Thus, the block copolymers showed higher values than Nafion, and comparable proton conductivities in liquid water, as well as under partially hydrated conditions at $80^{\circ}C$. The new materials are strong candidates for use in PEM systems.

• Applied Science and Convergence Technology
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• 제23권2호
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• pp.72-82
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• 2014

Lithium-ion batteries (LIBs) have become popular electrochemical devices. Due to the unique advantages of LIBs in terms of high operating voltage, high energy density, low self-discharge, and absence of memory effects, their application range, which was primarily restricted to portable electronic devices, is now being extended to high-power applications, such as electric vehicles (EVs) and hybrid electrical vehicles (HEVs). Among various anode materials, $Li_4Ti_5O_{12}$ (LTO) is believed to be a promising anode material for high-power LIBs due to its advantages of high working potential and outstanding cyclic stability. However, the rate performance of LTO is limited by its intrinsically low electronic conductivity and poor $Li^+$ ion diffusion coefficient. This review highlights the recent progress in improving the rate performance of LTO through doping, compositing, and nanostructuring strategies.

• 천문학회보
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• 제46권2호
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• pp.44.3-45
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• 2021

일반화된 excursion set 이론과 자기 유사 구형 유입(Self-similar spherical infall) 모형에 기반하여 Splashback 질량함수에 대한 해석적 단일 매개변수 모델을 착안하였다. Planck/WMAP7 관측결과를 토대로 구축된 EREBOS N-Body 시뮬레이션의 수치적 결과의 해석적 모델을 이용한 회귀분석을 통해 단일 매개변수이자 Splashback 경계의 확산적 특성을 수치화하는 확산계수(Diffusion Coefficient)의 추정치를 계산하였다. 계산된 확산계수를 적용한 해석적 모델과 수치적 결과가 5 ≤ M/(10¹²h^-1 M_⊙) < 10³의 질량범위에서 매우 근접히 일치하는 것을 보였으며 Baysian and Akaike Information Criterion 검정을 통해 0.3 ≤ z ≤ 3의 범위에서 기존의 모델들보다 본 모델이 선호 돼야함을 확인하였다. 또한 확산계수가 적색편이에 대하여 선형진화에 근접한 변화를 보임을 발견하였으며, 특정 임계 적색편이(z_c)를 기준으로 확산계수가 0에 수렴함을 발견하였다. 더 나아가 두 Planck모델과 WMAP7모델에서 도출된 확산계수는 서로 상당한 차이를 보였다. 이 결과는 암흑물질 헤일로의 splashback 질량함수가 z ≥ z_c에서 매개변수가 없는 온전한 해석적 모델로 설명되고 z_c가 독립적으로 우주의 초기조건을 독립적으로 특정지을 수 있는 가능성을 지님을 시사한다. 이 초록은 The Astrophysical Journal의 Ryu & Lee 2021, ApJ, 917, 98 (arxiv:2103.00730) 논문을 바탕으로 작성되었다.

• 한국주조공학회지
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• 제36권5호
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• pp.167-173
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• 2016

The effect of various types of heat-treatment on the mechanical properties of cast Alloy 718 has been investigated. Cast Alloy 718 bars were subjected to 'standard heat-treatment'_(SHT), 'HIP (Hot Isostatic Pressing) heat-treatment'_(HHT), and 'HIP-simulated heat-treatment'_(HS). In the absence of long time high temperature heat-treatment, a small amount of Laves phase remained in the 'SHT' specimen, and needle shaped ${\delta}$ precipitated in the vicinity of the Laves phase. Due to the formation of the Laves and ${\delta}$ phases in the 'SHT' specimen, it exhibited lower tensile properties than those of the others_specimens. On the other hand, the Laves phase was completely dissolved into the matrix after 'HHT' and 'HS' treatments. It is known that isostatic pressure reduces the self-diffusion coefficient, because of the lower self-diffusivity under HIP conditions in the interdendritic region, Nb segregation and the high amount of ${\gamma}^{{\prime}{\prime}}$ precipitation that occurs. Due to the higher fraction of coarse ${\gamma}^{{\prime}{\prime}}$ phases, the 'HHT' treated Alloy 718 showed excellent tensile strength.