• 제목/요약/키워드: Selective transport characteristics

검색결과 19건 처리시간 0.025초

감마선이 조사된 세포막모델을 통한 알칼리금속 이온의 선택적 전달 특성 (Selective transport characteristics of alkali metal ions through a cell membrane model which irradiated by γ-ray)

  • 고인호;여진동
    • 한국방사선학회논문지
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    • 제7권1호
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    • pp.85-91
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    • 2013
  • 감마선이 조사된 세포막 모델에서 $K^+$$Na^+$의 선택적 전달특성을 연구하였다. 이 실험에 사용된 세포막 모델은 $Na^+$ 슬폰화 폴리스티렌-디비닐벤젠(polystyrene-divinylbenzene) 혼성 중합막을 사용하였다. 이온의 초기플럭스는 $H^+$ 이온 농도의 증가와 함께 증가하였다. 이 실험의 조건을 pH 0.5-3, 온도 $15-65^{\circ}C$로 하여 첫 번째 조사되지 않은 막의 $K^+$$K^+/Na^+$의 선택도는 약 1.06 - 1.13이고 두 번째 조사된 막의 $K^+$$K^+/Na^+$의 선택도는 약 0에 가깝다. 조사된 막의 pH의 추진력은 조사되지 않은 막보다 약 4-5배 정도 유의성 있게 증가하였다. 세포막모델에서 $K^+$$Na^+$의 선택적 전달특성이 비정상적이기 때문에 세포장해가 세포에서 발현된다.

무선 채널에서의 Selective Repeat ARQ 프로토콜의 Delay 성능 분석 (Delay Analysis of Selective Repeat ARQ for a Markovian Source Over a Wireless Channel)

  • 김정근;김영수;이계산
    • 한국통신학회논문지
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    • 제29권11B
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    • pp.930-937
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    • 2004
  • 이 논문에서는 시간에 따라 채널 상태가 변화는 무선 채널 상에서 Markov 소스의 딜레이 성능을 분석하였다. 무선 링크의 양단에서 Selective-repeat (SR) ARQ 프로토콜을 사용한다고 가정했다. 이 논문에서는 대기 시간과 전송 및 재전송 시간 그리고 재 정렬 시간으로 구성된 단대단 평균 패킷 딜레이에 대한 근사화된 분석 방식을 제안하였다. 수치적인 분석과 시뮬레이tus 결과와의 분석을 통해서, 이 연구에서 제안한 분석 방식이 대부분의 경우 정확한 결과를 예측하고 있음을 증명하였다.

다공성 멤브레인의 표면 개질에 따른 구조 및 성능 특성에 대한 실험 연구 (Experimental Study on Structural and Functional Characteristics of Surface-Modified Porous Membrane)

  • 이상혁;김기웅
    • 한국가시화정보학회지
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    • 제19권1호
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    • pp.50-56
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    • 2021
  • With the advances in recent nanotechnology, mass transport phenomena have been receiving large attention both in academic researches and industrial applications. Nonetheless, it is not clearly determined which parameters are dominant at nanoscale mass transport. Especially, membrane is a kind of technology that use a selective separation to secure fresh water. The development of great separation membrane and membrane-based separation system is an important way to solve existing water resource problems. In this study, glass fiber-based membranes which are treated by graphene oxide (GO), poly-styrene sulfonate (GOP) and sodium dodecyl sulfate (GPS) were fabricated. Mass transport parameters were investigated in terms of material-specific and structure-specific dominance. The 3D structural information of GO, GOP, and GPS was obtained by using synchrotron X-ray nano tomography. In addition, electrostatic characteristic and water absorption rate of the membranes were investigated. As a result, we calculated internal structural information using Tomadakis-Sotrichos model, and we found that manipulation of surface characteristics can improve spacer arm effect, which means enhancement of water permeability by control length of ligand and surface charge functionality of the membrane.

Fabrication and characteristics of the flexible DSSC

  • 최은창;최원창;위진욱;홍병유
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.400.2-400.2
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    • 2016
  • Dye-sensitized solar cells (DSSCs) have been widely investigated as a next generation solar cell because of their simple structure and low manufacturing cost. To realize a commercially competitive technology of DSSCs, it is imperative to employ a technique to prepare nanocrystlline thin film on the flexible organic substrate, aiming at increasing the flexibility and reducing the weight as well as the overall device thickness of DSSCs. The key operation of glass-to-plastic substrates conversion is to prepare mesoporous TiO2 thin film at low temperature with a high surface area for dye adsorption and a high degree of crystallinity for fast transport of electrons. However, the electron transport in the TiO2 film synthesized at low temperature is very poor. So, in this study, TiO2 films synthesized at high temperature were transferred on the selective substrate. We fabricated DSSCs at low temperature using this method. So, we confirmed that the performance of DSSCs using TiO2 films synthesized at high temperature was improved.

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Efficient Electron Transfer in CdSe-py-SWNTs FETs

  • Jeong, So-Hee;Shim, H.C.;Han, Chang-Soo
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.63-63
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    • 2010
  • Ability to transport extracted carriers from NQDs is essential for the development of most NQD based applications. Strategies to facilitate carrier transport while preserving NQDs' optical characteristics include: 1) Fabricating neat films of NQDs with modified surfaces either by adapting series of ligands with certain limitations or by applying physical processes such as heat annealing 2) Coupling of NQDs to one-dimensional nanostructures such as single walled carbon nanotubes (SWNTs) or various types of nanowires. NQD-nanowire hybrid nanostructures are expected to facilitate selective wavelength absorption, charge transfer to 1-D nanostructures, and efficient carrier transport. Even with the vast interests in using NQD-SWNT hybrid materials in optoelectric applications, still, no reports so far have clearly elucidated the optoelectric behavior when they were assembled on the FET mainly because the complexity involving in both components in their preparation and characterization. We have monitored the optical properties of both components (NQDs, SWNTs) from the synthesis, to the assembly, and to the device. More importantly, by using pyridine molecules as a linker to non-covalently attach NQDs to SWNTs, we were able to assemble NQDs on SWNTs with precise density control without harming their electronic structures. Furthermore, by measuring electrical signals from the fabricated aligned SWNTs-FET using dielectrophoresis (DEP), we were able to elucidate the charge transfer mechanism.

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고에너지 엑스선을 조사한 갑상선의 세포막모델에서 요오드이온의 선택적 투과성 전달 특성 (Selective Permeate Transport Characteristics of Iodine ion at Cell Membrane Model of Thyroid which Irradiated by High Energy X-Ray)

  • 고인호;여진동
    • 한국방사선학회논문지
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    • 제15권2호
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    • pp.229-238
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    • 2021
  • 본 논문에서는 고에너지 엑스선(6 MV X선)을 조사한 갑상선의 소포세포막 모델에서 막의 두께차이, 고정전달자[VP-AN% (w/ w)]의 농도차이, OH-이온의 농도차이가 세포내부와 세포외부사이로 갑상선호르몬의 구성성분인 요오드이온의 농도차이로 발생하고 갑상선호르몬의 생성량에 영향을 미치는데 이러한 영향을 구명하기위해서 소포의 세포막을 통한 요오드의 선택적 투과전달 특성에 대하여 연구하였다. 이 실험에 사용한 세포막 모델은 피리딘 양이온을 고정전달자로 한 poly(4-vinylpyridine- co-acrylonitrile :VP-AN)분말을 인장강도의 강화용인 polysulfone과 결합시킨 불균질의 복합막을 사용하였다. 고정전달자[VP-AN% (w/ w)]의 농도차이(0~62 %)에서 36.5 ℃로 방사선을 조사한 소포의 고분자 막(세포막모델)은 형태학적 변화인 인장강도가 비 조사된 세포막모델보다 약 1.2 ~ 1.8배 정도 감소되었다. 방사선을 조사한 갑상선의 소포세포막모델 [2mole AN%(w/w)]에서 막의 두께차이, 고정전달자[VP-AN% (w/ w)]의 농도차이, OH-이온의 농도 차이로 발생하는 요오드이온의 선택적 투과플럭스는 비 조사된 세포막모델보다 막의 두께가 변화 할 때 각각 약 2.1 ~ 4.5배, 약 2.2 ~ 2.5배, 약 2.1 ~ 2.67배 정도 감소되었다. 결국 방사선조사로 인해서 갑상선의 소포세포막에서 요오드이온의 선택적 투과 전달기능이 비정상적으로 되어 세포장해가 발생하고 갑상선호르몬의 생성량 감소도 동반하게 되었다고 사료됐다.

유제화에 의한 경구용 항암제인 테가푸르의 장관 임파수송 (Mesenteric Lymphatic Delivery of Oral Anticancer Tegafur by Emulsion Formulations)

  • 이용복;남권호;장우익;오인준;고익배
    • Journal of Pharmaceutical Investigation
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    • 제25권1호
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    • pp.55-62
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    • 1995
  • W/O and O/W emulsions of tegafur (50 mg/5 ml/kg) were orally administered to rats to compare with their mesenteric lymphatic delivery effects. And also in order to demonstrate the lymph targeting associated to the oral route, it was deemed necessary to investigate the fate of solution after oral administration as a control. Lymph and plasma samples were periodically taken from each subject of mesenteric lymphatic duct cannulated rats. Then, lymph and plasma levels of tegafur and its active metabolite, 5-FU, were simultaneously observed. Also pharmacokinetic parameters were compared with each others. On the other hand, most previous studies of lymphatic transport have not addressed the question of whether an increase in mesenteric or thoracic lymph transport by the manipulation of a suspected variable was due to a selective delivery to the intestinal lymphatics or an overall increase availability. Therefore, based on a physiologically based pharmacokinetic model which represents the characteristics of lymphatic systems, we are also going to determine the contributions of mesenteric lymph transport versus thoracic lymph transport of tegafur reported in reference(13). In comparison with tegafur solution, AUC and mean residence time of plasma tegafur were significantly increased in W/O emulsion but significantly decreased in O/W emulsion. Lymph flow rates were similar in both solution and W/O emulsion but half in O/W emulsion. AUC of tegafur in mesenteric lymph and in plasma for W/O emulsion were 3.7 times and 2.9 times more than those for O/W emulsion, respectively. And AUC of 5-FU in thoracic lymph for W/O emulsion was 3.7 times more than that for O/W emulsion. These results suggested that lymphatic delivery or tegafur by W/O emulsion was more effective than that by on emulsion due to its differences or formation ability of chylomicrons.

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Green Phosphorescent OLED Without a Hole/Exciton Blocking Layer Using Intermixed Double Host and Selective Doping

  • Kim, Won-Ki;Kim, Hyung-Seok;Shin, Hyun-Kwan;Jang, Ji-Geun
    • 한국재료학회지
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    • 제19권5호
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    • pp.240-244
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    • 2009
  • Simple and high efficiency green phosphorescent devices using an intermixed double host of 4, 4', 4"-tris(N-carbazolyl) triphenylamine [TCTA], 1, 3, 5-tris (N-phenylbenzimiazole-2-yl) benzene [TPBI], phosphorescent dye of tris(2-phenylpyridine)iridium(III) [$Ir(ppy)_3$], and selective doping in the TPBI region were fabricated, and their electro luminescent characteristics were evaluated. In the device fabrication, layers of $70{\AA}$-TCTA/$90{\AA}$-$TCTA_[0.5}TPBI_{0.5}$/$90{\AA}$-TPBI doped with $Ir(ppy)_3$ of 8% and an undoped layer of $50{\AA}$-TPBI were successively deposited to form an emission region, and SFC137 [proprietary electron transporting material] with three different thicknesses of $300{\AA}$, $500{\AA}$, and $700{\AA}$ were used as an electron transport layer. The device with $500{\AA}$-SFC137 showed the luminance of $48,300\;cd/m^2$ at an applied voltage of 10 V, and a maximum current efficiency of 57 cd/A under a luminance of $230\;cd/m^2$. The peak wavelength in the electroluminescent spectral and color coordinates on the Commission Internationale de I'Eclairage [CIE] chart were 512 nm and (0.31, 0.62), respectively.

전단흐름 하에 이온교환막 위에서 발생하는 전기수력학적 와류 (Electroconvective vortex on an Ion Exchange Membrane under Shear Flow)

  • 곽노균
    • 한국가시화정보학회지
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    • 제16권1호
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    • pp.61-69
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    • 2018
  • Ion exchange membrane can transfer only cation or anion in electrically conductive fluids. Recent studies have revealed that such selective ion transport can initiate electroconvective instability, resulting vortical fluid motions on the membrane. This so-called electroconvective vortex (a.k.a. electroconvection (EC)) has been in the spotlight for enhancing an ion flux in electrochemical systems. However, EC under shear flow has not been investigated yet, although most related systems operate under pressure-driven flows. In this study, we present the direct visualization platform of EC under shear flow. On the transparent silicone rubber, microscale channels were fabricated between ion exchange membranes, while allowing microscopic visualization of fluid flow and ion concentration changes on the membranes. By using this platform, not only we visualize the existence of EC under shear flow, its unique characteristics are also identified: i) unidirectional vortex pattern, ii) its advection along the shear flow, and iii) shear-sheltering of EC vortices.

대청도 지두리 해안의 모래 퇴적층의 특성과 매몰연대에 대한 연구 (A Study on the Characteristics and Burial Ages of Sediment Deposits at Jiduri, Daecheong Island)

  • 김종연
    • 한국지형학회지
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    • 제25권1호
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    • pp.1-17
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    • 2018
  • The characteristics and burial ages of sand sediments on the Jiduri coast in Daechung-myeon, Ongjin-gun, Incheon were investigated. Daecheong Island is the area where the characteristics of the rocky coast and sand coast are shown. Various studies have been conducted on the Okjukdong sand dune that appears in the north of the island. However, there has been no study on the sandy sedimentary topography of the Jiduri and Moraewul area in the south. The sandy sedimentary terrain of Jiduri is divided into sandy beaches, sand dunes and sand deposits along the slope including climbing dune. Overall, the depth of sandy sediments in Jiduri is not deep. The characteristics of sandy sediments and burial ages were investigated at an elevation of about 23 m above sea level at the back of Jiduli Beach and 46 m above sea level at the ridge line between Jiduri and Moraewol. From the Jiduri coast to the hillside behind, the average grain size decreases and the sorting becomes better as it moves from the intertidal zone to the beach and the foredune. This indicates the selective sand transport by the wind and can be judged by the terrain formed under the current sedimentation environment. The average grain size at the upper part of the section of JD-1 (elevation of about 23m MSL) was $1.6918{\varphi}$ of medium sand. The sorting was $0.4584{\varphi}$, skewness was -1.0491 and kurtosis was -1.2411, respectively. Particularly, the average particle size of the crosssection issomewhat uniform, but the color of the constituent material changes from brown to black. In the case of JD-2 (about 46 m MSL), the mean grain size of the section was $1.7943{\varphi}$, the sorting was 0.4931, the skewness was -1.1163, and the kurtosis was 1.2133. On the other hand, the brown and black layers of JD-1 exhibited a burial age of $0.1{\pm}0.0ka$ and the JD-2 had a burial age of $0.7{\pm}0.0ka$.