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Green Phosphorescent OLED Without a Hole/Exciton Blocking Layer Using Intermixed Double Host and Selective Doping

  • Kim, Won-Ki (Department of Electronics Engineering, Dankook University) ;
  • Kim, Hyung-Seok (Department of Electronics Engineering, Dankook University) ;
  • Shin, Hyun-Kwan (Department of Electronics Engineering, Dankook University) ;
  • Jang, Ji-Geun (Department of Electronics Engineering, Dankook University)
  • Published : 2009.05.27

Abstract

Simple and high efficiency green phosphorescent devices using an intermixed double host of 4, 4', 4"-tris(N-carbazolyl) triphenylamine [TCTA], 1, 3, 5-tris (N-phenylbenzimiazole-2-yl) benzene [TPBI], phosphorescent dye of tris(2-phenylpyridine)iridium(III) [$Ir(ppy)_3$], and selective doping in the TPBI region were fabricated, and their electro luminescent characteristics were evaluated. In the device fabrication, layers of $70{\AA}$-TCTA/$90{\AA}$-$TCTA_[0.5}TPBI_{0.5}$/$90{\AA}$-TPBI doped with $Ir(ppy)_3$ of 8% and an undoped layer of $50{\AA}$-TPBI were successively deposited to form an emission region, and SFC137 [proprietary electron transporting material] with three different thicknesses of $300{\AA}$, $500{\AA}$, and $700{\AA}$ were used as an electron transport layer. The device with $500{\AA}$-SFC137 showed the luminance of $48,300\;cd/m^2$ at an applied voltage of 10 V, and a maximum current efficiency of 57 cd/A under a luminance of $230\;cd/m^2$. The peak wavelength in the electroluminescent spectral and color coordinates on the Commission Internationale de I'Eclairage [CIE] chart were 512 nm and (0.31, 0.62), respectively.

Keywords

References

  1. S. Lamansky, P. Djarovich, D. Murphy, F.A. Razzaq, R. Kwong, I. Tsyba, M. Bortz, B. Mui, R. Bau and M.E. Thompson, J. Am. Chem. Soc., 123, 4304 (2001) https://doi.org/10.1021/ja003693s
  2. J. H. Burroughs, D. D. C. Bradley, A. R. Brown, R. N. Marks, K. Mackay, R. H. Friend, P. L. Burn and A. B. Holmes, Nature., 347, 539 (1990) https://doi.org/10.1038/347539a0
  3. M. A. Baldo, S. Lamansky, P. E. Burro-Ws, M. E. Thompson and S. R. Forrest, Appl. Phys. Lett., 75, 4 (1999) https://doi.org/10.1063/1.124258
  4. Z. H. Kafafi, Organic Electroluminescence, p. 1, ed., B. J.Thompson, Taylor & Francis, New York, USA, (2005)
  5. W. Kern, Thin Film Process II, p. 501, ed., J. L. Vossen, Academic Press, San Diego, USA, (2002)
  6. J.S. Wilson, A.S. Dhoot, A.J.A.B. Seeley, M.S. Khan, A. Kohler and R.H. Friend, Nature., 413, 828 (2001) https://doi.org/10.1038/35101565
  7. W. Lu, B.-X. Mi, M.C.W. Chan, Z. Hui, C.-M. Che, N. Zhu and S.-T. Lee, J. Am. Chem. Soc., 126, 4958 (2004) https://doi.org/10.1021/ja0317776
  8. H. Matsushima, S. Naka, H. Okada and H. Onnagawa, Current Applied Physics., 5, 305 (2005) https://doi.org/10.1016/j.cap.2003.11.091
  9. X. Zhou, D.S. Qin, M. Pfeiffer, J. Blochwitz, A. Werner, J. Crechsel, B. Maennig, K. Leo, M. Bold, P. Erk and H. Hartmann, Appl. Phys. Lett., 81, 4070 (2002) https://doi.org/10.1063/1.1522495
  10. G. He, M. Pfeiffer, K. Leo, M. Hofmann, J. Birnstock, R. Pudzich and J. Salbeck, Appl. Phys. Lett., 85, 3911 (2004) https://doi.org/10.1063/1.1812378
  11. M. Ikai, S. Tokito, Y. Sakamoto, T. Suzuki and Y. Taga, Appl. Phys. Lett., 79, 156 (2001) https://doi.org/10.1063/1.1385182
  12. M. Mitsuya, T. Suzuki, T. Koyama, H. Shirai, M. Satuki, Y. Taniguchi, M. Satsuki and S. Suga, Appl. Phys. Lett., 77, 3272 (2000) https://doi.org/10.1063/1.1326491