• 약학회지
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• 제46권5호
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• pp.320-323
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• 2002

A method for the determination of acidic drug, mefenamic acid and ibuprofen with ion-selective electrode(ISE) using Fe(II)-di-2-pyridyl ketone oxime complex as a counter ion were developed. Benzyl-2-nitrophenyl ether(BNPE) plasticized membrane was more selective and sensitive than the other tested membranes. The acidic drug selective electrode exhibits a linear response for 10$^{-2}$ M 510$^{-5}$ M of acidic drugs, mefenamic acid and ibuprofen with a slope of -55.9 and -56.3 mV/dec. in borate buffer solution (pH 8.9). Potentiometric selectivity measurements revealed negligible interferences from aromatic and aliphatic carboxylic acid salts. The electrodes were found to be useful for the direct determination of mefenamic acid and ibuprofen in pharmaceutical preparations.

• 방사성폐기물학회지
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• 제21권1호
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• pp.43-53
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• 2023

Sulfide concentrations critically affect worker safety and the integrities of underground facilities, such as deep geological repositories for spent nuclear fuel. Sulfide is highly sensitive to oxygen, which can oxidize sulfide to sulfate. This can hinder precise measurement of the sulfide concentration. Hence, a literature review was conducted, which revealed that two methods are commonly used: the methylene blue and sulfide ion-selective electrode (ISE) methods. Inductively coupled plasma optical emission spectroscopy (ICP-OES) was used for comparison with the two methods. The sulfide ISE method was found to be superior as it yielded results with a higher degree of accuracy and involved fewer procedures for quantification of the sulfide concentration in solution. ICP-OES results can be distorted significantly when sulfide is present in solution owing to the formation of H₂S gas in the ICP-OES nebulizer. Therefore, the ICP-OES must be used with caution when quantifying underground water to prevent any distortion in the measured results. The results also suggest important measures to avoid problems when using ICP-OES for site selection. Furthermore, the sulfide ISE method is useful in determining sulfide concentrations in the field to predict the lifetime of disposal canisters of spent nuclear fuel in deep geological repositories and other industries.

• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2001년도 추계학술발표대회
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• pp.685-688
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• 2001

분자각인 막에 대한 선택적인 홉착을 알아보기 위해서 우리는 템플릿을 바꾸어 보기도 하고 중합방법과 세척조건을 다르게 하였다. 결과에서 우리는 템플릿 탈착에는 아세트산 10% 수용액으로 세척한 경우 가장 우수한 회수도를 보였다. 그러고 In-situ implanting method가 post implanting method에 비해 약 1.8 나 더 나은 선택 흡착성을 보였다.

• Bulletin of the Korean Chemical Society
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• 제35권11호
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• pp.3209-3212
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• 2014

This paper describes a selective synthetic method of fabricating Ag nanowires by using a modified polyol process. To synthesize the Ag nanowire, an ethylene glycolic solution of silver nitrate and an ethylene glycolic solution of polyvinylpyrrolidone solution containing a small amount of organic oxidant, 1,4-benzoquinone, were slowly added to a hot ethylene glycol medium at $160^{\circ}C$ for 8 min using a syringe pump. The reaction mixtures were heated for an additional 45 min and cooled to room temperature. Finally, the silver nanomaterials were isolated from the mixture by centrifugation. The crystal structure of the nanomaterials was investigated by powder X-ray diffraction analyses, and their morphology was investigated by scanning electron microscopy. A small amount of organic oxidant, 1,4-benzoquinone, played a significant role in controlling the morphology during crystal growth. Consequently, Ag nanowires rather than Ag nanoparticles were selectively obtained.

• 대한화학회지
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• 제8권3호
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• pp.109-112
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• 1964

A volumetric method of the determination of calcium carbonate and calcium fluoride in fluorspar concentrate is described. The carbonate is converted into solution by treatment of the sample in HNO$_3$-acetone (l% by volume) mixture, and the fluoride by treating the residue with H$_3BO_3$-HCl mixture. The calcium in the solution is determined volumetrically using EDTA standard solution. The selective dissolution of calcium carbonate by HNO$_3$-acetone mixture is superior to Bidtel's acetic method and little correction for the dissolution of calcium fluoride is needed. Triethanolamine is found to be superior to KCN in masking heavy metal ions.

• Journal of Electrical Engineering and Technology
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• 제10권3호
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• pp.944-951
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• 2015

Pulse Width Modulation (PWM) techniques are increasingly employed for PWM inverter fed induction motor drive. Among various popular PWM methods used, Selective Harmonic Elimination PWM (SHEPWM) has been widely accepted for its better harmonic elimination capability. In addition, using SHEPWM, it is also possible to maintain better voltage regulation. Hence, in this paper, an attempt has been made to apply Bacterial Foraging Algorithm (BFA) for solving selective harmonic elimination problem. The problem of voltage harmonic elimination together with output voltage regulation is drafted as an optimization task and the solution is sought through proposed method. For performance comparison of BFA, the results obtained are compared with other techniques such as derivative based Newton-Raphson method, and Genetic Algorithm. From the comparison, it can be observed that BFA based approach yields better results. Further, it provides superior convergence, reduced computational burden, and guaranteed global optima. The simulation results are validated through experimental findings.

• Journal of Power Electronics
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• 제17권5호
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• pp.1186-1194
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• 2017

This paper proposes an improved low frequency Selective Harmonic Mitigation-PWM (SHM-PWM) technique. The proposed method mitigates the low order harmonics of the output voltage up to the $50^{th}$ harmonic well and satisfies the grid codes EN 50160 and CIGRE-WG 36-05. Using a modified criterion for the switching angles, the range of the modulation index for non-linear SHM equations is improved, without increasing the switching frequency of the CHB converter. Due to the low switching frequency of the CHB converter, mitigating the harmonics of the converter up to the $50^{th}$ order and finding a wider modulation index range, the size and cost of the passive filters can be significantly reduced with the proposed technique. Therefore, the proposed technique is more efficient than the conventional SHM-PWM. To verify the effectiveness of the proposed method, a 7-level Cascaded H-bridge (CHB) converter is utilized for the study. Simulation and experimental results confirm the validity of the above claims.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.252.2-252.2
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• 2013

ZnO nanostructures have a lot of interest for decades due to its varied applications such as light-emitting devices, power generators, solar cells, and sensing devices etc. To get the high performance of these devices, the factors of nanostructure geometry, spacing, and alignment are important. So, Patterning of vertically- aligned ZnO nanowires are currently attractive. However, many of ZnO nanowire or nanorod fabrication methods are needs high temperature, such vapor phase transport process, metal-organic chemical vapor deposition (MOCVD), metal-organic vapor phase epitaxy, thermal evaporation, pulse laser deposition and thermal chemical vapor deposition. While hydrothermal process has great advantages-low temperature (less than $100^{\circ}C$), simple steps, short time consuming, without catalyst, and relatively ease to control than as mentioned various methods. In this work, we investigate the dependence of ZnO nanowire alignment and morphology on si substrate using of nanosphere template with various precursor concentration and components via hydrothermal process. The brief experimental scheme is as follow. First synthesized ZnO seed solution was spun coated on to cleaned Si substrate, and then annealed $350^{\circ}C$ for 1h in the furnace. Second, 200nm sized close-packed nanospheres were formed on the seed layer-coated substrate by using of gas-liquid-solid interfacial self-assembly method and drying in vaccum desicator for about a day to enhance the adhesion between seed layer and nanospheres. After that, zinc oxide nanowires were synthesized using a low temperature hydrothermal method based on alkali solution. The specimens were immersed upside down in the autoclave bath to prevent some precipitates which formed and covered on the surface. The hydrothermal conditions such as growth temperature, growth time, solution concentration, and additives are variously performed to optimize the morphologies of nanowire. To characterize the crystal structure of seed layer and nanowires, morphology, and optical properties, X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), Raman spectroscopy, and photoluminescence (PL) studies were investigated.

• 한국전자파학회논문지
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• 제22권12호
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• pp.1180-1183
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• 2011

본 논문에서는 단위-셀 EM 시뮬레이션 기법을 통해 주파수 선택적 전파투과막(FSS: Frequency Selective Surface)을 갖는 AEM(Advanced Enclosed Mast) 레이돔을 설계하고, $16{\times}16$ 배열안테나 방사 패턴 시험을 통해 레이돔의 성능을 검증하였다. 측정한 결과, 평면파 입사 조건을 가정한 시뮬레이션 결과와 원전계 및 근전계 조건에 레이돔을 두고 시험한 결과가 서로 잘 일치하는 결과를 확인하였다. 이 결과들을 통해 검증된 AEM형 FSS 레이돔을 활용하여 기존 마스트 대비 안테나의 RCS를 줄이는 것이 가능할 것이다.

• 한국전산구조공학회논문집
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• 제15권4호
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• pp.599-607
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• 2002

형상 최적설계 중에 발생하는 절점의 과도한 이동은 요소망을 왜곡하고, 결국 최적해의 저하를 유발한다. 이러한 문제를 개선한 형상 최적설계 기법을 개발하였다. 이 방법은 구조물의 형상이 변해 갈 수 있는 충분한 공간의 설계 영역을 정하여, 균일하고 세밀한 요소망을 미리 생성한다. 각각의 최적화 단계마다 모든 요소들과 구조물의 위치 관계를 검사하여, 내부의 요소에는 실제의 물성치를 부여하고, 외부에 존재하는 요소는 0에 가까운 물성치를 부여한다. 변위와 고유 진동수의 제한조건을 가진 두 개의 예제를 통해 이 방법의 특징을 살펴보았다.