• Title/Summary/Keyword: Selective extraction

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Selective Solvent Extraction of In from Synthesis Solution of MOCVD Dust using D2EHPA (MOCVD 더스트 합성용액으로부터 D2EHPA를 이용한 In의 선택적 용매추출)

  • Im, Byoungyong;Swain, Basudev;Lee, Chan Gi;Park, Jae Layng;Park, Kyung-Soo;Shim, Jong-Gil;Park, Jeung-Jin
    • Resources Recycling
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    • v.24 no.5
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    • pp.80-86
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    • 2015
  • The separation of In from the synthesis solution with Ga, Fe, and Al has been studied by the solvent extraction using D2EHPA as an extractant. The effects as a function of the concentration of extractant and HCl on the extraction of In were investigated. The extraction of In and Ga increased with decreasing HCl concentration, but that of Fe and Al was independent. Separation factor between In and Ga of 115 was obtained at 1.0 M D2EHPA in the presence of 0.5 M HCl of feed solution. Consequently, this study shows that D2EHPA is suitable extractant for In extraction from the synthesis solution. Extraction efficiency and separation factor could be increased by controlling HCl and extractant concentration.

Telephone Speech Recognition with Data-Driven Selective Temporal Filtering based on Principal Component Analysis

  • Jung Sun Gyun;Son Jong Mok;Bae Keun Sung
    • Proceedings of the IEEK Conference
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    • 2004.08c
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    • pp.764-767
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    • 2004
  • The performance of a speech recognition system is generally degraded in telephone environment because of distortions caused by background noise and various channel characteristics. In this paper, data-driven temporal filters are investigated to improve the performance of a specific recognition task such as telephone speech. Three different temporal filtering methods are presented with recognition results for Korean connected-digit telephone speech. Filter coefficients are derived from the cepstral domain feature vectors using the principal component analysis.

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Wavelet circular harmonic function frequency selective joint transform correlator for rotation invariant pattern recognition (회전불변 패턴인식을 위한 WCHF-FSJTC)

  • 방준학;이하운;노덕수;김수중
    • Journal of the Korean Institute of Telematics and Electronics S
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    • v.34S no.2
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    • pp.94-103
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    • 1997
  • The WCHF-FSJTC (wavelet circular harmonic function frequency selective joint transform correlator) using th wavelet transformed CHF as the reference image in FSJTC is proposed for rotation invariant pattern recognition. Since the wavelet transform has the property of feature extraction, the proposed system can have the better DC (discrimination cpability) and the higher SNR(signal to noise ratio) compared with the conventional CHF-CJTC(circular harmonic function conventional joint transform correlator). And since the structure of the proposed system is FSJTC which can eliminate auto-correlation and cross-correlation between input images, it can eliminate false alarm caused by the overlapping among correlation peaks. The used wavelet functio is the morlet function, which is proper for the reference image used in this paper. the optimal dialation parameter and oscillation frequency of the wavelet function are also achieved with varying the parameters of the wavelet function. The computer simulation shows that the proposed system has the best performance when the dilation parameter is 0.8 and the oscillation frequency is 0.48.

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Real-time Object Recognition with Pose Initialization for Large-scale Standalone Mobile Augmented Reality

  • Lee, Suwon
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.14 no.10
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    • pp.4098-4116
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    • 2020
  • Mobile devices such as smartphones are very attractive targets for augmented reality (AR) services, but their limited resources make it difficult to increase the number of objects to be recognized. When the recognition process is scaled to a large number of objects, it typically requires significant computation time and memory. Therefore, most large-scale mobile AR systems rely on a server to outsource recognition process to a high-performance PC, but this limits the scenarios available in the AR services. As a part of realizing large-scale standalone mobile AR, this paper presents a solution to the problem of accuracy, memory, and speed for large-scale object recognition. To this end, we design our own basic feature and realize spatial locality, selective feature extraction, rough pose estimation, and selective feature matching. Experiments are performed to verify the appropriateness of the proposed method for realizing large-scale standalone mobile AR in terms of efficiency and accuracy.

Spectrophotometric Determination of Copper After Selective Extraction with $\alpha$-(2-Benzimidazolyl)-$\alpha ^{\prime}, \alpha ^{\prime} ^{\prime}$-(N-5-nitro-2-pyridyl hydrazone)-toluene in the Presence of Brij 58

  • 박찬일;김현수;차기원
    • Bulletin of the Korean Chemical Society
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    • v.20 no.3
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    • pp.352-354
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    • 1999
  • The spectrophotometric determination of Cu(Ⅱ) with α-(2-benzimidazolyl)-α',α"-(N-5-nitro-2-pyridylhydrazone)-toluene has been investigated. The optimum conditions of pH, stability, concentration of ligand and surfactant were evaluated. This method is a simple and sensitive method for determination of Cu(Ⅱ) and offers a selective separation of Cu(Ⅱ) from sample solution containin- I ppm below amount of Ni(Ⅱ), Co(Ⅱ), Zn(Ⅱ) and Sn(Ⅱ). Copper was determined by measuring the absorbance of Cu(Ⅱ)-BINPHT complex extracted with benzene in Brij 58 surfactant at 410 nm. Beer's law is obeyed over the concentration range 0∼2.5 μgmL-1 and the detection limit (S/N=2) is 0.06 μgmL-1. The relative standard deviation at the 0.3 μgmL-1 is 2.4% (N=7). The method was applied for the determination of Cu(Ⅱ) in various milks.

The Separation of Vanadium and Tungsten from Spent Selective Catalytic Reduction Catalyst Leach Solution by Alamine 336 (탈질 폐촉매 침출액으로부터 Alamine 336에 의한 바나듐과 텅스텐의 분리)

  • Seongsu Kang;Gyeonghye Moon;In-Hyeok Choi;Dakyeong Baek;Kyoungkeun Yoo
    • Resources Recycling
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    • v.33 no.3
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    • pp.30-37
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    • 2024
  • In this study, we investigated the separability of vanadium and tungsten from spent SCR (Selective Catalytic Reduction) catalyst leach solution by reduction of vanadium and solvent extraction using Alamine 336 and conducted experiments to optimize process conditions. It is difficult to separate vanadium and tungsten due to their similar chemical behavior, but tungsten can be selectively extracted from acidic solution when vanadium extraction is prevented by reducing anionic pentavalent vanadium to cationic tetravalent vanadium. The results showed that NaHSO3 was most suitable as a reducing agent, and the extraction efficiency of vanadium decreased and the separation efficiency increased as the amount of reducing agent added, reaction time, and temperature increased. When reducing NaHSO3 1.5 eq, 60 min, and 60℃, which are optimal conditions of reduction, vanadium and tungsten were effectively separated with vanadium extraction efficiency of 5.8%, tungsten extraction efficiency of 99%, and separation factor of vanadium and tungsten of 7,564.

Competitive Solvent Extraction of the Mixture of Alkali Metal and Alkaline Earth Metal Cation containing Crown Ether Carboxylic Acid and Crown Ether Phosphonic Acid (크라운에테르 카르복시산과 크라운에테르 포스포닉산을 포함한 알칼리 금속과 알칼리 토금속 양이온 혼합물의 경쟁적 용매추출)

  • Chung, Yeong-Jin
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.3
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    • pp.219-227
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    • 2005
  • Competitive solvent extraction of the mixure of alkali metal and alkaline earth cation from water into organic solvent containing the crown ether carboxylic acid and anlogous crown ether phosphonic acid was investigated as follows. The lipophilic group is found to strongly influence to the selective extraction in the mixed systems from only alkali metal cation for sym-(n-decyldibenzo)-16-crown-5-oxyacetic acid $\underline{1}$ to mostly alkaline earth metal cation for sym-bis[4(5)-tert-butylbenzo]-16-crown-5-oxyacetic acid $\underline{3}$. Monoethyl sym-(n-decyldibenzo)-16-crown-5-oxymethylphosphonic acid $\underline{2}$. and monoethyl-sym- bis]4(5)-tert-butylbenzo]-16-crown-5-oxymethylphosphonic acid $\underline{4}$ showed good selectivity for $Na^+$ over $Mg^{2+}$, the second extracted ion. Structural variation in the crown ether phosphonic acid somewhat was influenced to the extraction selectivity in the mixed systems. when variation of the ionized group is influenced in the mixed systems, the selectivity of $Na^+$ as the second extracted ion was much better crown ether carboxylic acid $\underline{1}$ than crown ether phosphonic acid $\underline{2}$, while the efficiency of $Na^+$ extraction was better $\underline{2}$ (83% total loading) than $\underline{1}$ (32%).

Analysis of Aroma Compounds of Cinnamon by Solid Phase Microextraction (Solid Phase Microextraction을 이용한 계피의 향기성분 분석)

  • 이창국;이재곤;장희진;곽재진
    • The Korean Journal of Food And Nutrition
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    • v.16 no.4
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    • pp.372-378
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    • 2003
  • The volatile components of cinnamon bark were extracted by using different isolation methods, simultaneous distillation extraction (SDE) and solid phase microextraction (SPME). Then the volatile components were analyzed by gas chromatography(GC) and mass selective detector(MSD). 30 compounds were identified in cinnamon bark. In SPME technique, several factors influencing the equilibrium of the aroma compounds between sample and SPME fiber was taken into account, including the kind of SPME fiber, extraction temperature and extraction time. Four different SPME fibers were tested, namely polydimethylsiloxane (PDMS), poly acrylate(PA), divinyl- benzene-carboxen-polydimethylsiloxane (DVB/CAR/PDMS) and carbowax/divinylbenzene(CW/DVB). Among these SPME fiber, PDMS coating fiber showed the best results. The profile of volatile compounds of cinnamon bark at different extraction temperature and extraction time were investigated by 100$\mu\textrm{m}$ PDMS fiber.

Solvent Extraction of Zr(IV) and Hf(IV) from Sulfuric Acid Solutions by Acidic Extractants and Their Mixtures with TBP (황산용액에서 양이온계 추출제 및 TBP와의 혼합추출제에 의한 지르코늄(IV)과 하프늄(IV)의 용매추출)

  • Wang, Ling Yun;Lee, Man Seung
    • Resources Recycling
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    • v.25 no.2
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    • pp.3-9
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    • 2016
  • Separation of Zr(IV) and Hf(IV) from sulfuric acid solutions was investigated by extraction with several acidic extractants such as Versatic acid, LIX 63, and Cyanex 301. From strong sulfuric acid solutions, the separation of Zr(IV) and Hf(IV) by Versatic acid and LIX 63 was not possible, while selective extraction of Hf(IV) over Zr(IV) was obtained with Cyanex 301. However, the extraction percentage of the two metals was much lower compared to that by D2EHPA. Mixing of TBP with Cyanex 301 and D2EHPA led to negative effect on the extraction and separation of the two metal ions. The difference in the extraction reaction and separation selectivity between HCl, $HNO_3$ and $H_2SO_4$ media with each extractant was discussed.

Colorimetric Determination of Trace Mercury(II) in Water by Back Extraction and PAR (역추출과 PAR법에 의한 수질중 미량 수은의 비색정량에 관한 연구)

  • 정창웅
    • Journal of Environmental Health Sciences
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    • v.21 no.3
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    • pp.96-101
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    • 1995
  • A selective and highly sensitive spectrophotometric measurements have been developed for the determination of trace mercury(II) with thiosulfate and PAR. Hg(II)-thiosulfate complex was extracted into high molecular alkylamine such as quaternary ammonium salt and back extracted into 1 M-HCl solution. The Hg(II)-PAR complex has maximum absorbance at 499 nm and obeys Beer's law in the range of 0.04~1.0 $\mu g/mL$ of mercury(II). The molar absorptivity and Sandell's sensitivity are $6.27\times 10^4 L.mole^{-1} cm^{-1}$ and $3.2\times 10^{-3}g/cm^2$ respectively.

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