• Title/Summary/Keyword: Secondary Source

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Comparative Study on Photochemical Reactions of Aromatic Hydrocarbons in Indoor and Outdoor Smog Chambers (실내/외 스모그 챔버에서의 방향족계 탄화수소의 광화학 반응 비교 연구)

  • Dong Jong-In;Ahn Heung-Soon
    • Journal of Environmental Science International
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    • v.14 no.2
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    • pp.231-240
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    • 2005
  • The number of cases exceeding environmental standards of atmospheric ozone in the major cities in Korea has steadily increased during the past decades. In order to understand and analyze the atmospheric reactions in the atmosphere, especially the secondary photochemical reactions, smog chambers studies have been performed very actively by many research groups worldwide. However, these studies have focused on the mechanism of photochemical reactions in high concentration conditions, not at the ambient levels. Therefore, in-depth studies in these conditions are essentially needed to realize exact mechanism in the atmosphere near the earth surface, especially at Korean atmospheric conditions. In this experiment, the mechanism of photochemical smog was examined through a comparative experiment of smog chambers under sun light and black light conditions. The results of our study indicated that concentrations of ozone, aldehyde, and PAN increased as the radiation of light source increases. Photochemical reaction patterns can be considered quite similar for both black light and sun light experiments. Based on our experiments using toluene as a reactant which is present at significant high levels in ambient air relative to other VOCs, it was found that toluene could contribute notably to oxidize NO to $NO_2$, this reaction can eventually generate some other photochemical oxidants such as ozone, aldehyde, and PAN. The results of simulation and experiments generally showed a good agreement quite well except for the case of $O_3$. The restriction of oxidization of NO to $NO_2$ seems to cause this difference, which is mainly from the reaction of peroxy radical itself and other reactants in the real gas.

A Study on the Electrode Characteristics of Hypo-Stoichiometric Zr-based Hydrogen Storage Alloys

  • Lee, Sang-Min;Kim, Seoung-Hoe;Lee, Jai-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.10 no.4
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    • pp.197-210
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    • 1999
  • The hydrogen storage performance and electrochemical properties of $Zr_{1-X}Ti_X(Mn_{0.2}V_{0.2}Ni_{0.6})_{1.8}$(X=0.0, 0.2, 0.4, 0.6) alloys are investigated. The relationship between discharge performance and alloy characteristics such as P-C-T characteristics and crystallographic parameters is also discussed. All of these alloys are found to have mainly a C14-type Laves phase structure by X-ray diffraction analysis. As the mole fraction of Ti in the alloy increases, the reversible hydrogen storage capacity decreases while the equilibrium hydrogen pressure of alloy increases. Furthermore, the discharge capacity shows a maxima behavior and the rate-capability is increased, but the cycling durability is rapidly degraded with increasing Ti content in the alloy. In order to analyze the above phenomena, the phase distribution, surface composition, and dissolution amount of alloy constituting elements are examined by S.E.M., A.E.S. and I.C.P. respectively. The decrease of secondary phase amount with increasing Ti content in the alloy explains that the micro-galvanic corrosion by multiphase formation is little related with the degradation of the alloys. The analysis of surface composition shows that the rapid degradation of Ti-substituted Zr base alloy electrode is due to the growth of oxygen penetration layer. After comparing the radii of atoms and ions in the electrolyte, it is clear that the electrode surface becomes more porous, and that is the source of growth of oxygen penetration layer while accelerating the dissolution of alloy constituting elements with increasing Ti content. Consequently, the rapid degradation (fast growth of the oxygen-penetrated layer) with increasing Ti substitution in Zr-based alloy is ascribed to the formation of porous surface oxide through which the oxygen atom and hydroxyl ion with relatively large radius can easily transport into the electrode surface.

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A Study on the Actual Condition and Suggestions for Improvement in the Operation of the Field Practicum for Healthy Family (건강가정현장실습 운영실태와 개선방안에 관한 연구)

  • Son, Yeo-Kyoung;Lee, Song-Yi
    • Journal of Family Resource Management and Policy Review
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    • v.13 no.3
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    • pp.247-280
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    • 2009
  • The purpose of this study was to investigate the actual conditions of management of the healthy family field practicum and to present suggestions for its improvement. For this purpose, a preliminary investigation, survey, data analysis, interview as secondary source, and final data analysis were processed as research methods. The subjects of this study were the 42 supervisors in the centers which oversee the field practicum experience and the 12 supervisors in the centers which do not oversee the field practicum experience. 3 supervisors were interviewed to inquire about the reformation of field instruction in Healthy Family Support Centers. Analysis was made of the general characteristics of the above-mentioned 54 supervisors, including sex, age, academic background, certificate of qualification, class of position, and length of career related to the healthy family program. The environment of the field practice, such as the numbers of students supervised, time of field practice, practice hours, and so on, was examined in the centers which oversee the field practicum experience. The actual condition of operation investigated was divided into the preparatory stage, the early stage, the midterm stage, and the end stage. Research was conducted on the improvement of the field practicum, including the proper number of students supervised, adequate practice hours, interaction with universities or colleges, obstacles to the field practicum, and of practicum. The possibility and preparation of a further field practicum was conducted for 12 Healthy Family Support Centers, by inquiring about (a) the reasons for not overseeing the field practicum experience and (b) the needs of universities or colleges for a field practicum. The 54 supervisors surveyed suggested a particular need for improvement in human resources, the space of field instruction, system of field practicum, length of practice hours, orientation for students etc. This study investigated the actual conditions and suggested improvements of the field practicum in Healthy Family Support Centers. Therefore, its results should be meaningfully used to develop the Field Practicum for the Healthy Family and to conduct further studies.

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Anti-Inflammatory Properties of Flavone di-C-Glycosides as Active Principles of Camellia Mistletoe, Korthalsella japonica

  • Kim, Min Kyoung;Yun, Kwang Jun;Lim, Da Hae;Kim, Jinju;Jang, Young Pyo
    • Biomolecules & Therapeutics
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    • v.24 no.6
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    • pp.630-637
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    • 2016
  • The chemical components and biological activity of Camellia mistletoe, Korthalsella japonica (Loranthaceae) are relatively unknown compared to other mistletoe species. Therefore, we investigated the phytochemical properties and biological activity of this parasitic plant to provide essential preliminary scientific evidence to support and encourage its further pharmaceutical research and development. The major plant components were chromatographically isolated using high-performance liquid chromatography and their structures were elucidated using tandem mass spectrometry and nuclear magnetic resonance anlysis. Furthermore, the anti-inflammatory activity of the 70% ethanol extract of K. japonica (KJ) and its isolated components was evaluated using a nitric oxide (NO) assay and western blot analysis for inducible NO synthase (iNOS) and cyclooxygenase (COX)-2. Three flavone di-C-glycosides, lucenin-2, vicenin-2, and stellarin-2 were identified as major components of KJ, for the first time. KJ significantly inhibited NO production and reduced iNOS and COX-2 expression in lipopolysaccharide-stimulated RAW 264.7 cells at $100{\mu}g/mL$ while similar activity were observed with isolated flavone C-glycosides. In conclusion, KJ has a simple secondary metabolite profiles including flavone di-C-glycosides as major components and has a strong potential for further research and development as a source of therapeutic anti-inflammatory agents.

Study on Real-Time Digital Filter Design as Function of Scanning Frequency of Focused Electron Beam (집속 전자 빔 장치에서 스캔 주파수에 따른 실시간 디지털 필터 설계에 관한 연구)

  • Kim, Seung-Jae;Oh, Se-Kyu;Yang, Kyung-Sun;Jung, Kwang-Oh;Kim, Dong-Hwan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.5
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    • pp.479-485
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    • 2011
  • To acquire images in a thermionic-scanning electron-beam system, a scanning unit is needed to control the electron beam emitted from the tungsten filament source. In scanning the electron beam on the solid surface, the signalto-noise ratio depends on the scanning frequency. We used a digital filter to reduce noise by analyzing the real-time frequency of a secondary electron signal. The noise and the true image signal were well separated. We designed the digital filter via a DSP floating-point operation, and the noise elimination resulted in enhanced image quality in a highresolution mode.

Plasma Peptidome as a Source of Biomarkers for Diagnosis of Cholangiocarcinoma

  • Kotawong, Kanawut;Thitapakorn, Veerachai;Roytrakul, Sittiruk;Phaonakrop, Narumon;Viyanant, Vithoon;Na-Bangchang, Kesara
    • Asian Pacific Journal of Cancer Prevention
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    • v.17 no.3
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    • pp.1163-1168
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    • 2016
  • Cholangiocarcinoma (CCA) is the bile duct cancer which constitutes one of the important public health problems in Thailand with high mortality rate, especially in the Opisthorchis viverrini (a parasite risk factor for CCA) endemic area of the northeastern region of the country. This study aimed to identify potential biomarkers from the plasma peptidome by CCA patients. Peptides were isolated using 10 kDa cut-off filter column and the flow-through was then used as a peptidome for LC-MS/MS analysis. A total of 209 peptides were obtained. Among these, 15 peptides were concerned with signaling pathways and 12 related to metabolic, regulatory, and biosynthesis of secondary metabolite pathways. Five exclusive peptides were identified as potential biomarkers, i.e. ETS domain-containing transcription factor ERF (P50548), KIAA0220 (Q92617), phosphatidylinositol 4,5-bisphosphate 3-kinase catalytic subunit beta isoform isoform 1 (P42338), LP2209 (Q6XYC0), and casein kinase II subunit alpha (P19784). Three of these biomarkers are signaling related molecules. A combination of these biomarkers for CCA diagnosis is proposed.

Disease Dispersal Gradients of Rice Blast from a Point Source (점접종원으로부터 벼 도열병 확산의 경사)

  • Kim Choong Hoe
    • Korean Journal Plant Pathology
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    • v.3 no.2
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    • pp.131-136
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    • 1987
  • Rates of lesion development over time and disease gradients over distance for blast disease on the two rice varieties, Brazos and M-20 1 were significantly affected by two different cultural conditions, upland and flooded conditions. Flooding rice field plots lowered the rates of lesion increase and flattened the disease gradients for both varieties. Despite absence of statistically significant differences in the rate of lesion increase between four sampled distances from infection focus, rate of lesion development tended to be slightly greater as distance from the infection focus increases. Rate of lesion increase was greater with more susceptible variety M-201 than with Brazos. Disease gradient was steeper for M-201 than for Brazos. As blast disease progressed, disease gradients became flattened regardless of variety due to the infections originated from secondary foci. Between two empirical disease gradient models examined, Kiyosawa & Shiyomi model was fitted better over Gregory model. Rates of blast isopath movement under upland conditions were calculated as approximately 0.2m/day and 0.4 m/day for Brazos and M-201, respectively. The results in this study suggest that differences in varietal resistance to blast could be detected by measuring disease gradient as efficiently as by measuring infection rate.

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Diversity and Characterization of Endophytic Bacteria Associated with Tidal Flat Plants and their Antagonistic Effects on Oomycetous Plant Pathogens

  • Bibi, Fehmida;Yasir, Muhammad;Song, Geun-Cheol;Lee, Sang-Yeol;Chung, Young-Ryun
    • The Plant Pathology Journal
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    • v.28 no.1
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    • pp.20-31
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    • 2012
  • Endophytic bacterial communities of tidal flat plants antagonistic to oomycete plant pathogens were studied by the isolation of 256 root colonizing endophytic bacteria from surface-disinfected root tissues of six plants ($Rosa$ $rugosa$, $Suaeda$ $maritima$, $Vitex$ $rotundifolia$, $Carex$ $scabrifolia$, $Glehnia$ $littoralis$ and $Elymus$ $mollis$) growing in a tidal flat area of Namhae Island, Korea. To understand the antagonistic potential, an $in$ $vitro$ antagonistic assay was performed to characterize and identify strains that were antagonistic to the oomycete plant pathogens $Phytophthora$ $capsici$ and $Pythium$ $ultimum$ from the total population. Nine percent of the total number of isolated bacteria exhibited in vitro inhibitory activity against target plant pathogenic oomycetes. Taxonomic and phylogenetic placement of the antagonistic bacteria was investigated by analysis of the 16S rRNA gene sequences. The sequence analysis classified the antagonistic strains into four major classes of the domain bacteria ($Firmicutes$, ${\alpha}-Proteobacteria$, ${\gamma}-Proteobacteria$ and $Actinomycetes$) and 10 different genera. Further production of secondary metabolites, hydrolytic enzymes and plant growth promoting traits were determined for the putative new species of antagonistic endophytic bacteria. These new strains could not be identified as known species of ${\alpha}-Proteobacteria$, and so may represent novel bacterial taxa. The unexpected high antagonistic bacterial diversity associated with the tidal flat plants may be indicative of their importance in tidal flat plants as a promising source of novel antimicrobial compounds and biocontrol agents.

Analysis of Very High Resolution Solar Energy Based on Solar-Meteorological Resources Map with 1km Spatial Resolution (1km 해상도 태양-기상자원지도 기반의 초고해상도 태양 에너지 분석)

  • Jee, JoonBum;Zo, Ilsung;Lee, Chaeyon;Choi, Youngjean;Kim, Kyurang;Lee, KyuTae
    • New & Renewable Energy
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    • v.9 no.2
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    • pp.15-22
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    • 2013
  • The solar energy are an infinite source of energy and a clean energy without secondary pollution. The global solar energy reaching the earth's surface can be calculated easily according to the change of latitude, altitude, and sloped surface depending on the amount of the actual state of the atmosphere and clouds. The high-resolution solar-meteorological resource map with 1km resolution was developed in 2011 based on GWNU (Gangneung-Wonju National University) solar radiation model with complex terrain. The very high resolution solar energy map can be calculated and analyzed in Seoul and Eunpyung with topological effect using by 1km solar-meteorological resources map, respectively. Seoul DEM (Digital Elevation Model) have 10m resolution from NGII (National Geographic Information Institute) and Eunpyeong new town DSM (Digital Surface Model) have 1m spatial resolution from lidar observations. The solar energy have small differences according to the local mountainous terrain and residential area. The maximum bias have up to 20% and 16% in Seoul and Eunpyung new town, respectively. Small differences are that limited area with resolutions. As a result, the solar energy can calculate precisely using solar radiation model with topological effect by digital elevation data and its results can be used as the basis data for the photovoltaic and solar thermal generation.

Study of PSII-treated PMMA, PHEMA, and PHPMA ; Investigation of Their Surface Stabilities

  • Hyuneui Lim;Lee, Yeonhee;Seunghee Han;Jeonghee Cho;Moojin suh;Kem, Kang-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.204-204
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    • 1999
  • The plasma source ion implantation(PSII) technique which is a method using high negative voltage pulse in plasma system has the potential to change the surface properties of polymer. PSII technique increase the surface free energy by introducing polar functional groups on the surface so that it improves reactivity, hydrophilicity, adhension, biocompatability, etc. However, the mobility of polymer chains enables the modified surface layers to adapt their composition to interfacial force. This hydrophobic recovery interrupts the stability of modified surfaces to keep for the long time. In this study, poly(methyl methacrylate)(PMMA), poly(2-hydroxyethyl methacrylate)(PHEMA), and polu(2-hydroxypropyl methacylate)(PHPMA) for contact lens application, were modified to improve the wettability with PSII technique and were investigated the surface stabilities. Polymer film was prepared with solution casting(3 wt.% solution) and was annealed at 11$0^{\circ}C$ under vacuum oven to remove solvent completely and to eliminate physical ageing. The thickness of the film measured by scanning electron microscopy (SEM) and surface profilometer was about 10${\mu}{\textrm}{m}$. Polymers were treated with different kinds of gases, pulse frequency, pulse with, pulse voltage, and treatment time. Even though PMMA, PHEMA, and PHPMA have similar repeat unit structure, the optimal treatment conditions and the tendency to hydrophobic recovery were different. PHPMA, more hydrophilic polymer than PMMA and PHEMA showd better wettability and stability after mild treatment. Surface tensions were obtained by water and diiodomethane contact angle measurements to monitor the relation between hydrophobic recovery and polymer structure. Different ion species in plasma change the polar component and dispersion component of polymer surface. For better wettability surface, the increase of polar component was a dominant factor. We also characterized modified polymer surfaces using x-ray photoelectron spectroscopy(XPS), secondary ion mass spectrometry(SIMS), Fourier Transform infrared spectroscopy(FT-IR), and SEM.

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