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Effect of Sr Addition on Mechanical and Corrosion Properties of Mg-Zn-Ca Alloy for Biodegradable Implant Material (생체 분해성 임플란트용 Mg-Zn-Ca 합금의 기계적 및 부식특성에 미치는 Sr 첨가의 영향)

  • Kong, Bo-Kwan;Cho, Dae-Hyun;Yun, Pil-Hwan;Lee, Jeong-Hun;Park, Jin-Young;Park, Ik-Min
    • Journal of Korea Foundry Society
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    • v.35 no.6
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    • pp.155-162
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    • 2015
  • The effect of Sr addition on mechanical and bio-corrosion properties of as-cast Mg-3wt.%Zn-0.5wt.%Ca-xwt.%Sr (x = 0.3, 0.6, 0.9) alloys were examined for application as biodegradable implant material. The microstructure, mechanical properties and corrosion resistance of the as-cast Mg-Zn-Ca-Sr alloys were characterized by using optical microscopy, scanning electron microscopy, tensile testing and electrochemical measurement in Hank's solution. The as-cast alloys contained ${\alpha}$-Mg and eutectic $Ca_2Mg_6Zn_3$ phases, while the alloys contained ${\alpha}$-Mg, $Ca_2Mg_6Zn_3$ and Mg-Zn-Ca-Sr intermetallic compound when the Sr addition was more than 0.3 wt.%. The yield strength, ultimate tensile strength and elongation increased with the increasing of Sr content up to 0.6 wt.% but decreased in the 0.9 wt.% Sr-added alloy, whereas the corrosion resistance of 0.3 wt.% Sr-added alloy was superior to other alloys. It was thought that profuse Mg-Zn-Ca-Sr intermetallic compound deteriorated both the mechanical properties and corrosion resistance of the as-cast alloy.

Investigation of the Thermal-to-Electrical Properties of Transition Metal-Sb Alloys Synthesized for Thermoelectric Applications

  • Jong Min Park;Seungki Jo;Sooho Jung;Jinhee Bae;Linh Ba Vu;Kwi-Il Park;Kyung Tae Kim
    • Journal of Powder Materials
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    • v.31 no.3
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    • pp.236-242
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    • 2024
  • The development of thermoelectric (TE) materials to replace Bi2Te3 alloys is emerging as a hot issue with the potential for wider practical applications. In particular, layered Zintl-phase materials, which can appropriately control carrier and phonon transport behaviors, are being considered as promising candidates. However, limited data have been reported on the thermoelectric properties of metal-Sb materials that can be transformed into layered materials through the insertion of cations. In this study, we synthesized FeSb and MnSb, which are used as base materials for advanced thermoelectric materials. They were confirmed as single-phase materials by analyzing X-ray diffraction patterns. Based on electrical conductivity, the Seebeck coefficient, and thermal conductivity of both materials characterized as a function of temperature, the zT values of MnSb and FeSb were calculated to be 0.00119 and 0.00026, respectively. These properties provide a fundamental data for developing layered Zintl-phase materials with alkali/alkaline earth metal insertions.

Oxygen Consumption and Blood Physiology of Olive Flounder Paralichthys olivaceus Subjected to Salinity Changes (염분 변화에 따른 넙치(Paralichthys olivaceus)의 산소 소비율과 혈액 성상)

  • Oh, Sung-Yong;Jeong, Yu Kyung;Lee, Geun Su;Kang, Pil Jun;Park, Hye Mi
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.53 no.4
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    • pp.620-627
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    • 2020
  • Oxygen consumption and blood physiology of olive flounder Paralichthys olivaceus (mean body weight 106.6±6.8 g, mean±SD) was investigated at salinities of 34.0 (control), 33.7, 33.3, 32.6, 31.3, 28.6, 23.1, 12.2 and 0.0 psu at 20.0℃, respectively. Stepwise salinity changes (34.0→33.7→33.3→32.6→31.3→28.6→23.1→12.2→0.0 psu) with an interval of 24 h for each salinity induced a significant (P<0.05) increase of oxygen consumption rate (OCR) in fish exposed from 31.3 to 0.0 psu compared to that of control fish. The maximum OCR was found in fish exposed to 23.1 psu, which was accompanied by 36.2% higher energy consumption than the control fish. Fish exposed to each salinity for 24 h induced a significant decrease of blood plasma Na+ in 0.0 psu and Cl- in 12.2 and 0.0 psu (P<0.05), and increase of plasma glutamic oxaloacetic transaminase (GOT) in 0.0 psu compared to the control fish (P<0.05). The results of this experiment show that P. olivaceus exposed to concentrations below 31.3 psu requires more energy costs to adapt to salinity changes than 34.0 psu under our experimental conditions.

Mass Size Distribution of Atmospheric Aerosol Particles with Nanosampler Cascade Impactor in Jinju City (다단 임팩터 Nanosampler를 이용한 진주시 대기에어로졸입자의 입경별 질량농도 특성)

  • Park, Jeong-Ho;Jang, Min-Jae;Kim, Hyoung-Kab
    • Journal of Environmental Science International
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    • v.24 no.5
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    • pp.679-687
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    • 2015
  • Atmospheric aerosol particles were investigated at GNTECH university in Jinju city. Samples were collected using the Nanosampler period from January to December 2014. The Nanosampler is a 6 stage cascade impactor(1 stage : > $10{\mu}m$, 2 stage : $2.5{\sim}10{\mu}m$, 3 stage : $1.0{\sim}2.5{\mu}m$, 4 stage : $0.5{\sim}10{\mu}m$, 5 stage : $0.1{\sim}0.5{\mu}m$, back-up : < $0.1{\mu}m$) with the stages having 50% cut-off ranging from 0.1 to $10{\mu}m$ in aerodynamic diameter. The mass size distribution of Atmospheric aerosol particles was unimodal with peak at $1.0{\sim}2.5{\mu}m$ or $0.5{\sim}1.0{\mu}m$. The annual average concentrations of TSP, $PM_{10}$, $PM_{2.5}$, $PM_1$, $PM_{0.5}$ and $PM_{0.1}$ were $44.0{\mu}g/m^3$, $40.3{\mu}g/m^3$, $31.4{\mu}g/m^3$, $18.0{\mu}g/m^3$, $8.0{\mu}g/m^3$, $3.0{\mu}g/m^3$, respectively. On average $PM_{10}$, $PM_{2.5}$, $PM_1$, $PM_{0.5}$ and $PM_{0.1}$ make up 0.91, 0.70, 0.41, 0.19 and 0.07 of TSP, respectively. The annual average of $PM_{2.5}/PM_{10}$ ratio was 0.77.

Development of Prediction Technique of Landslide Hazard Area in Korea National Parks (국립공원의 산사태 발생 위험지역 예측기법의 개발)

  • Ma, Ho-Seop;Jeong, Won-Ok;Park, Jin-Won
    • Journal of Korean Society of Forest Science
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    • v.97 no.3
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    • pp.326-331
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    • 2008
  • This study was carried out to analyze the characteristics of each factors by using the quantification theory(I) for prediction of landslide hazard area. The results obtained from this study were summarized as follows; The stepwise regression analysis between landslide sediment ($m^3$ ) and environmental factors, factors affecting landslide sediment ($m^3$ ) were high in order of mixed (forest type), < 15 cm(soil depth), 801~1,200 m (altitude), $31{\sim}40^{\circ}$ (slope gradient), 46 cm < (soil depth), 1,201 m < (altitude) and s(aspect). According to the range, it was shown in order of soil depth (0.3784), altitude (0.2876), forest type (0.2409), slope gradient (0.1728) and aspect (0.1681). The prediction of landslide hazard area was estimated by score table of each category. The extent of prediction score was 0 to 1.2478, and middle score was 0.6239. Class I was over 1.1720, class II was 0.7543 to 0.1719, class III was 0.4989 to 0.7542 and class IV was below 0.4988.

Long-term Monitoring of Pesticide Residues in Arable Soils in Korea (전국 농경지 토양 중 농약 잔류량 모니터링 및 연차별 변화)

  • Park, Byung-Jun;Lee, Byeong-Moo;Kim, Chan-Sub;Park, Kyung-Hun;Park, Sang-Won;Kwon, Hyeyoung;Kim, Jin-Hyo;Choi, Geun-Hyoung;Lim, Sung-Jin
    • The Korean Journal of Pesticide Science
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    • v.17 no.4
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    • pp.283-292
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    • 2013
  • A series of monitoring studies were carried out to evaluate the residue level of pesticides in different native soils from 1999 to 2006. The nation-wide collection of soil samples from paddy, greenhouse, upland and orchard, were analyzed by GLC (ECD or NPD) and GC/MS. The results obtained are summarized as follows; out of 14 pesticides detected from paddy soils in 1999, the highest residue level was 0.25 mg $kg^{-1}$, and the frequency was 21.7% as butachlor, 20.0% as isoprothiolane, and 16.7% as iprobenfos. In 2003, 7 pesticides were detected and their frequencies were 0~36.0%; the frequency was 36.0% as isoprothiolane and 33.3% as oxadiazon. In the year 2000, 57 pesticides in the greenhouse soil samples were detected with the highest frequency of 65.3%. Of the pesticides detected, endosulfan and procymidone showed the frequency of 65.3 and 50.0%, respectively. In 2004, 19 pesticides were detected from greenhouse soils, and their frequencies and residue levels were decreased. Endosulfan and procymidone showed high detection frequencies and concentrations of 21.3 and 9.3% and 0.76 and 0.31 mg $kg^{-1}$, respectively. In 2001, a total of 25 pesticides were detected through monitoring in 170 upland soils and the highest residue level was 2.24 mg $kg^{-1}$. The detection frequencies showed the range of 0~53.5%. Especially, endosulfan showed the highest frequency of 53.5%. Residue levels and frequencies of pesticide in the year 2005 were almost the same compared with that of the year 2001. As a result of monitoring in 150 orchard soils in 2002, 26 pesticides were detected and the highest residue level was 1.43 mg $kg^{-1}$. Of them, the frequency of endosulfan showed the highest as 45.3%. In 2006, 20 pesticides were detected in orchard soils. The frequency of total endosulfan was the highest as 5.3% but was lower than that of the year 2002.

Physicochemical Meat Quality, Fatty Acid and Free Amino Acid Composition of Strip loin, Chuck Tender, and Eye of Round Produced by Different Age Groups of Hanwoo Cow

  • Cho, Soohyun;Kang, Sunmoon;Kang, Geunho;Seong, Pilnam;Park, Kyungmi;Chang, Sunsik;Lee, Seunghwan;Cho, Youngmoo;Park, Beomyoung
    • Food Science of Animal Resources
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    • v.33 no.6
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    • pp.708-714
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    • 2013
  • This study was performed to investigate the influence of age on the physicochemical properties of strip loin (m. longissimus lumborum), chuck tender (m. supraspinatus), and eye of round (m. semitendinosus) of Hanwoo cows. Hanwoo cows (n=126; 24-194 mon; live weight, 270-500 kg) were slaughtered and three muscles were obtained according to 3 age groups (G1, < 5 years old; G2, 6-8 years old; G3, > 9 years old). The chuck tender had significantly higher protein contents in G3 than in G1 or G2 (p<0.05). For strip loin and chuck tender, G1 had significantly higher intramuscular fat contents than G3 (p<0.05). The chuck tender had significantly higher $b^*$ (yellowness) values for G2 than for G1 (p<0.05). The three muscles had significantly higher cooking loss (%) and lower WHC (%) in G3 than in G1 or G2 (p<0.05). WBS values of strip loin were significantly higher in G3 than in the other groups (p<0.05). The three muscles had higher C18:1n9 in G1 than that in the other groups. The total content of saturated fatty acids was significantly higher in G3 than in G1 for all 3 muscles (p<0.05). Regarding free amino acid contents, G1 had significantly higher contents of threonine, alanine, valine, methionine, phenylalanine, leucine, and lysine in the strip loin than G2 or G3 (p<0.05). In conclusion, young cow beef were higher in the WHC, intramuscular fat and free amino acids contents, whereas old cow beef had higher cooking loss and WBS (p<0.05).

Correlations between the Polarization and Strain Induced by Electric field in $\textrm{0.9Pb}\textrm({Mg}_{1/3}\textrm{Nb}_{2/3})\textrm{O}_3$-$\textrm{0.1PbTiO}_3$ Relaxor Ferroelectrics ($\textrm{0.9Pb}\textrm({Mg}_{1/3}\textrm{Nb}_{2/3})\textrm{O}_3$-$\textrm{0.1PbTiO}_3$계 강유전체에서 전계인가에 따른 분극 및 변위의 상관관계)

  • Park, Jae-Hwan;Park, Jae-Gwan;Park, Sun-Ja
    • Korean Journal of Materials Research
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    • v.9 no.1
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    • pp.81-85
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    • 1999
  • Polarization and strain induced by unipolar electric field (P\ulcorner, S\ulcorner), those induced by bipolar electric field (P, S) and remanent polarization (P\ulcorner) were investigated in 0.9Pb(Mg\ulcornerNb\ulcorner)O$_3$-$0.1PbTiO_3$relaxor ferroelectric ceramics in the temperature range of $-50^{\circ}C$~$90^{\circ}C$. From the temperature dependence of polarization and strain, the transition from predominantly paraelectric (electrostrictive) to partially ferroelectric (piezoelectric) is visualized. Under the given temperature, the P\ulcorner/P\ulcorner is always larger than the S\ulcorner/S\ulcorner and the difference between them becomes larger ass the temperature decrease. The S\ulcorner/P\ulcorner increases as the temperature decreased below phase transition temperature. It was suggested that these experimental results might be explained with a simple rigid ion model concentrating on BO\ulcorner octahedron.

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Determination of Fat Accumulation Reduction by Edible Fatty Acids and Natural Waxes In Vitro

  • Issara, Utthapon;Park, Suhyun;Park, Sungkwon
    • Food Science of Animal Resources
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    • v.39 no.3
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    • pp.430-445
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    • 2019
  • Natural edible waxes mixed with plant oils, containing high levels of unsaturated fatty acids (FAs), are known as oleogels. Oleogels are used for replacing saturated FAs in animal-derived food with unsaturated FAs. However, the health effects of edible waxes are not yet clearly defined. The purpose of this study was to investigate the effect of FAs and natural waxes on the adipogenesis in 3T3-L1 cells. The 3T3-L1 cells were differentiated and treated with FAs and waxes. These FAs [Palmitic acid (PA), Stearic acid (SA), Oleic acid (OA), Linoleic acid (LA), and Alpha-linolenic acid (ALA)] and waxes [beeswax (BW) and carnauba wax (CW)] were prepared at varying concentrations, and cell toxicity, triglyceride accumulation, lipid droplets size, and distribution inside of cells were determined. Adipogenic gene expression including $PPAR{\gamma}$, FASN, $C/EBP{\alpha}$, SREBP-1, and CPT-1 was determined. Results showed that increasing the concentration of FAs and waxes led to a decrease in the adipocyte cells viability and metabolic performance. SA showed the highest level of triglyceride accumulation (p<0.05), whereas ALA showed the lowest (p<0.05). Both BW and CW at 3.0 ppm showed significantly higher lipid accumulation than in the control and other groups (p<0.05). ALA had significantly downregulated adipogenic gene expression levels, excluding those of CPT-1, compared to the other treatment groups (p<0.05). Moreover, BW demonstrated similar adipogenic gene expression levels as ALA compared to CW. Consequently, ALA and BW may have health benefits by reducing adipogenesis and can be used in processed meat.