• 한국결정성장학회지
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• 제15권6호
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• pp.244-251
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• 2005

수열합성법에 의해 제조된 티탄산바륨 (BT01, BT02, BT03, BT04, BT05)의 입자크기와 분체특성과의 상관관계를 비표면적, 제타전위, XPS, XRD 및 SEM에 의해 조사하였다. 레이져광산법에 의해 측정된 입자의 크기는 비표면적과 XRD를 통해 결정된 격자이방성과 밀접한 관계가 있음을 보였다. 분말의 비표면적은 입자의 크기가 증가함에 따라 감소하였으며, BT03 시료는 동일한 입자크기의 BT04에 비하여 큰 비표면적을 보였으며, 이는 입자들의 응집에 기인하는 것으로 SEM사진 및 XRD 분석을 통하여 밝혀졌다. 입자의 크기가 증가함에 따라 제타전위는 증가하는 경향을 보였으며, BT02와 BT03 분말은 다른 분말에 비하여 제타전위가 큰 음의 값을 나타내었다. XPS 분석결과 분쇄시 티탄산바륨과 물 사이의 반응에 의한 $Ba^{2+}$ 이온의 용출과 관련이 있는 것으로 분석되었다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.66.1-66.1
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• 2015

Plasma medicine is an upcoming research area that has attracted the scientists to explore more deeply the utility of plasma. So, apart from the treating biomaterials and tissues with plasma, we have studied the effect of plasma with different feeding gases on modification of biomolecules. Additionally, we have checked the action of nanosecond pulsed plasma on the biomolecules. We have checked the plasma action on proteins ((Hemoglobin (Hb) Myoglobin (Mb) and lysoenzyme), calf thymus DNA and amino acids. The structural changes or structural modification of proteins and DNA have been studied using circular dichroism (CD), dynamic light scattering (DLS), gel electrophoresis, protein oxidation test, UV-vis spectroscopy and 1D NMR, while Liquid Chromatograph/Capillary Electrophoresis-Mass Spectrometer(LC/CE-MS) based qualitative bio-analysis have been used to study the modification of amino acids. We have also shown the effect of NaCl and ionic liquid on the formation of OH radicals using electron spin resonance and fluorescence techinques.

• 대한원격탐사학회지
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• 제29권3호
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• pp.307-314
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• 2013

The Bidirectional Reflectance Distribution (BRD) effect is critical to interpret the surface information using remotely sensed data. This effect was caused by geometric relationship between sensor, target and solar that is inevitable effect for data of optical sensor. To remove the BRD effect, semi-empirical BRDF models are widely used. It is faster to calculate than physical models and demanded less observation than empirical models. In this study, Ross-Li kernel and Roujean kernel were used respectively in National Aeronautics and Space Administration (NASA) and European Organization for the Exploitation of Meteorological Satellites (EUMETSAT) that are used to compare each other. The semi-empirical model consists of three parts which are isotropic, geometric and volumetric scattering. Each part contained physical kernel and empirical coefficients that were calculated by statistical method. Red and NIR channel of SPOT/VEGETATION product were used to compute Nadir BRDF Adjusted Reflectance (NBAR) over East Asia area from January 2009 to December 2009. S1 product was provided by VITO that was conducted atmospheric correction using Simplified Method of Atmospheric Correction (SMAC). NBAR was calculated using corrected reflectance of red and NIR. Previous study has revealed that Roujean geometric kernel had unphysical values in large zenith angles. We extracted empirical coefficients in three parts and normalized reflectance to compare both BRDF models. Two points located forest in Korea peninsular and bare land in Gobi desert were selected for comparison. As results of time series analysis, both models showed similar reflectance change pattern and reasonable values. Whereas in case of empirical coefficients comparison, different changes pattern of values were showed in isotropic coefficients.

• Macromolecular Research
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• 제12권2호
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• pp.172-177
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• 2004

We have studied the lamella-level morphology of poly(ethylene terephthalate) (PET)/polycarbonate (PC) blends using small-angle X-ray scattering (SAXS). Measurements were made as a function of the holding time in the melt. We determined the morphological parameters at the lamellar level by correlation function analysis of the SAXS data. An increased amorphous layer thickness was identified in the blend, indicating that some PC was incorporated into the interlamellar regions of PET during crystallization. The blend also exhibits a larger lamella crystalline thickness (l$\sub$c/) than that of pure PET. A possible reason for the increase in l$\sub$c/ is that the inclusion of the PC molecules in the interlamellar regions causes an increase in the surface free energy of folding. At the early stage of isothermal crystallization, we observed a rapid drop in the value of l$\sub$c/ in the blend; this finding indicates that a relatively large fraction of secondary crystals form during the primary crystallization. In contrast, the value of l$\sub$c/ for the sample that underwent a prolonged holding time increased with time in the secondary crystallization-dominant regime; this observation suggests that the disruption of chain periodicity, which results from transesterification between the two polymers, favors the development of fringed micellar crystals that have larger values of l$\sub$c/ rather than the development of normal chain-folded crystals.

• 한국염색가공학회지
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• 제8권2호
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• pp.1-7
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• 1996

Thermotropic liquid-crystalline polyurethanes were synthesized by the polyaddition reaction of such para-substiuted diisocyanate monomer as 1,4-phenylene diisocyanate(1,4-PDI) and 2,5-tolylene diisocyanate(2,5-TDI), with 4,4'-bis($\omega$-hydroxyalkoxy)biphenyls(BPm: $HOC_{m}OC_{6}H_{4}C_{6}H_{4}OC_{m}H_{2m}OH$; m is the carbon number of the hydroxyalkoxy group). These polyurethanes have mesogenic biphenyl units in the main chain. Properties of polymers were studied by differential scanning calorimetry, wide-angle X-ray scattering, thermogravimetic analysis, polarizing microscopy, and infraed spectroscopy. DSC thermograms for these polymers exhibited two endothermic peaks corresponding to phase transitions of melting and isotropization. Mesomorphic behavior of the polyurethanes were also observed under the polarizing microscope. For example, polyurethane 2,5-YDI/BP5 with [$\theta$]=0.44 prepared from 2,5-TDI and BP5 exhibited a liquid crystalline phase from 194 to 205$^{\circ}C$. Infrared spectrum study indicated that the hydrogen bonding between urethane linkages affected the mesomorphism. The thermostabilities of polyurethanes 2,5-TDI/BP5 and 1,4-PDI/BP5 were measured at a heating rate of 1$0^{\circ}C$/min in air. The temperatures of 5% weight loss for 2,5-TDI/BP5 and 1,4-PDI/BP5 were 297 and 334$^{\circ}C$, respectively.

• 한국대기환경학회지
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• 제19권6호
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• pp.647-661
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• 2003

For continuous monitoring of atmospheric visibility in the city of Kwanaju, Korea, a transmissometer system consisting of a transmitter and a receiver was installed at a distance of 1.91 km across the downtown Kwanaju. At the transmitter site an integrating nephelometer and an aethalometer were also installed to measure the scattering and absorption coefficients of the atmosphere, respectively. At the receiver site. an URG PM$_{2.5}$ cyclone sampler and an URG-VAPS (Versatile Air Pollutant Sampler) with three filter packs and two denuders were used to collect both PM$_{2.5}$ and PM$_{10}$ samples at a 2-hour or 12-hour sampling interval for aerosol chemical analysis. Sulfate, organic mass by carbon (OMC), nitrate, elemental carbon (EC) components of fine aerosol were the major contributors to visibility impairment. Diurnal variation of visibility during best-case days showed rapid improvement in the morning hours, while it was delayed until afternoon during the worst-case days. Aerosol mass concentration of each aerosol component for the worst-case was calculated to be 11.2 times larger than the best-case for (NH$_4$)$_2$SO$_4$(NHSO), 19.0 times for NH$_4$NO$_3$ (NHNO), 2.2 times for OMC, respectively. Also result shows that elemental carbon and fine soil (FS) were 3.7 and 2.2 times more than those of best-case. respectively- Sum of total contributions of wet NHSO and NHNO to light extinction was calculated to be 301 Mm$^{-1}$ for the worst-case. However, sum of contributions by dry NHSO and NHNO was calculated to be 123 Mm$^{-1}$ for the best case. Mass extinction efficiencies of fine and coarse particles were calculated to be 5.8$\pm$0.3 $m^2$/g and 1.8$\pm$0.1 $m^2$/g, respectively.ely.

• 한국전자통신학회논문지
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• 제7권5호
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• pp.1079-1085
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• 2012

현재 전 세계의 많은 과학자들이 지속 가능한 에너지원을 찾기 위하여 많은 노력을 하고 있지만, 태양광에너지가 궁극적인 해답이 될 것으로 받아들여지고 있다. 이러한 광 에너지는 조명용, 발열용, 통신용 등으로 사용될 수 있으며, 심지어 최근에는 광에너지로 동작하는 광자구동 모터에 대한 연구결과도 나오고 있다. 본 논문에서는 이러한 광에너지를 광섬유를 통해 전송할 수 있는 기술에 대해 이론적인 분석을 수행하였다. 특히, 한 가닥의 광섬유에 여러 개의 코어(core)가 삽입된 멀티코어(multi-core) 광섬유를 이용한 광에너지 전송의 에너지 전송량에 대해 예측해 보았다. 본 논문의 분석 결과에 따르면, 한 가닥의 멀티코어 광섬유로 약 2 kW 의 광에너지 전송이 가능할 것으로 예측되었으며, 초고압선처럼 수 cm 의 직경으로 광섬유 다발을 묶을 경우에는 10 MW 이상의 광에너지 전송이 가능할 것으로 예측되었다. 이는 도체 전력선과 비교하여 절반수준의 에너지 전송량으로 충분한 경쟁력이 있을 것으로 생각된다.

• Journal of Biosystems Engineering
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• 제35권4호
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• pp.215-223
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• 2010

In order to develop an precision aerial pesticide application system to be attached to an unmanned helicopter which can be applied to small lots of land, this study analyzed the flowing and spraying characteristics of the spray droplets by the main rotor downwash by setting the application conditions at the flight altitude of 3 m, the diameter of main rotor of 3.1 m, the boom length of around 2.8 m, and the spraying rate of 8 L/ha. The results of this study are summarized below. Through analysis of the covering area ratio of the spray droplets by main rotor downwash by nozzle type, boom with tilt angle and height, it was found that the covering area ratio of the twin flat-fan nozzle of around 25% was more uniform than other types of nozzle, also boom with $10^{\circ}$ tilt angle and spraying height of 3 m was shown to be the appropriate conditions for aerial application of pesticides. It was found that the nozzle position to minimize the scattering loss of spray droplets due to vortex phenomenon at both ends of the main rotor was around 10 cm from the end of the main rotor. An application test for the aerial pesticide application system attached to the HUA-ACEI unmanned helicopter developed by the Rural Development Administration showed that the range of covering area ratio of the spray droplets was 10-25%, and the spraying width was approximately 7 m when over 10% of covering area ratio was considered for valid spraying.

• 한국응용과학기술학회지
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• 제26권2호
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• pp.117-123
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• 2009

Caprylic/Capric triglyceride-in-water emulsions stabilized by Nikkol HCO-60 and HCO-10 were prepared using emulsion inversion point method at different HLB values. Emulsions with various droplet sizes were formed, and emulsion inversion point was detected by electrical conductivity. The change in emulsion droplet sizes and long term stability were monitored using laser scattering method and visual method. The droplet sizes and stability of emulsions were affected by HLB of surfactant. At emulsion inversion point, the water volume fraction increased as the HLB of surfactants decreased. According to our analysis, this resulted from a tendency of forming the W/O (water-in-oil) emulsion as the HLB of surfactants was decreased. The emulsion inversion point was clearly detected by the microscope and the electric conductivity meter. Nanometer-sized emulsion was obtained at the optimum HLB by using emulsion inversion point method. The main pattern of instability of emulsions in HLB 12 and 13 systems was Ostwald ripening. However, The patterns of instability of emulsions below 11 of HLB systems were Ostwald ripening and coalescence. All emulsions produced with surfactants in the range of HLB 8-13, creaming caused by density difference between water phase and oil phase.

• 한국우주과학회:학술대회논문집(한국우주과학회보)
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• 한국우주과학회 1992년도 한국우주과학회보 제1권1호
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• pp.21-21
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• 1992

The X-ray binary pulsar Her X-1 was observed with Ginga on 1988 August 28 during the orbital phase of 0.76 to 0.85 at the main-on phase of the 35 day cycle. During the observations the X-ray intensity varied by a factor of five or more on a time scale as short as 30 sec, due mostly to the soft X-ray absorption in the pre-eclipse phase. From the studies of pulse profiles and energy spectra, we revealed that there exists in the dipphase an unpulsed component which is "3% of the intensity at the non-absorbed high-level. We suggest that scattering of the source continuum by the optically thin hot corona is responsible for the unpoised component. In the spectral analysis, we find that the high-state non-absorbed spectra can be fitted by a power-law without absorption, and the spectra observed in the different abgorption states by two components of a power-law with the same photon index. An iron-K emission line is required in to the cases of fitting. The estimated equivalent width of the iron line varies from 0.18 to 0.51 key according to the change in the absorption column density along the line of sight. We suggest that the fluorescent iron line arises in a cool and relatively small region, like the Alfvensur face, and may be partially intercepted by the optically thick gas cloud passing across the line of sight.1 Korea Astronomy Observatorya The Institute of Space and Astronautical Science in Japan3 Korea Advanced Institute of Science and Technology