• Title/Summary/Keyword: Scattering Analysis

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Effect of the TiO2 Nanotubes in the Photoelectrode on Efficiency of Dye-sensitized Solar Cell

  • Rahman, Md. Mahbubur;Son, Hyun-Seok;Lim, Sung-Su;Chung, Kyung-Ho;Lee, Jae-Joon
    • Journal of Electrochemical Science and Technology
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    • v.2 no.2
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    • pp.110-115
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    • 2011
  • The effect of $TiO_2$ nanotube (TNT) and nanoparticle (TNP) composite photoelectrode and the role of TNT to enhance the photo conversion efficiency in dye-sensitized solar cell (DSSC) have investigated in this study. Results demonstrated that the increase of the TNT content (1-15 %) into the electron collecting TNP film increases the open-circuit potential ($V_{oc}$) and short circuit current density ($J_{sc}$). Based on the impedance analysis, the increased $V_{oc}$ was attributed to the suppressed recombination between electrode and electrolyte or dye. Photochemical analysis revealed that the increased Jsc with the increased TNT content was due to the scattering effect and the reduced electron diffusion path of TNT. The highest $J_{sc}$ (12.6 mA/$cm^2$), Voc (711 mV) and conversion efficiency (5.9%) were obtained in the composite photoelectrode with 15% TNT. However, $J_{sc}$ and $V_{oc}$ was decreased for the case of 20% TNT, which results from the significant reduction of adsorbed dye amount and the poor attachment of the film on the fluorine-doped tin oxide (FTO). Therefore, application of this composite photoelectrode is expected to be a promising approach to improve the energy conversion efficiency of DSSC.

Molecular Genetic Testing and Diagnosis of Wilson Disease (윌슨병의 진단과 분자유전학적 검사)

  • Seo, Jeong Kee
    • Pediatric Gastroenterology, Hepatology & Nutrition
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    • v.11 no.sup1
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    • pp.72-82
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    • 2008
  • Wilson disease (WD) is an autosomal recessive disorder of copper metabolism that results in accumulation of copper primarily in the liver, the brain and the cornea. Mutations in the WD gene, ATP7B cause failure of copper excretion from hepatocyte into bile and a defective synthesis of ceruloplasmin. More than 370 mutations are now recognized, scattering throughout the ATP7B gene. Since WD has protean clinical presentations, awareness of WD in clinical practice is important for the early diagnosis and prevention of accumulated copper toxicity. None of the laboratory parameters alone allows a definite diagnosis of WD. There are numerous pitfalls in the diagnosis of WD. Low serum ceruloplasmin concentrations, increased 24 hour urinary copper excretion, increased hepatic copper concentrations and the presence of Kayser-Fleischer rings in the cornea are major diagnostic points. A combination of any two of these 4 laboratory findings is strong support for a diagnosis of WD. Molecular methods are now being used to aid diagnosis. Molecular genetic testing has confirmed the diagnosis in individuals in whom the diagnosis is not clearly established biochemically and clinically. Siblings should be screened for WD once an index case has been diagnosed. Discrimination of heterozygotes from asymptomatic patients is essential to avoid inappropriate lifelong therapy for heterozygotes. Genetic testing, either by haplotype analysis or by mutation analysis, is the only reliable tool for differentiating heterozygote carriers from affected asymptomatic patients. Currently, genetic testing is of limited value in the primary diagnosis. However, genetic testing will soon play an essential role in diagnosing WD as rapid advancement of biomedical technology will allow more rapid, easier and less expensive mutation detection.

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Numerical Analysis of Flow Fields for Optimum Design of Vehicle Vacuum Pump with Multivanes (자동차용 진공펌프 멀티 베인의 최적 설계를 위한 유동장 수치해석)

  • Lim, Tae-Eun;Lee, Kye-Bock
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.9
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    • pp.883-890
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    • 2011
  • A numerical study was conducted to determine the optimal design for a vehicle vacuum pump. The degree of vacuum was examined for different design factors such as the angle of vanes, number of vanes, angle and position of the pump inlet-outlet pipe, and angular rotational speed of vanes. The results show that there is a little difference in the degree of vacuum when the angle of vanes are changed, but an angular change in the outlet pipe reduces the pump loss. As the rotational speed is increased, the mass flow rate increases, but a high rotational speed does not result in the maximum degree of vacuum. In addition, when the number of vanes is increased, the scattering range of mass flow rate decreases and pressure drop is abated.

An Analysis of Aerosols Impacts on the Vertical Invigoration of Continental Stratiform Clouds (에어로솔의 대륙 층운형 구름 연직발달(Invigoration)에 미치는 영향 분석)

  • Kim, Yoo-Jun;Han, Sang-Ok;Lee, Chulkyu;Lee, Seoung-Soo;Kim, Byung-Gon
    • Atmosphere
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    • v.23 no.3
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    • pp.321-329
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    • 2013
  • This study examines the effect of aerosols on the vertical invigoration of continental stratiform clouds, using a dataset of Atmospheric Radiation Measurement (ARM) Intensive Operational Period (IOP, March 2000) at the Southern Great Plains (SGP) site. To provide further support to our observation-based findings, the weather research and forecasting (WRF) sensitivity simulations with changing cloud condensation nuclei (CCN) concentrations have been carried out for the golden episode over SGP. First, cross correlation between observed aerosol scattering coefficient and cloud liquid water path (LWP) with a 160-minutes lag is the highest of r = 0.83 for the selected episode, which may be attributable to cloud vertical invigoration induced by an increase in aerosol loading. Modeled cloud fractions in a control run are well matched with the observation in the perspective of cloud morphology and lasting period. It is also found through a simple sensitivity with a change in CCN that aerosol invigoration (AIV) effect on stratiform cloud organization is attributable to a change in the cloud microphysics as well as dynamics such as the corresponding modification of cloud number concentrations, drop size, and latent heating rate, etc. This study suggests a possible cloud vertical invigoration even in the continental stratiform clouds due to aerosol enhancement in spite of a limited analysis based on a few observed continental cloud cases.

Analysis of Acoustic Propagation using Spectral Parabolic Equation Method (스펙트럴 포물선 방정식 법을 이용한 수중음파 전달해석)

  • Kim, Kook-Hyun;Seong, Woo-Jae
    • The Journal of the Acoustical Society of Korea
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    • v.15 no.2
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    • pp.72-78
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    • 1996
  • This thesis deals with a method to solve a two-and-one-half-dimensional ($2\frac12$ D) problem, which means that the ocean environment is two-dimensional whereas the source is fully three-dimensionally propagating, including three-dimensional refraction phenomena and three-dimensional back-scattering, using two-dimensional two-way parabolic equation method combined with Fourier synthesis. Two dimensional two-way parabolic equation method uses Galerkin's method for depth and Crank-Nicolson method and alternating direction for range and provides a solution available to range-dependent problem with wave-field back-scattered from discontinuous interface. Since wavenumber, k, is the function of depth and vertical or horizontal range, we can reduce a dimension of three-dimensional Helmholtz equation by Fourier transforming in the range direction. Thus transformed two-dimensional Helmholtz equation is solved through two-way parabolic equation method. Finally, we can have the $2\frac12$ D solution by inverse Fourier transformation of the spectral solution gained from in the last step. Numerical simulation has been carried out for a canonical ocean environment with stair-step bottom in order to test its accuracy using the present analysis. With this spectral parabolic equation method, we have examined three-dimensional acoustic propagation properties in a specified site in the Korean Straits.

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Structure and Property Analysis of Nanoporous Low Dielectric Constant SiCOH Thin Films

  • Heo, Gyu-Yong;Lee, Mun-Ho;Lee, Si-U;Park, Yeong-Hui
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.05a
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    • pp.167-169
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    • 2009
  • We have carried out quantitative structure and property analysis of the nanoporous structures of low dielectric constant (low-k) carbon-doped silicon oxide (SiCOH) films, which were deposited with plasma enhanced chemical vapor deposition (PECVD) using vinyltrimethylsilane (VTMS), divinyldimethylsilane (DVDMS), and tetravinylsilane (TVS) as precursor and oxygen as an oxidant gas. We found that the SiCOH film using VTMS only showed well defined spherical nanopores within the film after thermal annealing at $450^{\circ}C$ for 4 h. The average pore radius of the generated nanopores within VTMS SiCOH film was 1.21 nm with narrow size distribution of 0.2. It was noted that thermally labile $C_{x}H_{y}$ phase and Si-$CH_3$ was removed to make nanopore within the film by thermal annealing. Consequently, this induced that decrease of average electron density from 387 to $321\;nm^{-3}$ with increasing annealing temperature up to $450^{\circ}C$ and taking a longer annealing time up to 4 h. However, the other SiCOH films showed featureless scattering profiles irrespective of annealing conditions and the decreases of electron density were smaller than VTMS SiCOH film. Because, with more vinyl groups are introduced in original precursor molecule, films contain more organic phase with less volatile characteristic due to the crosslinking of vinyl groups. Collectively, the presenting findings show that the organosilane containing vinyl group was quite effective to deposit SiCOH/$C_{x}H_{y}$ dual phase films, and post annealing has an important role on generation of pores with the SiCOH film.

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Sputtering of Solid Surfaces at Ion Bombardment

  • Kang, Hee-Jae
    • Proceedings of the Korean Vacuum Society Conference
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    • 1998.02a
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    • pp.20-20
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    • 1998
  • I Ion beam technology has recently attracted much interest because it has exciting t technological p아:ential for surface analysis, ion beam mixing, surface cleaning and etching i in thin film growth and semiconductor fabrication processes, etc. Es야~cially, ion beam s sputtering has been widely used for sputter depth profiling with x-photoelectron S spectroscopy (XPS) , Auger electron s$\pi$~troscopy(AES), and secondary-ion mass S야i따oscopy(SIMS). However, The problem of surface compositional ch없1ge due to ion b bombardment remains to be understo여 없ld solved. So far sputtering processes have been s studied by s따face an외ysis tools such as XPS, AES, and SIMS which use the sputtering p process again. It would be improbable to measure the modified surface composition profiles a accurately due to ion beam bombardment with surface analysis techniques based on sputter d depth profiling. However, recently Medium energy ion scattering spectroscopy(MEIS) has b been applied to study the sputtering of solid surface at ion bombardment and has been p proved that it has been extremely valuable in probing the surface composition 뻐d s structure nondestructively and quantita디vely with less than 1.0 nm depth resolution. To u understand the sputtering processes of solid surface at ion bombardment, The Molecular D Dynamics(MD) and Monte Carlo(MC) simulation has been used and give an intimate i insight into the sputtering processes of solid surfaces. In this presentation, the sputtering processes of alloys and compound samples at ion b bombardment will be reviewed and the MEIS results for the Ar+ sputter induced altered l layer of the TazOs thin film 뻐dd없nage profiling of Ar+ ion sputt얹"ed Si(100) surface will b be discussed with the results of MD and MC simulation.tion.

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Effect of Substrate Bias Voltage on DLC Films Prepared by ECR-PECVD (ECR-PECVD 방법으로 제작된 DLC 박막의 기판 Bias 전압 효과)

  • 손영호;정우철;정재인;박노길;김인수;김기홍;배인호
    • Journal of the Korean Vacuum Society
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    • v.9 no.4
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    • pp.328-334
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    • 2000
  • DLC (Diamond-Like Carbon) films were deposited by ECR-PECVD (electron cyclotron resonance plasma-enhanced chemical vapor deposition) method with the variation of substrate bias voltage under the others are constant except it. We have investigated the ion bombardment effect induced by the substrate bias voltage on films during the deposition of film. The characteristics of the film were analyzed using the Dektak surface profiler, SEM, FTIR spectroscopy, Raman spectroscopy and Nano Indentation tester. FTIR spectroscopy analysis shows that the amount of dehydrogenation in films was increased with the increase of substrate bias voltage and films thickness was decreased. Raman scattering analysis shows that integrated intensity ratio $(I_D /I_G)$ of the D and G peak was increased as the substrate bias voltage increased, and films hardness was increased. From these results, it can be concluded that films deposited at this experimental have the enhanced characteristics of DLC because of the ion bombardment effect on films during the deposition of film.

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Cognitive Emotional Schema Analysis through Characters' Network in Shakespeare in Love : The Writing Process of Romeo and Juliet and the Subject of Desire (<셰익스피어 인 러브> 인물 관계망을 통한 인지 감성 분석: 『로미오와 줄리엣』의 창작 및 욕망의 주체)

  • Park, Eun Jung;Sohn, Kirak
    • Journal of Digital Convergence
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    • v.14 no.4
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    • pp.425-435
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    • 2016
  • This paper has the aim to track down the viewers' cognitive emotion of how they are interacting with the story of Shakespeare in Love. Human minds have cognitive and emotional flows while plots, characters, and action-ideas are intertwined in the story of the film. This paper especially focused on the analysis of characters' networks with four statistical data pictures in order to schematize the storytelling architecture on how and why Shakespeare has strongly motivated to write a great star-crossed love play, Romeo and Juliet in his very young age. This paper examines that Shakespeare's subject of desire is to accomplish both a true love and a sincere play which can make the nature of love true. The desire of subject is always slipped aside into scattering with "object a." In the film of Shakespeare in Love, the "object a" is a writing process and has a product of Romeo and Juliet as well.

Development of Light Transmission Fluctuation for Particle Measurement in Solid-Gas Two Phase Flows

  • YANG, Bin;WANG, Zhan-ping;HE, Yuan;CAI, Xiao-Shu
    • Particle and aerosol research
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    • v.12 no.1
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    • pp.21-26
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    • 2016
  • In order to realize In-line and convenient measurement for solid-gas two phase flows, Light Transmission Fluctuation (LTF) based on the random variation of transmitted light intensity, light scattering theory and cross-correlation method was presented for online measurement of particle size, concentration and velocity. The statistical relationship among transmitted light intensity, particle size and particle number in measurement zone was described by Beer-Lambert Law. Accordingly, the particle size and concentration were determined from the fluctuation signal of transmitted light intensity. Simultaneously, the particle velocity was calculated by cross-correlation analysis of two neighboring light beams. By considering the influence of concentration variation in industrial applications, the improved algorithm based on spectral analysis of transmitted light intensity was proposed to improve measurement accuracy and stability. Therefore, the online measurement system based on LTF was developed and applied to measure pulverized coal in power station and raw material in cement plant. The particle size, concentration and velocity of powder were monitored in real-time. It can provide important references for optimal control, energy saving and emission reduction of energy-intensive industries.