• Proceeding of EDISON Challenge
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• 2014.03a
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• pp.1-13
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• 2014

Potential Energy Surface(PES)를 양자 계산을 통해 알아내는 것은 화학 반응을 이해하는 데에 큰 도움이 된다. 이를테면 Transition State(TS)의 configuration을 알 수 있고, 따라서 reaction path와 활성화 에너지 값을 예측하여, 진행시키고자 하는 화학반응의 이해를 도울 수 있다. 하지만 PES를 그리기 위해서는 해당 분자의 다양한 configuration에 대한 singlet point energy 계산이 필요하기 때문에, 계산적인 측면에서 많은 비용을 요구한다. 따라서 product와 reactant의 구조와 같은 critical point의 정보를 이용하여 최소한의 configuration을 sampling하여 전체 PES를 재구성하는 기계학습 알고리즘을 개발하여 다차원 PES 상에서의 화학반응의 예측을 가능하게 하고자 한다. 본 연구에서는 Barbaralane의 두 안정화 된 구조의 critical point로 하여 이 주변을 random normal distribution하여, B3LYP/6-31G(d) level의 DFT 계산을 통해 relaxed scanning하여 구조와 에너지를 구하였으며, 이 정보를 Support Vector Regression(SVR) 알고리즘을 적용하여 PES를 재구현하였으며, 반응경로와 TS의 구조 그리고 활성화 에너지를 구하였다. 또한 본 기계학습 알고리즘을 바닥상태에서 일어나는 반응이 아닌, 들뜬 상태와 전자 구조가 변하는 화학반응, avoid crossing, conical intersection과 같은 Non-adiabatic frame에서 일어나는 현상에 적용 가능성을 논하고자 한다.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.11 no.4
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• pp.565-574
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• 2000

A new ground penetrating radar imaging method for the estimation of buried artificial structures location and their approximate shapes in dispersive lossy ground is investigated. Fundamental idea is based on estimating delayed time and amplitude retrieval coefficients from scattered signals by buried scatterers. Using absolute value integration of each scanning site not only improve the accuracy of measured scattered signal, but also offers convenient ways to extract the image of buried structures. Multi-term Debye model was employed to describe a dispersive and lossy ground medium. We used the finite difference time domain method to discretize the wave equation in continuous form into the machine suitable form. This imaging method uses a new wave path tracing technique in time domain, which is helpful to identify the exact position of buried structures against the ground surface fluctuations.

• Structural Engineering and Mechanics
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• v.66 no.2
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• pp.249-262
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• 2018

In this paper, reaction of functionally graded (FG) thick nanoplates resting on a viscoelastic foundation to a moving nanoparticle/load is investigated. Nanoplate is assumed to be thick by using second order shear deformation theory and small-scale effects are taken into account in the framework of Eringen's nonlocal theory. Material properties are varied through the thickness using FG models by having power-law, sigmoid and exponential functions for material changes. FG nanoplate is assumed to be on a viscoelastic medium which is modeled using Kelvin-Voight viscoelastic model. Galerkin, state space and fourth-order Runge-Kutta methods are employed to solve the governing equations. A comprehensive parametric study is presetned to show the influence of different parameters on mechanical behavior of the system. It is shown that material variation in conjunction with nonlocal term have a significant effect on the dynamic deformation of nanoplate which could be used in comprehending and designing more efficient nanostructures. Moreover, it is shown that having a viscoelastic medium could play an important role in decreasing these dynamic deformations. With respect to the fresh studies on moving atoms, molecules, cells, nanocars, nanotrims and point loads on different nanosctructures using scanning tunneling microscopes (STM) and atomic force microscopes (AFM), this study could be a step forward in understanding, predicting and controlling such kind of behaviors by showing the influence of the moving path, velocity etc. on dynamic reaction of the plate.

• Journal of Institute of Control, Robotics and Systems
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• v.14 no.3
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• pp.236-241
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• 2008

This paper presents a method to recognize the plane regions for movement of walking robots. When the autonomous agencies using stereo camera or laser scanning sensor is under unknown 3D environment, the mobile agency has to detect the plane regions to decide the moving direction and perform the given tasks. In this paper, we propose a very fast method for plane detection using normal vector of a triangle by 3 vertices defined on a small circular region. To reduce the effect of noises and outliers, the triangle rotates with respect to the center position of the circular region and generates a series of triangles with different normal vectors based on different three points on the boundary of the circular region. The vectors for several triangles are normalized and then median direction of the normal vectors is used to test the planarity of the circular region. The method is very fast and we prove the performance of algorithm for real range data obtained from a stereo camera system.

• Journal of the Korean Ceramic Society
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• v.52 no.3
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• pp.173-179
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• 2015

We report the facile synthesis of graphene-$CdLa_2S_4$ composite through a facile solvothermal method at low temperature. The as-prepared products were characterized by X-ray diffraction (XRD) and by Scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis and BET analysis, revealing the uniform covering of the graphene nanosheet with $CdLa_2S_4$ nanocrystals. The as-prepared samples show a higher efficiency for the photocatalytic degradation of typical MB dye compared with P25 and $CdLa_2S_4$ bulk nanoparticles. The enhancement of visible-light-responsive photocatalytic properties by decolorization of Rh.B dye may be attributed to the following causes. Firstly, graphene nanosheet is capable of accepting, transporting and storing electrons, and thus retarding or hindering the recombination of the electrons with the holes remaining on the excited $CdLa_2S_4$ nanoparticles. Secondly, graphene nanosheet can increase the adsorption of pollutants. The final cause is that their extended light absorption range. This work not only offers a simple way to synthesize graphene-based composites via a one-step process at low temperature but also a path to obtain efficient functional materials for environmental purification and other applications.

• Proceedings of the KIEE Conference
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• 2003.07c
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• pp.1571-1573
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• 2003

Diamond films including nanocystalline and graphite phase are grown by microwave plasma chemical vapor deposition using $N_2$ additives and negative substrate bias at growth step. The microstructure of the films is controlled by changing $N_2$ gas ratio and negative bias. Defects and grain boundaries between diamond and graphite are proposed to be crucial factors for forming the conducting path of electron emissions. The effect of growth parameters on the film microstructure are investigated by Raman spectroscopy and scanning electron microscopy(SEM). Electron emission characteristics are also examined in terms of the film growth conditions.

• Journal of the Korean Electrochemical Society
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• v.24 no.1
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• pp.1-6
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• 2021

In this study, new morphology of NCA cathode material for lithium ion batteries was obtained through the electrospinning method. The prepared NCA nanofibers formed a nano-bush structure, and the primary particles were formed on the surface of the nanofibers. The embossing primary particles increased the surface area thus increasing the reactivity of lithium ions. The nano-bush structure could shorten the Li+ diffusion path and improve the Li+ diffusion coefficient. Scanning electron microscopy (SEM) revealed that the synthesized material consisted of nanofibers. The surface area of the nanofibers increased by primary particles was measured using atomic force microscopy (AFM). X-ray diffraction (XRD) analysis was carried out to determine the structure of the NCA nanofibers.

• Convergence Security Journal
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• v.23 no.1
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• pp.55-61
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• 2023

QR Code is a two-dimensional code in the form of a matrix that contains data in a square-shaped black-and-white grid pattern, and has recently been used in various fields. In particular, in order to prevent the spread of COVID-19, the usage increased rapidly by identifying the movement path in the form of a QR code that anyone can easily and conveniently use. As such, Qshing attacks and damages using QR codes are increasing in proportion to the usage of QR codes. Therefore, in this paper, a system was implemented to block movement to harmful sites and installation of malicious codes when scanning QR codes.

• Nuclear Engineering and Technology
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• v.55 no.1
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• pp.215-221
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• 2023

Proton treatment may deliver a larger dose to a patient's skin than traditional photon therapy, especially when a range shifter (RS) is inserted in the beam path. This study investigated the effects of an RS on skin dose while considering RS with different thicknesses, airgaps and materials. First, the physical model of the scanning nozzle with RS was established in the TOol for PArticle Simulation (TOPAS) code, and the effects of the RS on the skin dose were studied. Second, the variations in the skin dose and isocenter beam size were examined by reducing the air gap. Finally, the effects of different RS materials, such as polymethylmethacrylate (PMMA), Lexan, polyethylene and polystyrene, on the skin dose were analysed. The results demonstrated that the current RS design had a negligible effect on the skin dose, whereas the RS significantly impacted the isocenter beam size. The skin dose was increased considerably when the RS was placed close to the phantom. Moreover, the magnitude of the increase was related to the thickness of the inserted RS. Meanwhile, the results also revealed that the secondary proton primarily contributed to the increased skin dose.

• Journal of Sensor Science and Technology
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• v.32 no.5
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• pp.267-274
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• 2023

LiDAR, one of the most important sensing methods used in mobile robots and cars with assistive/autonomous driving functions, is used to locate surrounding obstacles or to build maps. For real-time path generation, the detection of potholes or puddles on the driving surface is crucial. To achieve this, we used the coordinates of the reflection points provided by LiDAR as well as the intensity information to classify water areas, which was achieved by applying a linear regression method to the intensity distribution. The rationale for using the LiDAR index as an input variable for linear regression is presented, and we demonstrated that it is not affected by errors in the distance measurement value. Because of LiDAR vertical scanning, if the reflective surface is not uniform, it is divided into different groups according to the intensity distribution, and a mathematical basis for this is presented. Through experiments in an outdoor driving area, we could distinguish between flat ground, potholes, and puddles, and kinematic analysis was performed to calculate the maximum width that could be crossed for a given vehicle body size and wheel radius.