• Clean Technology
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• v.21 no.2
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• pp.102-107
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• 2015

Rhodamine dyes are widely used as fluorescent probes because of their excellent photophysical properties, such as high extinction coefficients, excellent quantum yields, great photostability, relatively long emission wavelengths. A great synthetic effort has been focused on developing efficient and practical procedures to prepare rhodamine derivatives, because for most applications the probe must be covalently linked to another (bio)molecule or surface. Sulforhodamine B is one of the most used rhodamine dyes for this purpose, because it carries two sulfoxy functions which can be easily utilized for binding with other molecules. Recently, we needed an expedient, practical synthesis of sulforhodamine derivatives. We found the existing procedure for obtaining those compounds unsatisfactory, particularly, with the cyclization process of the dihydroxytriarylmethane (1) to produce the corresponding xanthene derivative (2). We report here our findings, which represent modification of the existing literature procedure and provide access to the corresponding xanthene derivative (2) in a high yield. Use of methanol as a co-solvent was found quite effective to prohibit the water molecule produced during the cyclization reaction from retro-cyclizing back to the starting dihydroxytriarylmethane and the yield of the cyclization was increased (up to 84% from less than 20%). The reaction temperature was significantly lowered (80 vs. 135 ℃). Thus, the reaction proceeds in a higher yield and energy-saving manner where the use of reactants and the production of chemical wastes is minimized.

• Journal of the Korean Wood Science and Technology
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• v.44 no.1
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• pp.75-84
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• 2016

Thermal performance of wooden houses used by building materials effectively contributing to building energy saving has been improved. However, the performance was decreased to the condensation and mould growth from exterior wall because the moisture control was difficult to high insulation and airtightness. Therefore, the hygrothermal performance of exterior wall, that selected 5 types of wooden houses, evaluated using the hygrothermal simulation program: heat and moisture behavior, condensation and mould growth risk. Wooden houses were selected Rural houses standard plans '10 and '14, $2^{{\prime}{\prime}}{\times}6^{{\prime}{\prime}}$ type, EIFS and wood-based passive house. And the wall A, B, C, D and E were determined by layer component of each wall. The U-value of exterior wall are 0.171, 0.172, 0.221, 0.150, $0.079W/m^2K$. The OSB absolute water content of the wall A and C was exceeds the reference value of 20%, and it was confirmed that condensation occur at insulation material inner surface through the condensation evaluation in the winter. The wall D and E showed excellent results with condensation and water content evaluation compared to others. However, mould growth risk assessment in all five types of wall had have risk. We were determined that hygrothermal performance difference of exterior wall occur the difference in the layer structure rather than in thermal performance.

• Journal of Advanced Marine Engineering and Technology
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• v.8 no.1
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• pp.17-36
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• 1984

Since 1973, the competition on the development of fuel saving type internal combustion engines has become severe by the two times oil shock, and new type engines are reported every several months. Whenever these new type engines are developed, new designs are required and they will be offered in the market after performing the endurance test for a long time. But the engine market is faced with a heavy burden of finance, as the developing of a new engine requires tremendous expenses. For this reason, the computer simulation method has been lately developed to cope with it. The computer simulation method can be available to perform the reasonable research works by the theoretical analysis before carrying out practical experiments. With these processes, the developing expenses are cut down and the period of development is curtailed. The object of this study is the development of simulation computer program for the small naturally aspirated four-stroke diesel engine which is intended to product by the original design of our country. The process of simulation is firstly investigated for the ideal engine cycle, and secondly for the real engine cycle. In the ideal engine cycle, each step of the cycle is simulated by the energy balance according to the first law of thermodynamics, and then the engine performance is calculated. In the real cycle imulation program, the injection rate, the preparation rate and the combustion rate of fuel and the heat transfer through the wall of combustion chamber are considered. In this case, the injection rate is supposed as constant through the crank angle interval of injection and the combustion rate is calculated by the Whitehouse-Way equation and the heat transfer is calculated by the Annand's equation. The simulated values are compared with measured values of the YANMAR NS90(C) engine and Mitsubishi 4D30 engine, and the following conclusions are drawn. 1. The heat loss by the exhaust gas is well agree with each other in the lower load, but the measured value is greater than the calculated value in the higher load. The maximum error rate is about 15% in the full load. 2. The calculated quantity of heat transfer to the cooling water is greater than the measured value. The maximum error rate is about 11.8%. 3. The mean effective pressure, the fuel consumption, the power and the torque are well agree with each other. The maximum error is occurred in the fuel consumption, and its error rate is about 7%. From the above remarks, it may be concluded that the prediction of the engine performance is possibly by using the developed program, although the program needs to reform by adding the simulation of intake and exhaust process and assumping more reliable mechanical efficiency, volumetric efficiency, preparation rate and combustion rate.

• Journal of the Korean Home Economics Association
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• v.42 no.10 s.200
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• pp.91-104
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• 2004

The purpose of this study was to examine the differences of clothing microclimates and the subjective sensations according to age, gender and clothing weight for $19^{\circ}C$ air temperature. This study was done to gain fundamental data related to saving heating energy and to improve health through wearing underwear (long johns) in lower indoor temperatures. The subjects were divided into four groups (6 young males, 5 young females, 6 old males, 6 old females), and our experiment consisted of three conditions; the first condition was wearing long underwear in $19^{\circ}C$ air (19CUW condition); the second condition was without wearing long underwear in $19^{\circ}C$ air (19C condition); and the third condition was without wearing underwear in $24^{\circ}C$ air (24C condition). The experiment showed that the clothing microclimate temperature and humidity was the lowest in the 19C condition and the highest in the 24C condition irrespective of age and gender. The clothing microclimate in the 19CUW condition was not significantly distinguishable from the other conditions. Clothing microclimate temperature and humidity when the subjects responded thermal comfort was $28\~34^{\circ}C$ and $15\~40\%$RH without any significant difference according to age and gender. For the thermal sensation, the 24C condition was regarded as the warmest environment by the four groups, and the next preference was the 19CUW condition (p<0.001). Young females and old males showed a tendency to feel colder than young males and old females. For the thermal sensation of hands and feet, the young groups felt the warmest in the 24C condition and the coolest in the 19 C condition (p<0.001). However, old males felt neutral for the foot thermal sensation without any significant difference between the three conditions. Old females felt neutral for both the hands and feet thermal sensations without any significant difference between the three conditions. Thermal preference was the highest in the 24C condition for the 4 groups. In the 19CUW condition, for the thermal preference, most young males and females responded 'No change'; on the other hand, mea of the old responded 'Warmer'(p<0.001). It was the 24C condition that the 4 subject groups felt the most thermally comfortable. In the 19CUW condition, over $80\%$ of responses of each group expressed satisfaction and in the 19C condition, over $80\%$ of responses of each group, except young females, expressed satisfaction. In conclusion, in view of the clothing microclimate and subjective sensations, the 24C condition was the condition that gave subjects the least cold stress and the best subjective preference. However, the 19C condition and the 19CUW condition was not such a cold stress as to give healthy subjects a thermal burden.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.4
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• pp.71-78
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• 2012

Recycled aggregates are made from construction wastes, and they have many national and social benefits by saving energy, developing substitute resources, and protecting environment. However, low-quality recycled aggregate with low density and high absorption rate cannot be used for structural concrete aggregate but is used mainly for low added value. Therefore, this study aims to identify the characteristics of the materials of recycled aggregates made after crashing and pulverizing waste concrete. For this, their major physical characteristics of cement content, absolute dry density, absorption rate, etc. were reviewed to make a mix design (draft) for the production of the secondary product and performance evaluation was done on the bending strength, absorption rate, bending strength after freezing and thawing, compressive strength, air-dried gravity, etc. of the test products produced by applying the mix design to compare the results with the quality standards of GR mark. The results of the tests showed that the substitution rate of recycled aggregate increased to 50~90 %, which is of superior quality than the performance standards of GR F 4007. Therefore, it is thought that they can be used for various construction works with certain physical characteristics applicable to the production of secondary concrete products using recycled aggregates.

• Journal of the Society of Disaster Information
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• v.14 no.2
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• pp.107-114
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• 2018

Purpose : This study is to develop walls using wall recording technology applied on roofs to prevent fire spread in traditional markets. Method : The spray head installed on the developed wall was designed so that the fire does not spread to adjacent buildings after being used for plants. In addition, a spray head was attached to the upper section and some sections for the growth of plants planted on the wall to prevent the spread of fire. Results : These technologies suggested the development of walls that can be installed at the upper level of buildings, such as traditional markets, and separate isolation facilities were not necessary because they are integrated with structures and sprinklers. In addition, sprinklers can perform both the plant spray and fire spread prevention functions. It is believed that this is the only alternative technology proposed in Korea to prevent the spread of fire. Conclusion : In this study, the wall design, designed directly to derive the quantitative performance of the fire spread reduction effect, demonstrated the fire suppression method of the wall system, the durability of the wall itself, and the flame retardability performance.

• Korean Journal of Environment and Ecology
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• v.24 no.5
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• pp.591-600
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• 2010

We estimated and compared C storages and annual $CO_2$ uptakes by 9 dominant tree species planted along the streets. DBH and age by tree species were measured in the sites selected considering the planting status and distributions of tree species, and biomass, C storage, growth rate, and annual $CO_2$ uptake were estimated for each species. As a result, L. tulipifera, M. glyptostroboides, P. occidentalis were classified into fast-growing group, P. serrulata, G. biloba, Z. serrata, S. japonica, A. palmatum showed intermediate growth rates, and P. densiflora was slow-growing. Average C storage per tree was 205kgC/tree and ranged from 518kgC/tree(L. tulipifera) to 41kgC/tree(P. densiflora). Average annual $CO_2$ uptake by urban street trees over their lifespan ranged from $7.6kgCO_2$/tree/y to $99.1kgCO_2$/tree/y and L. tulipifera was the greatest, followed by glyptostroboides and P. occidentalis, and P. densiflora was the lowest. Total annual $CO_2$ uptake by all street trees in Gyeonggi-do, estimated based on the annual $CO_2$ uptake by each species, was as small as approximately 0.67% of that by forest in Gyeonggi-do. However, urban trees are still important because forest area continues to decrease and urbanization occurs annually in Gyeonggi-do, and should be managed considering their multi-functional aspects, including mitigation of heat island effect and building energy saving(indirect $CO_2$ uptake).

• The Journal of Korean Institute of Communications and Information Sciences
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• v.38B no.1
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• pp.72-79
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• 2013

In wireless sensor networks, the selective wakeup scheme is one of the energy saving mechanisms, that is used for an object detecting or tracking. Recently, many protocols are proposed using the selective wakeup scheme for the continuous objects tracking such as forest fires and poison gas. They predict the future shape of continuous objects and activate only sensors in the predicted boundary area of the objects. It works correctly in a uniformly deployed wireless sensor networks. However, it cannot be directly applied to a randomly deployed sensor networks with voids. When the predicted area is in the void area, the activation message cannot reach and the predicted area cannot be activated at the right time. It leads to many detection errors for continuous object. Moreover, if a sensor is once foiled in a activation control then the next activation control might be continuously failed. The detection errors can be result in serious harm to people. In this paper, we propose a chaining selective wakeup scheme for robust continuous object tracking in wireless sensor networks. In our protocol, we collect the information of a void area during the network configuration time; if the next boundary area is in the void area, we activate the chained area surrounding the void area with activation control message.

• Journal of Advanced Marine Engineering and Technology
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• v.37 no.4
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• pp.409-417
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• 2013

Mu-communication board supported by multi-communication is designed with Atxmega 128A1 which is a low power energy consuming of 8-bit microcontroller. ATxmega128A1 microcontroller consists of 8 UART(Universal asynchronous receiver/transmitter) ports which can be setting appropriate user interface having command line interpreter(CLI) program with each port, 2 kbytes EEPROM, 128 kbytes flash memory, 8 kbytes SRAM. 8 URAT ports are used for the multi communication modem, GPS module, etc. and EEPROM is used for saving a configuration for program running, and flash memory of 128 kbytes is used for storing a Firm Ware, and 8 kbytes SRAM is used for stack, storing memory of global variables while program running. If we uses the hybrid communication of path optimization of VHF, TRS and CDMA to remote control AtoN(aid to navigation), it is able to remove the communication shadow area. Even though there is a shadow area for individual communication method, we can select an optimum communication method. The compatibility of data has been enhanced as using of same data frame per communication devices. For the test, 8640 of data has been collected from the each buoy during 30 days in every 5 minutes and the receiving rate of the data has shown more than 99.4 %.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.35 no.5
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• pp.62-71
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• 2003

This study was carried out to develop the bio-chemical pulping method to enhance the energy saving and decrease the capital cost through the soda pulping under atmospheric pressure ($100^{\circ}C$). Nonwood substrates, rice straw, were pretreated by white-rot fungi, Pleurotus cornucopiae. Several basic pieces of data that can be applied in soda pulping were acquired. The results of this study were as follows. Under the conditions without any nutrients or with glucose, N and glucose + N, the weight losses of rice straws inoculated by Pleurotus cornucopiae were 12.1∼32.6 %, 12.0∼26.3 %, 13.0∼25.4 % and 15.3∼24.7 % for 5, 10, 15, 20, 25 and 30 days incubation periods respectively. The more the fungal incubation was extended, the more the weight losses were gained. The yield of untreated rice straw was 54.8 % after pulping. When any nutrients was not added or glucose, N and glucose ＋ N were added for the pretreatment, the total yields were ranged to 57.3∼42.9 %, 51.0∼43.3 %, 51.7∼43.9 % and 52.1∼46.1 % for 5 different incubation periods respectively. The yields were gradually decreased based on the extending of the incubation periods. The physical properties of the rice straw soda pulp without fungal treatment, the density, breaking length, burst index, tear index and folding endurance were 0.24g/㎤, 2.32 Km, 0.91 kPaㆍ$m^2$/g, 46.7 mNㆍ$m^2$/g and 21 times, respectively. In the case of pretreatment without any nutrients or with glucose, N and glucose + N as nutrients, the density was 0.24g/㎤, the breaking length was 3.30∼6.46 Km, the burst index was 1.36∼3.01 kPaㆍ$m^2$/g, the tear index was 33.0∼57.0 mNㆍ$m^2$/g and the folding endurance was 14∼381 times at most incubating periods, when pulping was done. The physical properties were increased as the incubation duration was extended. Especially, when N and glucose ＋ N were added, the physical properties showed superior results during each incubation period.