• Title/Summary/Keyword: Saturated liquid density

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Calculation of the Thermodynamic Properties of R-134a and A Preliminary Study of the Refrigeration Performance (R-134a의 열역학적 물성치 계산과 냉동 성능에 관한 연구)

  • Park, Y.M.;Lee, H.W.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.3 no.4
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    • pp.286-296
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    • 1991
  • The thermodynamic properties of R134a, the prospective R12 alternative, have been computerized using Martin-Hou equation of state and the coefficients given by Willson-Basu. Several experimental results in literatures for PVT data, saturated vapor pressure, saturated liquid density are compared with the calculated results to investigate the accuracy. The average deviation (max. deviation) is 0.13% (0.25%) for saturated liquid density, 0.25% (0.8%) for PVT data. Thermodynamic properties, enthalpy, entropy are compared with the NIST's. The maximum percent difference is 3% for saturated liquid enthalpy, 1.5% for saturated vapor enthalpy, 4% saturated liquid entropy, and 0.7% for saturated vapor entropy. Correction of W-B's coefficients and inclusion of the sixth term of M-H EOS for improvement of accuracy are recommended. R134a and R12 are compared with respect to refrigeration performance. COP's are different from each other within 3%. Refrigeration effect of R134a is superior to that of R12 but refrigeration capacity of R134a is inferior to that of R12 because the volumetric efficiency of the system using R134a is lower than that of the system using R12.

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Performance Comparison of Correlations of the Saturated Liquid Densities for Pure Substances (순수물질에 대한 포화액체밀도 상관식의 성능비교)

  • Lee, Kyoung-Youl;Park, Kyoung-Kuhn
    • Proceedings of the SAREK Conference
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    • 2005.11a
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    • pp.373-379
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    • 2005
  • A few correlation equations of the saturated liquid density are reviewed and a new equation is proposed. Performance of each equation is examined using the data listed in the ASHRAE table for 22 pure substance refrigerants. The new four-parameter equation yields an average absolute deviation of 0.03% for 22 refrigerants. Performance of the new four-parameter equation is found to be equivalent to those of the existing equations such as Hou-Martin equation(0.03%) and Iglesias-Silva-Hall equation(0.08%).

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An Experimental study on the Freezing Phenomena of Saturated Porous Media in a Rectangular Cavity (장방형내 함수 다공성 물질의 동결거동에 관한 실험적 연구)

  • Kim, B.C.;Kim, J.I.;Kim, J.H.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.3 no.5
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    • pp.386-394
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    • 1991
  • Freezing of saturated porous media contained in a rectangular cavity has been studied experimentally. Water and different diameter glass beads consitituted the liquid and porous media. Solidification front shape, the effects of bead diameter and initial liquid temperature was investigated. When the hot wall temperature was below $4^{\circ}C$, the freezing rate was higher at the top than at the bottom due to the density inversion, but with increasing the hot wall temperature the freezing rate at the top was effected by the liquid temperature and was lower than at the bottom. With increasing the bead diameter, the difference of freezing rate between top and bottom was increased and depends on thermal conductivity. When the liquid temperature was low in the beginning, the freezing rate was high, but with increasing the time almost the same with those of high temperature liquid.

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Measurements of Droplet Sizes and Velocities with Optimum Probability Density Function in a Transient Liquefied Butane Spray (액상부탄 간헐분무의 액적 크기 및 속도 측정과 최적 확률분포 연구)

  • Kim, J.H.;Kim, J.W.;Koo, J.Y.
    • Journal of ILASS-Korea
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    • v.5 no.1
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    • pp.30-40
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    • 2000
  • The characteristics of liquefied butane spray are expected to be different from conventional diesel fuel spray, because a kind of flash boiling spray is expected when the back pressure is below the saturated vapor pressure of the butane(0.23MPa at 298K). The ambient pressure was held at a pressure above(0.37MPa) and below(0.15MPa) the fuel vapor pressure. The axial velocities, radial velocities, and size distributions in butane sprays were measured with PDPA(Phase Doppler Particle Analyzer) system. The PDPA measurement showed a smaller SMD at the 0.15MPa chamber pressure, compared to the 0.37MPa case. Log-hyperbolic density function for the droplets size distribution can be fitted to the experimental results of a liquefied butane spray.

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Superitical fluid (SCF) technology application to the regeneration of industrial catalyst contaminated with toxic materials (독성폐기물로 오염된 산업촉매 재생공정에 초임계유체기술의 적용)

  • 이재동;윤용수;홍인권;정일현
    • Journal of the Korean Society of Safety
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    • v.7 no.1
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    • pp.13-19
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    • 1992
  • Supercritical fluid technology was applied to the regeneration of industrial catalyst contaminated with toxic materials. The regeneration process of activated loaded with phenol was proposed, then the adsorphon tower was packed with the activated carbon-bed. Phenol diffuses into supercritical carbon dioxide(SCC) through the micro-pore and voldge of the activated carbon. The saturated solubility of phenol in SCC depended on the density of SCC varing with temperature and pressure conditions. Therefore, the fasile phase equilibrium calculation model of dxpanded liquid One was proposed, and equilibrium solubility of phenol in SCC was calculated using the model theoretically. The regeneration mechanism of activated carbon was analysed by degree of saturation of phenol and diffusion in SCC. The solubility prediction was more satisfactory for the wide range of SCC density than the dense gas model and the desorption of phenol depended on the degree of saturation of phenol in SCC.

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Effeet of Al2O3, MgO and SiO2 on Sintering and Hydration Behaviors of CaO Ceramics

  • Kim, Do-Kyung;Cho, Churl-Hee;Goo, Bong-Jin;Lee, Kee-Sung
    • Journal of the Korean Ceramic Society
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    • v.39 no.6
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    • pp.528-534
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    • 2002
  • CaO ceramics were prepared by conventional sintering process and their hydration behaviors were evaluated by measuring weight increment on saturated water vapor pressure at ambient temperature. CaCO$_3$ and limestone were used as CaO source materials and $Al_2$O$_3$, MgO and SiO$_2$ were added as sintering agents. $Al_2$O$_3$ was a liquid phase sintering agent to increase densification and grain growth rates, whereas MgO and SiO$_2$, densification and grain growth inhibitors. Regardless of composition, all of the prepared CaO ceramics showed the improved hydration resistance as bulk density increased. Especially, when bulk density was more than 3.0 g/㎤, there was no weight increment after 120 h of hydration. Therefore, to decrease contact area between CaO and water vapor by increasing bulk density with the $Al_2$O$_3$ sintering additive was effective for the improvement of CaO hydration resistance.

Changes in Physical Properties of Dredged Soils by Drying (건조에 의한 준설 매립 지반에 물리적 특성변화)

  • Yonn Yong-Han;Kim Won-Tae
    • Journal of the Korean Institute of Landscape Architecture
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    • v.34 no.2 s.115
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    • pp.36-43
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    • 2006
  • This study was carried out to determine the ways in which drying improves and develops dredged soils which exist widely in the lowlands of Korea. Before drying there were large variations in the fundamental physico-chemical properties of dredged soils collected from different places. In the sample soils, saturated hydraulic conductivity decreased gradually with an increase in bulk density with the exception that in air-dried soils a reverse trend was observed. Also in the sample soils, the sedimentation volume and the consistency limits decreased gradually with the decrease in soil water content after the air-drying treatment. The porosity of the sample soils decreased from $0.67{\sim}0.87m^3/m^3\;to\;0.58{\sim}0.66m^3/m^3$ and the liquid-phase range decreased from $0.41{\sim}0.83m^3/m^3\;to\;0.29{\sim}0.71m^3/m^3$. The solid-phase range of sample soils increased $0.13{\sim}0.33m^3/m^3\;to\;0.24{\sim}0.37m^3/m^3$ same as above with air-drying treatment. In conclusion the air-drying treatment caused an irreversible effect on some physical properties. Accordingly, these facts indicate that the effects of air-drying treatment on these properties are considered to be resulted from irreversible changes in the structural status of the sample soils.

Metal-Organic Chemical Vapor Deposition of $Pb(Zr_xTi_{1-x})O_3$ Thin Films for High-Density Ferroelectric Random Access Memory Application

  • Lee, June-Key;Ku, June-Mo;Cho, Chung-Rae;Lee, Yong-Kyun;Sangmin Shin;Park, Youngsoo
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.2 no.3
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    • pp.205-212
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    • 2002
  • The growth characteristics of metal-organic chemical vapor deposition (MOCVD) $Pb(Zr_xTi_{1-x})O_3 (PZT) thin films were investigated for the application of high-density ferroelectric random access memories (FRAM) devices beyond 64Mbit density. The supply control of Pb precursor plays the most critical role in order to achieve a reliable process for PZT thin film deposition. We have monitored the changes in the microstructure and electrical properties of films on increasing the Pb precursor supply into the reaction chamber. Under optimized conditions, $Ir/IrO_2/PZT(100nm)/Ir capacitor shows well-saturated hysteresis loops with a remanent polarization (Pr) of $~28{\mu}C/textrm{cm}^2$ and coercive voltage of 0.8V at 2.5V. Other issues such as step coverage, compositional uniformity and low temperature deposition was discussed in viewpoint of actual device application.

A Study on the Parameters Influencing the Failed Soil-Slope in Okcheon Metamorphic Zone (옥천변성대 절개지 사면의 토층붕괴 영향인자에 관한 연구)

  • Lee, Kyoung-Mi;Kim, Byung-Chan;Seo, Yong-Seok
    • The Journal of Engineering Geology
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    • v.19 no.4
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    • pp.501-508
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    • 2009
  • This study aims to clarify the characteristics of the physical and mechanical properties of soil-slope failure of Okcheon metamorphic zone. Soil samples were collected from 35 collapsed and uncollapsed artificial slopes along national roads. A series of laboratory experiments was carried out to examine physical and mechanical properties of soils and rocks. The results show that failure slopes have weakness of failure at 0.75 of AMI or higher, 32% of liquid limit or higher, and 31% of saturated moisture content or higher. The plastic index of failure slopes is correlated to wet density and saturated density. It turned out that failure could easily happen according to a high plastic index even if the void ratio was low. The greater the contents of bigger-sized soil, i.e. contents of sands and gravels rather than of clays, is the greater the chance to fail at the slope.

Synthesis of Au Nanowires Using S-L-S Mechanism (S-L-S 성장기구를 이용한 양질의 골드 나노선 합성)

  • No, Im-Jun;Kim, Sung-Hyun;Shin, Paik-Kyun;Cho, Jin-Woo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.11
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    • pp.922-925
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    • 2012
  • Single crystalline Au nanowires were successfully synthesized in a tube-type furnace. The Au nanowires were grown by vapor phase synthesis technique using solid-liquid-solid (SLS) mechanism on substrates of corning glass and Si wafer. Prior to Au nanowire synthesis, Au thin film served as both catalyst and source for Au nanowire was prepared by sputtering process. Average length of the grown Au nanowires was approximately 1 ${\mu}m$ on both the corning glass and Si wafer substrates, while the diameter and the density of which were dependent on the thickness of the Au thin film. To induce a super-saturated states for the Au particle catalyst and Au molecules during the Au nanowire synthesis, thickness of the Au catalyst thin film was fixed to 10 nm or 20 nm. Additionally, synthesis of the Au nanowires was carried out without introducing carrier gas in the tube furnace, and synthesis temperature was varied to investigate the temperature effect on the resulting Au nanowire characteristics.