• Title/Summary/Keyword: Saponification

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Autogenous Property and Mock-up Test of the High Performance Concrete with Emulsified Refined Cooking Oil (유화처리 정제식용유(ERCO) 사용에 따른 고성능 콘크리트의 Mock-up 및 자기수축특성)

  • Jo, Man-Ki;Kim, Jun-Ho;Lee, Dong-Gyu;Park, Kyu-Yeon;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.05a
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    • pp.134-135
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    • 2014
  • In this study, mock-up test for high strength concrete with ERCO has been carried to analyse the effect of autogenous shrinkage reducing of using ERCO. The following results could be made as the conclusion. Results of EIS were lower than 2.5 and showed good resistance for separation of materials. For the setting time, specimen with ERCO showed delay of setting comparing with Plain. For the autogenous shrinkage, as the generation of saponification, capillary pores inside the concrete were filled by soap and the autogenous shrinkage has been obviously decreased. It could be identified that using ERCO in high strength showed good effect on reducing autogenous shrinkage in high strength concrete.

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Paeonol-glycoside of the Root of Pycnostelma paniculatum Kitagawa (산해박의 배당체(配糖體)에 관한 연구(硏究))

  • Lee, Heum-Sook;Han, Dae-Suk;Kang, Tak-Lim
    • Korean Journal of Pharmacognosy
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    • v.11 no.2
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    • pp.66-68
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    • 1980
  • Paeonol-glycoside could be extracted and isolated from the fresh roots of Pycnostelma paniculatum Kitagawa and compared with paeonolide(paeonol-6-[L-arabinosyl]-${\beta}-D-glucoside)$ by IR and UV spectra. By saponification with mineral acid, it was known that isolated glycoside was composed of aglycon and sugar parts. Aglycon was identified by comparing with paeonol by TLC and UV spectra. Of two kinds of sugar, only glucose was identified by GLC.

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Carbonation Mitigation of the High Volume Admixture Concrete according to Application Method of Carbonation Resistance Material (탄산화 억제제 사용 따른 혼화재 다량 치환 콘크리트의 탄산화 억제)

  • Jo, Man-Ki;Choi, Young-Doo;Son, Ho-Jung;Woo, Dae-Hun;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.05a
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    • pp.271-273
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    • 2012
  • This paper is to investigate the effect of waste cooking oil(WCO) on carbonation resistance of high volume fly ash and blast furnace slag concrete. WCO and paint were applied for carbonation resistance materials. As expected, the application of WCO to the concrete help it reduce carbonation depth remarkably, regardless of mixture types. This may be due to the fact that WCO makes the capillary pore block by activating saponification. It is found that the degree of carbonation reduce due to WCO is much higher than the case by Paint.

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Correlations for Predicting Viscosity of Vegetable Oils and Its Derivatives for Compression Ignition Engines

  • No, Soo-Young
    • Journal of ILASS-Korea
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    • v.14 no.3
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    • pp.122-130
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    • 2009
  • Vegetable oil and its derivatives as an alternative diesel fuel have become more attractive recently because of its environmental benefits and the fact that they are made from renewable resources. Viscosity is the most significant property to affect the utilization of vegetable oil and its derivatives in the compression ignition engines. This paper presents the existing correlations for predicting the viscosity of vegetable oil and its derivatives for compression ignition engines. According to the parameter considered in the correlations, the empirical correlations can be divided into six groups: correlations as a function of temperature, of proportion, of composition, of temperature and composition, of temperature and proportion, and of fuel properties. Out of physical properties of fuel, there exist in the literature several parameters for giving the influence on kinematic viscosity such as density, specific gravity, the ratio of iodine value over the saponification value, higher heating value, flash point and pressure. The study for the verification of applicability of existing correlations to non-edible vegetable oil and its derivatives is required.

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A Studies on the Chemical Composition of Apricot Seed (살구씨의 화학적 조성에 관한 연구)

  • 이성민;임효진
    • The Korean Journal of Food And Nutrition
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    • v.5 no.1
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    • pp.1-6
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    • 1992
  • For the effective utilization of apricot seed resources of food protein and lipid, the general composition, amino acid composition and chemical characteristics were analysed. The skinned and non-skinned apricot seed contained 53.9% and 48.0% of crude lipid, 24.7% and 26.8% of crude protein, respectively. There were no significant difference in the amino acid composition among skinned and non-skinned apricot seed, The major amino acids were glutamic acid, aspartic acid, alanine, tyrosine and threonine, holding 14.6 to 16.9%, 12.4 to 13.7%, 9.2 to 12.1%, 7.2 to 7.5% and 7.0 to 7.2% of total amino acid content, respectively. The sum of these ammo acids occupied about 50% to total amino acids. While the quantities of methionine, histidine, and Lysine were poor content. The essential amino acids occupied about 30% to total amino acids. The acid, iodine and saponification value of apricot seed oil were 0.7 to 7.1, 80.8 to 107.5 and 182.7 to 208.4, respectively. These values were significant difference in skinned and non-skinned apricot seed.

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Studies on the Coumarins of the Root of Angelica gigas $N_{AKAI}$ (I) (참당귀근의 coumarin성분에 관한 연구(I))

  • 류경수;육창수
    • YAKHAK HOEJI
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    • v.11 no.3_4
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    • pp.22-26
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    • 1967
  • From the root of Angelica gigas $N_{AKAI}$ (Umbelliferae), known as "Tang Gui" in Korea, substance A (colorless needle crystal, $C_{14}H_{14}O_{4}$, m.p. $178^{\circ}$) and B (white plate crystal, $C_{19}H_{20}O_{5}$, m.p. $111^{\circ}$) were obtained. Acetylation of "A" gave its monoacetate, white needles, $C_{16}H_{16}O_{5}$. Saponification of "B" with 5% sodium hydroxide produced "A" and senecionic acid. Examination using I.R. and N.M.R. spectra shows that "A" is identical with decursinol and that "B" with decursin. The root also appears to contain five coumarin derivatives and two steroidal compounds.

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Strength and Autogenous Shrinkage of High Strength Mortar Using Water Substituting Liquid

  • Han, Min-Cheol;Lee, Dong-Gyu
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.6
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    • pp.538-546
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    • 2011
  • This paper is to experimentally investigate the strength and autogenous shrinkage of high strength mortar with the 20 % of water?binder ratio(W/B). In this study, the water substituting liquid(WSL) was used including gasoline, light oil, lamp oil, edible oil, HFE, ethanol, methanol and acetone in order to explore changes in strength and autogenous shrinkage depending on WSL type and replacement. For fresh properties, the replacement of WSL did not affect the fluidity of mortar mixtures considerably, except for ethanol and methanol. However, the replacement of WSL resulted in a slight decrease in flexural and compressive strength. For autogenous shrinkage, the replacement of WSL led to reduce autogenous shrinkage, and especially, the replacement of edible oil led to reduce autogenous shrinkage significantly due to saponification between edible oil and cement.

Effect of Molecular weight of Atactic Poly(vinyl alcohol) (PVA) on the Polarizing Efficiency of PVA/Azo Dye Polarizer (PVA/아조염료계 편광필름의 편광효율에 따른 혼성배열 폴리비닐알코올의 분자량 효과)

  • Park, Joo-Min;Kim, Sam-Soo;Lyoo, Won-Seok
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.104-107
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    • 2003
  • Poly(vinyl alcohol) (PVA) obtained by the saponification of poly(vinyl ester) like poly(vinyl acetate) o. poly(vinyl pivalate) is a linear semicrystalline polymer, which has been widely used as fibers for clothes and industries, films, membranes, medicines for drug delivery system, and cancer cell-killing embolic materials[1-3]. PVA fibers and films have high tensile and compressive strengths, high tensile modulus, and good abrasion resistance due to its highest crystalline lattice modulus. (omitted)

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Lipase-catalyzed Transeseterification of Corn Oil, Conjugated Linoleic Acid, and Capric Acid in Batch Type Reactor

  • Vu, Phuong-Lan;Shin, Jung-Ah;Lee, Ki-Teak
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 2003.10a
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    • pp.164.2-165
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    • 2003
  • Structured lipids (SLs) are defined as triacylglycerols to change the fatty acid composition in the glycerol backbone and lipases are known as a powerful tool for the syntheses of SLs. Structured lipid from corn oil, capric acid, and conjugated linoleic acid (CLA) by transesterification reaction and using several amounts of immobilized lipase RM IM (from Rhizomucor miehei) was studied, and 4% of lipase amount was selected for further study as the optimal amount. Comparison the chemical properties (free fatty acid value, iodine value, saponification value, tocopherols, and color analysis), solidification behavior, and volatile fractions (from headspace SPME GC-MS) between com oil and SL com oil was obtained.

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Effect of ERCO Coating on the Carbonation Resistance of High Volume Mineral Admixture Concrete (ERCO 도포가 혼화재 다량치환 콘크리트의 탄산화저항성에 미치는 영향)

  • Kim, Sangsup;Yun, Jeongwan;Kim, Minyoung;Choi, Youngdoo;Han, Mincheol;Han, Cheongoo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.05a
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    • pp.23-24
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    • 2015
  • As this study is an experiment for solving problem on the carbonation acceleration of high volume admixture concrete, the capillary pore getting filled up by saponification as cooking oil gets absorbed to the concrete surface in case of applying a cooking oil based coating agent to the concrete has been verified in the previous studies. Accordingly, this study has performed a comparative experiment on the cooking oil and the anticorrosive coating agent sold on the market while the result followed by this experiment has shown the fact of indicating similar carbonation penetration depth and porosity.

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