• 제목/요약/키워드: Sampling and analytical method

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PCM과 TEM을 이용한 서울지역 일부 공공 건축물의 실내공기 중 석면농도 조사 (An Investigation on the Airborne Asbestos Concentrations using PCM and TEM in the Public Buildings in Seoul)

  • 정숙녀;남은정;황순용;오석률;신진호;엄석원;채영주
    • 한국산업보건학회지
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    • 제21권3호
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    • pp.139-145
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    • 2011
  • Objectives: This investigation is purposed to evaluate the airborne asbestos concentrations in the public buildings having asbestos containing materials(ACMs) in Seoul. Methods: The Seoul Metropolitan Government carried out an asbestos survey to the city-owned public buildings to identify the level of risk exposure, classified into low, moderate and high risk. To evaluate the airborne concentration of asbestos, 11 sampling sites in ten buildings based on the survey were selected. The air samples from the eleven sites were analyzed by Phase Contrast Microscopy(PCM) and Transmission Electron Microscopy (TEM), and compared the analytical results from the both. Results: 1. The airborne fiber concentrations by PCM were less than the detection limit($7f/mm^2$) in 9(82%) out of 11 sampling sites. The highest concentration was 0.0043 f/cc, but it was below the guideline value for indoor air quality(0.01 f/cc), proposed by the Ministry of Environment, Korea. 2. In two sampling sites, having moderate risk level, the chrysotile was identified and showed it's concentrations of 0.0102 s/cc and 0.0058 s/cc, less than $5{\mu}m$ lengths. 3. The ACMs identified in the two sampling sites were a packing material(65% of chrysotile) in mechanical area and a thermal system insulation(5% of chrysotile) in a boiler room. Having more possibility of asbestos emission in the mechanical area, it would be required to set up and carry out the asbestos management plan. Conclusions: Based on the result of this study, the airborne asbestos concentrations in the public buildings with ACMs were generally lower than the guideline value for indoor air quality. There are widespread concerns about the possible health risk resulting from the presence of airborne asbestos fibers in the public buildings. Most of the previous studies about airborne asbestos analysis in Korea were performed based on PCM method that asbestos and non-asbestos fibers are counted together. In the public and commercial buildings, having ACMs, it is suggested that the asbestos be analyzed by TEM method to identify asbestos due to concerns about asbestos exposure to workers and unspecified people.

디스크타입 고상추출장치 및 컬럼커플링을 이용한 물시료의 PCDD/Fs 간이분석법 (Fast Analytical Method of PCDD/Fs in Water by Combination of Disk Type Solid Phase Extraction and Column Coupling Chromatography)

  • 최재원;문부식;김경심;김정희;김순흥;백경희
    • 한국물환경학회지
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    • 제22권5호
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    • pp.879-886
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    • 2006
  • The analytical methods of polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans (PCDD/Fs) for water sample with extremely low concentration was developed to extract large volume and to improve fast chromatography for clean up. Semi-automated solid phase extraction (SPE) system and column coupling chromatography using elution pump was optimized and applied to each processes of treatment plant. Results of disk type SPE indicated that this system was applicable below 40 L of aqueous sample with a flow rate of 0.08 ~ 0.2 L/min. Average recoveries of SPE using labeled sampling spike of $^{37}Cl$-2,3,7,8-TCDD was 97%. Column coupling method resulted in reduced clean up time, solvent volume, increased average recoveries with constant elution rate. The combined methods were applied to the monitoring of drinking water treatment plant. Limits of detection (LOD) of each process were calculated. For example, LOD of raw and treated water ranged 0.094~0.968 pg/L and 0.028~0.364 pg/L, respectively. Combined methods of extraction and cleanup techniques provided fast analysis of PCDD/Fs with high accuracy and low LODs for water samples.

중성자방사화분석에 의한 지하수중 우라늄의 정량 (Determination of Uranium in Groundwater by Instrumental Neutron Activation Analysis)

  • 정용삼;문종화;정영주;박광원
    • 대한지하수환경학회지
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    • 제5권4호
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    • pp.210-214
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    • 1998
  • 담수나 해수와 같은 자연수중의 우라늄(U)의 농도는 0.0l∼5 ppb 수준으로서 극미량 원소분석법을 필요로 한다. 본 연구는 고감도의 비파괴법인 중성자방사화분석법을 이용하여 지하수중의 우라늄을 신속, 정확하게 정량할 수 있는 방법에 대하여 시료를 증발농축 전처리하는 방법과 직접 분석하는 방법을 비교 검토하였다. 표준용액(0.5∼100 ppb)을 이용하여 분석법을 검증하였다. 주어진 농도범위에서 검정곡선의 평균편차는 2% 이하를 나타냈으며, 각 측정값의 상대표준편차는 2∼l2% 이내이었다. 동일시료에 대한 시기별 농도의 편차는 10.3%이었다 본 방법을 이용하여 충청지역의 17개 관정으로부터 지하수시료를 채취하여 우라늄 농도를 정량한 결과 1 ppb에서 80 ppb수준인 것으로 확인되었다.

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공기중 이소시아네이트류의 측정 및 분석방법에 관한 비교연구 (A Comparison of Sampling and Analytical Methods for Airborne Isocyanates)

  • 변혜정;윤충식;백남원
    • 한국환경보건학회지
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    • 제22권2호
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    • pp.32-42
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    • 1996
  • This study was performed to evaluate accuracy and precision of filter method and impinger method for analyzin airborne isocyanates in mixture (2, 6-TDI, HDI, 2, 4-TDI, MDI). Filter method was performed using the OSHA Method 42 and impinger method using the NIOSH Method 5521. The samples were analyzed by high performance liquid chromatography-ultraviolet detector (HPLC-UVD). After the optimum operating conditions for each method were investigated, samples with various concentration levels were quantified at the conditions. The precision was expressed by the pooled coefficient of variation(C.V.) and the accuracy by overall accuracy. The results are summarized as follows: 1. The optimum condition of filter method was determined at 35/65 ACN/buffer (0.01 M ammonium acetate) in mobile phase. And in case of impinger method, it was at 30/70 ACN/buffer(0.2 M sodium acetate). The effect of concentrations of acetate on the separation of the peaks was not significant, but, the effect of ACN/buffer ratio was significant. 2. The correlation coefficients for the two methods were above 0.9 in all isocyanate compounds. Average recovery efficiencies for 2, 6-TDI, HDI, 2, 4-TDI and MDI in filter method were 92.4%, 102.6%, 87.3% and 101.0%, respectively. Those in impinger method were 106.6%, 106.7%, 99.0% and 103.6%, respectively. As a result, the recovery efficiency of impinger method was higher than those of filter method in analyzing isocyanate compounds. 3. The pooled coefficients of variations of the methods were slightly higher than expected. The overall accuracies of the methods were within $\pm 25%$ for each isocyanate compound. Since these results satisfy NIOSH criteria, the accuracy of the experiment is appropriate. 4. As seen above, impinger method is more efficient than filter method. But, there are many disadvantages in impinger method. Therefore, solid sorbent such as a glass fiber filter must be developed in order to have the high efficiency not less than that of impinger method in the future.

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Identification and Categorization of Jul Designs and Patterns in the Sāsānian Period

  • Davood, SHADLOU;Amir, SHADLOU
    • Acta Via Serica
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    • 제7권2호
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    • pp.39-64
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    • 2022
  • Ancient Iranians highly esteemed the horse and horse tacks, one of which is the jul (saddlecloth). It is a felt, sheepskin, or woven pad placed between the horse's back and saddle. The aim of this paper is to identify and categorize jul designs in the Sāsānian period. The research questions are about the variety of jul designs and how to categorize them. This is fundamental research and the method is descriptive and analytical. Neither a jul nor a saddle-cover remains from the Sāsānian period, therefore the statistical population includes all available items, such as metal and stone items and parget and plasterworks, in which juls are recognizable. Due to the scarcity of such items, all the available samples were studied; so the sampling method is a total enumeration. This is documentary research by means of note-taking and using reliable websites; the data has been analyzed qualitatively. The results show that jul designs were not diverse in the Sāsānian period. All-over designs were dominant. In terms of pattern types, these designs are classified into five groups, each of which has its own formal and aesthetic characteristics: all-over design with a four-petal flower pattern, allover design with a checkered pattern, all-over design with a spotted pattern, allover design with a tiger stripe pattern, and all-over design with a zigzag pattern.

Antecedents of Career Development and Its Impact on Employee Performance: An Empirical Study in Indonesia

  • KUSNADI, Kusnadi;PRASETYO, Johan Hendri;MARKONAH, Markonah;ARIAWAN, Joko
    • The Journal of Asian Finance, Economics and Business
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    • 제9권9호
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    • pp.115-120
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    • 2022
  • This research aims to investigate the antecedents of career growth and its impact on employee performance. The research design is quantitative with a causal method. The sample used is 242 respondents working in different hospitals in Banten Province and were selected through the snowball sampling technique. The analytical method used to examine the research model is PLS-SEM. The analysis result shows that work environment and training have an impact on increasing career development and hospital employee performance. Career development can also directly be an antecedent in improving the performance of hospital employees, but only has a moderate effect in mediating the influence of work environment and training on the employees' performance in the hospital. Based on these findings, hospital management in Banten Province must create and maintain a comfortable working environment for employees, offer training specific to each employee's line of work to help them improve their abilities, and create a system for career planning that takes into account each employee's potential.

환경 중의 엔도톡신 노출 및 건강에 미치는 영향 (Exposure to Environmental Endotoxin and Health Effects)

  • 박주형
    • 한국환경보건학회지
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    • 제40권4호
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    • pp.265-278
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    • 2014
  • Microbes such as bacteria, fungi, archaea, protists, and viruses are ubiquitous and people are exposed to them continuously. Endotoxin is a component of the outer membrane of Gram-negative bacteria and a potent proinflammaotry substance. When a person is exposed to environmental endotoxin, an innate immune response is initiated upon the initial recognition and this response produces various inflammatory mediators and recruits inflammatory cells to the exposed tissues. A purified chemical form of endotoxin is called lipopolysaccharide (LPS), and the lipid A portion of the molecule is a biologically active moiety. Exposure to endotoxin may result in various complex health effects depending on time, route, and dose of exposure, as well as host susceptibility. Gene-environment interactions play important roles in health effects of endotoxin exposure, e.g. development or aggravation of asthma. To accurately assess exposure to endotoxin in environmental or epidemiologic studies, methods of sampling, extraction, and analysis must be carefully selected since the selected methods may substantially affect analytical results and there is no internationally-agreed standard method to date. The lack of a standardized method hampers the establishment of exposure-response relationships. While an internationally-agreed health-based exposure limit does not exist, the Dutch Expert Committee on Occupational Safety recently recommended $90EU/m^3$ as a health-based occupational exposure limit. The current article reviews various scientific issues on how we measure environmental endotoxin and the health effects of endotoxin exposure.

Development of Polymeric Water Absorbent Film(PWAF) for the Collection of Size-classified Fog Droplets

  • Ma, Chang-Jin;Mikilo-kasahara;Park, Kum-Chan
    • Journal of Korean Society for Atmospheric Environment
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    • 제17권E1호
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    • pp.17-24
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    • 2001
  • For the purpose of collecting fog droplets as a function of size a new sampling method was developed in this study. Formation of 100$\pm$10㎛ thickness of polymeric water absorbent film (PWAF) on a nuclepore filter could be successfully realized. Also applicability of particle induced X-ray emission (PIXE) method to the chemical analysis of size-segregated fog droplets collected on PWAF was examined experimentally with synthetic fog droplets generated from a nebulizer. Absorption capacity of S-PAAS polymeric water absorbent shows marked decreases in the range less than 1 wt% and slight decrease between 1 and 3.5 wt% of every salt concentration. Dependency of absorption capacity on pH shows the maximum at pH 7. No apparent peak which can influence the quantitative analysis of elements dissolved and suspended in fog droplets was found at PIXE spectrum of PWAF blank. PWAF kept the original shape without rupture under the PIXE analytical conditions of beam intensity for 10 to 60 nA and irradiation time of 4∼5 min. It should be said that the proposed new technique in the work is helpful to get more detailed information of fog droplets, to clarify the fog formation processes, and to develop a model of acid deposition process.

Corporate Governance and Environmental Performance: How They Affect Firm Value

  • WAHIDAHWATI, Wahidahwati;ARDINI, Lilis
    • The Journal of Asian Finance, Economics and Business
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    • 제8권2호
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    • pp.953-962
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    • 2021
  • This study aims to examine the effect of environmental performance and good corporate governance (GCG) on the firm values mediated by corporate social responsibility (CSR). The sample in this study was obtained using a purposive sampling method and collected from 205 companies. The analytical method used is moderating regression analysis. The results of this study indicate, first, that corporate social responsibility affects the value of the company. The results of this study indicate that the better corporate governance will increase the value of the firm and vice versa. Second, corporate social responsibility has a direct effect on the firm value, but the effect is still smaller when compared with the internal mechanisms of good corporate governance. This study also found that corporate social responsibility cannot mediate the effect of good corporate governance on firm value. Third, the company's environmental performance influences the company's value. Finally, the effect of environmental performance on company value will be better if mediated by corporate social responsibility. This result shows that environmental performance is a proof that the company's environmental and social concern, which is manifested in corporate social responsibility, will be responded positively by the market so that it will increase share prices (firm value).

달성광산지역 토양의 중금속함량 분석결과의 평가 (Evaluation of Analytical Results of Heavy Metal Concentrations in Soils from the Dalsung Mine Area, Korea)

  • 김경웅
    • 대한지하수환경학회지
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    • 제4권1호
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    • pp.20-26
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    • 1997
  • 광산활동이 주변지역 토양중의 중금속함량에 미치는 영향을 조사하기 위하여 국내 달성 동-중석 광산지역을 중심으로 지화학적 조사를 수행하여 표토와 심토시료를 채취하였다. 토양의 오염정도를 조사하는 것외에도 여러 토양분석방법의 비교와 국내토양환경기준의 문제점을 알아보기 위하여 0.1 N 염산, 질산-과염소산과 왕수를 이용하여 토양분석을 위한 용액을 준비한 후 원자흡광분석법으로 Cd, Cu, Pb와 Zn을 분석하였다. 또한 토양내 중금속의 존재형태를 파악하기 위하여 연속추출법을 수행하였다. 질산-과염소산을 이용한 분석법에 의하면 달성광산 주변지역의 토양에 최고 28 $\mu\textrm{g}$/g Cd, 5000 $\mu\textrm{g}$/g Cu, 2390 $\mu\textrm{g}$/g Pb와 930 $\mu\textrm{g}$/g Zn이 존재하였으며, 허용한계치로부터 계산되어진 표토와 심토의 오염지수가 환경문제를 야기할수 있을 정도로 높게 나타났다. 그러나 국내 환경오염 공정시험법상의 0.1 N 염산을 이용한 결과는 토양환경보전법령상의 토양오염우려기준보다 낮게 나타나 국내 토양관련 법규 및 분석법에 대한 재고가 필요한 실정이다. 연속추출법 결과 토양내 총 Cu, Pb와 Zn함량은 질산-과염소산 및 왕수를 이용한 분석결과에 의해 설명되어지며, 이온교환형태로 존재하는 양은 0.1 N 염산을 이용한 결과로 나타낼 수 있다.

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