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Synthesis and Characterization of La0.75Sr0.25FeO3 Used as Cathode Materials for Solid Oxide Fuel Cell by GNP Method (GNP법을 이용한 고체산화물 연료전지의 공기극용 La0.75Sr0.25FeO3의 제조 및 특성)

  • Park, Ju-Hyun;Son, Hui-Jeong;Lim, Tak-Hyoung;Lee, Seung-Bok;Yun, Ki-Seok;Yoon, Soon-Gil;Shin, Dong-Ryul;Song, Rak-Hyun
    • Journal of the Korean Electrochemical Society
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    • v.10 no.1
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    • pp.7-13
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    • 2007
  • We synthesized and investigated $La_{0.75}Sr_{0.25}FeO_3$ by Glycine Nitrate Process(GNP) method used as cathode materials for SOFC(solid oxide fuel cell). Optimized amount of glycine is 3.17 mol. ICP elemental composition analysis indicated that the stoichiometry of the synthesized powders have nearly nominal values. SEM images and XRD patterns reveal that the synthesized powder has uniform size distribution and high degree of crystallinity. The sample powders were isostatically pressed to form a pellet. The green body was sintered at $1200^{\circ}C$ and the relative density of the sintered specimens were measured by Archimedes mettled. We measured electrochemical performance of LSF by AC impedance spectroscopy. Resistance of LSF shows lower value than that of LSM throughout all temperature region. The anode-supported solid oxide fuel cell showed a performance of $342mW/cm^2(0.7V,\;488mA/cm^2)$ at $750^{\circ}C$. The electrochemical characteristics of the single cell were examined by at impedance method.

KMTNET SUPERNOVA PROGRAM VARIABLE OBJECTS I. NGC 2784 FIELD

  • HE, MATTHIAS YANG;MOON, DAE-SIK;NEILSON, HILDING;LEE, JAE-JOON;KIM, SANG CHUL;PAK, MINA;PARK, HONG SOO;KIM, DONG-JIN;LEE, YONGSEOK;KIM, SEUNG-LEE;LEE, CHUNG-UK
    • Journal of The Korean Astronomical Society
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    • v.49 no.5
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    • pp.209-223
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    • 2016
  • We present analyses of ~1250 variable sources identified in a 20 square degree field toward NGC 2784 by the KMTNet Supernova Program. We categorize the variable sources into three groups based on their B-band variability. The first group consists of 31 high variability sources with their B-band RMS variability greater than 0.3 magnitudes. The second group of medium variability contains 265 sources with RMS variability between 0.05 and 0.3 magnitudes. The remaining 951 sources belong to the third group of low variability with an RMS variability smaller than 0.05 magnitudes. Of the entire ~1250 sources, 4 clearly show periods of variability greater than 100 days, while the rest have periods shorter than ~51 days or no reliable periods. The majority of the sources show either rather irregular variability or short periods faster than 2 days. Most of the sources with reliable period determination between 2 and 51 days belong to the low-variability group, although a few belong to the medium-variability group. All the variable sources with periods longer than 35 days appear to be very red with B - V > 1.5 and V - I > 2.1 magnitudes. We classify candidates of 51 Cepheids, 17 semi-regular variables, 3 Mira types, 2 RV(B) Tauri stars, 26 eclipsing binary systems and 1 active galactic nucleus. The majority of long-term variables in our sample belong to either Mira or semi-regular types, indicating that long-term variability may be more prominent in post-main sequence phases of late-type stars. The depth of the eclipsing dips of the 26 candidates for eclipsing binaries is equivalent to ~0.61 as the average relative size of the two stars in the binary system. Our results illustrate the power of the KMTNet Supernova Program for future studies of variable objects.

Quality Characteristics of Jeungpyun with Brown Rice and Barley Flour (현미와 보리 가루를 첨가한 증편의 품질특성)

  • Park, Mie-Ja
    • Korean journal of food and cookery science
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    • v.23 no.5
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    • pp.720-730
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    • 2007
  • This study was investigated (replaced) the sensory and physicochemical properties of Jeungpyun substituted with 30% or 60% of brown rice and barley flours, respectively. The quality changes of the functional Jeougpyun during the storage periods were analyzed by a texturometer. We found that batter pH was decreased as fermentation progressed, but showed a higher pH resulted after steaming. The brown rice replaced Jeungpyun had higher specific gravity and lower viscosity; however, the barley-replaced Jeungpyun had lower specific gravity and higher viscosity compared to those of the control(0% replace with brown rice or barley flour). The barley-replaced samples showed significantly larger volume indexes than that of the control. The L-value of the for lightness decreased significantly within the replaced samples(p<0.001). All samples had negative a-values, with slight peen colors rather than red. The barley-replaced samples were darker than those of the brown rice sample groups, with less green and yellow color. The brown rice-replaced samples had larger values for adhesiveness, overall, and moistness, and the barley-replaced samples showed intensities greater in cell size, springiness, hardness, and flavor by sensory evaluation. The 30% flour-replaced samples of the comparisons had higher values for overall desirability(p<0.001). The replaced samples showed slow increases in hardness when measured by a texturometer, indicating that, the retrogradation rates decreased as the storage periods increased. The control stored for 72 hr had a hardness value that was 8.0 times harder than that of the control stored for one hour. The 30 and 60% brown rice-replaced samples stored for 72 hr were 5.8 times and 4.7 times harder of their replacement level, respectively, and the 30 and 60% barley-replaced samples stored for 72 hr were 5.7 times and 4.2 times harder of their replacement level, respectively. The adhesiveness and cohesiveness of all samples tended to decrease as the storage period increased. The barley-replaced samples showed significantly the lower adhesiveness and cohesiveness during the storage periods. The springiness of all samples decreased slowly during the storage periods. In conclusion, Jeungpyun that was substituted with brown rice and barley flours demonstrated improved functionality and higher dietary fiber replaced effect. Furthermore, the storage period of was extended as the retrogradation rate was delayed as a result of the dietary fibers.

Effects of Metal Ions Mole Ratio, pH and Heat Treatment Condition on the Magnetic Properties and Formation of Co-precipitated M-type Barium Ferrite Powders (공침법으로 합성한 바륨 페라이트(BaM)의 형성과 자기적 성질에 미치는 금속이온 몰 비 및 pH와 열처리 조건의 영향)

  • Baek, In-Seung;Nam, In-Tak
    • Journal of the Korean Magnetics Society
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    • v.19 no.6
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    • pp.209-215
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    • 2009
  • M-type barium ferrite (BaFe12O19) powders were synthesized through the co-precipitation method. Starting material composition $Fe^{3+}:\;Ba^{2+}$ mole ratio was fixed as 8 and the relative amount of $Fe^{3+}$ and $Ba^{2+}$ was controlled. Structure and magnetic properties and powder morphology were investigated using XRD, SEM, VSM. Powder showing high coercivity and small magnetization was obtained at pH8 and $Fe_{3+}:\;Ba_{2+}$ of 12 : 1.5. Small magnetization value was originated from the existence of ${\alpha}-Fe_2O_3$. Single-phase Mtype barium ferrite were obtained regardless of the heat treatment condition and the amount of $Fe_{3+}\;and\;Ba_{2+}$ at pH$\approx$10. The largest value of magnetization (55.7 emu/g) under investigation were obtained when $Fe_{3+}:\;Ba_{2+}$ of 13.6 : 1.7 and furnace cooled powder in $O_2$. Particle size of powder was in the range of 50~200 nm.

Pie-establishment of Microwave-Assisted Extraction Conditions for Antioxidative Extracts from Cabbage (양배추의 항산화성 추출물 제조를 위한 마이크로웨브 추출조건 설정)

  • Noh Jungeun;Choi You-Kyoung;Kim Hyun-Ku;Kwon Joong-Ho
    • Food Science and Preservation
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    • v.12 no.1
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    • pp.62-67
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    • 2005
  • Microwave-assisted extraction (50 W, 2,450 MHz, MAE) with properties of selective heating and subsequent extraction for certain phytochemicals from natural materials was applied to pre-establish the extraction conditions for total yield total phenolics, and electron donating ability (EDA) from Brossica oleacea. The experiments with $50\%$ EtOH solvent showed that 20 mesh in particle size of cabbage flake $(moisture\;4.5\%)$ and 1:10 (g/mL) in the sample to solvent ratio for both raw $(moisture\;90.2\%)$ and flake cabbages were optimal for MAE efficiency. Under these conditions, total yield increased with extraction tim, which was highest for raw cabbage extract in $50\%\;EtOH$ solvent followed by $100\%\;EtOH$ and water. While that of flake cabbage extracts was highest in $50\%\;EtOH$ followed by water and $100\%\;EtOH$. The contents of total phenolics and EDA in extracts gradually increased after 3 min of MAE, which were highest when using $100\%\;EtOH$ solvent followed by $50\%\;EtOH$ and water in raw cabbage and $50\%\;EtOH$ followed by water and $100\%\;EtOH$ in flake cabbage, respectively.

Prevalence of Nosema and Virus in Honey Bee (Apis mellifera L.) Colonies on Flowering Period of Acacia in Korea

  • Hong, In-Pyo;Woo, Soon-Ok;Choi, Yong-Soo;Han, Sang-Mi;Kim, Nam-Suk;Kim, Hye-Kyung;Han, Sang-Hoon;Lee, Man-Young;Lee, Myeong-Lyeol;Byeon, Kyu-Ho
    • Mycobiology
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    • v.39 no.4
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    • pp.317-320
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    • 2011
  • Honey production from approximately 1.6 million colonies owned by about 199,000 Korean beekeepers was almost 23,000 metric tons in 2009. Nosema causes significant losses in honey production and the virus decreases population size. We initiated a survey of honey bee colonies on the blooming period of Acacia to determine the prevalence of Nosema and virus in 2011. Most Korean beekeepers have moved from the south to north of Korea to get Acacia nectar for 2 mon. This provided a valuable opportunity to sample bees originating from diverse areas in one location. Twenty hives owned by 18 beekeepers were sampled in this year. Nosema spore counts ranged from zero to 1,710,000 spores per bee. The average number of nosema spores per bee was 580,000. Approximately 95% of the colonies were infected with Nosema, based on the presence of spores in the flowering period of Acacia. This indicates that Nosema is the predominant species affecting honeybee colonies. Also, the seven most important honeybee viruses were investigated by reverse transcription-PCR. Among them, four different viruses were detected in samples. Black queen cell virus was present in all samples. Chronic bee paralysis virus was detected in 10% of samples. Deformed wing virus was present in only 5% of the samples. Prevalence of Sacbrood virus was 15%. However, Cloudy wing virus, Israel acute paralysis virus and kashmir bee virus were not detected in any of samples.

Assessment of Aging Effects on Computed Tomographic Glomerular Filtration Rate in Dogs (개에서 연령에 따른 동적 컴퓨터단층촬영을 이용한 사구체여과율의 평가)

  • Chang, Jin-Hwa;Kim, Hwan-Cheol;Choi, Ji-Young;Choi, Ho-Jung;Lee, Hee-Chun;Chang, Dong-Woo;Lee, Young-Won
    • Journal of Veterinary Clinics
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    • v.29 no.2
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    • pp.130-133
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    • 2012
  • The purpose of this study is to assess the relationship between glomerular filtration rate (GFR) and age by using dynamic computed tomography (CT) and Patlak plot analysis in dogs. Fifteen dogs were used in this study. CT-GFR study was performed under general anesthesia using propofol and isoflurane. 1 ml/kg dosage of 300 mgI/ml iohexol was administered at a rate of 3 ml/s during GFR measurement. CT-GFR was determined with a single-slice dynamic acquisition and Patlak plot analysis. The individual and global GFR values were calculated to plasma clearance per body weight (ml/min/kg). Bodyweight ($mean{\pm}SD$) ranged from 2.0 to 5.7 kg ($3.31{\pm}1.13$ kg). Age ranged from 3 years to 13 years old ($7.14{\pm}3.30$). $Mean{\pm}SD$ creatinine ($0.53{\pm}0.34 $mg/dl), phosphorus ($4.1{\pm}1.2$ mg/dL), and albumin ($3.3{\pm}0.3$ mg/dL) concentrations and urine protein-to-creatinine ratios (all ratios were < 0.5) were within reference ranges. Abdominal ultrasonography revealed small-sized renal calculi, mineralization, or renal cyst at eight dogs. The global CT-GFR ranges shown in this study was 2.57 to 6.60 ml/min/kg. In this study, there was no trend toward weight-adjusted CT-GFR with increasing age. We found no relationships between age-related kidney dysfunction in fifteen dogs. Small-sized renal calculi or cysts did not affect renal function in this study. However, it is thought that a large sample size may have been required to document an age effect.

Effect of Chemical Composition of Nut Material on the Fracture Behavior in Nut Projection Welding of Hot-Stamped Steel Sheet (핫스탬핑강의 너트 프로젝션 용접시 너트 재질이 용접부 파단모드 변화에 미치는 영향)

  • Lim, Sung-Sang;Kim, Young-Tae;Chun, Eun-Joon;Nam, Ki-Sung;Park, Young-Wan;Kim, Jae-Wan;Lee, Sun-Young;Choi, Il-dong;Park, Yeong-Do
    • Journal of Welding and Joining
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    • v.34 no.2
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    • pp.1-10
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    • 2016
  • The use of materials for modern lightweight auto-bodies is becoming more complex than hitherto assemblies. The high strength materials nowadays frequently used for more specific fields such as the front and rear sub frames, seat belts and seats are mounted to the assembled body structure using bolt joints. It is desirable to use nuts attached to the assembled sheets by projection welding to decrease the number of loose parts which improves the quality. In this study, nut projection welding was carried out between a nut of both boron steel and carbon steel and ultra-high strength hot-stamped steel sheets. Then, the joints were characterized by optical and scanning electron microscope. The mechanical properties of the joints were evaluated by microhardness measurements and pullout tests. An indigenously designed sample fixture set-up was used for the pull-out tests to induce a tensile load in the weld. The fractography analysis revealed the dominant interfacial fracture between boron steel nut weld which is related to the shrinkage cavity and small size fusion zone. A non-interfacial fracture was observed in carbon steel nut weld, the lower hardness of HAZ caused the initiation of failure and allowed the pull-out failure which have higher in tensile strengths and superior weldability. Hence, the fracture load and failure mode characteristics can be considered as an indication of the weldability of materials in nut projection welding.

The role of grain boundary modifier in $BaTiO_3$ system for PTCR device ($BaTiO_3$계 PTC 재료에서 입계 modifier의 역할)

  • Lee, Jun-Hyeong;Jo, Sang-Hui
    • Korean Journal of Materials Research
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    • v.3 no.5
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    • pp.553-561
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    • 1993
  • In this study, thr effect of $Bi_2O_3$ and BN addition as grain boundary modifiers on sintering and electrical properties of semiconducting PTCR(Positive Temperature Coefficient of Resistivity) mate rial were analyzed using TMA, XRD and Complex Impedance Spectroscopy method. Bismut.h Ox~de and Boron Nitride were added to Y-doped $BaTiO_3$ respectively. Bismuth sesquioxide up to O.lmol%solubil~ ty limit of $Bi_2O_3$ in Y--$BaTiO_3$ ceramics-retarded densification and grain growth, and further addition mitigated these retardation effects. The resistivity at room temperature increased with increasing amount of $Bi_2O_3$ and thus decreased the PTCR effect, probably due to the $Bi_2O_3$ segregation on the grain boundaries. From the complex ~mpedance pattern, it is known that the grain boundary resisitivity is dominant on the whole resistivity of sample. In the result of applying the defect chemistry, $Bi^{3+} \;and \; Bi^[5+}$ are substituted for Ua and Ti site, respectively. Boron nitride decomposed and formed liquid phase among the $BaTiO_3$ grains. The decomposed com~ ponents made the second phase and existed the tr~ple juntion from the result of EPMA. From the complex impendencc pattern, the gram and grain boundary resistivity were small. The grain size increased with increasing BN contents, and decreased grain boundary resistivity enhanced the PTCR effect.

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Novel influenza A (H1N1) 2009 infection in the pediatric patients with hematologic and oncologic diseases in the Yeungnam region in Korea

  • Kang, Seok-Jeong;Lee, Jae-Min;Hah, Jeong-Ok;Shim, Ye-Jee;Lee, Kun-Soo;Shin, Hyun-Jung;Kim, Heung-Sik;Choi, Eun-Jin;Jeon, So-Eun;Lim, Young-Tak;Park, Ji-Kyeong;Park, Eun-Sil
    • Clinical and Experimental Pediatrics
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    • v.54 no.3
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    • pp.117-122
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    • 2011
  • Purpose: Natural history and consequences of the novel 2009 influenza A H1N1(2009 H1N1) infection in immunocompromised pediatric patients are not yet fully understood. In this study, we investigated the clinical features and outcomes of the 2009 H1N1 infection in pediatric patients with hematological and oncological diseases. Methods: We retrospectively reviewed the medical records of 528 patients who had hematological and oncological diseases and who were treated at 7 referral centers located in the Yeungnam region. Among the 528 patients, 27 with definite diagnosis of 2009 H1N1 infection were the subjects of this study. All patients were divided into the following 3 groups: patients who were receiving chemotherapy (group 1), patients who were immunosuppressed due to a nonmalignant hematological disease (group 2), and patients who were off chemotherapy and had undergone their last chemotherapy course within 2 years from the influenza A pandemic (group 3). Results: All 28 episodes of 2009 H1N1 infection were treated with the antiviral agent oseltamivir ($Tamiflu^{(R)}$), and 20 episodes were treated after hospitalization. Group 1 patients had higher frequencies of lower respiratory tract infection and longer durations of fever and hospitalization as compared to those in group 2. Ultimately, all episodes resolved completely with no complications. Conclusion: These results suggest that early antiviral therapy did not influence the morbidity or mortality of pediatric patients with hematological and oncological diseases in the Yeungnam region of Korea after the 2009 H1N1 infection. However, no definite conclusions can be drawn because of the small sample size.