• Title/Summary/Keyword: Salt transport

검색결과 160건 처리시간 0.022초

여름철 남해의 저염화와 수송양 (Salinity Decrease and the Transport in the South Sea of Korea in Summer)

  • 조양기;김구;노홍길
    • 한국해안해양공학회지
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    • 제7권1호
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    • pp.126-134
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    • 1995
  • 국립수산진흥원이 관측한 염분자료를 분석하여 여름철 남해의 저염화 현상을 규명하였다. 6월과 8월에 남해 전 수심의 저염화는 강수량과 강물의 유입으로는 설명될 수 없고, 주위 해역 중 유일하게 저염수가 존재하는 제주해협 서편 해역 저염수의 유입으로만 설명이 가능하다. 염보존 Box 모델의 결과에 의하면, 대한해협 서수도의 수송량을 1.4-2.0$\times$$10^{6}$ ㎥/sec이라고 할 때, 이 수송량의 31-36% 정도인 0.5-0.6$\times$$10^{6}$ ㎥/sec(평균유속은 10-13cm/sec)의 수송량이 제주해협을 경유하여 남해로 유입되고, 나머지는 제주도와 대마도 사이로 유입된다.

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리튬 p-[메톡시 올리고(에틸렌옥시)]벤젠설폰산염으로 제조된 젤형 고분자 전해질의 리튬 이온 운반 특성 (Lithium ion Transport Characteristics of Gel-Type Polymer Electrolytes Containing Lithium p-[Methoxyoligo(ethyleneoxy)] benzenesulfonates)

  • 허윤정;강영구;한규승;이창진
    • 폴리머
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    • 제27권4호
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    • pp.385-391
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    • 2003
  • 본 연구에서는 에틸렌 옥사이드의 반복 단위 길이 (n=3, 7.3, 11.8, 그리고 16.3)가 다른 리튬 p-[메톡시 올리고(에틸렌옥시)]벤젠설폰산염 (LiEOnBS)을 합성하였다. 이 전해질 염을 이용하여 고분자 전해질을 제조하였으며, 에틸렌 옥사이드의 반복 단위 길이 및 농도에 따른 이온 전도도 그리고 리튬 이온의 운반율에 대해 조사하였다. 고분자 전해질의 이온 전도도는 3$0^{\circ}C$에서 4.89$\times$$10^{-4}$ S/cm (LiEO7.3BS, 0.5 M)로 최고 이온 전도도를 보였다. Dc분극과 ac 임피던스를 혼합하여 측정한 고분자 전해질의 리튬 이온의 운반율은 0.75~0.92 이였으며, 농도가 증가할수록 리튬 이온 운반율은 감소하였다. LiEO7.3BS의 전해질 염을 0.1 M로 사용한 고분자 전해질인 경우 0.92로 최고의 리튬 이온 운반율을 보였다. 이로부터 벤젠설포네이트에 치환된 에틸렌 옥사이드의 반복 단위가 3이상만 되어도 높은 리튬 이온 운반율을 가지는 단일 이온 전해질 특성을 보임을 알 수 있었다.

A computer simulation of ion exchange membrane electrodialysis for concentration of seawater

  • Tanaka, Yoshinobu
    • Membrane and Water Treatment
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    • 제1권1호
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    • pp.13-37
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    • 2010
  • The performance of an electrodialyzer for concentrating seawater is predicted by means of a computer simulation, which includes the following five steps; Step 1 mass transport; Step 2 current density distribution; Step 3 cell voltage; Step 4 NaCl concentration in a concentrated solution and energy consumption; Step 5 limiting current density. The program is developed on the basis of the following assumption; (1) Solution leakage and electric current leakage in an electrodialyzer are negligible. (2) Direct current electric resistance of a membrane includes the electric resistance of a boundary layer formed on the desalting surface of the membrane due to concentration polarization. (3) Frequency distribution of solution velocity ratio in desalting cells is equated by the normal distribution. (4) Current density i at x distant from the inlets of desalting cells is approximated by the quadratic equation. (5) Voltage difference between the electrodes at the entrance of desalting cells is equal to the value at the exits. (6) Limiting current density of an electrodialyzer is defined as average current density applied to an electrodialyzer when current density reaches the limit of an ion exchange membrane at the outlet of a desalting cell in which linear velocity and electrolyte concentration are the least. (7) Concentrated solutions are extracted from concentrating cells to the outside of the process. The validity of the computer simulation model is demonstrated by comparing the computed results with the performance of electrodialyzers operating in salt-manufacturing plants. The model makes it possible to discuss optimum specifications and operating conditions of a practical-scale electrodialyzer.

AMBIDEXTER 원자력 복합체 - 신뢰성 있는 미래 원자력에너지 이용 방안 (AMBIDEBTER Nuclear Complex - A Credible Option for Future Nuclear Energy Applications)

  • 오세기;정근모
    • 한국에너지공학회:학술대회논문집
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    • 한국에너지공학회 1998년도 춘계 학술발표회 논문집
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    • pp.235-242
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    • 1998
  • Aiming at one of decisive alternatives for long term aspect of nuclear power concerns, an integral and closed nuclear system, AMBIDEXTER (Advanced Molten-salt Break-even Inherently-safe Dual-mission Experimental and TEst Reactor) concept is under development. The AMBIDEXTER complex essentially comprises two mutually independent loops of the radiation/material transport and the heat/energy conversion, centered at the integrated reactor assembly, which enables one to utilize maximum benefits of nuclear energy under minimum risks of nuclear radiation. And it provides precious radioisotopes and radiation sources from its waste stream. Also the reactor operates at very low level of fission products inventory throughout its lifetime. The nuclear and thermalhydraulic characteristics of the molten TH/$^{233}$ U fuel salt extend the capability of the self-sustaining AMBIDEXTER fuel cycle to enhance resource security and safeguard transparency. The reactor system is consisted of a single component module of the core, heat exchangers and recirculation pumps with neither pipe connections nor active valves in between, which will significantly improve inherent features of nuclear safety. States of the core technologies associated with designing and developing the AMBIDEXTER concept are mostly available in commercialized form and thus demonstration of integral aspects of the concept should be the prime area in future R&D programs.

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구기자 성분의 혈당강하작용 (Anti-diabetic Activity of Constituents of Lycii Fructus)

  • 김경순;심상희;정기화;정춘식;고광호;박정일;허훈;이봉진;김박광
    • Biomolecules & Therapeutics
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    • 제6권4호
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    • pp.378-382
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    • 1998
  • In the previous screening on antidiabetic effect of Lycii fructus by glucose transport method using $N_2$-STZ diabeted rat model, each extracts showed the potent antidiabetic activity. We obtained three compounds isolated from the water fraction, EtOAc fraction and n-BuOH fraction of Lycii fructus in the present work and their structures were identified as 1-carboxy-N,N,N-trimethylmethanaminium hydroxide inner salt, 2,4(1H,3H)-pyrimidinedione and 3,3',4',5,7-pentahydroxyflavone-3-rutinoside . Among the constituents separated from Lycii fructus, 2,4(IH,3H)-pyrimidinedione, 3,3',4',5,7-pentahydroxyflavone-3-rutinoside and ascorbic acid were shown a remarkable antidiabetic effect.

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Attachment Behavior of Fission Products to Solution Aerosol

  • Takamiya, Koichi;Tanaka, Toru;Nitta, Shinnosuke;Itosu, Satoshi;Sekimoto, Shun;Oki, Yuichi;Ohtsuki, Tsutomu
    • Journal of Radiation Protection and Research
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    • 제41권4호
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    • pp.350-353
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    • 2016
  • Background: Various characteristics such as size distribution, chemical component and radio-activity have been analyzed for radioactive aerosols released from Fukushima Daiichi Nuclear Power Plant. Measured results for radioactive aerosols suggest that the potential transport medium for radioactive cesium was non-sea-salt sulfate. This result indicates that cesium isotopes would preferentially attach with sulfate compounds. In the present work the attachment behavior of fission products to aqueous solution aerosols of sodium salts has been studied using a generation system of solution aerosols and spontaneous fission source of $^{248}Cm$. Materials and Methods: Attachment ratios of fission products to the solution aerosols were compared among the aerosols generated by different solutions of sodium salt. Results and Discussion: A significant difference according as a solute of solution aerosols was found in the attachment behavior. Conclusion: The present results suggest the existence of chemical effects in the attachment behavior of fission products to solution aerosols.

Changes of Organic Solutes and Antioxidative Enzyme Activity in Rice Seedling under Salt Stress

  • Park So-Hyeon;Sung Jwa-Kyung;Lee Su-Yeon;Lee Ju-Young;Jang Byoung-Choon;Song Beom-Heom;Kim Tae-Wan
    • 한국작물학회지
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    • 제50권5호
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    • pp.325-331
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    • 2005
  • Seedlings of two rice genotyopes, cvs. Ilpumbyeo and Gancheokbyeo, were exposed to 0, 50 and 100 mM NaCl in nutrient solution for nine days. Plants were collected at the interval of 3 days and organic and inorganic solutes in leaves and roots and antioxidative enzyme activity in leaves were determined. Under salinity, the accumulation of soluble sugars occurred considerably in the older leaves of stressed seedlings compared to younger leaves and roots. The endogenous Na+ contents markedly increased at higher NaCl concentration in leaves and roots of seedlings, though it was higher accumulated in roots. Salinity resulted in an excessive proline accumulation in the stressed plants. A more pronounced increase was observed in Gancheokbyeo leaves. SOD activity in Impumbyeo cannot found any remarkable change, whereas, in Gancheokbyeo, its activity was rapidly decreased. CAT and POD activities increased with an increase in NaCl concentration in both genotypes. In sum­mary, the high capacity of rice seedlings to overcome an unfavorable growth condition such salt stress appears to be related to an adequate partition of organic solutes between shoots and roots and to changes in absorption, transport and re-translocation of salts.

Interpretation of the Chemical Transformation of Individual Asian Dust Particles Collected on the Western Coast of Korean Peninsula

  • Ma, Chang-Jin;Kim, Jong-Ho;Kim, Ki-Hyun
    • Asian Journal of Atmospheric Environment
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    • 제6권1호
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    • pp.14-22
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    • 2012
  • This paper is focused on the comprehensive and detailed interpretation for the chemical transformation of individual Asian dust (hereafter called "AD") particles during long-range transport from source regions to receptor area. A multi-stage particle sampler was operated at a ground-based site in Taean, Korea directly exposed to the outflow of air masses from China during AD period in April 2003. Both quantitative and qualitative analyses for size-classified individual particles were carried out by a microbeam X-ray fluorescence (XRF) method and a microbeam Particle Induced X-ray Emission (micro-PIXE), respectively. Among major characteristic elements, the elemental masses of soil derived components, sulfur, and chloride varied as a function of particle size showing the monomodal maximum with a steeply increasing at 3.3-4.7 ${\mu}m$ particle size. Although the details on chemical composition of AD particle collected on a straight line from source area to our ground-based site are needed, a large amount of Cl coexisted in and/or on AD particles suggests that AD particles collected in the present study might be actively engaged in chemical transformation by sea-salt and other Cl containing pollutants emitted from the China's domestic sources. Through the statistical analyses it was possible to classify individual AD particles into six distinct groups. The internally mixed AD particles with Cl, which has various sources (e.g., sea-salt, coal combustion origin HCl, gaseous HCl derived from the adsorption of acids to sea-salt, and Cl containing man-made particles) were thoroughly fractionated by the elemental spectra drivened by the double detector system of micro-PIXE.

리튬전지용 에테르가 기능화된 이온성 액체 기반 이온성 액정 전해질의 전기화학적 특성 (Ionic Liquid Crystal Electrolytes based on Ether Functionalized Ionic Liquid for Lithium Batteries)

  • 김일진;김기수;이진홍
    • 공업화학
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    • 제31권3호
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    • pp.305-309
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    • 2020
  • 본 연구에서는 에테르가 기능화된 이온성 액체인 [DMIm][MPEGP] (1,3-dimethylimidazolium (2-methoxy(2-ethoxy(2-ethoxy)))-ethylphosphite)와 리튬염인 LiTf2N (lithium bis(trifluoromethanesulfonyl)imide)을 혼합하였고, 리튬염의 함량을 조절하여 전해질을 특성을 조사하였다. 제조된 전해질은 리튬염 혼합에 따라 불투명해지고 흐름성이 제한된 열방성 액정을 형성하였으며, 이때 리튬염의 함량에 따라 형성되는 이온성 액정의 자기조립구조와 이온 전도 현상을 다양한 분광학적 분석을 통해 조사하였다. 그 결과 이온성 액정의 향상된 이온전도도는 정렬된 구조를 통한 이온 전도 특성과 관계가 있음을 확인하였으며, 리튬이온전지 특성 평가에서 우수한 전기화학적 특성을 나타냄을 확인하였다.

배추 염 저항성 관련 유전자의 네트워크 모델 구축 (Construction of a Network Model to Reveal Genes Related to Salt Tolerance in Chinese Cabbage)

  • 이기호;유재경;박지현;박영두
    • 원예과학기술지
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    • 제32권5호
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    • pp.684-693
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    • 2014
  • 저온, 건조, 염과 같은 비생물적 스트레스는 식물의 생리적 형태적 변화와 수확량 감소를 초래한다. 이러한 이유로 식물체는 불리한 환경을 극복하기 위해 다양한 대사과정에 관련된 유전자들간의 복잡한 상호 관계를 조절함으로써 저항성을 획득한다. 본 연구는 배추에서 염 스트레스에 반응하는 유전자를 다각적으로 분석하기 위해 상호발현 네트워크를 구축하였다. 네트워크를 구축하기 위하여 배추를 염스트레스 조건 하에서 시간 경과에 따라 KBGP-24K 마이크로어레이 분석을 실시한 [BrEMD (Brassica rapa EST and Microarray Database)] 실험 결과를 수집하여 분석하였다. 구축된 네트워크 모델은 1,853개 node, 5,740개 edge, 및 142개 connected component(상관계수 > 0.85)로 구성되었다. 구축된 네트워크 분석 결과, ROS 신호 전달을 통한 N$Na^+$ 수송활성화와 proline 축적이 배추의 염 저항성 획득과 밀접한 연관이 있는 것으로 판단하였다.