• 제목/요약/키워드: Salt transport

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한국 부안 지역 해안 대수층 내의 지하수 유동 및 염분 이동에 대한 단층 존재의 영향 삼차원 수치 모의 (Three-Dimensional Numerical Simulation of Impacts of Fault Existence on Groundwater Flow and Salt Transport in a Coastal Aquifer, Buan, Korea)

  • 박주현;김중휘;김한태;김준모
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제13권5호
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    • pp.33-46
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    • 2008
  • 해안 대수층 내의 밀도 의존적 지하수 유동 및 염분 이동에 대한 단층 존재의 영향을 효과적으로 모사하고 정량적으로 평가하기 위하여 하나의 범용 다차원 수리동역학적 분산 수치 모델을 이용한 일련의 삼차원 수치 모델링이 수행되었다. 먼저 단층이 존재하는 실제 해안 대수층에 대해 보정을 병행한 일련의 정상 상태 수치 모델링을 수행한 다음에 이러한 단층이 존재하지 않는 해안 대수층에 대해 일련의 정상 상태 수치 모델링을 수행하여 그 결과를 서로 비교 분석하였다. 수치 모델링 결과는 단층이 실제 해안 대수층 내에 수리지질학적으로 중대한 불균질성과 진이방성을 야기시키며, 해안 대수층 내의 밀도 의존적 지하수 유동 및 염분 이동 그리고 해수 침투 양상이 이러한 단층의 존재 여부에 크게 그리고 광범위하게 좌우됨을 보여준다. 특히 단층은 단층면과 평행한 방향으로는 지하수 유동과 염분 이동에 대해서 통로로 작용하지만, 단층면과 수직한 방향으로는 지하수 유동과 염분 이동에 대해서 방벽으로 작용하는 것으로 해석된다.

올레핀 촉진수송 분리막용 AgCF3SO3를 활용한 PEBAX-2533/Ag Salt/Al(NO3)3 복합체 (PEBAX-2533/Ag Salt/Al(NO3)3 Composite Using AgCF3SO3 for Facilitated Olefin Transport Membrane)

  • 김소영;강상욱
    • 멤브레인
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    • 제31권1호
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    • pp.61-66
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    • 2021
  • 본 연구는 현재 올레핀/파라핀 분리에서 사용되는 극저온 분리법을 대체하기 위한 촉진수송 분리막에 대한 연구이다. 촉진수송 분리 막을 상업화하기 위해서는 비용 절감 또한 매우 중요한 요소이다. 하지만 많은 연구가 이루어지고 있는 AgBF4는 상대적으로 고가인 은 염이기 때문에 이를 대체하기 위해 비교적 저렴한 AgCF3SO3를 이용하여 PEBAX-2533/AgCF3SO3/Al(NO3)3 복합막을 제조하였다. 분리막의 특성은 SEM, FT-IR, RAMAN을 통해 분석되었으며, 이번 연구를 통해 고분자 매트릭스가 장기 안정성에 영향을 준다는 사실을 확인하였다.

열대 대서양에서의 계절별 담수 및 염분의 수송 (On the Seasonal Transports of Freshwater and Salt in the Tropical Atlantic Ocean)

  • Jung-Moon Yoo
    • International Union of Geodesy and Geophysics Korean Journal of Geophysical Research
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    • 제22권1호
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    • pp.1.1-15
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    • 1994
  • 열대 대서양의 해표면으로부터 500m 깊이까지의 계절별 담수 및 염분의 수송량과 방향을 조사하기 위하여, 먼저 연속방정식과 염분보존방정식에서 각각 이론적인 계산방법을 유도하고 관측자료를 사용하여 수송값들을 얻었다. 담수(강수량, 증발량, 그리고 강물방출량)의 기후자료에서 계산된 표면의 당수발산장을 북쪽에서 남쪽방향으로 적분하여 담수수송값을 얻었디. 연간 담수수송량의 방향은 북향으로 수송량은 적도부근에서 가장 적었고 (0 Sv), $12^{\circ}N와{\;}20^{\circ}{\;}N$부근에서 가장 많았다(0.3 Sv). 게절별 수송량의 크기는 북향 1.35 Sv괴 남향 O.45 Sv의 사이의 값을 보였고 강한 북향 수송량이 여름과 가을사이의 전이기간에서 나타났다. 이러한 계절별화는 지역적인 담수저장의 변화 뿐만 아니라 열대 수렴대의 이동과 관련이 있었다. 1900~86 기간의 염분관측값을 객관분석(objective analysis)한 후, 연간 및 계절별 염분 수송값을 계산하는데 사용하였다. 수평이류에 의한 염분수송량이 수형확산에 의한 수송량과 균형을 이룸으로 해서 연간 수송량은 없었다. 딘지 수평확산에 의한 염분수송량은 북향이었고 $15^{\circ}{\;}N$에서 최대값($5{\times}10^6kg/s$)을 보였다. 계절별 수송량의 크기는 북향 $30{\times}10^6kg/s$과 남향 $35{\times}l0^6kg/s$사이의 범위내에 있었다. 계절별 수송방향은 여릉과 가을사이의 기간을 제외하고 다른 기간에서 북향이었다.

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올레핀 촉진수송 분리막의 성능향상을 위한 Valine의 효과 (Effect of Valine on facilitated O1e1in Transport Membranes)

  • Yong Soo Kang;Sang Wook Kang;Jong Hak Kim;Jongok Won;Kookheon Char
    • 멤브레인
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    • 제13권2호
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    • pp.125-129
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    • 2003
  • 은염이 함유된 고분자 전해질을 이용한 올리핀 촉진수송 분리막은 고체상에서 높은 올레핀/파라핀 분리 성능을 나타내었다 본 연구에서는, 프로필렌/프로판 분리 선택도와 투과도의 성능을 향상시키기 위해 아미노산의 일종인 valine을 고분자 전해질막에 첨가하였다. FT-lR 분광학을 통해 valine의 양이온과 은염의 음이온이 상호작용을 하고, 그 결과 valine은 은이온의 활성도를 증가시킴을 알 수 있었다. 따라서 valine을 포함하고 있는 촉진수송 분리막은 valine이 없을 때보다 더 높은 선택도와 투과도를 나타내었다.

Effect of Salt on Facilitated Propylene Transport through Crosslinked PVA/Silver Salt Complex Membranes

  • Kim, Jong-Hak;Min, Byoung-Ryul;Lee, Ki-Bong;Kang, Yong-Soo
    • Korean Membrane Journal
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    • 제8권1호
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    • pp.43-49
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    • 2006
  • Complex membranes consisting of silver salt ($AgBF_4,\;AgCF_3SO_3,\;AgSbF_6,\;AgNO_3$) and poly(vinyl alcohol) (PVA) or crosslinked PVA (CPVA) were prepared and tested for the separation of propylene/propane mixtures. For the tested membranes, the complex membranes containing $AgBF_4$ exhibited the highest separation properties, i.e., approximately 20 GPU ($1 GPU=10^{-6}cm^3 (STP)/(cm^2 sec cmHg)$) and 100 of selectivity at 0.2 of silver mole fraction. The CPVA membranes containing silver salt always showed higher selectivity than PVA membranes, presenting silver ions coordinated to -CHO are more effective than those to -OH groups. The threshold silver concentration of CPVA membranes was lower than that of PVA membranes, which might be due to stronger interaction of silver ions with -CHO than that with -OH. The composition at which the selectivity is the highest did not significantly depend on the crosslinking, but did on the kind of silver salt.

The Effects of Salt Stress on Photosynthetic Electron Transport and Thylakoid Membrane Proteins in the Cyanobacterium Spirulina platensis

  • Sudhir, Putty-Reddy;Pogoryelov, Denys;Kovacs, Laszlo;Garab, Gyozo;Murthy, Sistla D.S.
    • BMB Reports
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    • 제38권4호
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    • pp.481-485
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    • 2005
  • The response of Spirulina (Arthrospira) platensis to high salt stress was investigated by incubating the cells in light of moderate intensity in the presence of 0.8 M NaCl. NaCl caused a decrease in photosystem II (PSII) mediated oxygen evolution activity and increase in photosystem I (PSI) activity and the amount of P700. Similarly maximal efficiency of PSII (Fv/Fm) and variable fluorescence (Fv/Fo) were also declined in salt-stressed cells. Western blot analysis reveal that the inhibition in PSII activity is due to a 40% loss of a thylakoid membrane protein, known as D1, which is located in PSII reaction center. NaCl treatment of cells also resulted in the alterations of other thylakoid membrane proteins: most prominently, a dramatic diminishment of the 47-kDa chlorophyll protein (CP) and 94-kDa protein, and accumulation of a 17-kDa protein band were observed in SDS-PAGE. The changes in 47-kDa and 94-kDa proteins lead to the decreased energy transfer from light harvesting antenna to PSII, which was accompanied by alterations in the chlorophyll fluorescence emission spectra of whole cells and isolated thylakoids. Therefore we conclude that salt stress has various effects on photosynthetic electron transport activities due to the marked alterations in the composition of thylakoid membrane proteins.

Salt and Sand Transport from Aral Sea Basin

  • 이귀주
    • 한국해양공학회지
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    • 제19권3호
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    • pp.47-53
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    • 2005
  • Model for dust and salt transportation from the dried bottom of the Aral Sea is suggested. Theoretical analysis is based on the turbulent diffusion equation for the averaged function of passive impurity concentration. One-layer model of the atmospheric boundary layer is assumed. Impurity precipitation rates are calculated as the functions of the particle size and the distance source of particles. Analytical solutions for the point and two-dimensional sources of impurities are found. Model calculations for salt and sand transport from the Aral Sea basin are made on the basis of 2D source model with a constant intensity.

Modeling of continuous diffusion dialysis of aqueous solutions of sulphuric acid and nickel sulphate

  • Bendova, Helena;Palaty, Zdenek
    • Membrane and Water Treatment
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    • 제2권4호
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    • pp.267-279
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    • 2011
  • At steady state, the simultaneous transport of sulphuric acid and nickel sulphate through an anion-exchange membrane Neosepta-AFN (Astom Corporation, Tokyo, Japan) was investigated in a two-compartment counter-current dialyzer with single passes. The transport was quantified by the recovery yield of acid, rejection of salt and four phenomenological coefficients, which were correlated with the acid and salt concentrations in the feed. The phenomenological coefficients were determined by the numerical integration of the basic differential equations describing the concentration profiles of the components in the dialyzer. This integration was combined with an optimizing procedure. The experiments proved that the acid recovery yield is in the limits from 63 to 91 %, while salt rejection is in the limits from 79 to 97 % in the dependence on the volumetric liquid flow rate and composition of the feed.

Continuous dialysis of selected salts of sulphuric acid

  • Bendova, Helena;Snejdrla, Pavel;Palaty, Zdenek
    • Membrane and Water Treatment
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    • 제1권3호
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    • pp.171-179
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    • 2010
  • The transport of selected salts of sulphuric acid (cobalt, copper, iron(II), manganese, nickel and zinc sulphate) through an anion-exchange membrane Neosepta-AFN was investigated in a counter-current continuous dialyzer at various salt concentrations and volumetric liquid flow rates. The basic transport characteristics - the rejection coefficient of salt and the permeability of the membrane - were calculated from measurements at steady state. The salt concentration in model mixtures was changed in the limits from 0.1 to 1.0 kmol $m^{-3}$ and the volumetric liquid flow rate of the inlet streams was in the limits from $8{\times}10^{-9}$ to $24{\times}10^{-9}m^3\;s^{-1}$. Under the experimental conditions given, the rejection coefficient of salts tested was in the range from 65% to 94%. The lowest values were obtained for iron(II) sulphate, while the highest for copper sulphate. The maximum rejection of salt was reached at the highest volumetric liquid flow rate and the highest salt concentration in the feed. The permeability ($P_A$) of the Neosepta-AFN membrane for the individual salts was in the range from $0.49{\times}10^{-7}m\;s^{-1}$ to $1.8{\times}10^{-7}m\;s^{-1}$ and it can be described by the following series: $P_{FeSO_4}$ < $P_{NiSO_4}$ < $P_{ZnSO_4}$ < $P_{CoSO_4}$ < $P_{MnSO_4}$ < $P_{CuSO_4}$. The permeability of the membrane was strongly affected by the salt concentration in the feed - it decreased with an increasing salt concentration.

Genomic Analysis of Halotolerant Bacterial Strains Martelella soudanensis NC18T and NC20

  • Jung-Yun Lee;Dong-Hun Kim
    • Journal of Microbiology and Biotechnology
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    • 제32권11호
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    • pp.1427-1434
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    • 2022
  • Two novel, halotolerant strains of Martelella soudanensis, NC18T and NC20, were isolated from deep subsurface sediment, deeply sequenced, and comparatively analyzed with related strains. Based on a phylogenetic analysis using 16S rRNA gene sequences, the two strains grouped with members of the genus Martelella. Here, we sequenced the complete genomes of NC18T and NC20 to understand the mechanisms of their halotolerance. The genome sizes and G+C content of the strains were 6.1 Mb and 61.8 mol%, respectively. Moreover, NC18T and NC20 were predicted to contain 5,849 and 5,830 genes, and 5,502 and 5,585 protein-coding genes, respectively. Both strains contain the identically predicted 6 rRNAs and 48 tRNAs. The harboring of halotolerant-associated genes revealed that strains NC18T and NC20 might tolerate high salinity through the accumulation of potassium ions in a "salt-in" strategy induced by K+ uptake protein (kup) and the K+ transport system (trkAH and kdpFABC). These two strains also use the ectoine transport system (dctPQM), the glycine betaine transport system (proVWX), and glycine betaine uptake protein (opu) to accumulate "compatible solutes," such as ectoine and glycine betaine, to protect cells from salt stress. This study reveals the halotolerance mechanism of strains NC18T and NC20 in high salt environments and suggests potential applications for these halotolerant and halophilic strains in environmental biotechnology.