• Title/Summary/Keyword: Salt rejection

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Effect of Salt Concentration and Temperature in Synthetic Dyestuff Wastewater Treatment using Plate and Frame Membrane Module (평판형 막모듈을 이용한 합성염료 폐수처리에 있어서 염농도 및 온도의 영향)

  • Kim, Sun-Il;Lee, Bong-Woo;Yun, Young-Jae
    • Journal of Environmental Science International
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    • v.7 no.2
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    • pp.209-216
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    • 1998
  • Nanofiltration[NF45] and reverse osmosis membrane(HR98PP) separation treatment of dyestuff wastewater was carried out In order to separate relatively pure water from synthetic dyestuff wastewater, which consists of reactive dye, acid dye, basic dye, direct dye, and disperse dye. The experiments were performed by using the plate and frame membrane module. In the nanofiltration and reverse osmosis membrane separation, When the NaCl concentration was 0.1, 5.0, and 20.091, retention was 63.0, 46.0, 0.9%, respectively. When permeate flux was 125.0, 67.5, and 45.0 L/$m^2$ h, the osmotic pressure increased with Increasing the NaCl concentration. Permeate flux of two membranes Increased as temperature Increased due to segmental movement of polymer of the membrane and the rejection rate of dyestuff was decreased gradually. It was found that the rejection rate was about 95% in the nanofiltratlon, while the reverse osmosis membrane showed a high rejection rate of 99% under all temperature and pressures conditions.

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Desalination performance of Al2O3 positively charged nanofiltration composite membrane

  • Li, Lian;Zhang, Xiating;Li, Lufen;Yang, Zhongcao;Li, Yuan
    • Membrane and Water Treatment
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    • v.13 no.2
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    • pp.105-110
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    • 2022
  • Al2O3 positively charged nanofiltration composite membrane was successfully prepared with aluminate coupling agent (ACA) as modifier, sodium bisulfite (NaHSO3) and potassium persulfate (K2S2O8) as initiator and methacryloyloxyethyl trimethylammonium chloride (DMC) as crosslinking monomer. The surface of the membrane before grafting and after polymerization were characterized by SEM and FT-IR. Three factor and three-level orthogonal experiments were designed to explore the optimal conditions for membrane preparation, and the optimal group was successfully prepared. The filtration experiments of different salt solutions were carried out, and the retention molecular weight was determined by polyethylene glycol (PEG). The results showed that the polymerization temperature had the greatest effect on the rejection rate, followed by the reaction time, and the concentration of DMC had the least effect on the rejection rate. The rejection rates of CaCl2, MgSO4, NaCl and Na2SO4 in the optimal group were 83.8%, 81.3%, 28.1% and 23.6% (average value), respectively. The molecule weight cut-off of 90% (MWCO) of the optimal group was about 460, which belongs to nanofiltration membrane.

NANOFILTRATION MEMBRANES BASED ON POLY(VINYL ALCOHOL) AND IONIC POLYMERS (폴리비닐알콜과 이온성고분자로 제조된 나노분리막)

  • 오남운;제갈종건;이규호
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.124-126
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    • 1998
  • 1. INTRODUCTION : With good physical and chemical properties as a membrane material, poly(vinyl alcohol) (PVA) has been widely used for the preparation of several kinds of membranes for different applications. Considering such good physical chemical properties, some people have tried to use it for the formation of reverse osmosis (RO) membranes with a good chemical stability as well as high flux and high rejection rate. However, unfortunately, the performance of the RO membranes based on PVA has not been satisfactory yet. The PVA RO membranes thermally crosslinked have shown very low flux and relatively low salt rejection. In this experiment, ionic polymers such as sodium alginate and chitosan were used together with PVA to increase the nanofiltration performance of the PVA membranes.

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Development of Graphene Nanocomposite Membrane Using Layer-by-layer Technique for Desalination (다층박막적층법을 이용한 담수화용 그래핀 나노복합체 분리막 개발)

  • Yu, Hye-Weon;Song, Jun-Ho;Kim, Chang-Min;Yang, Euntae;Kim, In S.
    • Membrane Journal
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    • v.28 no.1
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    • pp.75-82
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    • 2018
  • Forward osmosis (FO) desalination system has been highlighted to improve the energy efficiency and drive down the carbon footprint of current reverse osmosis (RO) desalination technology. To improve the trade-off between water flux and salt rejection of thin film composite (TFC) desalination membrane, thin film nanocomposite membranes (TFN), in which nanomaterials as a filler are embeded within a polymeric matrix, are being explored to tailor the separation performance and add new functionality to membranes for water purification applications. The objective of this article is to develop a graphene nanocomposite membrane with high performance of water selective permeability (high water flux, high salt rejection, and low reverse solute diffusion) as a next-generation FO desalination membrane. For advances in fabrication of graphene oxide (GO) membranes, layer-by-layer (LBL) technique was used to control the desirable structure, alignment, and chemical functionality that can lead to ultrahigh-permeability membranes due to highly selective transport of water molecules. In this study, the GO nanocomposite membrane fabricated by LBL dip coating method showed high water flux ($J_w/{\Delta}{\pi}=2.51LMH/bar$), water selectivity ($J_w/J_s=8.3L/g$), and salt rejection (99.5%) as well as high stability in aqueous solution and under FO operation condition.

THE REVERSE OSMOSIS PROCESS

  • Erickson, Steve
    • Proceedings of the Membrane Society of Korea Conference
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    • 1991.04a
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    • pp.9-9
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    • 1991
  • This paper will begin by describing osmosis and how reverse osmosis works. It will show how osmotic pressure affects reverse osmosis operations. It uill explain salt rejection, membrane flux, and recovery rates and the affect that salt built up has on membrane performance. It wil 1 explain the limitations of RO performance and why pretreatment is important. It will describe the two basic types of membrane, asymmetric and thin-film composite and explain the difference between these types plus compare cellulose acetate types to aromatic polyamide type membranes. It will discuss operating efficiences as it compares to feedwater pressure, concentration, temperature and pH. Finally, it will discuss the differences between tubular, plate and frame, hollow fiber and spiral wound element design. It will be a paper that talks about the basics of RO systems and should give a person who is unfamiliar with RO a basic introduction to this type of separation technology.

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Noise Removal Method using Entropy in High-Density Noise Environments (고밀도 잡음 환경에서 엔트로피를 이용한 잡음 제거 방법)

  • Baek, Ji-Hyeon;Kim, Nam-Ho
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.24 no.10
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    • pp.1255-1261
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    • 2020
  • Currently, the spread of mobile devices is gradually increasing. Accordingly, various techniques using images or photos are actively being researched. However, image data generates noise for complex reasons, and the accuracy of image processing increases according to the performance of removing noise. Therefore, noise reduction is one of the essential steps. Salt and pepper noise is a typical impulse noise in the image, and various studies are being conducted to remove the noise. However, existing algorithms have poor noise rejection performance in high frequency areas, and average filters have blurring. Therefore, in this paper, we propose an algorithm that effectively removes salt and pepper noise in the high frequency region as well as the low frequency region using entropy. For objective and accurate judgment of proposed algorithms, MSE and PSNR were used to compare and analyze existing algorithms.

Sensitivity analysis and Taguchi application in vacuum membrane distillation

  • Upadhyaya, Sushant;Singh, Kailash;Chaurasia, Satyendra Prasad;Baghel, Rakesh;Singh, Jitendra Kumar;Dohare, Rajeev Kumar
    • Membrane and Water Treatment
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    • v.9 no.6
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    • pp.435-445
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    • 2018
  • In this work, desalination experiments were performed on vacuum membrane distillation (VMD). Process parameters such as feed flow rate, vacuum degree on permeate side, feed bulk temperature and feed salt concentration were optimized using sensitivity analysis and Taguchi method. The optimum values of process parameters were found to be 2 lpm of feed flow rate, $60^{\circ}C$ of feed bulk temperature, 5.5 kPa of permeate-side pressure and 5000 ppm of salt concentration. The permeate flux at these conditions was obtained as $26.6kg/m^2{\cdot}hr$. The rejection of salt in permeate was found to be 99.7%. The percent contribution of various process parameters using ANOVA results indicated that the most important parameter is feed bulk temperature with its contribution of 95%. The ANOVA results indicate that the percent contribution of permeate pressure gets increased to 5.384% in the range of 2 to 7 kPa as compared to 0.045% in the range of 5.5 to 7 kPa.

A Characterization of the Permeation and Separation of Electrolyte Solutions Through Charged Membranes in the Reverse Osmosis Process (이온성 막을 이용한 역삼투압 막 분리 공정에서 전해질 수용액의 투과분리 특성연구)

  • 염충균;최정환;이정민;서동수
    • Membrane Journal
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    • v.11 no.1
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    • pp.22-28
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    • 2001
  • Various charged homogeneous membranes were fabricated by blending of ionic polymer with a non-ionic polymer with different ratios. In this study. sodium alginate, chitosan and poly(vinyl alcohol) were employed as anionic. cationic and non-ionic polymers, respectively. The permcation and separation behaviors of aquCOll::; salt solutions have been investigated through the charged membranes. As the content of ionic polymer increases in the membrane, the hydrophilicity of the membrane increases and pure water flux as well as solution flux increases correspondingly, indicating that the permeation performance through the membrane is cletemunecl mainly by its hydrophilicity-, Electrostatic interaction between the charged membrane and ionic solute molecules, that is. Donnan exclusion was observed to be attributed to salt rejection to a great deal of extent, and molecular sieve mechanism was effective [or the separation of the salt solution under a similar electrostatic circumstance of solutes.

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Water desalination by membrane distillation using PVDF-HFP hollow fiber membranes

  • Garcia-Payo, M.C.;Essalhi, M.;Khayet, M.;Garcia-Fernandez, L.;Charfi, K.;Arafat, H.
    • Membrane and Water Treatment
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    • v.1 no.3
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    • pp.215-230
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    • 2010
  • Poly(vinylidene fluoride-co-hexafluoropropylene), PVDF-HFP, hollow fiber membranes were prepared by the dry/wet spinning technique using different polyethylene glycol (PEG) concentrations as non-solvent additive in the dope solution. Two different PEG concentrations (3 and 5 wt.%). The morphology and structural characteristics of the hollow fiber membranes were studied by means of optical microscopy, scanning electron microscopy, atomic force microscopy (AFM) and void volume fraction. The experimental permeate flux and the salt (NaCl) rejection factor were determined using direct contact membrane distillation (DCMD) process. An increase of the PEG content in the spinning solution resulted in a faster coagulation of the PVDF-HFP copolymer and a transition of the cross-section internal layer structure from a sponge-type structure to a finger-type structure. Pore size, nodule size and roughness parameters of both the internal and external hollow fiber surfaces were determined by AFM. It was observed that both the pore size and roughness of the internal surface of the hollow fibers enhanced with increasing the PEG concentration, whereas no change was observed at the outer surface. The void volume fraction increased with the increase of the PEG content in the spinning solution resulting in a higher DCMD flux and a smaller salt rejection factor.

Seawater-driven forward osmosis for direct treatment of municipal wastewater

  • Sun, Yan;Bai, Yang;Tian, Jiayu;Gao, Shanshan;Zhao, Zhiwei;Cui, Fuyi
    • Membrane and Water Treatment
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    • v.8 no.5
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    • pp.449-462
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    • 2017
  • Direct treatment of municipal wastewater by forward osmosis (FO) process was evaluated in terms of water flux decline, reverse salt diffusion, pollutants rejection and concentration efficiency by using synthetic seawater as the draw solution. It was found that when operating in PRO mode (active layer facing the draw solution), although the FO membrane exhibited higher osmotic water flux, more severe flux decline and reverse salt diffusion was also observed due to the more severe fouling of pollutants in the membrane support layer and accompanied fouling enhanced concentration polarization. In addition, although the water flux decline was shown to be lower for the FO mode (active layer facing the feed solution), irreversible membrane fouling was identified in both PRO and FO modes as the water flux cannot be restored to the initial value by physical flushing, highlighting the necessity of chemical cleaning in long-term operation. During the 7 cycles of filtration conducted in the experiments, the FO membrane exhibited considerably high rejection for TOC, COD, TP and $NH_4{^+}-N$ present in the wastewater. By optimizing the volume ratio of seawater draw solution/wastewater feed solution, a concentration factor of 3.1 and 3.7 was obtained for the FO and PRO modes, respectively. The results demonstrated the validity of the FO process for direct treatment of municipal wastewater by using seawater as the draw solution, while facilitating the subsequent utilization of concentrated wastewater for bioenergy production, which may have special implications for the coastline areas.