• Title/Summary/Keyword: Saline water resistance

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Sulfonated poly(arylene ether copolymer)-g-sulfonated Polystyrene Membrane Prepared Via E-beam Irradiation and Their Saline Water Electrolysis Application (전자빔조사를 이용한 술폰화 폴리아릴렌 에테르 술폰-g-술폰화 폴리스틸렌 분리막 제조 및 염수전기분해 특성평가)

  • Cha, Woo Ju;Lee, Chang Hyun
    • Membrane Journal
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    • v.26 no.6
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    • pp.458-462
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    • 2016
  • Saline water electrolysis, known as chlor-alkali (CA) membrane process, is an electrochemical process to generate valued chemicals such as chlorine, hydrogen and sodium hydroxide with high purities higher than 99%, using an electrolytic cell composed of cation exchange membrane, anode and cathode. It is necessary to reduce energy consumption per a unit chemical production. This issue can be solved by decreasing intrinsic resistance of the membrane and the electrodes and/or by reducing their interfacial resistance. In this study, the electron radiation grafting of a $Na^+$ ion-selective polymer was conducted onto a hydrocarbon sulfonated ionomer membrane with high chemical resistance. This approach was effective in improving electrochemical efficiency via the synergistic effect of relatively fast $Na^+$ ion conduction and reduced interfacial resistance.

Soil Resistant and Blood Repellent Finishes of Nonwoven Fabrics Using Foam (거품을 이용한 부직포의 방오방혈가공)

  • 이정민;배기서;노덕길;전병열
    • Textile Coloration and Finishing
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    • v.4 no.3
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    • pp.74-81
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    • 1992
  • Chemical bonded nonwoven fabric for apparel use and spunlaced nonwoven fabric for medical use were finished for soil resistance and blood replellency with fluorochemicals utilizing foam finishing technology (FFT) and conventional padding application techniques. The FFT process improved soil and abrasion resistance properties of nonwoven fabrics compared with the conventional padding process. Excellent water-oil-saline-alcohol repellency values and water impact penetration values were obtained in the spunlaced nonwoven fabrics with both techniques.

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An Experimental Study on the Salt Damage Resistance of High Durable Concrete (고내구성콘크리트의 염해저항성에 관한 실험적 연구)

  • Yoon, Jai-Hwan;Jaung, Jae-Dong
    • Journal of the Korea Institute of Building Construction
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    • v.3 no.3
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    • pp.73-81
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    • 2003
  • In this paper, salt damage resistance of high durable concrete was tested. High durable concrete was made by using low water cement ratio, chemical admixture called super-durable admixture and mineral admixtures such as fly-ash, ground granulated blast-furnace slag, silica fume. Two kinds of salt damage resistance test were carried out. One method is chloride ion penetration test(ASTM C1202), and the other one is depth of chloride penetration test in saline solution. Test results were as followers: 1) The depth of chloride ion penetration increased exponentially as water cement ratio was increased and time passed. 2) Super-durable admixture had little effect on the improvement of salt damage resistance of concrete. 3) Silica fume and ground granulated blast-furnace slag were effective on salt damage resistance because of pozzolanic reaction, but fly-ash had a little effect.

Interfacial and Mechanical Properties of Glass Fiber Reinforced Epoxy Composites with Different Crosslinking Density after Saline Water Aging (기지재의 가교밀도에 따른 유리섬유 복합재료의 염수노화 후 계면 및 기계적 물성)

  • Shin, Pyeong-Su;Kim, Jong-Hyun;Baek, Yeong-Min;Park, Ha-Seung;Kwon, Dong-Jun;Park, Joung-Man
    • Composites Research
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    • v.31 no.5
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    • pp.186-191
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    • 2018
  • Condition and properties of composites with different chemical structure of epoxy matrix were observed after saline solution treatment. Epoxy was used as matrix and the flexibility was controlled by using 2 typed-epoxies and 3 types hardeners (amine, acid anhydride and amide). Saline water treatment was conducted with 6 wt% NaCl solution at $60^{\circ}C$ for 0, 15, and 30 days. Cross section was observed and interfacial and mechanical and properties was evaluated. Amine type exhibited the highest crosslinking density and mechanical and interfacial properties whereas water absorbance was lowest. It is because that the water molecules can be hardly penetrate into the epoxy matrix or the interface between epoxy and glass fiber and it leads to saline water resistance of composites.

Effects of Heavy Metal and Salinity on Electrical Conductivity in Fully Saturated Sand (포화된 사질토의 전기전도도에 중금속과 염분 농도가 미치는 영향)

  • Lee, Dongsoo;Hong, Young-Ho;Hong, Won-Teak;Chae, Kwang-Seok;Lee, Jong-Sub
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.10
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    • pp.23-34
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    • 2017
  • As the electrical property of fully saturated soils is dependent on the pore water, it has been commonly used for the detection of the contamination into the ground. The objective of this study is to investigate the electrical characteristics according to the salinity and the lead concentration in fully saturated soils. Fresh water and saline water with the salinity of 1%, 2% and 3%, which are mixed with 6 different lead solutions with the range of 0~10 mg/L, are prepared in the cylindrical cell incorporated with sensors for measuring electrical resistance and time domain reflectometry signal. Then, the dried sands are water-pluviated into the cell. The electrical resistance and the time domain reflectometry signal are used to estimate the electrical conductivity. Test results show that electrical conductivity determined from electrical resistance at the frequency of 1 kHz continuously increases with an increase in the lead concentration, thus it may be used for the estimation of the contaminant level. In addition, the electrical conductivity estimated by the time domain reflectometry changes even at very low concentration of lead, the variation rate decreases as the lead concentration increases. Thus, the time domain reflectometry can be used for the investigation of the heavy metal leakage. This study demonstrates that complementary characteristics of electrical resistance and time domain reflectometry may be used for the detection of the leakage and contamination of heavy metal in coastal and marine environments.

Thermal Resistance and Inactivation of Enterobacter sakazakii Isolates during Rehydration of Powdered Infant Formula

  • Kim, Soo-Hwan;Park, Jong-Hyun
    • Journal of Microbiology and Biotechnology
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    • v.17 no.2
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    • pp.364-368
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    • 2007
  • Enterobacter sakazakii may be related to outbreaks of meningitis, septicemia, and necrotizing enterocolitis, mainly in neonates. To reduce the risk of E. sakazakii in baby foods, thermal characteristics for Korean E. sakazakii isolates were determined at 52, 56, and $60^{\circ}C$ in saline solution, rehydrated powdered infant formula, and dried baby food. In saline solution, their D-values were 12-16, 3-5, and 0.9-1 min for each temperature. D-values increased to 16-20, 4-5, and 2-4 min in rehydrated infant formula and 14-17, 5-6, and 2-3 min in dried baby food. The overall calculated z-value was 6-8 for saline, 8-10 for powdered infant formula, and 9-11 for dried baby food. Thermal inactivation of E. sakazakii during rehydration of powdered infant formula was investigated by viable counts. Inactivation of cultured E. sakazakii in infant formula milk did not occur for 20 min at room temperature after rehydration with the water at $50^{\circ}C$ and their counts were reduced by about 1-2 log CFU/g at $60^{\circ}C$ and 4-6 log CFU/ml with the water at 65 and $70^{\circ}C$. However, the thermo stability of adapted E. sakazakii to the powdered infant formula increased more than two times. Considering that the levels of E. sakzakii observed in powdered infant formula have generally been 1 CFU/100 g of dry formula or less, contamination with E. sakazakii can be reduced or eliminated by rehydrating water with at least $10^{\circ}C$ higher temperature than the manufacturer-recommended $50^{\circ}C$.

Single-dose Intravenous Injection Toxicity of Water-soluble Danggui Pharmacopuncture (WDP) in Sprague-Dawley Rats

  • Park, Sunju;Park, Hae-Mo;Sun, Seung-Ho
    • Journal of Pharmacopuncture
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    • v.21 no.2
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    • pp.104-111
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    • 2018
  • Objective:This study is to evaluate both the single-dose intravenous injection toxicity and the approximate lethal dose of Water-soluble Danggui Pharmacopuncture (WDP) in Sprague-Dawley (SD) rats. Methods: Toxicity experiments were conducted at Good Laboratory Practice (GLP) laboratory in Biotoxtech Co., according to the regulations of GLP. WDP injection of dose 0.125, 0.25, and 0.5 mL/animal were experimental groups and normal saline injection group was control group. WDP and normal saline were injected once to 6- week old 5 male and 5 female SD rats at the tail veins at approximately 2 mL/min. During 14 days after the injection, general symptoms were observed and weight were measured. After the observation period, hematological and blood biochemical examination, macroscopic autopsy, topical resistance test at the injection area were performed. Results: RThe WDP 0.5 mL/animal injection group in 4 cases of male rats and all cases of female rats showed hematuria 30 minutes after the administration. However, after 1 hour, no more abnormal general symptoms were observed. The WDP did not affect weight, hematological and blood biochemical examination, macroscopic autopsy, and topical resistance test at the injection area. Conclusion: WDP single dose intravenous injection results showed that WDP have no toxic effects and a lethal dose of WDP should be over 0.5 mL/animal in male and female rats under the study condition. So WDP may be safe.

Treatment of high-salinity wastewater after the resin regeneration using VMD

  • Gao, Junyu;Wang, Manxiang;Yun, Yanbin
    • Membrane and Water Treatment
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    • v.9 no.1
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    • pp.53-62
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    • 2018
  • In this study, vacuum membrane distillation (VMD) was used to treat high-salinity wastewater (concentration about 17%) discharged by chlor-alkali plant after resin regeneration. The feasibility of VMD for the treatment of real saline wastewater by using Polyvinylidene fluoride (PVDF) microporous plate membrane with a pore diameter of $0.2{\mu}m$ was investigated. The effects of critical operating parameters such as feed temperature, velocity, vacuum degree and concentration on the permeate water flux were analyzed. Numerical simulation was used to predict the flux and the obtained results were in good agreement with the experimental data. The results showed that an increase in the operating conditions could greatly promote the permeate water flux which in turn decreased with an increase in the concentration. When the concentration varied from 17 to 25%, the permeate water flux dropped marginally with time indicating that the concentration was not sensitive to the decrease in permeate water flux. The permeate water flux decreased sharply until zero due to the membrane fouling resistance as the concentration varied from 25 to 26%. However, the conductivity of the produced water was well maintained and the average value was measured to be $4.98{\mu}s/cm$. Furthermore, a salt rejection of more than 99.99% was achieved. Overall, the outcome of this investigation clearly indicates that VMD has the potential for treating high-salinity wastewater.

A preliminary study of watertightness and salt water resistance of spray-applied membrane (뿜어붙임멤브레인의 방수성능 및 염수저항성의 기초평가)

  • Choi, Soon-Wook;Kang, Tae-Ho;Chang, Soo-Ho;Lee, Cheol-Ho;Kim, Jintae;Choi, Myung-Sik
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.19 no.2
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    • pp.283-299
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    • 2017
  • The leakage of tunnel causes the long-term durability of the structures such as concrete lining to deteriorate. The cause of durability degradation can be various substances contained in groundwater such as chloride, sulphate, water, and gas. In this study, a series of test were carried out to determine the watertightness performance and the resistance to salt water of the spray-applied membrane used as non-structural rock support or as a waterproof material for tunnels. As a result, it was found that the penetration of water could occur in a specimen, and the reason was that the internal pores generated by the mixing of the liquid polymer and the powder material and the internal pores were connected by the water pressure. The tensile strength of the test specimens immersed in distilled water and saline water was found to be reduced to less than half of the tensile strength in normal condition. In addition, The elongation was measured to be higher in distilled water than in salt water. However, this result will require further investigation.

Preparation of Superabsorbent PVA Films with Polycarboxylic Acid Crosslinkers (폴리카르복시산 가교제를 이용한 고흡수성 PVA 필름의 제조)

  • Koo, Gwang-Hoe;Yoon, Sung-Jong;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.21 no.4
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    • pp.39-45
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    • 2009
  • PVA films were crosslinked with dimethylol dihydroxy ethylene urea (DMDHEU) and three polycarboxylic acids of butanetetracarboxylic acid (BTCA), citric acid and malic acid Different factors influencing the crosslinking treatment with BTCA were investigated including BTCA and sodium hypophosphite (SHP) concentration, curing temperature and time. The cured films was extracted with boiling water and gel fraction was calculated based on weight change of the PVA films. The gel fraction of PVA films increased with increasing curing temperature and time. And the resistance to water and thermal stability of the crosslinked PVA films improved with the BTCA crosslinking treatment. While crosslinking with citric acid gave the highest gel fraction among the crosslinkers, crosslinking with malic acid showed the highest absorbancy in 0.9% saline solution, which was attributed to lower crosslink density and high number-average molecular weight between crosslinks. The superabsorbent PVA films could be prepared by adjusting the crosslinking condition of PVA with polycarboxilic acids.