• 제목/요약/키워드: SURFACE MORPHOLOGY

검색결과 3,459건 처리시간 0.034초

파형점류전해에 의한 Pb-Sn 합금의 현미경조직 및 우선배향 (The Microstructure and the Prerred Orientation of Pb-Sn-Alloy Electrodeposits in Pulse Plating)

  • 예길촌;김용응
    • 한국표면공학회지
    • /
    • 제22권4호
    • /
    • pp.207-214
    • /
    • 1989
  • The surface morphology and the proferred orientation of the Pb-Sn alloy electrodeposite were investated by the change of electrolysis conditions in pulse current electroplating. The preferred orientation of Pb-phase in alloy deposits was changed in the sequence of (110)longrightarrow(100)or(100)+(111)longrightarrow(111) with increasing peak current density, while that of $\beta$-Sn phase changed from (321)+(301)to(301)+(111) mixed orientation. The surface morphology was closely related to the preferred orientation of alloy electrodeposits. The alloy deposits, which had (100)or(111) for pb-phase and (321)or(100)(301)for $\beta$-Sn sespectively, showed the surface structure of granular crystallites. The alloy deposits whih mixed orientations for both phases had microstructure of closely the closely stacked crysrallites, which was inclined to the surface.

  • PDF

펄스 레이저 조사 후 알루미늄 합금의 표면상태에 대한 표면 거칠기의 영향 (Influence of Surface Roughness on Morphology of Aluminum Alloy After Pulsed-Laser Irradiation)

  • 최성호;김정석;장경영;신완순
    • 대한기계학회논문집A
    • /
    • 제35권9호
    • /
    • pp.1105-1111
    • /
    • 2011
  • 본 연구의 목적은 Nd:YAG 펄스레이저 조사 후 알루미늄 합금 6061-T6 시편의 표면상태에 대한 표면 거칠기의 영향을 연구하는 것이다. 초기 표면 거칠기를 다르게 하기 위해 다아이몬드 입자($1{\mu}m$)와 연마지(#100, #220, #600, #2400)를 이용하여 표면을 가공하였다. 10 번의 펄스레이저를 조사한 후 주사전자현미경과 광학현미경 그리고 원자현미경을 이용하여 표면상태를 관찰하였다. 그 결과 표면 거칠기가 증가할수록 용융부의 지름이 증가하였는데, 이는 표면 거칠기에 따라 표면부에서 레이저 빔의 다중반사와 다중흡수가 일어나 레이저 빔의 흡수율이 변하기 때문이다. 이를 검증하기 위해 용융부의 지름으로부터 표면 거칠기에 의해 증가하는 상대적인 흡수율을 계산하였으며 평균 표면 거칠기가 증가함에 따라 상대적인 흡수율이 용융부의 지름과 유사한 형태로 증가하는 것을 보였다.

Paradigm Forces in English Derivational Morphology

  • Kim, Jin-Hyung
    • 한국영어학회지:영어학
    • /
    • 제1권2호
    • /
    • pp.243-272
    • /
    • 2001
  • This paper focuses on the applicability of paradigm to derivational morphology and the pressure of paradigm enforced on derivational phonology and morphology. Through a close examination of well-attested data, we will demonstrate that apparent surface idiosyncrasies in phonology are the results of paradigm leveling, and that paradigmatic forces of analogy are productively operating in English word formation. On the basis of these observations, it can be argued that the notion of paradigm has at least some justification within derivational morphology as well, even if not to the same extent that it has with inflectional morphology and that the paradigm forces are independently needed in any adequate phonological and morphological theory. This can also be extended to provide evidence against the split morphology hypothesis that inflectional and derivational morphology belong to different grammatical modules.

  • PDF

원자힘현미경을 이용한 지지 지질층의 특성규명 (Characterization of Supported Lipid Layers Using Atomic Force Microscopy)

  • 박진원
    • Korean Chemical Engineering Research
    • /
    • 제47권4호
    • /
    • pp.395-402
    • /
    • 2009
  • 원자힘현미경은 초미세크기의 물리적 특성을 규명하기 위한 수단으로서 지지 지질층의 물리적특성 규명에 이용되어 왔다. 원자힘현미경이 출현하기 이전에는 초미세관점에서 지지 지질층에서 발생하는 물리적 현상의 관찰이 전무하였다. 이 현미경은 탐침바늘(Cantilever)로 표면을 주사(Scanning)함으로써 표면의 초미세 형상(Morphology)을 제공하고 표면에 접근(Approach)했다가 후퇴(Retraction)하는 탐침바늘의 거동을 모니터링함으로써 힘곡선(Force Curve)을 나타낼 수 있다. 형상 파악을 통해 지지 지질층의 구조와 막 단백질이 지질층의 구조에 미치는 영향을 밝히는 연구가 진행되어 왔으며, 힘곡선을 통하여 지지 지질층 표면 특성-기계적 정전기적 특성-에 대한 연구가 진행되었다. 본 총설에서는 원자힘현미경을 이용하여 현재까지 진행된 지지 지질층의 구조와 표면 특성 연구에 대하여 소개하고 향후 연구 진행 방향에 대하여 논의하고자 한다.

TiO2 전극의 소결 온도에 따른 DSSCs의 전기적 특성 및 AFM 형상 비교 (Comparison of Electrical Properties and AFM Images of DSSCs with Various Sintering Temperature of TiO2 Electrodes)

  • 김현주;이동윤;이원재;구보근;송재성
    • 한국전기전자재료학회논문지
    • /
    • 제18권6호
    • /
    • pp.571-575
    • /
    • 2005
  • In order to improve the efficiency of dye-sensitized solar cell (DSSC), $TiO_2$ electrode screen-printed on transparent conducting oxide (TCO) substrate was sintered in variation with different temperature$(350\;to\;550^{\circ}C)$. $TiO_2$ electrode on fluorine doped tin oxide (FTO) glass was assembled with Pt counter electrode on FTO glass. I-V properties of DSSCs were measured under solar simulator. Also, effect of sintering temperature on surface morphology of $TiO_2$ films was investigated to understand correlation between its surface morphology and sintering temperature. Such surface morphology was observed by atomic force microscopy (AFM). Below sintering temperature of $500^{\circ}C$, efficiency of DSSCs was relatively lower due to lower open circuit voltage. Oppositely, above sintering temperature of $500^{\circ}C$, efficiency of DSSCs was relatively higher due to higher open circuit voltage. In both cases, lower fill factor (FF) was observed. However, at sintering temperature of $500^{\circ}C$, both efficiency and fill factor of DSSCs were mutually complementary, enhancing highest fill factor and efficiency. Such results can be explained in comparison of surface morphology with schematic diagram of energy states on the $TiO_2$ electrode surface. Consequently, it was considered that optimum sintering temperature of a-terpinol included $TiO_2$ paste is at $500^{\circ}C$.

실리콘 박막 태양전지 전면 전극용 ZnO : Al 투명전도막의 표면형상 및 산란광 특성 (Characterization of Surface Morphology and Light Scattering of Transparent Conducting ZnO:Al Films as Front Electrode for Silicon Thin Film Solar Cells)

  • 김영진;조준식;이정철;왕진석;송진수;윤경훈
    • 한국재료학회지
    • /
    • 제19권5호
    • /
    • pp.245-252
    • /
    • 2009
  • Changes in the surface morphology and light scattering of textured Al doped ZnO thin films on glass substrates prepared by rf magnetron sputtering were investigated. As-deposited ZnO:Al films show a high transmittance of above 80% in the visible range and a low electrical resistivity of $4.5{\times}10^{-4}{\Omega}{\cdot}cm$. The surface morphology of textured ZnO:Al films are closely dependent on the deposition parameters of heater temperature, working pressure, and etching time in the etching process. The optimized surface morphology with a crater shape is obtained at a heater temperature of $350^{\circ}C$, working pressure of 0.5 mtorr, and etching time of 45 seconds. The optical properties of light transmittance, haze, and angular distribution function (ADF) are significantly affected by the resulting surface morphologies of textured films. The film surfaces, having uniformly size-distributed craters, represent good light scattering properties of high haze and ADF values. Compared with commercial Asahi U ($SnO_2$:F) substrates, the suitability of textured ZnO:Al films as front electrode material for amorphous silicon thin film solar cells is also estimated with respect to electrical and optical properties.

UV레이저를 이용한 Cr 박막의 어블레이션 (The UV Laser Ablation of Cr film on Glass Substrate)

  • 윤경구;이성국;김재구;최두선;황경현;정재경;장원석;나석주
    • 한국정밀공학회지
    • /
    • 제17권8호
    • /
    • pp.134-139
    • /
    • 2000
  • In order to understand the removal mechanism and seek the optimal conditions. KrF excimer laser ablation of Cr films on glass substrates is investigated. The surface morphology of the laser-irradiated spot is examined by SEM. The measured single-shot ablation rate is found to be about two times the result of numerical analysis based on a surface vaporization model and heat conduction theory. Surface morphology examination indicates that the Cr film is removed by the sequence of melting-surface vaporization-,melt expulsion by plasma recoil and that the outmost ripple of the diffraction pattern gives a strong effect on the morphology of molten Cr during the melting and vaporization processes. To seek the optimal process parameters for micro patterning morphological investigation is carried out experimentally on samples having different chromium film thicknesses. Optimal processing conditions are determined to enhance the accuracy and quality of thin film removal for micro patterning.

  • PDF

Morphology of Bone-like Apatite Formation on Sr and Si-doped Hydroxyapatite Surface of Ti-6Al-4V Alloy after Plasma Electrolytic Oxidation

  • Yu, Ji-Min;Choe, Han-Cheol
    • 한국표면공학회:학술대회논문집
    • /
    • 한국표면공학회 2017년도 춘계학술대회 논문집
    • /
    • pp.79-79
    • /
    • 2017
  • Metallic biomaterials have been mainly used for the fabrication of medical devices for the replacement of hard tissue such as artificial hip joints, bone plates, and dental implants. Because they are very reliable on the viewpoint of mechanical performance. This trend is expected to continue. Especially, Ti and Ti alloys are bioinert. So, they do not chemically bond to the bone, whereas they physically bond with bone tissue. For their poor surface biocompatibility, the surface of Ti alloys has to be modified to improve the surface osteoinductivity. Recently, ceramic-like coatings on titanium, produced by plasma electrolytic oxidation (PEO), have been developed with calciumand phosphorus-enriched surfaces. A lso included the influences of coatings, which can accelerate healing and cell integration, as well as improve tribological properties. However, the adhesions of these coatings to the Ti surface need to be improved for clinical use. Particularly Silicon (Si) has been found to be essential for normal bone, cartilage growth and development. This hydroxyapatite, modified with the inclusion of small concentrations of silicon has been demonstrating to improve the osteoblast proliferation and the bone extracellular matrix production. Strontium-containing hydroxyapatite (Sr-HA) was designed as a filling material to improve the biocompatibility of bone cement. In vitro, the presence of strontium in the coating enhances osteoblast activity and differentiation, whereas it inhibits osteoclast production and proliferation. The objective of this work was to study Morphology of bone-like apatite formation on Sr and Si-doped hydroxyapatite surface of Ti-6Al-4V alloy after plasma electrolytic oxidation. Anodized alloys was prepared at 270V~300V voltages with various concentrations of Si and Sr ions. Bone-like apatite formation was carried out in SBF solution. The morphology of PEO, phase and composition of oxide surface of Ti-6Al-4V alloys were examined by FE-SEM, EDS, and XRD.

  • PDF

질소와 암모니아 존재하에서 1 keV 에너지의 알곤과 수소 이온 조사에 의한 PTFE(polytetrafluoroethylene)의 표면형상 변화연구 (Surface Modification of Polytetrafluoroethylene by 1 keV Argon and Hydrogen Irradiated in Nitrogen and Ammonia Gas Environment)

  • 유대환;김기환;강동엽;김중수;고석근;김현주
    • 한국재료학회지
    • /
    • 제16권6호
    • /
    • pp.367-372
    • /
    • 2006
  • Polytetrafluoroethylene (PTFE) surface was modified for improving hydrophilicity by ion irradiation in environmental gas of $N_2$ and $NH_3$, respectively. The water contact angle onto the PTFE surface increased from $104{\circ}$ to over $140{\circ}$ by Ar ion irradiation in $N_2$ gas. In the case of $NH_3$ as environmental gas, there were a slight increase of contact angle from ion dose of $1{\times}10^{15}\;to\;5{\times}10^{15}\;ions/cm^2$, and its dramatic decrease to the value of 35o at the conditions of ion dose higher than $1{\times}10^{16}\;ions/cm^2$. It was found from SEM results that the surface morphology of PTFE was changed into one with filament structure after Ar ion irradiation in $N_2$ gas environments. On the contrary, Ar ion irradiation in $NH_3$ gas condition induced the PTFE surface with network structure. Hydrogen ion irradiation resulted in a little change of PTFE surface morphology, comparing with the case of Ar ion irradiation. The water contact angle of hydrogen ion irradiated PTFE surface in reactive gas decreased with increment of ion dose. Hydrogen ion irradiation could improve hydrophilicity with little change of surface morphology. It might be considered from FT-IR results that the improvement in wettability of PTFE surface by ion irradiation in $N_2$ and $NH_3$ gases could be due to the hydrophilic groups of NHx bonds.