• Title/Summary/Keyword: SURFACE MODIFICATION

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Surface Modification of PET Irradiated by Ultra-Violet (Part II) - Transformation of moisture properties and physical Properties - (UV조사를 통한 PET의 표면개질(제2보) -수분특성 및 물리적 특성 변화-)

  • Choi Hae Young;Lee Jung Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.5 s.142
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    • pp.617-625
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    • 2005
  • The purpose of this study was to develop functional and environment-friendly polyester fabric by irradiating Ultra-Violet, which was produced by the low-pressure mercury lamp. UV irradiation was conducted with various treatment times and distances. Also, pretreatments of solvents and photoinitiator were used to improve the surface modification effects. The effects of UV irradiation on the moisture regain were found to increase gradually with increase of UV treatment time and decrease of treatment distance. Compared the effects of UVC and UVA, UVC was more effective than UVA. Moisture regain and wicking of PET was increased after UV treatment in our experimental condition. And owing to increasing of moisture regain, static charge was decreased. Pretreatment of solvents such as methanol, ethyl ether and addition of photoinitiator such as Benzophenone accelerated surface modification. The moisture regain was increased but wicking was decreased with pretreatment and addition of photoinitiatior. Therefore it is considered as inappropriate f3r clothing because of wicking effects. Yellowness, tensile strength and elasticity slightly decreased after UV irradiation.

Micro/Nano Adhesion and Friction Characteristics of PTFE Coating Film Deposited by IBAD Method (IBAD 방법으로 코팅된 PTFE 박막의 마이크로/나노 응착 및 마찰 특성)

  • 윤의성;오현진;한흥구;공호성;장경영
    • Tribology and Lubricants
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    • v.20 no.5
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    • pp.237-244
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    • 2004
  • Micro/nano tribological characteristics of PTFE coating films were experimentally studied. PTFE (polytetrafluoroethylene) modified polyethylene and low molecular weight PTFE were used as a coating materials. These films were deposited on Si-wafer (100) by IBAD (ion beam assisted deposition) method. The Ar ion beam sputtering was performed to change the surface topography of films using a hollow cathode ion gun under different Ar ion dose conditions in a vacuum chamber. Micro/nano tribological characteristics, water wetting angles and roughness were measured with a micro tribotester, SPM (scanning probe microscope), contact anglemeter and profilometer, respectively. The durability of the films were measured with macro tribotester. Results showed that the PTFE coating surfaces were converted to hydrophobic. The water contact angle of coated surfaces and surface roughness increased with the coating thickness. Adhesion and friction in micro and nano scale were governed by magnitude of normal load in soft material such as PTFE films. As the increase of sputtering time on low molecular weight PTFE films, the surface roughness was increased and nano adhesion and friction were decreased. The nano tribological characteristics of surfaces are mainly improved by chemical modification such as PTFE coating and given a synergy effect by the physical modification such as topographic modification.

Structural Dynamics Modification Using Surface Grooving Technique : The Effectiveness of Check board Pattern and Comparison the Algorithm for Initial Starting Point (그루브를 이용한 표면형상변형 동특성 변경법 : 체크무늬 그루브의 효용성과 초기 시작점의 선택 알고리즘에 대한 비교)

  • Park, Mi-You;Park, Young-Jin;Park, Youn-Sik
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2005.05a
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    • pp.128-131
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    • 2005
  • Structural Dynamics Modification (SDM) is a very effective technique to improve structure's dynamic characteristics by adding or removing auxiliary structures. changing material properties and shape of structure. Among those of SDM technique, the method to change shape of structure has been mostly relied on engineer's experience and trial-and-error process which are very time consuming. In order to develop a systematic method to change structure shape, surface grooving technique is studied and successfully applied to HDD cover model. To check the effectiveness of this surface grooving technique, the grooved HDD cover design was manufactured using rapid prototyping and experimentally tested to prove the effectiveness of the grooving method as one of SDM techniques. And the modal strain energy and eigenvalue sensitivity method for choosing the initial starting point are compared.

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Development of 20-kHz Ultrasonic Equipment for UNSM (UNSM 위한 20 kHz급 초음파 장치 개발)

  • Shin, Hyun-Geun;Kim, Hyunse;Lim, Euisu
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.24 no.5
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    • pp.530-534
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    • 2015
  • Ultrasonic nanocrystal surface modification (UNSM) is an example of a nanoscale-surface modification that has become noticeable because of its effects on the mechanical improvement of metallic materials. UNSM equipment needs to be both utilized and improved. The equipment is based on an ultrasonic waveguide whose role is to strike surfaces of metallic materials to achieve nanoscale deformation. In this paper, we introduce the development of one kind of UNSM equipment. Using piezoelectric elements, we repeatedly design and fabricate a 20-kHz ultrasonic waveguide. With respect to the composition of the equipment, the waveguide is automatically transferred by two axial stages automatically. In addition, a static force is constantly applied by pneumatic devices. We perform an experiment to verify the feasibility of the equipment.

The Synthesis of Hydrophobic Silica Aerogel in the Macroporous Ceramic Structure by Ambient Drying Process (상압 건조 공정을 이용한 다공성 세라믹스 구조체 내부에 소수성 실리카 에어로겔의 합성)

  • Hong, Sun-Wook;Song, In-Hyuck;Park, Young-Jo;Yun, Hui-Suk;Hahn, Yoo-Dong;Hwang, Ki-Young;Rhee, Young-Woo
    • Journal of Powder Materials
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    • v.18 no.3
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    • pp.269-276
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    • 2011
  • The synthesis behavior of nanoporous silica aerogel in the macroporous ceramic structure was observed using TEOS as a source material and glycerol as a dry control chemical additive (DCCA). Silica aerogel in the macroporous ceramic structure was synthesized via sono-gel process using hexamethyldiazane (HMDS) as a modification agent and n-hexane as a main solvent. The wet gel with a modified surface was dried at $105^{\circ}C$ under ambient pressure. The addition of glycerol appears to give the wet gel a more homogeneous microstructure. However, glycerol also retarded the rate of surface modification and solvent exchange. Silica aerogel completely filled the macroporous ceramic structure without defect in the condition of surface modification (20% HMDS/nhexane at 36hr).

Comparative Analysis of Two Selective Bleaching Methods on Alpaca Fibers

  • Liu, Xin;Hurren, Christopher J.;Wang, Xungai
    • Fibers and Polymers
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    • v.4 no.3
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    • pp.124-128
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    • 2003
  • Dark brown Alpaca fiber was reduced in shade via selective bleaching with peroxide. Two selective oxidative bleaching methods were tested on alpaca top to assess their effectiveness for color removal and fiber quality properties. Color change, bundle strength, weight loss, fiber diameter, surface modification, dye-ability and dye wash fastness were assessed for both methods and compared with the original brown top. Bleach method 1 (BL-I) showed little surface modification, 5.8% weight loss and 2.4% strength loss. D1925 yellowness index was reduced to 74.3 from 83.1 and provided a good base for the dyeing of medium to deep shades. Bleach method 2 (BL-II) displayed considerable surface modification, 7.8% weight loss and 18% strength loss. BL-II also resulted in a mean diameter reduction of 1.9 micron during bleaching. Yellowness was reduced to 64.5 from 83.1 and provided a very good base for the dyeing of medium to deep shades. BL-I showed better exhaustion of the premetallised dye Lanaset Violet B than BL-II. Wash fastness for BL-II was 1 grey scale unit poorer than BL-I. BL-II showed far better color clarity at pale depths however the wash fastness of the finished product was not good enough to maintain the depth or clarity of the color. BL-I showed poorer clarity of color but exhibited better wash fastness results.

Characterization of Biocompatible Polyelectrolyte Complex Multilayer of Hyaluronic Acid and Poly-L-Lysine

  • Hahn, Sei-Kwang;Allan S. Hoffman
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.9 no.3
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    • pp.179-183
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    • 2004
  • A biocompatible polyelectrolyte complex multilayer (PECML) film consisting of poly-L-lysine (PLL) as a polycation and hyaluronic acid (HA) as a polyanion was developed to test its use for surface modification to prevent cell attachment and protein drug delivery. The formation of PECML through the electrostatic interaction of HA and PLL was confirmed by contact angle measurement, ESCA analysis, and HA content analysis. HA content increased rapidly up to 8 cycles for HA/PLL deposition and then slightly increased with an increasing number of deposition cycle. In vitro release of PLL in the PECML continued up to 4 days and ca. 25% of HA remained on the chitosan-coated cover glass after in vitro release test for 7 days. From the results, PECML of HA and PLL appeared to be stable for about 4 days. The surface modification of the chitosan-coated cover glass with PECML resulted in drastically reduced peripheral blood mononuclear cell (PBMC) attachment. Concerned with its use for protein drug delivery, we confirmed that bovine serum albumin (BSA) as a model protein could be incorporated into the PECML and its release might be triggered by the degradation of HA with hyaluronidase.

Functionalization of Fe3O4 Nanoparticles and Improvement of Dispersion Stability for Seperation of Biomolecules (생체분자 분리를 위한 Fe3O4 나노입자의 표면수식과 분산 안정성 향상)

  • Kim, Min-Jung;An, Guk-Hwan;Lim, Borami;Kim, Hee-Taik;Choa, Yong-Ho
    • Journal of Powder Materials
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    • v.14 no.4
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    • pp.256-260
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    • 2007
  • The surface of magnetite ($Fe_{3}O_{4}$) nanoparticles prepared by coprecipitation method was modified by carboxylic acid group of poly(3-thiophenacetic acid (3TA)) and meso-2,3-dimercaptosuccinic acid (DMSA). Then the lysozyme protein was immobilized on the carboxylic acid group of the modification of the magnetite nanoparticles. The magnetite nanoparticles are spherical and the particle size is approximately 10 nm. We measured quantitative dispersion state by dispersion stability analyzer for each $Fe_{3}O_{4}$ nanoparticles with and without surface modification. The concentration of lysozyme on the modified magnetite nanoparticles was also investigated by a UV-Vis spectrometer and compared to that of magnetite nanoparticles without surface modification. The functionalized magnetite particles had higher enzymatic capacity and dispersion stability than non-functionalized magnetite nanoparticles.