• Title/Summary/Keyword: SURFACE MODIFICATION

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A Study on the Hydrophobicity Modification and Physical Properties of Tencel Regenerated Fibers for Polypropylene Resin Composites (폴리프로필렌 수지 복합을 위한 텐셀 재생섬유의 소수화 표면개질 특성 연구)

  • Yoon, Songhyun;Kim, Mikyung;Lee, Eunsoo
    • Textile Coloration and Finishing
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    • v.33 no.4
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    • pp.258-268
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    • 2021
  • This study conducted on the introduction of recycled cellulose fibers, which are widely used in the textile industry as eco-friendly biomass materials, into polypropylene resins, which are mainly used for interior and exterior materials such as door trims and console parts of automobiles. In general, cellulose fibers can affect mechanical properties and have a lightening effect when used as a reinforcing agent. However, since cellulose fibers have hydrophilic properties and have relatively low compatibility with industrial polymer resins, they are used in combination through fiber hydrophobic surface treatment. Therefore, through this study, the reforming reaction conditions optimized in terms of hydrophobicity and workability for cellulose fibers are studied. Furthermore, polypropylene containing surface-modified cellulose fibers was prepared to compare physical properties by fiber content and study optimized content.

Interfacial Characteristics of Polymeric Composite Materials (고분자 복합재료의 계면특성)

  • Park Soo-Jin;Seo Min-Kang
    • Polymer(Korea)
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    • v.29 no.3
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    • pp.221-230
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    • 2005
  • Interfacial interactions and interphases played a key role in multicomponent materials irrespectively of the number and type of their components or their actual structure. They were equally important in particulate filled polymer, polymer blends, fibers-reinforced advanced composites, nanocomposites or biomimetic materials. Recognition of the role of the main factors influencing interfacial adhesion and proper surface modification could lead to significant progress in many fields of research and development, as well as in related technologies. Although the role and importance of interfaces and interphases were the same for all multicomponent materials, the surface modification could be always selected according to the objectives targeted, as well as to the characteristics of the particular system. In this wort therefore, several types of surface modification were performed to improve the interfacial interactions between two components in composite system and their results for the composites were investigated.

Applied Cases and Application Technologies of Ultrasonic Nanocrystalline Surface Modification and Accelerated Fatigue Life Evaluation Using Ultrasonic Elastic Vibrational Energy (초음파탄성진동에너지를 이용한 표면개질처리 및 가속피로수명평가 기술의 적용사례 및 응용기술)

  • Jo, In-Sik;Jo, In-Ho;Oh, Joo-Yeon;Lee, Chang-Soon;Pyoun, Young-Sik;Park, In-Gyu
    • Transactions of the KSME C: Technology and Education
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    • v.1 no.1
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    • pp.115-121
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    • 2013
  • It is greatly expected that the technologies of durability enhancement and evaluation for the core structures of plant facilities, marine plant and bridge constructures will be greatly expanded in the plant industry fields. In this study, the actively ongoing applied cases were tried to be analyzed in the present domestic industry fields through the Ultrasonic Nanocrystalline Surface Modification (UNSM) and Ultrasonic Fatigue Test (UFT) technologies using ultrasonic elastic vibrational energy, and the new application technology to improve the durability of plant industry field, especially plant facilities, marine plant and core weld components of bridge constructures will be presented.

Modification of polyamide reverse osmosis membranes seeking for better resistance to oxidizing agents

  • Silva, Lucinda F.;Michel, Ricardo C.;Borges, Cristiano P.
    • Membrane and Water Treatment
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    • v.3 no.3
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    • pp.169-179
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    • 2012
  • One of the major limitations in the use of commercial aromatic polyamide thin film composite (TFC) reverse osmosis (RO) membranes is to maintain high performance over a long period of operation, due to the sensitivity of polyamide (PA) skin layer to oxidizing agents, such as chlorine, even at very low concentrations in feed water. This article reports surface modification of a commercial TFC RO membrane (BW30-Dow Filmtec) by covering it with a thin film of poly(vinyl alcohol) (PVA) crosslinked with glutaraldehyde (GA) to improve its resistance to chlorine. Crosslinking reaction was carried out at 25 and $40^{\circ}C$ by using PVA 1.0 wt.% solutions at different GA/PVA mass ratio, namely 0.0022, 0.0043 and 0.013. Water swelling measurements indicated a maximum crosslinking density for PVA films prepared at $40^{\circ}C$ and GA/PVA 0.0043. ATR-FTIR and TGA analysis confirmed the reaction between GA and PVA. SEM images of the original and modified membranes were used to evaluate the surface coating. Chlorine resistance of original and modified membranes was evaluated by exposing it to an oxidant solution (NaClO 300 mg/L, NaCl 2,000 mg/L, pH 9.5) and measuring water permeability and salt rejection during more than 100 h period. The surface modification effectively was demonstrated by increasing the chlorine resistance of PA commercial membrane from 1,000 ppm.h to more than 15.000 ppm.h.

Pressureless Infiltration Processing of B4C/Al Composite by Surface Modification (표면 개질에 의한 상압에서의 B4C/Al복합체 제조 방법)

  • 임경란;강덕일;김창삼
    • Journal of the Korean Ceramic Society
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    • v.40 no.2
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    • pp.128-131
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    • 2003
  • Formation of$B_4C/Al$composite by pressureless infiltration was investigated by lowering wetting angle via surface modification of $B_4C$powder with alumina precursor. Surface modification was confirmed by zeta potential analysis. The$B_4C/Al$composite was prepared by placing an Al 6061 disk on the$B_4C$preform and heating at $1030{\circ}C$/20 min under a flowing argon, but no infiltration took place for a bare $B_4C$ preform even at$1250{\circ}C$/30 min. Analysis of XRD and SEM showed the $Al_3BC$phase besides$B_4C$and Al, but no trace of deteriorative$A1_4C_3$.

Effect of aerodynamic modifications on the surface pressure patterns of buildings using proper orthogonal decomposition

  • Tse, K.T.;Chen, Zeng-Shun;Lee, Dong-Eun;Kim, Bubryur
    • Wind and Structures
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    • v.32 no.3
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    • pp.227-238
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    • 2021
  • This study analyzed the pressure patterns and local pressure of tall buildings with corner modifications (recessed and chamfered corner) using wind tunnel tests and proper orthogonal decomposition (POD). POD can distinguish pressure patterns by POD mode and more dominant pressure patterns can be found according to the order of POD modes. Results show that both recessed and chamfered corners effectively reduced wind-induced responses. Additionally, unique effects were observed depending on the ratio of corner modification. Tall building models with recessed corners showed fluctuations in the approaching wind flow in the first POD mode and vortex shedding effects in the second POD mode. With large corner modification, energy distribution became small in the first POD mode, which shows that the effect of the first POD mode reduced. Among building models with chamfered corners, vortex shedding effects appeared in the first POD mode, except for the model with the highest ratio of corner modifications. The POD confirmed that both recessed and chamfered corners play a role in reducing vortex shedding effects, and the normalized power spectral density peak value of modes showing vortex shedding was smaller than that of the building model with a square section. Vortex shedding effects were observed on the front corner surfaces resulting from corner modification, as with the side surface. For buildings with recessed corners, the local pressure on corner surfaces was larger than that of side surfaces. Moreover, the average wind pressure was effectively reduced to 88.42% and 92.40% in RE1 on the windward surface and CH1 on the side surface, respectively.

Surface Modification Technology and Research Trends of Separators for Lithium-Ion Batteries (리튬이온 전지용 분리막의 표면 개질 기술 및 연구 동향)

  • Ha, Seongmin;Kim, Daesup;Kwak, Cheol Hwan;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.33 no.4
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    • pp.343-351
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    • 2022
  • Lithium-ion batteries (LIBs) are considered promising energy storage devices with good performance such as high energy density, slow self-discharge rate, high rate charge capacity, and long battery life. However, the application of these LIBs in the high-energy density electric vehicle and large device industries poses a major safety problem. In order to solve this problem, developing a material having high thermal stability and intrinsic safety is the ultimate solution for improving the stability and electrochemical performance of LIBs. This review introduced a surface modification technology of a separator to overcome the stability problem of a commercial separator, and summarized and summarized the research trends using the modified separator for a lithium-ion battery. Based on this, the future prospects for the separator development by surface modification were discussed.

Micro Pulverization and Surface Modification of Biomass Byproducts for Developing Bio-Degradable Plastic Film (생분해 플라스틱 필름 제조를 위한 바이오매스 부산물의 분체화 및 표면개질 연구)

  • Chung, Sung Taek;Han, Jung-Gu;Lee, Roun;Kim, Pan-Chae;Kuk, YoungRye;Choi, ChunHoan;Park, Hyung Woo
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.28 no.1
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    • pp.23-30
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    • 2022
  • This study investigated the characteristics for rice husk pulverization and surface modification of biomass byproducts composed of rice husk, corn extract gourd, wheat bran, and soybean curd. The size of particles of rice husk was at 6.44 ㎛ and represented the most affordable material for preparing the bio-degradable film among the tested byproducts. The silane treatment and adding 2% of ESO (Epoxidized soybean oil) and 3-aminopropyl triethoxysilane solution mixed in a 1:1 ratio were best to the surface modification and SEM-based particle shape. Above the results, adding 2% of mixed solution after silane treatment of rice husks processed through an air classifying mill (ACM) allows for its use as a raw material of bio-degradable plastic film.

Effect of Post Surface Modifications on Tribological Properties of Electrodeposited Ni/Ni-SiC coatings

  • Gyawali, Gobinda;Joshi, Bhupendra;Tripathi, Khagendra;Lee, Soo Wohn
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.05a
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    • pp.43-44
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    • 2015
  • Electrodeposited Ni and Ni-SiC composite coatings were prepared on Cu substrates by using the Ni-Sulfamate electrolytic bath. Thus prepared samples were subjected for the two different types of post surface modification techniques; i.e. Laser Surface Texturing (LST) and Ultrasonic Nano Surface Modification (UNSM), respectively in order to investigate their effects on surface and interface related properties of the coatings. Hemispherical dimples, with 80 to 200 um dimple spacing, were created and examined on the surfaces of the materials studied. The results revealed that micro-surface texturing with 150 um dimple spacing considerably improved the coefficient of friction. Dimple spacing accuracy and incorporated second phase ceramic particles both contributed significantly to reduction in coefficient of friction. On the other hand, application of UNSM considerably modified the surface topography, led to increase the Vickers microhardness, and reduced the wear and coefficient of friction as compared to non UNSM treated Ni and Ni-SiC samples.

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Changes in Pasting and Fluid Properties of Corn and Rice Starches after Physical Modification by Planetary Mill

  • Kim, Bum-Keun;Lee, Jun-Soo;Cho, Yong-Jin;Park, Dong-June
    • Food Science and Biotechnology
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    • v.17 no.4
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    • pp.814-818
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    • 2008
  • Com and rice starches were physically modified by planetary mill. While native starches showed high peak viscosities (1,001 and 563 cp), it decreased largely (42 and 20 cp for rice and com starch, respectively) after 2 hr of physical modification. When two starches were co-ground, peak viscosities decreased more largely than single ground one only in 30 min, indicating the pasting properties could be easily changed by co-grinding. Especially, the higher the amount of com starch, the viscosity decreased more largely, which means that paste stability could be controlled also by changing the ratio of com and rice starch. Mean particle size increased with physical modification time since particles became spread because of shear force. There were also changes in surface morphology after physical modification. Fluid property, such as mean time to avalanche (MTA), was improved (from $6.16{\pm}0.47$ and $8.37{\pm}1.23\;sec$ to $5.47{\pm}0.78$ and $5.26{\pm}1.37\;sec$ for rice and com starch, respectively) by physical modification. Pasting property, such as swelling power, was also improved by physical modification. These mean that native starches can be applied to both conventional powder and new paste-food industry more efficiently by physical modification.