• Title/Summary/Keyword: SSPC

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Charge Carrier Photogeneration and Hole Transport Properties of Blends of a $\pi$-Conjugated Polymer and an Organic-Inorganic Hybrid Material

  • Han, Jung-Wook;An, Jong-Deok;Jana, R.N.;Jung, Kyung-Na;Do, Jung-Hwan;Pyo, Seung-Moon;Im, Chan
    • Macromolecular Research
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    • v.17 no.11
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    • pp.894-900
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    • 2009
  • This study examined the charge carrier photogeneration and hole transport properties of blends of poly (9-vinylcarbazole) (PVK), $\pi$-conjugated polymer, with different weight proportions (0~29.4 wt%) of (PEA)$VOPO_4{\cdot}H_2O$ (PEA: phenethylammonium cation), a novel organic-inorganic hybrid material, using IR, UV-Vis, and energy dispersive spectroscopy (EDS), thermogravimetric analysis (TGA), steady state photocurrent (SSPC) measurement, and atomic force microscopy (AFM). The SSPC measurements showed that the photocurrent of PVK was reduced by approximately three orders of magnitude by the incorporation of a small amount (~12.5 wt%) of (PEA) $VOPO_4{\cdot}H_2O$, suggesting that hole transport occurred through the PVK carbazole groups, whereas a reverse trend was observed at high proportions (>12.5 wt%) of (PEA)$VOPO_4{\cdot}H_2O$, suggesting that transport occurred via (PEA)$VOPO_4{\cdot}H_2O$ molecules. The transition to a trap-controlled hopping mechanism was explained by the difference in ionization potential and electron affinity of the two compounds as well as the formation of charge percolation threshold pathways.

Solar Thermal Propulsion System for Microsatellites

  • Sahara, Hironori;Shimisu, Morio;Osa, Keitaro;Matsui, Yasuhiro;Fukuda, Miho;Daisuke, Maeyama;Nakamura, Yoshihiro
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.318-319
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    • 2004
  • This paper shows an application of single crystal metals and Single Shell Polymer Concentrator (SSPC) to Solar Thermal Propulsion (STP). Based on it, we fabricated a breadboard model of STP system (STP-BBM) for microsatellites. We also proposed Eco-Friendly End-of-Life De-Orbiting (EFELDO) by using such a high performance STP system.

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Evaluation of Deterioration Propagation Life of Steel Bridge Paints According to Surface Treatment Methods and Heavy-Duty Painting Types (표면처리방법에 따른 강교용 일반중방식도장계의 열화진행수명 평가)

  • Kim, Gi-Hyeok;Jeong, Young-Soo;Ahn, Jin-Hee;Kim, In-Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.1
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    • pp.75-84
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    • 2021
  • In this study, to evaluate deterioration propagation life and deterioration curve of the shop painted and field re-painted steel bridges, accelerated corrosion tests were carried out on 4 types of heavy-duty painting systems with different surface treatments. The surface treatments prior to painting were examined by hand tool(SSPC SP-2), power tool(SP-3,) or blast cleaning(SP-10) considering shop painting and field re-painting. The paint deterioration curves for each painting system and surface treatment were evaluated based on corrosion propagation from the initial paint defects. From the test results, the paint deterioration life of shop painted and field re-painted system was evaluated and compared by using corrosivity categories and durability performance evaluation of structural steel. The deterioration propagation life of shop and field paint was estimated in 18 to 21 years and 5.3 to 8.0 years with atmospheric corrosion category C4.

A Study on the Modeling and Simulation Analysis of Rermote Solid State Power Controller (원격전력제어 장치의 모델링 및 시뮬레이션 분석에 대한 연구)

  • Jeon, Yeong Cheol;Lee, Hyuek Jae;Chong, Won Yong
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2009.10a
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    • pp.461-464
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    • 2009
  • The conventional electro-mechanical circuit break and relay are widely used in large-sized DC power system. However, recently due to high reliability, remote controllability and small power dissipation of a RSPC (Remote Solid State Power Controller), high-friendly DC power systems have increasingly adopted the RSPC as an essential element. In this paper, we have conducted the modeling of a RSPC circuit and the simulation analysis for $I^2t$ curve, respectively.

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Effect of Retaining Preconsruction Primer (PCP) on the Quality of High Performance Protective Coatings Systems

  • Chung, M.K.;Baek, K.K.;Lee, H.I.;Lee, C.H.;Shin, C.S.
    • Corrosion Science and Technology
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    • v.3 no.2
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    • pp.59-66
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    • 2004
  • In construction of new ships and large steel bridges in Korea, pre-construction primers (PCP), also known as shop primer, are routinely used and retained as an integral part of the protective coating system. Retention of PCP's can significantly reduce building schedule and cost. Retaining PCP through the so-called "sweep blasting" procedure eliminates or minimizes the necessity of a second blast operation, thus shortening overall schedule as well as reducing labor cost and hazardous waste disposal cost. This study evaluates the feasibility of retaining PCP as the part of primer for high performance protective coating systems applied to ships' hull, bottom and ballast tanks. Upon proving that the retention of the PCP is a viable option, the process of coating application can he improved significantly in terms of cost and working schedule of new ships and large steel bridges. Results indicate that use of the PCP via sweeping blasting in conjunction with standard high performance protective coating systems does not degrade the overall performance of the coating systems. At the same time, it is also highly recommended that the secondary surface preparation should consist of grit blasting of weld burnt and other damaged areas to SSPC SP-IO grade (Sa 2.5 Gr.), Near White Blast Cleaning with proper application and attention to detail.